• Title/Summary/Keyword: corrosion area

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Electrochemical Behaviors of PEO-treated Ti-6Al-4V Alloy in Solution Containing Zn and Si Ions

  • Hwang, In-Jo;Choe, Han-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.160-160
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    • 2017
  • Commercially pure titanium (Cp-Ti) and Ti alloys (typically Ti-6Al-4V) display excellent corrosion resistance and biocompatibility. Although the chemical composition and topography are considered important, the mechanical properties of the material and the loading conditions in the host have, conventionally. Ti and its alloys are not bioactive. Therefore, they do not chemically bond to the bone, whereas they physically bond with bone tissue. The electrochemical deposition process provides an effective surface for biocompatibility because large surface area can be served to cell proliferation. Plasma electrolyte oxidation (PEO) enables control in the chemical composition, porous structure, and thickness of the TiO2 layer on Ti surface. Silicon (Si) in particular has been found to be essential for normal bone and cartilage growth and development. Zinc (Zn) plays very important roles in bone formation and immune system regulation, and is also the most abundant trace element in bone. The objective of this work was to study on electrochemical behaviors of PEO-treated Ti-6Al-4V Alloy in solution containing Zn and Si ions. The morphology, the chemical composition, and the microstructure analysis of the sample were examined using FE-SEM, EDS, and XRD. The potentiodynamic polarization and AC impedance tests for corrosion behaviors were carried out in 0.9% NaCl solution at similar body temperature using a potentiostat. The promising results successfully demonstrated the immense potential of Si/Zn-TiO2 coatings in dental and biomaterials applications.

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The Corrosivity Evaluations on Soil Surrounding the Buried Steel Piles under Manufacturing Plants (플랜트 하부의 강파일 인접 토양의 부식성 평가)

  • Jung, Sungwon;Park, Kyeong-Wan;Jeon, Jae-Young
    • Plant Journal
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    • v.12 no.1
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    • pp.37-43
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    • 2016
  • The corrosivity evaluations on soil surrounding the buried steel piles under manufacturing plants. It was proven that the soil structure of this sample area is composed of several soil layers, and that each layer show the different corrosivity. The predicted average corrosion rates of some layers are about 0.33mm/y, which is over than the general corrosion rate, 0.01-0.02mm/y.

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High Temperature Oxidation Behavior of Plasma Sprayed $ZrO_2$ Having Functionally Gradient Thermal Barrier Coating

  • Park, Cha-Hwan;Lee, Won-Jae;Cho, Kyung-Mox;Park, Ik-Min
    • Corrosion Science and Technology
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    • v.2 no.3
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    • pp.155-160
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    • 2003
  • Plasma spraying technique was used to fabricate functionally graded coating (FGC) of NiCrAIY/YSZ 8wt%$Y_2O_3-ZrO_2$ on a Co-base superalloy (HAYNES 188) substrate. Six layers were coated on the substrate for building up compositionally graded architecture. Conventional thermal barrier coating (TBC) of NiCrAIY/SZ with sharp interface was also fabricated. As-coated FGC and TBC samples were exposed at the temperature of $1100^{\circ}C$ for 10, 50, 100 hours in air. Microstructural change of thermally exposed samples was examined. Pores and microcracks were formed in YSZ layer due to evolution of thermal internal stress at high temperature. The amount of pores and microcracks in YSZ layer were increased with increasing exposure time at high temperature. High temperature oxidation of coatings occurred mainly at the NiCrAIY/YSZ interface. In comparison with the case of TBC. the increased area of the NiCrAIY/YSZ interface in FGC is likely to attribute to forming the higher amount of oxides.

