• Title/Summary/Keyword: contaminated water

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A Study on the Cleanup Process of HOCs-Contaminated Soil by Ex-situ Soil Washing Technology (Ex-situ 토양세척기법에 의한 소수성 유기오염물질로 오염된 토양의 정화에 관한 연구)

  • Choi, Sang-Il;Ryoo, Doo-Hyun;Jang, Min
    • Journal of Korea Soil Environment Society
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    • v.2 no.1
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    • pp.99-107
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    • 1997
  • In this study, a series of batch-scale tests were conducted to optimize the design parameters for the application of soil washing techniques to the hydrophobic organic compounds(HOCs)-contaminated soil and to find the effective methods for the recovery of surfactants from washing effluent by using solvent. Several nonionic surfactants (polyoxyethylene oleyl ester) and sophorolipid were applied to the artificially contaminated soil (4,000 mg n-dodecane/kg dry soil). The effects of washing time, concentration of surfactant solution, dilution ratio, and temperature on washing efficiencies were examined. Hydrophile-liphophile balance (HLB) number was proven to be one of the important parameters for soil washing. The HLB numbers of OA-5 and sophorolipid are too low to form a stable soil-water emulsion. They showed very low washing efficiencies less than 10e1o. If HLB number is in the proper range to form a stable soil-water emulsion, surfactant having higher solubility for HOCs shows higher washing efficiency. OA-14 having higher HLB number than OA-9 formed more stable soil-water emulsion. But its washing efficiency was about 20% due to a lower molar solubility ratio (MSR) than OA-9. OA-9, which forms a stable soil-water emulsion and has comparatively high sotubility for HOCs, showed about 60% washing efficiency by itself. To recover anthracene effectively from OA-9 washing effluent by using benzene as an organic solvent, desirable temperature and pH were $30^{\circ}C$ and 2, respectively.

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The Biological Treatment of Soil Washing Water Contaminated with Heavy Metal (중금속오염 토양 세척수의 생물학적 처리)

  • Jeong, Jeong-Hwa;Seo, Pil-Soo;Kong, Sung-Ho;Seo, Seung-Won;Kim, Min-Kyoung;Lee, Jong-Yeol;Lee, Sang-Seob
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.11
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    • pp.1222-1227
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    • 2006
  • In this study, nine strains were isolated from heavy metal-contaminated soil in a mine. The high efficiency bacteria, JH1, to be able removal cadmium and copper, was selected by the screen test. JH1 was identified as Ralstonia eutropha by 16S rDNA analysis, fatty acid analysis, and its morphological and biochemical characteristics. After the cadmium-contaminated soil was washed with citric acid solution(pH 6, 10 mM), Ralstonia eutropha JH1 was inoculated in the soil washing water. In order to determine the optimal cell concentration for inoculation, cell concentrations were considered in 0.5, 1.0, 2.0, 4.0 g/L, respectively. The removal efficiencies for cadmium in each cell concentration of Ralstonia eutropha JH1 were 49.9, 84.4, 89.7% and 89.9% of 110 mg/L(Cd), after 5 days culture in soil washing water. When Ralstonia eutropha JH1 was inoculated in soil washing water containing each cadmium(110 mg/L) and copper(100 mg/L), each of them was removed completely during 6 days culture. The completely removing time for cadmium and copper in each low concentration, 10, 30 and 60 mg/L were 12, 18 and 48 hrs, respectively.

Applications of Acid/Base Modified Activated Carbon for Stabilization of Sediment Contaminated with Organic Compounds (산/염기 개질활성탄을 이용한 유기오염물질 오염 퇴적토 안정화를 위한 적용성 연구)

  • Seunghyun Kang;Jaewoo Park
    • Journal of the Korean GEO-environmental Society
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    • v.25 no.5
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    • pp.5-13
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    • 2024
  • This paper investigates the stabilization feasibility of contaminated sediment contaminated with benzyl butyl phthalate (BBP) using acid/base-modified activated carbon. The efficiency of stabilizers was evaluated by analyzing the impact of the activated carbon on the decomposition and adsorption of the contaminant, along with the biological effects on earthworms. Additionally, the contaminant migration was monitored with the BBP concentration in pore water using low-density polyethylene. The research results indicated that the accumulated concentration of BBP was approximately 2% lower in the experimental group applying a 5% mixture ratio of modified activated carbon compared to the group applying a 10% mixture ratio. The leaching into water was reduced by over 18% in all experimental conditions after 7-day exposure period. Over 25% reduction was observed after 28-day exposure. The pore water concentrations were measured. After 7 days of exposure, the mechanically mixed experimental group exhibited a higher pore water stabilization rate compared to the biologically mixed group. Within the mechanically mixed group, the experimental group with 10% mixture of modified activated carbon showed a 1% higher stabilization rate than the group with 5% mixture. After 28 days of exposure, the biologically mixed experimental group demonstrated a higher pore water stabilization rate compared to the mechanically mixed group. Moreover, within the biologically mixed group, the experimental group with 10% mixture of modified activated carbon showed approximately 0.1% higher stabilization rate than the group with 5% mixture.

