• 대한물리치료과학회지
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• 제16권3호
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• pp.1-9
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• 2009

Background: The purpose of this study is to have examined the influence on the blood circulation by comparing the differences between stimulating the sympathetic ganglion and the muscle group among the stimulation variables in interferential current stimulation. Method: The object of the study is the twenties(M=8, F=12), who are in great condition and have no pathological report for the blood circulation influence. The intensity of the inferential current stimulation is the medium degree, 100 bps constant current, which is the comfort and degree to confirm the muscle contraction. The areas stimulated are the stellate ganglion area in the seventh cervical vertebrae and the forearm muscle area. Results: We have made sure that there is no change in blood pressure and pulse and that the change in the skin temperature occurred highly. Conclusion: In considering the change of the blood circulation in case of stimulation area by the inferential current stimulation, we have seen that stimulating the sympathetic ganglion area is more effective than stimulating muscle area directly.

• Bulletin of the Korean Chemical Society
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• 제35권6호
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• pp.1754-1758
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• 2014

The nucleophilic substitution reactions of bis(Y-aryl) chlorothiophosphates (1) with X-pyridines are investigated kinetically in acetonitrile at $35.0^{\circ}C$. The free energy relationships with both X and Y are biphasic concave upwards with a break point at X = 3-Ph and Y = H, respectively. The sign of cross-interaction constants (CICs; ${\rho}_{XY}$) is positive with all X and Y. Proposed mechanism is a stepwise process with a rate-limiting leaving group departure from the intermediate with all X and Y. The kinetic results of 1 are compared with those of Y-aryl phenyl chlorothiophosphates (2). In the case of Y = electron-withdrawing groups, the cross-interaction between Y and Y, due to additional substituent Y, is significant enough to change the sign of ${\rho}_{XY}$ from negative with 2 to positive with 1, indicative of the change of mechanism from a rate-limiting bond formation to bond breaking.

• 대한수학회보
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• 제47권1호
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• pp.73-79
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• 2010

A pair of point vortices of the same strength but opposite sign is called a vortex dipole. We consider the limiting case where two vortices approach infinitely close while the ratio of the strength to the distance kept constant. The motion of such point vortex dipole on the ellipsoid of revolution is investigated geometrically to conclude that the trajectory draws a geodesic up to the leading order of perturbation, whose direction is determined by the initial orientation of the dipole. Related issues are also remarked.

• Bulletin of the Korean Chemical Society
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• 제19권12호
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• pp.1334-1336
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• 1998

Kinetic studies are carried out on the reactions of 2-chloro-2-propen-1-yl arenesulfonates with anilines and N,N-dimethylanilines in acetonitrilile at 45.0 ℃. The 2-chloro substituent is found to deactive the allyl moiety with considerable decrease in the rates. The sign and magnitude of the cross-interaction constant (ρxz 0.3) and the inverse secondary kinetic isotope effect (kH/kD 0.92) support an SN2 mechanism with a relatively tight transition state. The possibility of an SN2' mechanism can be safely precluded based on the ρxz values observed.

• EDISON SW 활용 경진대회 논문집
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• 제2회(2013년)
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• pp.25-35
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• 2013

The intramolecular magnetic coupling constant (J) values of diradical-based magnet models (S1-S5) were studied using unrestricted density functional theory. The model systems were designed with series of oxoverdazyl radicals (o-Ver(N) and o-Ver(C)) linked through a benzene coupler. They were divided according to either connectivity of the radical (C or N) or geometrical topology (meta- and para-) of benzene coupler. Reasonable relationship was found between spin density distribution and sign of J value. With our results we determined ferromagnetic (positive J value) and antiferromagnetic (negative J value) interactions. J values were also calculated along the twisting movement by the scan of dihedral angles between the radical and the coupler. An overall trend was found as absolute value of J decreased over increasing torsion angles.

• 대한전자공학회논문지
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• 제13권1호
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• pp.11-15
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• 1976

게이트 전류가 흐르지 않는 MOSFET를 사용한 단안정 멀티바치브레이터는 도전시에도 게이트 전압이 일정하게 유지되지 않기 때문에 이 전압을 기준으로 한 회로해석이나 설계는 매우 어려워서, 비교적 간단히 해결할 수있는 도식방법을 소개하였다. 즉 각FET의 전압이득곡선을 구하고 이 유선의 기본적인 성질과 국로 설계에 이용하는 방법들에 대해서 논하였다. In a MOSFET multivibrator, the gate do not hold into a constant clamp voltage during a conduction period. The analysis of the operation and the 43sign of a MOSFET multivibrator circuit are much more discult than that using a bipolar transistor and a electron tube because of above reason. And therefore, in the designing procedures of the MOSFET monostable multivibrator of this paper, a graphical method is adopted in order to analyze and design easily. The voltage gain curves of the both FETs are drawn using a parameter the voltage Vc across the coupling condenser, and the curves are utilized to investigate the voltages of the drains and the gates and determine the gate bias voltage. The diagram gives also important informations for the design of the multivibrator.

