• Title/Summary/Keyword: contact effect

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STUDY OF CONTACT ION PAIR DYNAMICS IN VIEW OF THE MOLECULAR SHAPES

  • Han, Chul-Hee
    • Journal of Photoscience
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    • v.3 no.3
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    • pp.147-151
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    • 1996
  • Dynamics of contact ion-pair between 1, 2, 4, 5-tetracyanobenzene anion and cation of biphenyl derivatives was investigated on the picosecond time scale. Solvent effect on the electron transfer was observed and electron transfer rates were examined using Marcus equation which contains distance dependence of the electron transfer rate in the frequency factor, along with the consideration of molecular shape. From the discussion based on disk model for molecular shape, contribution of interring torsional motion of biphenyl to the inner-sphere reorganization energy is strongly suggested, which leads to the physical explanation for the observed solvent effect on the rate of electron transfer.

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Preliminary Study for the Development of Optimum Fuel Contact Conductance Model (최적 핵연료 접촉 열전도도 모델 개발을 위한 예비 연구)

  • Yang, Yong-Sik;Shin, Chang-Hwan
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2488-2493
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    • 2007
  • A gap conductance is very important factor which can affect nuclear fuel temperature. Especially, in case of an annular fuel, a gap conductance effect can lead an unexpected heat split phenomena which is caused by a large difference of an inner and outer gap conductance. The gap conductance mechanism is very complicated behavior due to the its strong dependency on microscopic factors such as a contact surface roughness, local contact pressure and local temperature. In this paper, for the decision of test temperature and pressure range, a procedure and calculation results of in-reactor fuel temperature and pressure analysis are summarized which can be applied to test equipment design and determination of test matrix. Based upon analysis results, it is concluded that the minimum and maximum test temperature are $300^{\circ}C$ and $530^{\circ}C$ respectively, and the maximum pellet/cladding interfacial contact pressure should be observed up to 45MPa.

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Friction transition diagram considering the effects of oxide layer formed on contact parts of TiN coated steel ball

  • Cho, C.W.;Lim, J.S.;Lee, Y.Z.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.179-180
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    • 2002
  • In this study. the friction transition diagram based on the effect of oxide layer formation on contact surface between TiN coated steel ball and uncoated steel disk was constructed. From the diagram. it can be seen that as the contact load increases. the contact number of cycle at the beginning of oxide layer formation decreases linearly and as the coating thickness increases and the surface roughness of steel disk increases under same contact load. that increases. For the coated ball specimen, a AISI 52100 steel ball was used and AISI 1045 steel was used for the disk counter part.

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Effects of Alloying Elements and Nitrocarburizing on Rolling Contact Fatigue Life (회전접촉피로수명에 미치는 합금원소 및 침질탄화처리의 영향)

  • Jin, Jai Koan;Kim, Dong Keon
    • Journal of the Korean Society for Heat Treatment
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    • v.7 no.4
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    • pp.262-269
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    • 1994
  • This study has been carried out to evaluate effects of alloying elements and nitrocarburizing on rolling contact fatigue life. Manganese has a significant influence on the distribution of retained carbides and microstructural changes after rolling contact fatigue test. The effect of the manganese addition stabilized fine retained carbide particles during rolling contact fatigue life test, and so increased fatigue life markedly. High carbon chromium bearing steel with different matrixes were nitrocarbunzed by austenitic nitrocarburizing process at $850^{\circ}C$ for 4hrs. Rolling contact fatigue life of the nitrocarburized specimen was increased 2 times than full hardening treated.

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Analysis of conducted noise on modeling methods for loss of contact during traction of high-speed rail vehicle (고속전철 주행시 이선현상 모델링 방법에 따른 전도성 노이즈 해석)

  • Kim, Jae-Moon;Kim, Yang-Soo;Chang, Chin-Young
    • Proceedings of the KIEE Conference
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    • 2008.09a
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    • pp.72-75
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    • 2008
  • The Electromagnetic Interference(EMI) in railway applications is largely due to doing the power conversion for traction and Auxiliary system on the Highspeed Electric Multiple Unit-400X(HEMU-400X). In order to research on EMI in railway applications, it were included how much the HEMU-400X generates it and it has an effect on the equipments of electric system which resulted from Power Line Disturbance (PLD) phenomenon by the loss of contact during its running. In this study, the dynamic characteristic of a contact wire and pantograph suppling electrical power to high-speed trains are investigated. The analysis of the loss of contact based on Power Simulator program software is performed to develop power line disturbance model suitable for high speed operation. It is confirmed that a contact wire and pantograph model are necessary for studying the dynamic behavior of the pantograph system.

