• Title/Summary/Keyword: confined polymer

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Hysteretic Behavior Evaluation of Reinforced Concrete Columns Retrofitted with Iron-based Shape Memory Alloy Strips (철계 형상기억합금 스트립으로 보강된 콘크리트 기둥의 반복이력거동 평가)

  • Jeong, Saebyeok;Jung, Donghyuk
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.35 no.5
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    • pp.287-297
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    • 2022
  • This paper presents experimental and analytical studies on the lateral cyclic behavior of RC columns actively confined with iron-based shape memory alloy (Fe-SMA) strips. Based on the Anexperimental study, we investigated the effectiveness of active confinement through compression testings of concrete cylinders confined by Fe SMA strips and carbon fiber-reinforced polymer (CFRP) sheets. The test results showed that the specimens confined with Fe SMA strips significantly increased the deformation capacity of the concrete, even under lower confining pressures, compared to those specimensconfined with CFRP sheets. The experimental results were used to develop finite-element models of RC columns confined with Fe SMA or CFRP in their plastic-hinge region. After validating the proposed analytical model through comparison with the results from a previous RC column test, a series of lateral cyclic load analyses were carried out for the RC columns confined with Fe SMA and CFRP. The analytical results revealed that the lateral cyclic behavior of the Fe SMA-confined column was greatly enhanced in terms of deformation and energy dissipation capacities compared with tothat of the as-built and CFRP-confined columns.

Evaporative Self-Assembly of Single-Walled Carbon Nanotubes for Field Effect Transistor (용매증발기반 자기조립을 이용한 단일벽 탄소나노튜브 정렬 및 트랜지스터 응용)

  • Kang, Seok Hee;Jeong, Do Young;Eom, Seong Un;Hwang, Cheong Seok;Hong, Suck Won
    • Korean Journal of Materials Research
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    • v.23 no.8
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    • pp.453-461
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    • 2013
  • Controlling the stick and slip motions of the contact lines in a confined geometry comprised of a spherical lens with a flat substrate is useful for manufacturing polymer ring patterns. We used a sphere on a flat geometry, by which we could control the interfaces of the solution, vapor and substrate. By this method, hundreds of concentric ring-pattern formations of a linear conjugated polymer, poly [2-methoxy-5-(2-thylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), were generated with excellent regularity over large areas after complete solvent evaporation. Subsequently, the MEH-PPV ring patterns played a role as a directed template to organize highly regular concentric rings of single-walled carbon nanotubes(SWCNTs); when a droplet of the SWCNT suspension in water was casted onto the prepared substrate, hydrophobic polymer patterns confined the water dispersed SWCNTs in between the hydrophilicized $SiO_2/Si$ substrate. As the solvent evaporated, SWCNT-rings were formed in between MEH-PPV rings with controlled density. Finally, we used a lift-off process to produce SWCNT patterns by the removal of a sacrificial polymer template with organic solvent. We also fabricated a field effect transistor using self-assembled SWCNT networks on a $SiO_2/Si$ substrate.

Nanostructures of diblock copolymers under curved confinement

  • Shin, Kyu-Soon;Huh, June;Jo Won-Ho;Xiang hongqi;McCarthy Thomas J.;Russell Thomas P.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.294-294
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    • 2006
  • Diblock copolymers whose morphology in the bulk is dictated by the volume fraction of the components and segmental interactions were confined within nanoscopic cylindrical pores. Since the confining geometry is nonplanar and nanoscopic, the extreme imposed curvature, comparable to molecular dimensions, places significant packing frustration on the chains. When incommensurability between the repeating period of diblock copolymers and the diameter of nanopore is coupled with the curvature, it causes the marked departures from bulk or even thin film behavior. The entropy penalty from the constraints and the curvature of the physical confinement determines unique nanostructures available only with this curved confinement.

