• Title/Summary/Keyword: conductive material

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An Experimental Study on the Evaluation of EMP Shielding Performance of Concrete Applied with ATMSM Using Zn-Al Alloy Wire (Zn-Al 합금 선재를 이용한 금속용사 공법 적용 콘크리트의 전자파 차폐 성능 평가에 관한 실험적 연구)

  • Choi, Hyun-Jun;Park, Jin-Ho;Min, Tae-Beom;Jang, Hyun-O;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.3
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    • pp.209-217
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    • 2019
  • EMP (Electromagnetic Pulse) usually means High Power Electromagnetic Wave (HPEM). In the case of the shielding plate against the EMP, there is a possibility of deterioration of the electromagnetic wave shielding performance due to the skill of the constructor, bad construction, deformation of the shielding plate at the connection portion (joint portion). The inefficient use of space due to the separation distance is also pointed out as a problem. Therefore, this study aims to derive the optimum electromagnetic shielding condition by applying ATMSM to concrete as a part of securing electromagnetic wave shielding performance with reflection loss against concrete wall. Experimental parameters included concrete wall thickness and application of Zn-Al ATMSM. For the concrete wall, the wall thickness was 100 to 300mm, which is generally applied, and experimental parameters were set for the application of Zn-Al metal spraying method to evaluate electromagnetic shielding performance. Experimental results showed that as the thickness increases, the electromagnetic shielding performance increases due to the increase of absorption loss. In addition, after the application of Zn-Al ATMSM, the average shielding performance increased by 56.68 dB on average, which is considered to be increased by the reflection loss of the ATMSM. In addition, it is considered that the shielding performance will be better than that when the conductive mixed material and the ATMSM are simultaneously applied.

High Transparent Planar Dipole Antenna using Ionized Salt-water of ASA Structure (이온화된 소금물을 이용한 ASA 구조의 고 투명 평면형 다이폴 안테나)

  • Phan, Duy Tung;Jung, Chang Won
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.3
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    • pp.492-498
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    • 2021
  • This feasibility study evaluated an optically transparent planar antenna using liquid salt-water as the conducting material. The most significant reason behind using liquid salt-water for transparent antenna applications is its excellent average optical transparency (OTav) (> 95% at a salinity of 40 ppt) compared to other typical solid transparent thin-film electrodes, such as indium tin oxide (ITO:> 73%) or multi-layer films (MLF: > 78%). Each conductive arm of the proposed dipole is constructed from a salt-water layer held between two clear planar acrylic layers (��r = 2.61, tan�� = 0.01, OTav > 90%) (acrylic/salt-water/acrylic; ASA) due to surface tension. To examine the electrical and optical properties of the ASA structure, the surface tension was measured to determine the thickness of the salt-water layer that finalized its sheet resistance and OTav. The average gain and efficiency of the antenna were 1.72 dBi and 74%, respectively, in the operating UHF (Ultra high frequency) band (470-771 MHz). Therefore, the proposed antenna can be a good candidate for applications as a transparent planar antenna using salt-water.

Development of CNT Coating Process using Argon Atmospheric Plasma (아르곤 상압플라즈마를 이용한 CNT 코팅 공정 기술 개발)

  • Kim, Kyoung-Bo;Lee, Jongpil;Kim, Moojin
    • Journal of Industrial Convergence
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    • v.20 no.10
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    • pp.33-38
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    • 2022
  • In this paper, a simple method of forming a solution-based carbon nanotube (CNT) for use as a conductive material for electronic devices was studied. The CNT thin film coating was performed on the glass by applying the spin coating method and the argon atmospheric pressure plasma process. In order to observe changes in electrical and physical properties according to the number of coatings, samples formed in the same manner from times 1 to 5 were prepared, and surface shape, reflectance, transmittance, absorbance, and sheet resistance were measured for each sample. As the number of coatings increased, the transmittance decreased, and the reflectance and absorptivity increased in the entire measurement wavelength range. Also, as the wavelength decreases, the transmittance decreases, and the reflectance and absorption increase. In the case of electrical properties, it was confirmed that the conductivity was significantly improved when the second coating was applied. In conclusion, in order to replace CNT with a transparent electrode, it is necessary to consider the number of coatings in consideration of reflectivity and electrical conductivity together, and it can be seen that 2 times is optimal.

