• Title/Summary/Keyword: corrosion area

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Phosphorus Removal by Aluminium Ion Generated with the Pitting Corrosion of Aluminium (알루미늄의 부식으로 발생한 알루미늄 이온에 의한 인 제거)

  • Cheong Kyung-Hoon;Jung Oh-Jin
    • Journal of Environmental Science International
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    • v.8 no.6
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    • pp.705-710
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    • 1999
  • The fundamental experiments on the phosphorus removal from water were carried out by the batch and continuous reactors which used aluminium and copper plate. In this systems, the phosphorus was removed by aluminium ion generated with the electrochemical interaction (pitting corrosion) of aluminium and copper. In the batch experiments, the efficiencies of phosphorus removal increased when the surfaces of aluminium and copper plate were brushed. The phosphorus removal by aluminium ion was affected the copper plate and NaCI in this system. The optimal pH values were 5 and 6 for the phosphorus removal. The efficiency of phosphorus removal increased with increasing NaCI concentration, surface area of aluminium and copper plate. The $CUSO_4{\cdot}5H_2O$ instead of copper plate could be used as Cu source. The effluent $PO_4-P$ concentration as low as 2 $mg/{\ell}$ could have been obtained during the continuous experiment at HRT of 48 hrs.

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Analysis of the Stray Current Conditions in Subway DC Electrification System (I) Seoul Metropolitan Area (지하철 직류 급전시스템의 표유전류 실태 분석(I) 서울 지역)

  • Ha Yoon-Cheol;Ha Tae-Hyun;Bae Jeong-Hyo;Kim Dae-Kyeong;Lee Hyun-Goo
    • Proceedings of the KIEE Conference
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    • summer
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    • pp.1364-1366
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    • 2004
  • When an underground pipeline runs parallel with DC-powered railways, it suffers from electrolytic corrosion caused by the stray current leaked from the railway negative returns. Perforation due to the electrolytic corrosion may bring about large-scale accidents even cathodically protected systems. Traditionally, bonding methods such as direct drainage, polarized drainage and forced drainage have been used in order to mitigate the damage on pipelines. In particular, the forced drainage method is widely adopted in Seoul. In this paper, we report the analysis of the stray current conditions in Seoul subway DC electrification system.

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Formation and Control of Dual Porous Structures of Metal by an Electrochemical Method (전기화학적 방법을 통한 금속 이중기공구조 형성 및 제어)

  • Ha, Seong-Hyeok;Shin, Heon-Cheol
    • Korean Journal of Materials Research
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    • v.29 no.2
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    • pp.65-72
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    • 2019
  • Dual porous structures are observed for the first time on a metallic Cu surface underneath anodic Cu oxide by the application of an anodizing voltage to Cu in oxalic acid. The as-prepared porous Cu surface contains macropores of less than $1{\mu}m$ diameter and mesopores of about tens of nanometers diameter with circular shapes. The size and density (number of pores/area) of the macropores are dependent on the applied voltage. It is likely that the localized dissolution (corrosion) of Cu in oxalic acid under the anodizing voltages is responsible for the formation of the mesopores, and the combination of a number of the mesopores might create the macropores, especially under a relatively high anodizing voltages or a prolonged anodizing time. The variations of pore structure (especailly macropores) with applied voltage and time are reasonably explained on the basis of the proposed mechanism of pore formation.

Optimization of Process Parameters for Dry Film Thickness to Achieve Superior Water-based Coating in Automotive Industries

  • Prasad, Pranay Kant;Singh, Abhinav Kr;Singh, Sandeep;Prasad, Shailesh Kumar;Pati, Sudhanshu Shekher
    • Corrosion Science and Technology
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    • v.21 no.2
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    • pp.121-129
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    • 2022
  • A study on water-based epoxy coated on mild steel using the electroplating method was conducted to optimize the process parameters for dry film thickness to achieve superior paint quality at optimal cost in an automotive plant. The regression model was used to adjust various parameters such as electrode voltage, bath temperature, processing time, non-volatile matter, and surface area to optimize the dry film thickness. The average dry film thickness computed using the model was in the range of 15 - 35 ㎛. The error in the computed dry film thickness with reference to the experimentally measured dry film thickness value was - 0.5809%, which was well within the acceptable limits of all paint shop standards. Our study showed that the dry film thickness on mild steel was more sensitive to electrode voltage and bath temperature than processing time. Further, the presence of non-volatile matter was found to have the maximum impact on dry film thickness.