Remediation of Contaminated Soil with Organic Contaminants using Microemulsion (마이크로이멀젼을 이용한 유기오염물로 오염된 지반의 정화)

  • Park, Ki-Hong;Kwon, Oh-Jung;Park, Jun-Boum
    • Proceedings of the Korean Geotechical Society Conference
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    • 2003.03a
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    • pp.597-604
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    • 2003
  • In the soil washing process, the contaminants are usually removed by abrasion from soil particles using mechanical energy and water However, organic contaminants with low water solubility like polycyclic aromatic hydrocarbons (PAH) are remained on soil particles. Previous studies have shown that surfactant possessing amphipathic activity enhances the solubility of organic materials. For this reason solutions with surfactants have been used to improve removal of organic contaminants on soil washing process. But, in this manner, many problems were found like complete loss of surfactants and additional contamination by surfactant. The remediation method using microemulsion has been introduced to overcome these disadvantages. In this case, surfactants are recycled by phase separation of microemulsion after remediation. In microemulsion process, the surfactant will be recycled by phase separation of the microemulsion into a surfactant-rich aqueous phase and an oil phase after extraction. That is why remediation concept applying microemulsion as washing media has been Introduced. Suitable microemulsion have to be used in order to have the chance of refilling the soil after decontamination and to avoid any risk due to toxicity. The purpose of this research is to evaluate effect of microemulsion to remediation of contaminated soil. We performed test with various organic contaminants like Pyrene and BTEX, also compared efficiency of remediation in microemulsion process with soil washing

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A Study on Efficient Improvement Method of Rainwater Utilization Facilities in Jeju Island (제주지역 빗물이용시설의 효율적 개선방안 연구)

  • Park, Won-Bae;Moon, Deok-Cheol;Koh, Gi Won
    • Journal of Soil and Groundwater Environment
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    • v.17 no.6
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    • pp.1-8
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    • 2012
  • This study is to suggest a few efficient ways of rainwater utilization, through monitoring and analyzing 143 rainwater storage systems and 110 artificial recharge systems, which are installed in the recommended facilities by law, among the rainwater harvesting systems in Jeju Island. In the case that catchment facilities are damaged, rainwater could be contaminated by leaves and debris so that the rates of rainwater usages come to be lower. It is possible that contaminated rainwater could contaminate artificial recharge wells or rainwater discharging out of the rainwater harvesting system could result in flood and damage for the downgradient area. For maintaining high quality of rainwater and increasing rainwater utilization rate, it is necessary to install screening facilities and purification plant functioning precipitation and filtration. Also, in order to efficiently preclude the overflowing rainwater exceeding storage capacity, it is recommended to associate rainwater storage tanks with artificial recharge well or infiltration trench facilities.

Evaluation of Heavy Metal Contamination in Geochemical Environment around the Abandoned Coal Mine - With special reference to geochemical environment around the Imgok Creek in the Gangreung Coal Field - (폐석탄광 주변 지구화학적 환경의 중금속 오염 평가 - 강릉탄전 임곡천 일대를 중심으로 -)

  • Chon, Hyo-Taek;Kim, Ju-Yong;Choi, Si-Young
    • Economic and Environmental Geology
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    • v.31 no.6
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    • pp.499-508
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    • 1998
  • The Imgok Creek is located in the Gangreung coal field, which has been known that sulfides are more abundant than other coal fields in Korea, and it has been severly contaminated by acid mine drainage (AMD) discharging from the abandoned coal mines, such as the Youngdong, the Dongduk and the Waryong coal mines. The purposes of this study are to synthetically assess the contamination of natural water, stream sediment and cultivated soils, and to provide the basic data for AMD treatment. Geochemical samples were collected in December, 1996 (dry season) and April, 1997 (after three day's rainfall). TDS of the Youngdong mine water was remarkably higher than those of other mine waters. In the Imgok Creek, concentrations of most elements, except Fe decreased with distance by dilution caused by the inflow of uncontaminated tributaries. From the results of NAMDI and $I_{geo}$ calculation, the Youngdong coal mine was the main contamination source of the study area. Groundwater pollution was not yet confirmed in this study and the paddy and farm land soils were also not yet contaminated by mining activity based on the pollution index ranging from 0.27 to 0.47.

