• Title/Summary/Keyword: connection form

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Synthesis of α-Ketobutyrolactones and γ-Hydroxy-α-Keto Acids

  • Kang, Han-Young;Ji, Yu-Mi;Yu, Yeon-Kwon;Yu, Ji-Yeon;Lee, Young-Hoon;Lee, Sang-Joon
    • Bulletin of the Korean Chemical Society
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    • v.24 no.12
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    • pp.1819-1826
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    • 2003
  • In connection with the studies for developing new enzymes that could be useful in organic synthesis, practical preparation of racemic and enantiopure forms of ${\gamma}$-hydroxy-${\alpha}$-keto acids has been successfully achieved. For racemic form of ${\gamma}$-hydroxy-${\alpha}$-keto acids, indium-mediated allylation of aldehydes with 2-(bromomethyl)acrylic acid has been employed as a key step. Oxidative cleavage of the thus formed 2-methylenebutyrolactones provided the desired ${\alpha}$-ketobutyrolactones. Enzymatic resolution of the ${\gamma}$-hydroxy-${\alpha}$-methylene esters provided the desired${\gamma}$-hydroxy-${\alpha}$-methylene acids which were successfully converted to ${\gamma}$-hydroxy-${\alpha}$-ketobutyrolactones in optically pure forms.

A Modified Shooting Method Technique for the Analysis of the Limited Slip Capacity of UHPFRC-NC Composite Structure

  • Han, Sang-Mook;Wu, Xiangguo;Kim, Sung-Wook;Kang, Su-Tae
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.1061-1064
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    • 2008
  • Shear connectors have a finite slip capacity because of the mechanism by which they transfer the shear between UHPFRC and NC elements. At high degree of shear connection, non-linear analysis techniques are required to allow for compressive plasticity and tensile cracking behaviour of the elements. As with all non-linear problems, a closed form solution is difficult to find. A Modified Shooting Method Technique is developed here for non-linear analysis of UHPFRC/concrete composite. The initial effective moment is derived according to the prestressing force. The composite structure is divided into small segments which length is much less than the length of the structure and it can be assumed that the forces and displacements within each segment are constant. An equivalent analysis in composite girders would be to fix the slip strain in each segment and develop a moment curvature relationship for this slip strain in each segment. Additive forces and moment analysis on each section of the segments are analyzed by MSMT. Finally the ultimate slippage of the interface can be evaluated by the MSMT model. This paper presents a nonlinear analysis method for limited slip capacity of UHPFRC-NC interface.

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A Study on methodology of physical Fabrication & reorganization of Epidermis in Space Design - Focused on reorganization of Epidermis, Fabrication - (공간디자인에서 디지털 표피 재 조직화, 물리적 구현 방법 연구 - 표피 재 조직화, 가공 중심으로 -)

  • Park, Jeong-Joo
    • Korean Institute of Interior Design Journal
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    • v.17 no.2
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    • pp.150-161
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    • 2008
  • It requires more close cooperation process and mediator for smooth communication in this industry structure where design and engineers are separated. The database of design integrates separate system and helps connection between organizations. The application category is utilized variously from formation to operation. Architectures addressed in this content as Frank Gehry and Nox are making differentiated design on the base of 3d digital methodology and using it widely from generation to fabrication. Especially they got to be free from the generative limit as it became available to analyse, digital surface organization, and realize the complex system form. Now more integrated and delicate works got to be affordable owing to various kinds of improved CNC, RP(rapid-prototype) machines, and architecture hardwares. With a linkage of software now at their disposal, architects can create a digital model of a building and all of its design elements, and in turn use this 3d information to construct actual building components using machines driven by CNC and other advanced manufacturing techniques. Digital technologies are enabling a direct correlation between what design and construction, thus bringing to the forefront the issue of the significance of information, the production, communication, application, and control of digital information in the industrial system. The central requirement is the clear, reliable, and consistent exchange of information among all parties involved in creating a given project.