A Study on the Cathodic Protection Design Optimization of Steel Piles for LNG Storage Tanks by Numerical Analysis (수치해석에 의한 LNG 저장탱크용 강관파일 전기방식 설계 최적화 연구)

  • Kim, Young Keun;Song, Hong Seok
    • Corrosion Science and Technology
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    • v.16 no.6
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    • pp.294-297
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    • 2017
  • For the longer service life of steel pile, cathodic protection is selected sometimes at corrosive environment. The cathodic protection design improvement was investigated in this study. The current demand for cathodic protection was calculated from the potentiostatic current monitoring of the steel specimen in the deaerated soil samples. In this study, the current distribution was studied using the Boundary Element Method (BEM) and the Finite Element Method (FEM) numerical analysis methods. The optimum layout of the anode was developed and confirmed by numerical analysis. Under the conventional design of the anode, the length of the anode hole is same as the pile length. We found that, at the bottom end of the pile, the current density is too high. When the anode hole length was 80% of the pile length, the current consumption at the end was reduced. The construction cost of anode hole drilling was decreased about 20%, as compared to the conventional design. Furthermore, the life of the anode materials could be extended by reducing the current consumption at the end section. Using this approach, the construction cost was reduced significantly without any under-protection area on the steel piles.

Machining Characteristics of Ti-6Al-4V Thread (Ti-6Al-4V 티타늄 합금나사의 절삭 특성)

  • Kim, Hyung-Sun;Choi, Jong-Guen;Kim, Dong-Min;Lyu, Min-Young
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.18 no.5
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    • pp.514-520
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    • 2009
  • Titanium is one of the most attractive materials due to their superior properties of high specific strength and excellent corrosion resistance. The applications in aerospace and medical industries demand machining process more frequently to obtain more precise products. Machining of titanium is faced with strong challenges such as increased component complexity i.e. airframe components manufacturing processes. The machining cost on titanium have traditionally demanded high cutting tool consumable cost and slow machining cycle times. Similarly, the high wear of the cutting tools restricts the cutting process capabilities. Titanium screws applied to fasten parts In the several corrosion environment. In the thread cutting of titanium alloys, the key point for successful work is to select proper cutting methods and tool materials. This study suggests a guidance fur selecting the cutting methods and the tool materials to improve thread quality and productivity. Some experiments investigate surface roughnesses, cutting forces and tool wear with change of various cutting parameters including tool materials, cutting methods, cutting speed. As the results, the P10 type insert tip was assured of the best for thread cutting of Ti-6Al-4V titanium alloy. Also the initial depth of infeed was desirable to use the value below 0.5mm as the uniform cutting area method is applied.

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A Study on the Relief of Shell Wall Thinning of High pressure Feedwater Heater (고압형 급수가열기 동체 감육 완화에 관한 연구)

  • Kim, Hyung-Joon;Park, Sang-Hoon;Seo, Hyuk-Ki;Kim, Kyung-Hoon;Hwang, Kyung-Mo
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2664-2669
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    • 2008
  • Feedwater heaters of many nuclear power plants have recently experienced severe wall thinning damange, which will increase as operating time progresses. Several nuclear power plants in Korea have experienced wall thinning damage in the area around the impingement baffle-installed downstream of the high pressure turbine extraction stream line- inside number 5A and 5B feedwater heaters. At that point, the extracted steam from the high pressure turbine is two phase fluid at high temperature, high pressure, and high speed. Since it flows in reverse direction after impinging the impingement baffle, the shell wall of the number 5 high pressure feedwater heater may be affected by flow-accelerated corrosion. This paper describes operation of experience and numerical analysis composed similar condition with real high pressure feedwater heater. This study applied squared, curved and new type impingement baffle plates to feedwater heater same as previous study. In addition, it shows difference of pressure distribution and value between single phase and two phase based on experience and numerical analysis.

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The corrosion of the opaque zone induced under stress oscillation in PET film (PET 필름에서 응력 진동으로 유도된 불투명 존의 부식)

  • 이종영;윤석영;박찬영;박성수
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.5
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    • pp.367-372
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    • 2000
  • The film-type specimen of poly ethylene terephthalate (PET) was stepwise elongated under tension with various speed range of about 0.5~500 mm/min, and then the necking behavior during its plastic deformation was observed. When elongated at the speed range of about 20~100 mm/min, stress oscillation was apparently occurred in the stress-strain curve. When elongated at the speed range of about 200~500 mm/min, stress oscillation was not did. The transparent/opaque zone and cross-section area in the specimen elongated at the speed of about 50 mm/min were examined using the optical microscopy and scanning electron microscopy. The corrosion characteristic of the specimen elongated at the speed of about 50 mm/min in 3.8 M NaOH alkali solution was examined using the optical microscopy.