Finite Element Analysis of Copper Clad Steel Wire Drawing Process (동피복 강 선재 인발 공정의 유한요소해석)

  • Kim H. S.;Kim B. M.;Jo H. H.;Jo H.
    • Transactions of Materials Processing
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    • v.14 no.2 s.74
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    • pp.147-152
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    • 2005
  • The objective of this study is to develop an optimal drawing die for the clad wire drawing process. Cu-clad wire, which has the advantages of the high strength of a steel core and the electro-conductivity, corrosion resistance of a copper layer, is widely being used in the field of the telecommunications, electric-electronic and military technology industries. It is important to obtain uniformly coated rate when producing clad wires. Drawing process of clad wire will be influenced on damage and coated rate of core and sleeve for process variables such as semi-die angle and reduction in area. Therefore, in this study, the finite-element result obtained in this study was analyzed to the effect of the various forming parameters, which included the semi-die angle and reduction in area. The coated rate will be predicted with observation of copper coated rate variation according to total reduction in area and the optimal pass schedule will be set up through proper reduction in area and semi-die angle variation.

Area index of airborne chlorides at the seashore in Korea (우리나라 해안의 비래염분에 대한 지역계수 산정)

  • Lee, Jong-Suk;Choi, Won-Sung;Ahn, Ki-Hong;Lee, Jang-Hwa
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.609-612
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    • 2006
  • Concrete structures in the seashore are greatly affected by salt attack primarily due to airborne chlorides like it can be seen through the corrosion of rebar. This study intends to investigate characteristics on the salinity of the airborne chlorides in terms of areas. Salinity measurement devices were installed at 27 areas along with seashore throughout the country. The area index for airborne chlorides were established according to the measurements. In Gochang and Taean area showed higher value of area index over 10. In addition, the Eastern coast showed higher index compared to the Western and Southern coast.

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A Study on Wear and Corrosion Properties of Plasma Carburized Austenitic Stainless Steel (플라즈마 침탄된 오스테나이트계 스데인리스강의 마모 및 부식 특성에 관한 연구)

  • Shin, Dong-Myung;Lee, Chang-Youl;Lee. Kyung-Sub
    • Korean Journal of Materials Research
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    • v.12 no.10
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    • pp.776-783
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    • 2002
  • Austenitic stainless steel (STS304) has been carburized using glow discharge plasma and its microstructure, wear resistance and corrosion property have been investigated. A repeat boost-diffuse carburizing was used as an effective plasma carburizing method. The effective case depth of the plasma carburized specimens was increased with the carbon concentration at the surface area. The specimens prepared by 3 hours plasma carburizing under $600^{\circ}C$ did not have the standard hardness for the effective case depth, but the specimen prepared by 11 hours plasma carburizing at $500^{\circ}C$ had nearly the same hardness with the specimen plasma carburized for 3 hours at $800^{\circ}C$. The wear resistance increased with temperature but the corrosion properties of the specimens prepared over $600^{\circ}C$ decreased rapidly due to the grain boundary sensitization. However, the specimen plasma carburized for 11 hours at $500^{\circ}C$ had nearly the same wear resistance with the specimen plasma carburized for 3 hours at $800^{\circ}C$ without deterioration of corrosion property. This could be resulted from the fact that the microstructure of the specimen plasma carburized for 11 hours at $500^{\circ}C$ was composed of martensite and austenite, because a partial martensite transformation was occurred only in the specimen plasma carburized for 11 hours at 50$0^{\circ}C$.