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Noble LCD with a Single Supporting Substrate

  • Wook, Jung-Jong;Kim, Jae-Hoon
    • Journal of Information Display
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    • v.3 no.4
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    • pp.4-7
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    • 2002
  • A recently developed phase separated composite film method has been employed to fabricate a liquid crystal (LC) based electro-optical device using a single glass substrate. The resulting device is made of adjacent parallel layers of LC and polymer maded by phase separation. The LC layer is confined between the solidified polymer layer on one side and the glass substrate on the other. The electro-optical properties of these devices demonstrate their technological potential in light weight and hand-held electronic products.

Noble LCD with a single supporting substrate

  • Kim, Il;Kim, Jae-Hoon;Agra-Kooijman, Dena M.;Kumar, Satyendra
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.463-466
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    • 2002
  • A new type of LCD has been developed using recently developed phase separated composite film method with a single glass substrate. The resultant structures are made of adjacent parallel layers of liquid crystal and polymer. The LC layer is confined between the solidified polymer layer and glass substrate. The electra-optical properties of the display have been investigated. This technique has the potential to realize a lightweight display for hand-held portable electronic products.

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Strength and strain modeling of CFRP -confined concrete cylinders using ANNs

  • Ozturk, Onur
    • Computers and Concrete
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    • v.27 no.3
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    • pp.225-239
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    • 2021
  • Carbon fiber reinforced polymer (CFRP) has extensive use in strengthening reinforced concrete structures due to its high strength and elastic modulus, low weight, fast and easy application, and excellent durability performance. Many studies have been carried out to determine the performance of the CFRP confined concrete cylinder. Although studies about the prediction of confined compressive strength using ANN are in the literature, the insufficiency of the studies to predict the strain of confined concrete cylinder using ANN, which is the most appropriate analysis method for nonlinear and complex problems, draws attention. Therefore, to predict both strengths and also strain values, two different ANNs were created using an extensive experimental database. The strength and strain networks were evaluated with the statistical parameters of correlation coefficients (R2), root mean square error (RMSE), and mean absolute error (MAE). The estimated values were found to be close to the experimental results. Mathematical equations to predict the strength and strain values were derived using networks prepared for convenience in engineering applications. The sensitivity analysis of mathematical models was performed by considering the inputs with the highest importance factors. Considering the limit values obtained from the sensitivity analysis of the parameters, the performances of the proposed models were evaluated by using the test data determined from the experimental database. Model performances were evaluated comparatively with other analytical models most commonly used in the literature, and it was found that the closest results to experimental data were obtained from the proposed strength and strain models.

Data-driven prediction of compressive strength of FRP-confined concrete members: An application of machine learning models

  • Berradia, Mohammed;Azab, Marc;Ahmad, Zeeshan;Accouche, Oussama;Raza, Ali;Alashker, Yasser
    • Structural Engineering and Mechanics
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    • v.83 no.4
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    • pp.515-535
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    • 2022
  • The strength models for fiber-reinforced polymer (FRP)-confined normal strength concrete (NC) cylinders available in the literature have been suggested based on small databases using limited variables of such structural members portraying less accuracy. The artificial neural network (ANN) is an advanced technique for precisely predicting the response of composite structures by considering a large number of parameters. The main objective of the present investigation is to develop an ANN model for the axial strength of FRP-confined NC cylinders using various parameters to give the highest accuracy of the predictions. To secure this aim, a large experimental database of 313 FRP-confined NC cylinders has been constructed from previous research investigations. An evaluation of 33 different empirical strength models has been performed using various statistical parameters (root mean squared error RMSE, mean absolute error MAE, and coefficient of determination R2) over the developed database. Then, a new ANN model using the Group Method of Data Handling (GMDH) has been proposed based on the experimental database that portrayed the highest performance as compared with the previous models with R2=0.92, RMSE=0.27, and MAE=0.33. Therefore, the suggested ANN model can accurately capture the axial strength of FRP-confined NC cylinders that can be used for the further analysis and design of such members in the construction industry.