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Design Modification and Correlation Verification between Reattachment Flow of Dispersed Jet and Local Thinning of Feedwater Heater (충돌로 인해 분산된 2상 제트스팀의 재부착 현상과 국부 감육 상관관계 규명 및 설계개선에 관한 연구)

  • Kim, Hyung-Joon;Kim, Kyung-Hoon;Hwang, Kyeong-Mo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.21 no.9
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    • pp.483-495
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    • 2009
  • Feedwater heaters of many nuclear power plants have recently experienced severe wall thinning damange, which will increase as operating time progresses. Several nuclear power plants in Korea have experienced wall thinning damage in the area around the impingement baffle-installed downstream of the high pressure turbine extraction stream line-inside number 5A and 5B feedwater heaters. At that point, the extracted steam from the high pressure turbine is two phase fluid at high temperature, high pressure, and high speed. Since it flows in reverse direction after impinging the impingement baffle, the shell wall of the number 5 high pressure feedwater heater may be affected by flow-accelerated corrosion. This paper describes operation of experience and numerical analysis composed similar condition with real high pressure feedwater heater. This study applied squared, curved and new type impingement baffle plates to feedwater heater same as previous study. In addition, it shows difference of pressure distribution and value between single phase and two phase based on experience and numerical analysis.

Shell Wall Thinning and Mitigation Plan and Design Modification of a Feedwater Heater Impingement Baffle (급수가열기 동체 감육 현상과 완화 방안 및 충격판 설계개선)

  • Kim, Kyung-Hoon;Hwang, Kyeong-Mo;Park, Sang-Hoon
    • Journal of the Korean Society for Precision Engineering
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    • v.27 no.6
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    • pp.55-63
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    • 2010
  • Feedwater heaters of many nuclear power plants have recently experienced severe wall thinning damage, which will increase as operating time progresses. Several nuclear power plants in Korea have experienced wall thinning damage in the area around the impingement baffle inside feedwater heater installed downstream of the turbine extraction stream line. At that point, the extract steam from the turbine is two phase fluid at high temperature, high pressure, and high speed. Since it flows to reverse direction after impinging the impingement baffle, the shell wall of feedwater heaters may be affected by flow-accelerated corrosion. In this paper, to compare degree of shell wall thinning mitigation rate to squared type with mitigation rate of other type baffle plate, three different types of impingement baffle plate-squared, curved and mitigating type-applied inside the shell. With these comparison data, this paper describes operation of experiments and numerical analysis which is composed similar condition with real feed water heater. And flow visualization is operated for verification of experiments and numerical analysis. In conclusion, this study shows that mitigating type baffle plate is more effective than other baffle plate about prevention of pressure concentration and pressure value decrease.

Determination of Knoop Indentation Stress Conversion Factors for Measuring Equibiaxial Residual Stress (인장 및 압축 등방 잔류응력 측정을 위한 누프 압입시험의 응력환산계수 결정)

  • Jeong, Min Jae;Kim, Young-Cheon
    • Corrosion Science and Technology
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    • v.20 no.6
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    • pp.484-490
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    • 2021
  • Instrumented indentation testing has been widely used for residual stress measurement. The Knoop indentation is mainly selected for determining anisotropic mechanical properties and non-equibiaxial residual stress. However, the measurement of equibiaxial stress state and compressive residual stress on a specimen surface using Knoop indentation is neither fully comprehended nor unavailable. In this study, we investigated stress conversion factors for measuring Knoop indentation on equibiaxial stress state through indentation depth using finite element analysis. Knoop indentation was conducted for specimens to determine tensile and compressive equibiaxial residual stress. Both were found to be increased proportionally according to indentation depth. The stress field beneath the indenter during each indentation test was also analyzed. Compressive residual stress suppressed the in-plane expansion of stress field during indentation. In contrast, stress fields beneath the indenter developed diagonally downward for tensile residual stress. Furthermore, differences between trends of stress fields at long and short axes of Knoop indenter were observed due to difference in indenting angles and the projected area of plastic zone that was exposed to residual stress.