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Development of Microbe Carrier for Bioremediation of Zn, As by using Desulfovibrio Desulfuricans and Zeolite in Artificial Sea Water (Desulfovibrio Desulfuricans과 제올라이트를 이용한 해양 내의 Zn, As 제거용 미생물 담체 개발)

  • Kim, In Hwa;Choi, Jin-Ha;Joo, Jeong Ock;Oh, Byung-Keun
    • KSBB Journal
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    • v.30 no.3
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    • pp.114-118
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    • 2015
  • In this study, we have developed a microbe-carrier that combined Desulfovibrio desulfuricans and zeolite for removal of Zn and As in contaminated seawater. Desulfovibrio desulfuricans, one of the sulfate-reducing bacteria (SRB) microorganism was exhibited stable growth characteristics in highly salted water and strong resistance to Zn and As contaminated seawater. Moreover, zeolites are one of the most useful carrier to remove heavy metals from wastewaters. The results showed that SRB immobilized zeolite carrier can enhance removal ratio of Zn and As. In addition, heavy metals tended to be better removed in medium at conditions of $37^{\circ}C$. In case of heavy metal concentration, they were effectively removed ranging from 50 to 100 ppm. These results show that SRB-zeolite carriers hold great potential to remove cationic heavy metal species from industrial wastewater in marine environment.

Concentrations and Daily Intake of Arsenic and Heavy Metals in Polished Rice Around Abandoned Metal Mines in Korea (국내 휴·폐금속광산 주변 백미의 비소 및 중금속 함량과 일일 섭취량)

  • Kwon, Ji Cheol;Lee, Goontaek;Kim, Jeong Wook;Jung, Myung Chae
    • Journal of Soil and Groundwater Environment
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    • v.23 no.1
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    • pp.63-73
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    • 2018
  • Rice is a staple food source in Asian countries. In paddy field, rice plant can take up toxic elements through its roots from contaminated soils, and its leaves and grain can absorb the toxic elements deposited on the soil surface. A totla of 40 soil and polished rice samples were collected around four abandoned metal mines in Korea and analyzed for As, Cd, Cu, Pb and Zn by atomic absorption spectrophotometer (AAS). The average contents of As, Cd, Cu, Pb and Zn in rice grain grown on the contaminated soils were 0.247, 0.174, 4.694, 0.804 and 16.78 mg/kg, respectively. These levels are higher than worldwide average concentrations. Assuming the rice consumption of 169 g/day by overall households in Korea, the estimated daily intakes from the rices were found to be 33, 48, and 63% for As, Cd, and Pb, respectively, of the acceptable daily intake (ADI) suggested by the FAO/WHO Joint Food Additive and Contaminants Committee.

Electrical Characteristics against Frequency and Concentration of Contaminated Soils by Mercury and Arsenic (수은과 비소로 오염된 시료의 측정주파수와 농도 변화에 따른 전기적 특성)

  • Son, Young-Hwan;Bong, Tae-Ho;Chang, Pyoung-Wuck
    • Journal of The Korean Society of Agricultural Engineers
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    • v.50 no.6
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    • pp.15-24
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    • 2008
  • In general, ground pollution can be classified with soil pollution and underground water pollution. And ground pollution contaminates the land with garbage dumps and other harmful waste products as heavy metals that can also eventually enter our water supply. This study was conducted to define a characteristics of the electrical resistivity and the permittivity of weathered soil that was contaminated with heavy metals as Mercury and Arsenic. It is not easy whether contamination of soil as subsurface contamination is decided or not and at an early stage especially do that. Therefore the electrical resistivity and the permittivity were used to make up for this defects. These methods are more economical and more effective than the existing methods. And variation of the electrical resistivity and the permittivity values were found against the change of concentration of Mercury and Arsenic aqueous solutions and measuring frequency. These analyzed results indicate that the electrical resistivity and the permittivity tend to decrease against increasing measuring frequency. The electrical resistivity and the permittivity are also found to show the function of frequency.

Development of IoT-based non-cleaning water quality measuring equipment

  • Kim, Heung Soe;Ko, Woori;Ko, Kyoung Hak
    • Agribusiness and Information Management
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    • v.9 no.1
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    • pp.18-22
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    • 2017
  • It takes lots of time and labor if a worker have to measure the water quality at a certain but designated time every day in an un-automated aqua farm. In addition, if the equipment is soaked in the sea water consistently, it will be contaminated by diverse floating matters and barnacles, and it often becomes mal-functional within 2~3 months. Therefore, we need to develop a system with which the sensed data could be checked in real time and operated automatically, while preventing the contamination of the sensor, a crucial component for water quality measuring equipment, as much as possible, and increasing the replacement cycle. We have developed a non-cleaning water quality measuring equipment and its software which are used in the fishery household of offshore aqua farms. By providing the workers with a mobile application which has a function of monitoring the water quality in real time, they can check the situation directly without going to the fishery household.