Tracer diffusion in a polymer network: influence of network flexibility

  • Kim, Haein;Kim, Jun Soo
    • Proceeding of EDISON Challenge
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    • 2017.03a
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    • pp.39-45
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    • 2017
  • We present a Brownian dynamics simulation study on the diffusion of a neutral tracer particle confined in a regularly crosslinked polymer network, especially, when the tracer size is comparable to the mesh size of the network. Polymer networks with different mesh sizes are prepared and compressed to the extent that the total polymer densities become the same. Irrespective of the network mesh size, the tracer diffusion in the networks is slowed down, showing the subdiffusion on intermediate time scales followed by the normal diffusion at long times. However, the confinement effect on the tracer diffusion becomes more significant when network strands are tightly stretched with smaller mesh size. The time scales of dynamic transitions are analyzed in terms of the probability distribution of time-correlated particle displacements.

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Numerical modelling of circular reinforced concrete columns confined with GFRP spirals using fracture-plastic model

  • Muhammad Saad Ifrahim;Abdul Jabbar Sangi;Shuaib H. Ahmad
    • Computers and Concrete
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    • v.31 no.6
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    • pp.527-536
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    • 2023
  • Fiber Reinforced Polymer (FRP) bar has emerged as a viable and sustainable replacement to steel in reinforced concrete (RC) under severe corrosive environment. The behavior of concrete columns reinforced with FRP bars, spirals, and hoops is an ongoing area of research. In this study, 3D nonlinear numerical modelling of circular concrete columns reinforced with Glass Fiber Reinforced Polymer (GFRP) bars and transversely confined with GFRP spirals were conducted using fracture-plastic model. The numerical models and experimental results are found to be in good agreement. The effectiveness of confinement was accessed through von-mises stresses, and it was found that the stresses in the concrete's core are higher with a 30 mm pitch (46 MPa) compared to a 60 mm pitch (36 MPa). The validated models are used to conduct parametric studies. In terms of axial load carrying capacity and member ductility, the effect of concrete strength, spiral pitch, and longitudinal reinforcement ratio are thoroughly investigated. The confinement effect and member ductility of a GFRP RC column increases as the spiral pitch decreases. It is also found that the confinement effect and member ductility decreased with increase in strength of concrete.

Performance of FRP confined and unconfined geopolymer concrete exposed to sulfate attacks

  • Alzeebaree, Radhwan;Gulsan, Mehmet Eren;Nis, Anil;Mohammedameen, Alaa;Cevik, Abdulkadir
    • Steel and Composite Structures
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    • v.29 no.2
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    • pp.201-218
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    • 2018
  • In this study, the effects of magnesium sulfate on the mechanical performance and the durability of confined and unconfined geopolymer concrete (GPC) specimens were investigated. The carbon and basalt fiber reinforced polymer (FRP) fabrics with 1-layer and 3-layers were used to evaluate the performances of the specimens under static and cyclic loading in the ambient and magnesium sulfate environments. In addition, the use of FRP materials as a rehabilitation technique was also studied. For the geopolymerization process of GPC specimens, the alkaline activator has selected a mixture of sodium silicate solution ($Na_2SiO_3$) and sodium hydroxide solution (NaOH) with a ratio ($Na_2SiO_3/NaOH$) of 2.5. In addition to GPC specimens, an ordinary concrete (NC) specimens were also produced as a reference specimens and some of the GPC and NC specimens were immersed in 5% magnesium sulfate solutions. The mechanical performance and the durability of the specimens were evaluated by visual appearance, weight change, static and cyclic loading, and failure modes of the specimens under magnesium sulfate and ambient environments. In addition, the microscopic changes of the specimens due to sulfate attack were also assessed by scanning electron microscopy (SEM) to understand the macroscale behavior of the specimens. Results indicated that geopolymer specimens produced with nano-silica and fly ash showed superior performance than the NC specimens in the sulfate environment. In addition, confined specimens with FRP fabrics significantly improved the compressive strength, ductility and durability resistance of the specimens and the improvement was found higher with the increased number of FRP layers. Specimens wrapped with carbon FRP fabrics showed better mechanical performance and durability properties than the specimens wrapped with basalt FRP fabrics. Both FRP materials can be used as a rehabilitation material in the sulfate environment.