Thick Positive Electrode using Polytetrafluorethylene (PTFE) Binder for High-Energy-Density Lithium-ion Batteries (높은 에너지 밀도의 리튬이온 이차전지를 위한 PTFE 바인더를 적용한 고로딩 양극)

  • Kang, Jeong Min;Kim, Hyoung Woo;Jang, Young Seok;Kim, Haebeen;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.24 no.2
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    • pp.28-33
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    • 2021
  • Many researchers have increased the loading level of electrodes to improve the energy density of secondary batteries. In this study, high-loading NCM523 (LiNi0.5Co0.2Mn0.3O2) positive electrode is manufactured using a polytetrafluoroethylene (PTFE) binder, not the conventional polyvinylidene fluoride (PVdF) binder, which has been commonly used in lithium-ion batteries. Through the kneading process using PTFE suspension, not the conventional slurry process using PVdF solution in N-methyl-2-pyrrolidinone (NMP), thick electrodes with high loading are easily manufactured. When the PTFE and PVdF-based electrodes are prepared at a loading level of 5.0 mAh/cm2, respectively, the PTFE-based electrode shows better cycle performance and rate capability than those of PVdF-based electrodes. The electrode manufactured by the kneading process using a PTFE binder has high electrode porosity due to insufficient roll-press, but the porosity can be lowered by high temperature roll-press over 120℃. However, there is no significant difference in cycle performance according to the roll press temperature. In addition, the cycle performance of the high loading electrode is slightly improved by increasing the content of the conductive material. Overall, the PTFE binder can improve the performance of the high loading electrode, but additional solutions will be needed.

Development of Solution-based Carbon Nanotube and Silver Nanowire Coating Technology using Silk Printing Technique (실크 스크린 프린팅 기법을 적용한 용액 기반의 탄소나노튜브와 은 나노 와이어 코팅 기술 개발)

  • Moojin Kim
    • Journal of Industrial Convergence
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    • v.21 no.9
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    • pp.33-39
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    • 2023
  • Nano-sized materials can be coated on various substrates, and since this material is transparent and conductive, it can be used as a transparent electrode for electronic devices or an electrode for power supply. In this study, CNT and Ag nanowires were repeatedly coated using the silk screen technique, and samples formed up to 5 times were fabricated, and their optical and electrical properties were measured and analyzed. It was confirmed that marks were formed on the surface of the silkscreen-coated sample according to the coating direction, and the trend of transmittance and surface resistance according to the number of times of coating was investigated. As the number of coatings increased, transmittance and surface resistance tended to decrease. In particular, in the case of transmittance, the range of change was large in the samples coated 2 and 5 times. These changes were confirmed by the Ag nanowire coating. In addition, starting from 700 nm, the previous wavelength region increased according to the wavelength, while the above showed a tendency to decrease. The surface resistance was lowered from 9Ω/cm2 when coating once to 0.856Ω/cm2 when coating five times. It was found that the resistance value was affected by Ag similarly to the permeability. In the future, it is necessary to realize a desired transparent electrode through Ag concentration and coating of Ag nanowires with other methods and fusion with highly transparent CNT to apply to electronic devices.

Direct growth of carbon nanotubes on LiFePO4 powders and the application as cathode materials in lithium-ion batteries (LiFePO4 분말 위 탄소나노튜브의 직접 성장과 리튬이온전지 양극재로의 적용)

  • Hyun-Ho Han;Jong-Hwan Lee;Goo-Hwan Jeong
    • Journal of the Korean institute of surface engineering
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    • v.57 no.4
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    • pp.317-324
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    • 2024
  • We demonstrate a direct growth of carbon nanotubes (CNTs) on the surface of LiFePO4 (LFP) powders for use in lithium-ion batteries (LIB). LFP has been widely used as a cathode material due to its low cost and high stability. However, there is a still enough room for development to overcome its low energy density and electrical conductivity. In this study, we fabricated novel structured composites of LFP and CNTs (LFP-CNTs) and characterized the electrochemical properties of LIB. The composites were prepared by direct growth of CNTs on the surface of LFP using a rotary chemical vapor deposition. The growth temperature and rotation speed of the chamber were optimized at 600 ℃ and 5 rpm, respectively. For the LIB cell fabrication, a half-cell was fabricated using polytetrafluoroethylene (PTFE) and carbon black as binder and conductive additives, respectively. The electrochemical properties of LIBs using commercial carbon-coated LFP (LFP/C), LFP with CNTs grown for 10 (LFP/CNTs-10m) and 30 min(LFP/CNTs-30m) are comparatively investigated. For example, after the formation cycle, we obtained 149.3, 160.1, and 175.0 mAh/g for LFP/C, LFP/CNTs-10m, and LFP/CNTs-30m, respectively. In addition, the improved rate performance and 111.9 mAh/g capacity at 2C rate were achieved from the LFP/CNTs-30m sample compared to the LFP/CNTs-10m and LFP/C samples. We believe that the approach using direct growth of CNTs on LFP particles provides straightforward solution to improve the conductivity in the LFP-based electrode by constructing conduction pathways.