A Study on the Expression by Anamorphose Phenomenon (아나모르포즈(anamorphose)지각현상에 의한 공간 표현 연구)

  • Lee, Jeong-Yoon;Kim, Kai-Chun
    • Korean Institute of Interior Design Journal
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    • v.23 no.4
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    • pp.63-71
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    • 2014
  • Anamorphosis is highly favored in modern days as the atmosphere of pursuing unusual manners is growing while transformation and distortion of images are freely available. This research is to understand the affect of these distorted images on space designs and the close connection between anamorphosis and visual perceptions, and to identify the new perceptual phenomenon created through it, and the methods of expressing those. Four expressional methods were defined through the process of studying Anamorphosis based on its definition by Niceron, examining artworks such as paintings and photographs, and case-studying example spaces of visual perception experiments. Expressing anamorphosis through visual perceptions are broadly categorized to directional, dimensional, flatness, and optical. The analysis of 10 case projects suggests that the experimental spaces offer joys of finding and interpreting metaphorical forms and meanings caused by the four characteristic categories above. Also, they artificially show the boundaries between reality and virtual spaces in 2-dimensional or 3-dimensional spaces, and form hyper-boundaries, new experience, and an internal mechanism that is vague and chaotic. Therefore, this research concludes that anamorphosis which is a distorted perspective, is not only a simple measure to overcome perspectival errors, but is an existence suitable to the current era, that will extend its potential and value in spatial design.

The Behavior of the Term Structure of Interest Rates with the Markov Regime Switching Models (마코프 국면전환을 고려한 이자율 기간구조 연구)

  • Rhee, Yu-Na;Park, Se-Young;Jang, Bong-Gyu;Choi, Jong-Oh
    • Journal of Korean Institute of Industrial Engineers
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    • v.36 no.3
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    • pp.203-211
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    • 2010
  • This study examines a cointegrated vector autoregressive (VAR) model where parameters are subject to switch across the regimes in the term structure of interest rates. To employ the regime switching framework, the Markov-switching vector error correction model (MS-VECM) is allowed to the regime shifts in the vector of intercept terms, the variance-covariance terms, the error correction terms, and the autoregressive coefficient parts. The corresponding approaches are illustrated using the term structure of interest rates in the US Treasury bonds over the period of 1958 to 2009. Throughout the modeling procedure, we find that the MS-VECM can form a statistically adequate representation of the term structure of interest rate in the US Treasury bonds. Moreover, the regime switching effects are analyzed in connection with the historical government monetary policy and with the recent global financial crisis. Finally, the results from the comparisons both in information criteria and in forecasting exercises with and without the regime switching lead us to conclude that the models in the presence of regime dependence are superior to the linear VECM model.

The Activation Plan of Chain Information Network And Efficent NDB Design (효율적인 NDB 설계 및 유통 정보 NETWORK 활성화 방안)

  • 남태희
    • KSCI Review
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    • v.1 no.2
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    • pp.73-94
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    • 1995
  • In this paper, design of efficient NDB(Network Data Base) for the activation plan of chain information network. The DB structure build up, logical structure, store structure, physical structure, the data express for one's record, and the express using linked in the releation of data. Also express as hierarchical model on the DSD(Data Structure Diagram) from the database with logical structure. Each node has express on record type, the linked in course of connective this type, the infuence have efficent of access or search of data, in the design for connection mutually a device of physical, design for database, and construction a form of store for logical. Also activation of chain information network of efficent, using POS(Point Of Sale) system in OSI(Open Systems Interconnection) environment for network standardization, and build up network a design for system.