Concentration of elemental ions released from non-precious dental casting alloys (치과주조용 비귀금속 합금의 금속 용출 수준)

  • Sakong, Joon;Park, Soo-Chul
    • Journal of Technologic Dentistry
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    • v.35 no.1
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    • pp.1-17
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    • 2013
  • Purpose: This study was to assess the extents of the release of metals from the non-precious alloys used for dental casting by measuring the differences in the extents of the release of metals by types of alloys, pH level and elapsed time. Methods: Uniform-sized specimens(10 each) were prepared according to the Medical Device Standard of the Korea Food and Drug Administration(2010) and International Standard Organization(ISO22674, 2006), using four types of alloys(one type of Ni-Cr and one type of Co-Cr used for fixed prosthesis, and one type of Ni-Cr and one type of Co-Cr used for removable prosthesis). A total of 12 metal-release tests were performed at one-day, three-day, and two-week intervals, for up to 20 weeks. The metal ions were quantified using an Inductively Coupled Plasma-Atomic Emission Spectrometer. Results: The results showed that the extent of corrosion was higher in the ascending order of Jdium-$100^{(R)}$, Bellabond-$Plus^{(R)}$, Starloy-$C^{(R)}$, and Biosil-$F^{(R)}$. The lower the pH and the longer the elapsed time were, the greater the increase in metal corrosion. At pH 2.4, the release of Ni from Jdium-$100^{(R)}$, a Ni-Cr alloy, was up to 15 times greater than the release of Co from the Co-Cr alloy from two weeks over time, indicating that the Ni-Cr alloy is more susceptible to corrosion than the Co-Cr alloy. Conclusion: It is recommended that Co-Cr alloy, which is highly resistant to corrosion, be used for making dental prosthesis with a non-precious alloy for dental casting, and that non-precious alloy prosthesis be designed in such a way as to minimize the area of its oral exposure. For patients with non-precious alloy prostheses, a test of the presence or absence of periodontal tissue inflammation or allergic reaction around the prosthesis should be performed via regular examination, and education on the good management of the prosthesis is needed.

ICCP Control and Monitoring System for Ships

  • Oh, Jin-Seok;Moon, Serng-Bae
    • Journal of Navigation and Port Research
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    • v.30 no.4
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    • pp.291-294
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    • 2006
  • Corrosion is never avoided in the use rf materials with various environments. The underwater hull is normally protected against rusting by several coatings of anti-corrosive paint. The purpose of ICCP(Impressed Current Cathodic Protection) system is to eliminate the rusting or corrosion, which occurs on metal immersed in seawater. This thesis is about the ICCP control and monitoring system, which brings protection against the corrosion of the ship's hull in the sea environments. The test system for ICCP is composed of a power supply, anode, reference electrode and controller. The test system is composed power supply, anode, ref electrode, shunt and etc. The protection current is sent to the protection area though anode. Reference electrode senses whether or not the detected potential is within a range of protection of test equipment and then it is automatically controlled to increase or decrease the amount of protective current to be sent to the anode by controller. The monitoring system with LabView is also detected in order to check the normal state of the system at operation period, because an operator does not always watch over this system and thus the system cannot operate well because rf his or her negligent management. This paper was studied the variation of potential and current density with environment factors, velocity and time, and the experimental results will be explained Also, It is suggested that this system can accommodate a ship's automation for SCMS(Ship Control and Management System) and will be very useful.

Structural Performance Investigation for the Reinforced Concrete Frames Deteriorated by the Reinforcement Corrosion (철근부식에 의한 철근콘크리트골조의 구조성능분석)

  • Choi, Se-Woon
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.28 no.5
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    • pp.563-570
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    • 2015
  • The existing research on the damage detection method for building structures has considered the damages from the excessive loadings such as the earthquake. However, the structural performance of building structures could be reduced due to the deterioration based on the chloride, carbonation during the long-term time. Thus, to effectively manage the healthiness of structures, the deterioration influences on the structures should be checked. In this study, the corrosion of rebars by the chloride is considered as the deterioration factor. To consider the structural performance reduction of the corroded rebars, the yield strength, cross-sectional area, rupture strain of rebars and the compressive strength of cover concrete based on the corrosion level are estimated. These properties of rebars and cover concrete are used for the procedure to evaluate the structural performance reduction of structural member level and the building level. The moment-curvature analysis is performed to evaluate the structural performance reduction of structural member level. Also, the eigenvalue analysis and the pushover analysis are performed to investigate the natural period and mode shape and the strength and deformation performance of buildings, respectively.