The development of conductive 10B thin film for neutron monitoring (중성자 모니터링을 위한 전도성 10B 박막 개발)

  • Lim, Chang Hwy;Kim, Jongyul;Lee, Suhyun;Jung, Yongju;Choi, Young-Hyun;Baek, Cheol-Ha;Moon, Myung-Kook
    • Journal of Radiation Protection and Research
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    • v.39 no.4
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    • pp.199-205
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    • 2014
  • In the field of neutron detections, $^3He$ gas, the so-called "the gold standard," is the most widely used material for neutron detections because of its high efficiency in neutron capturing. However, from variable causes since early 2009, $^3He$ is being depleted, which has maintained an upward pressure on its cost. For this reason, the demands for $^3He$ replacements are rising sharply. Research into neutron converting materials, which has not been used well due to a neutron detection efficiency lower than the efficiency of $^3He$, although it can be chosen for use in a neutron detector, has been highlighted again. $^{10}B$, which is one of the $^3He$ replacements, such as $BF_3$, $^6Li$, $^{10}B$, $Gd_2O_2S$, is being researched by various detector development groups owing to a number of advantages such as easy gamma-ray discrimination, non-toxicity, low cost, etc. One of the possible techniques for the detection is an indirect neutron detection method measuring secondary radiation generated by interactions between neutrons and $^{10}B$. Because of the mean free path of alpha particle from interactions that are very short in a solid material, the thickness of $^{10}B$ should be thin. Therefore, to increase the neutron detection efficiency, it is important to make a $^{10}B$ thin film. In this study, we fabricated a $^{10}B$ thin film that is about 60 um in thickness for neutron detection using well-known technology for the manufacturing of a thin electrode for use in lithium ion batteries. In addition, by performing simple physical tests on the conductivity, dispersion, adhesion, and flexibility, we confirmed that the physical characteristics of the fabricated $^{10}B$ thin film are good. Using the fabricated $^{10}B$ thin film, we made a proportional counter for neutron monitoring and measured the neutron pulse height spectrum at a neutron facility at KAERI. Furthermore, we calculated using the Monte Carlo simulation the change of neutron detection efficiency according to the number of thin film layers. In conclusion, we suggest a fabrication method of a $^{10}B$ thin film using the technology used in making a thin electrode of lithium ion batteries and made the $^{10}B$ thin film for neutron detection using suggested method.

The Effect of Strong Acid and Ionic Material Addition in the Microwave-assisted Solubilization of Waste Activated Sludge (Microwave를 이용한 폐활성슬러지의 가용화 반응에서 강산과 이온성 물질의 첨가가 미치는 영향)

  • Lee, Jeongmin;Lee, Jaeho;Lim, Jisung;Kim, Youngwoo;Byun, Imgyu;Park, Taejoo
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.1
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    • pp.60-68
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    • 2015
  • The study of waste activated sludge (WAS) solubilization has been increased for sludge volume reduction and enhancing the efficiency of anaerobic digestion. Microwave (MW)-assisted solubilization is an effective method for the solubilization of WAS because this method can lead to thermal, nonthermal effect and ionic conduction by dielectric heating. In this study, the solubilization of WAS by MW heating and conductive heating (CH) was compared and to enhance the MW-assisted solubilization of WAS at low MW output power, chemical agents were applied such as $H_2SO_4$ as the strong acid and $CaCl_2$, NaCl as the ionic materials. Compared to the COD solubilization of WAS by CH, that by MW heating was approximately 1.4, 6.2 times higher at $50^{\circ}C$, $100^{\circ}C$, respectively and the highest COD solubilization of WAS was 10.0% in this study of low MW output power condition. At the same MW output power and reaction time in chemically agents assisted experiments, the COD solubilization of WAS were increased up to 18.1% and 12.7% with the addition of $H_2SO_4$ and NaCl, however, that with the addition of $CaCl_2$ was 10.7%. This result might be due to the fact that the precipitation reaction occurred by calcium ion ($Ca^{2+}$) and phosphate ion (${PO_4}^{3-}$) produced in WAS after MW-assisted solubilization. In this study, $H_2SO_4$ turned out to be the optimal agent for the enhancement of MW efficiency, the addition of 0.2 M $H_2SO_4$ was the most effective condition for MW-assisted WAS solubilization.