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The meaning of Sullivan's function and Loos' ornament - Focused on Louis Sullivan's Carson Pirie Scott Store(1898-1904) & Adolf Loos' Goldman&Salatsch Store(1909-1911) - (루이스 설리반과 아돌프 로스의 '기능'과 '장식'의 진의(眞意)와 그 연관성에 관한 고찰)

  • Kang, Tae-Woong
    • Journal of architectural history
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    • v.17 no.5
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    • pp.55-69
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    • 2008
  • One of the most notable architectural aphorisms in modern period must be undeniably Louis Sullivan's, 'Form Follows Function.' The aphorism has been not only an important source of new aesthetic but also an formal principle of machine age. Other most famous source in order to justify modern aesthetic was the short essay by an cynical critic, Adolf Loos(1870-1933), 'Ornament and Crime' of 1908. Apart from what the essay asserted it is also famous for the influence of Sullivan's architectural notion during Loos' States staying. For Architectural historians of the early 20th century this connection is so useful to create a legacy of modern architecture. The historians seemed to believe that Loos understanded Sullivan's aphorism on which the historians wanted to focused. When we however look into two buildings designed and built in the period of publishing both aphorism and essay there must be a big fissure between the buildings and the historians interpretations. With this view point this study aims at showing the true meanings of Sullivan's aphorism and Loos' essay and also the big difference between the machine age's aesthetic and theirs.

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Developing the Evaluation Indicator of Pedestrian Environment for Promoting Walking Activity (걷기활동 증진을 위한 보행환경 평가지표의 개발)

  • Park, Kyung-Hun;Park, Jong-Wan;Jung, Sung-Gwan;You, Ju-Han
    • Journal of Environmental Science International
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    • v.16 no.11
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    • pp.1231-1238
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    • 2007
  • The promotion of walking and bicycling is recently a hot topic in the urban planning and design field. Many planners have already examined the many components of the land use-transportation connection and built environment-physical activity link. A rapidly growing area of urban form research is to measure the level of walk-ability in urban environments. With this background, this research conducted a preliminary study to develop the evaluation indicators of pedestrian environments. Based on the literature reviews on walking or pedestrian environments, we proposed the seventeen indicators related with pedestrian facilities, road attributes and walking environment. We also performed a questionary survey to evaluate the satisfaction of their neighborhood pedestrian environments for 302 randomly selected adults living in the City of Changwon, Gyeongsangnam-do. Finally, this research provided the valid model to evaluate the effects of physical environmental factors on the walking satisfaction using factor analysis and multiple regression analysis.

Algorithm for the Reinforced Concrete Framework Materials Take-off (철근콘크리트조의 골조물량산출 알고리즘)

  • Kim Tae-Hui;Hong Chae-Gon;Kim Sun-Kuk
    • Korean Journal of Construction Engineering and Management
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    • v.4 no.1 s.13
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    • pp.114-121
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    • 2003
  • The precise quantity of materials is not yet taken off by the CAD system although it has Influenced in design productivity and automatic estimate. And various estimate systems developed so far deal with the quantity take-off of building members separately, which caused to over-estimate the part of each member. Therefore, the purpose of this paper is to develop algorithms of more precise estimate than that of current estimate by solving boundary conditions of the connection parts of building members, such as column, girder, beam, wall and slab. The algorithms are proposed to take off the quantity of concrete and form work and they will be used for the estimate of building structure more precisely and automatically than ever.

A Study on Enhanced Self-Generation Supervised Learning Algorithm for Image Recognition (영상 인식을 위한 개선된 자가 생성 지도 학습 알고리듬에 관한 연구)

  • Kim, Tae-Kyung;Kim, Kwang-Baek;Paik, Joon-Ki
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.30 no.2C
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    • pp.31-40
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    • 2005
  • we propose an enhanced self-generation supervised algorithm that by combining an ART algorithm and the delta-bar-delta method. Form the input layer to the hidden layer, ART-1 and ART-2 are used to produce nodes, respectively. A winner-take-all method is adopted to the connection weight adaption so that a stored pattern for some pattern is updated. we test the recognition of student identification, a certificate of residence, and an identifier from container that require nodes of hidden layers in neural network. In simulation results, the proposed self-generation supervised learning algorithm reduces the possibility of local minima and improves learning speed and paralysis than conventional neural networks.