• Bulletin of the Korean Chemical Society
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• 제34권12호
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• pp.3597-3601
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• 2013

The reactions of bis(Y-aryl) chlorothiophosphates (1) with substituted anilines and deuterated anilines are investigated kinetically in acetonitrile at $55.0^{\circ}C$. The Hammett plots for substituent Y variations in the substrates show biphasic concave upwards with a break point at Y = H. The cross-interaction constants (${\rho}_{XY}$) are positive for both electron-donating and electron-withdrawing Y substituents. The kinetic results of 1 are compared with those of Y-aryl phenyl chlorothiophosphates (2). The cross-interaction between Y and Y, due to additional substituent Y, is significant enough to result in the change of the sign of ${\rho}_{XY}$ from negative with 2 to positive with 1. The effect of the cross-interaction between Y and Y on the rate changes from negative role with electron-donating Y substituents to positive role with electron-withdrawing Y substituents, resulting in biphasic concave upward free energy correlation with Y. A stepwise mechanism with a rate-limiting leaving group departure from the intermediate involving a predominant frontside attack hydrogen bonded, four-center-type transition state is proposed based on the positive sign of ${\rho}_{XY}$ and primary normal deuterium kinetic isotope effects.

• 한국통신학회논문지
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• 제18권11호
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• pp.1714-1725
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• 1993

본 논문에서는 스칼라 인수 a1, a2, a3를 매개변수화하여 갱신항을 첨가한 비선형 적응 알고리즘의 특성을 해석하고 그 구조를 나타낸다. 수렴 특성의 해석에서 평균 필터계수 벡터에 대하여 전이행열의 값이 기술된다. 그 알고리즘이 안정하기 위한 범위도 증명된다. 또한 본 알고리즘의 시정수도 유도되고, Sign 알고리즘, 기존의 LMS 알고리즘, LFG 알고리즘, QFG 알고리즘의 계산량도 비교해 본다. 평균자승의 수렴특성을 해석하고 평균자승 순환식과 초과 평균자승 오차(excess mean square error) 표현식을 유도하고 본 알고리즘이 안정하기 위한 조선도 정한다. 컴퓨터 모의실험(simulation)에서 CFG 알고리즘이 LMS, LFG 및 QFG 알고리즘보다 계산량이 증가하는 반면 수렴속도에서 현저한 향상을 보여준다.

• Bulletin of the Korean Chemical Society
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• 제29권4호
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• pp.851-855
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• 2008

The reactions of O,O-diphenyl Z-S-phenyl phosphorothiolates with X-pyridines have been studied kinetically in acetonitrile at $35.0{^{\circ}C}$. The Hammett plots for substituent (Z) variations in the leaving group (log $k_2$ vs. $\sigma$ Z) are biphasic concave downwards with breaks at Z = H. The large magnitudes of ${\rho}X(\rho_{nuc})$, ${\beta}X(\rho_{nuc})$, and the cross-interaction constant, $\rho$XZ, suggest frontside nucleophilic attack toward the leaving group. The sign reversal of $\rho$Z from positive in $\sigma$ Z $\leq$ 0 to negative in $\sigma$ Z $\geq$ 0 is interpreted as the change in mechanism from concerted to stepwise with rate-limiting expulsion of the leaving group. The anomalous negative sign of $\rho$ Z for leaving groups with electron-withdrawing substituents is interpreted as the intramolecular ligand exchange process of the leaving group from the equatorial position in the intermediate to the apical position in the TS.

• 한국정보통신학회논문지
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• 제20권1호
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• pp.123-130
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• 2016

본 논문에서는 멀티미디어용 알고리즘을 고속으로 처리하기 위한 고성능 연산 회로를 설계하였다. 3단 파이프라인 구조로 동작하는 연산회로는 4개의 16-비트${\times}$16-비트 곱셈기의 효율적인 구성, 캐리 보존 형식 데이터에 대한 새로운 부호 확장 기법과 다수 개의 부분 곱셈 결과의 통합과정에 부호 확장을 제거하는 교정 상수 기법을 사용하여 복소수 데이터와 가변 길이 고정 소수점 데이터에 대한 38개의 연산을 처리할 수 있다. 설계한 프로세서는 45nm CMOS 공정에서 최대 동작 속도는 300 MHz이며 약 37,000 게이트로 구성되며 300 MCOPS의 연산 성능을 갖는다. 연산 프로세서는 높은 연산 속도와 응용 분야에 특화된 다양한 연산 지원으로 멀티미디어 프로세서에 효율적으로 응용 가능하다.