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Partial-EHL Analysis of Wheel Bearing for a Vehicle (자동차용 휠 베어링의 부분탄성유체윤활 해석)

  • Kim Dong-Won;Lee Sang-Don;Cho Yong-Joo
    • Tribology and Lubricants
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    • v.21 no.6
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    • pp.289-295
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    • 2005
  • Most machine element, such as gears and bearings, are operated in the mixed lubrication region. Contact between two asperities has an effect on machine life by increasing local pressure. To estimate fatigue life exactly, asperity contact should be considered as a factor of fatigue life because this happening produce friction, abrasion and make flash temperature. In this paper, asperity contact is considered as a result of film breakdown when lubricant pressure is not enough to separate two asperities. Contact pressure is calculated to asperity overlap region and added to lubricant pressure. For this model, numerical procedure is introduced and the result on surface roughness and velocity for wheel bearing is presented. Results of EHL analysis for wheel bearing show that asperity contact is occurred at the edge ofEHL conjunction where has a insufficient lubricant pressure to separate two surface.

Effect of power line disturbance on loss of contact between contact wire and pantograph (전차선-팬터그래프 사이의 이선현상에 따른 전원외란이 보조전원장치에 미치는 영향)

  • Kim, Jae-Moon;Kim, Yang-Soo;Jang, Jin-Young;Gimm, Yoon-Myoung
    • Proceedings of the KIEE Conference
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    • 2008.04b
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    • pp.179-181
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    • 2008
  • In this study, the dynamic characteristic of a contact wire and pantograph suppling electrical power to high-speed trains are investigated. The analysis of the loss of contact based on Power Simulator program software is performed to develop power line disturbance model suitable for high speed operation. It is confirmed that a contact wire and pantograph model are necessary for studying the dynamic behavior of the pantograph system.

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Four Cases of Contact Dermatitis Treated by Oriental Medicine (접촉피부염 한방치험 4례)

  • Yu, Seung-Min;Choi, In-Hwa
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.22 no.2
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    • pp.281-289
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    • 2009
  • Background : With the growing use of chemical products such as cosmetics, hair dyes, reports of side effects following application of these products is increasing. Contact dermatitis commonly occurs with the use of chemical products. Objective : This study investigated the effect of Oriental medicine for Four outpatients with contact dermatitis due to chemical products. Method : Four patients were treated with acupuncture, herbal medication etc. We used visual analogue scales(VAS) to estimate erythema, pruritus, edema, scales, etc. We took the photos of lesions. Results : Two patients were due to hair dyes, the other two patients were due to cosmetics. Erythema and Pruritus were decreased from nine days to one month. Conclusion : We expect that Oriental medicine could be helpful for contact dermatitis.

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Investigation of Ohmic Contact for $n^+$-GaN/AlGaN/GaN HFET ($n^+$-GaN/AlGaN/GaN HFET 제작을 위한 오믹접촉에 관한 연구)

  • 정두찬;이재승;이정희;김창석;오재응;김종욱;이재학;신진호;신무환
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.2
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    • pp.123-129
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    • 2001
  • The optimal high temperature processing conditions for the formation of Ohmic contact of Ti/Al/Pt/Au multiple layers were established for the fabrication of n$^{+}$-GaN/AlGaN/GaN HFET device. Contact resistivity as low as 3.4x10$^{-6}$ ohm-$\textrm{cm}^2$ was achieved by the annealing of the sample at 100$0^{\circ}C$ for 10 sec. using the RTA (Rapid Thermal Annealing) system. The fabricated HFET (Heterostructure Field Effect Transistor) with a structure of n'-GaN/undoped AlGaN/undoped GaN exhibited a low knee voltage of 3.5 V and a maximum source-drain current density of 180 mA/mm at Vg=0V.V.

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Wetting Phenomena between Sealing Glass and Free Cutting Steel (접합유리와 쾌삭강간의 Wetting 현상)

  • Kim, Heung;Kim, Chong-Hee
    • Journal of the Korean Ceramic Society
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    • v.19 no.1
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    • pp.24-34
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    • 1982
  • The effect of the several variables on wetting of AISIB1113 steel by molten glass was studied by Sessible-drop method. Experimental variables were temperature, firing atmospheres, Fe2O3 addition to the sealing glass and steel surface conditions. The degree of wetting in terms of contact angles between molten glass and metal tested at different test conditions was analyzed by using Young's equation. The results showed that contact angles in H2 atmosphere in the glass metal systems were high but in N2 atmosphere, were small for studied glass metal systems. Especially, when the glass drop was in contact with oxidized steel in N2 atmosphere, The best adherence with contact angle of approximately 9°was obtained. In the case of Fe2O3 addition in glass contact angles subtantially increased due to the increase of surface tension of glass. Wetting phenomena were also discussed under the basis of these experimental results.

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