A review on the design requirement of temperature in high-level nuclear waste disposal system: based on bentonite buffer (고준위폐기물처분시스템 설계 제한온도 설정에 관한 기술현황 분석: 벤토나이트 완충재를 중심으로)

  • Kim, Jin-Seop;Cho, Won-Jin;Park, Seunghun;Kim, Geon-Young;Baik, Min-Hoon
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.21 no.5
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    • pp.587-609
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    • 2019
  • Short-and long-term stabilities of bentonite, favored material as buffer in geological repositories for high-level waste were reviewed in this paper in addition to alternative design concepts of buffer to mitigate the thermal load from decay heat of SF (Spent Fuel) and further increase the disposal efficiency. It is generally reported that the irreversible changes in structure, hydraulic behavior, and swelling capacity are produced due to temperature increase and vapor flow between $150{\sim}250^{\circ}C$. Provided that the maximum temperature of bentonite is less than $150^{\circ}C$, however, the effects of temperature on the material, structural, and mineralogical stability seems to be minor. The maximum temperature in disposal system will constrain and determine the amount of waste to be disposed per unit area and be regarded as an important design parameter influencing the availability of disposal site. Thus, it is necessary to identify the effects of high temperature on the performance of buffer and allow for the thermal constraint greater than $100^{\circ}C$. In addition, the development of high-performance EBS (Engineered Barrier System) such as composite bentonite buffer mixed with graphite or silica and multi-layered buffer (i.e., highly thermal-conductive layer or insulating layer) should be taken into account to enhance the disposal efficiency in parallel with the development of multilayer repository. This will contribute to increase of reliability and securing the acceptance of the people with regard to a high-level waste disposal.

The study of thermal change by chemoport in radiofrequency hyperthermia (고주파 온열치료시 케모포트의 열적 변화 연구)

  • Lee, seung hoon;Lee, sun young;Gim, yang soo;Kwak, Keun tak;Yang, myung sik;Cha, seok yong
    • The Journal of Korean Society for Radiation Therapy
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    • v.27 no.2
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    • pp.97-106
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    • 2015
  • Purpose : This study evaluate the thermal changes caused by use of the chemoport for drug administration and blood sampling during radiofrequency hyperthermia. Materials and Methods : 20cm size of the electrode radio frequency hyperthermia (EHY-2000, Oncotherm KFT, Hungary) was used. The materials of the chemoport in our hospital from currently being used therapy are plastics, metal-containing epoxy and titanium that were made of the diameter 20 cm, height 20 cm insertion of the self-made cylindrical Agar phantom to measure the temperature. Thermoscope(TM-100, Oncotherm Kft, Hungary) and Sim4Life (Ver2.0, Zurich, Switzerland) was compared to the actual measured temperature. Each of the electrode measurement position is the central axis and the central axis side 1.5 cm, 0 cm(surface), 0.5 cm, 1.8 cm, 2.8 cm in depth was respectively measured. The measured temperature is $24.5{\sim}25.5^{\circ}C$, humidity is 30% ~ 32%. In five-minute intervals to measure the output power of 100W, 60 min. Results : In the electrode central axis 2.8 cm depth, the maximum temperature of the case with the unused of the chemoport, plastic, epoxy and titanium were respectively $39.51^{\circ}C$, $39.11^{\circ}C$, $38.81^{\circ}C$, $40.64^{\circ}C$, simulated experimental data were $42.20^{\circ}C$, $41.50^{\circ}C$, $40.70^{\circ}C$, $42.50^{\circ}C$. And in the central axis electrode side 1.5 cm depth 2.8 cm, mesured data were $39.37^{\circ}C$, $39.32^{\circ}C$, $39.20^{\circ}C$, $39.46^{\circ}C$, the simulated experimental data were $42.00^{\circ}C$, $41.80^{\circ}C$, $41.20^{\circ}C$, $42.30^{\circ}C$. Conclusion : The thermal variations were caused by radiofrequency electromagnetic field surrounding the chemoport showed lower than in the case of unused in non-conductive plastic material and epoxy material, the titanum chemoport that made of conductor materials showed a slight differences. This is due to the metal contents in the chemoport and the geometry of the chemoport. And because it uses a low radio frequency bandwidth of the used equipment. That is, although use of the chemoport in this study do not significantly affect the surrounding tissue. That is, because the thermal change is insignificant, it is suggested that the hazard of the chemoport used in this study doesn't need to be considered.

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