• Bulletin of the Korean Chemical Society
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• 제26권5호
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• pp.697-706
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• 2005

We review the evolution of electrochemical studies of conducting polymers into the current state-of-the-art based primarily on our work. While conventional electrochemical experiments sufficed for the needs in the phase of studies of both electrochemical synthesis and characterization of conducting polymers, developments of various new experimental techniques have led to their introduction to this field for more refined information. As a result, the conventional electrochemical, spectroelectrochemical, electrochemical quartz crystal microbalance, impedance, and morphological as well as electrical characterization studies all made important contributions to a better understanding of the polymerization mechanisms and the conductive properties of these classes of polymers. From this review, we hereby expect that the electrochemical techniques will continue to play important roles in bringing this field to the practical applications such as nanoscale electronic devices.

• 폴리머
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• 제30권5호
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• pp.367-372
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• 2006

전도성 고분자에 곁가지로 chromophore를 결합시켜 만든 다양한 전기 변색 물질과 그 특성을 소개하였다. 전도성 고분자로는 Polypyrrole, Polythiophene, Poly(3,4-ethylenedioxythiophene), Poly(cyclopen-tadithiophene), 및 poly (1,4-bis [2- (3,4-ethylenedioxy)thienyl] benzene)를 사용하고, chromophore로는 viologen과 perylenetetracarboxylic diimide를 사용한 경우에 대하여 설명하였다. 전도성 고분자와 thromophore의 변색 파장 범위가 다른 경우에는 변색의 다양성을 성취할 수 있었으며, 변색 파장 범위가 비슷한 경우에는 색대비를 높일 수 있다. 최대 색대비를 나타내는 필름의 두께를 쉽게 예측할 수 있는 방법도 설명하였다.

• Elastomers and Composites
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• 제52권1호
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• pp.69-80
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• 2017

Conducting polymers and carbon nanomaterials offer a wide range of applications because of their unique soft conducting properties. Specifically, these conducting polymer-carbon nanocomposites have recently been utilized in bioengineering applications, partly because of their improved biocompatibility compared to conventional conducting materials such as metals and ceramics. Based on the assumption that these composites offer an important application potential as functional materials for biomedical devices or even as biomaterials, this review surveys the recent research trends on conducting polymers-carbon nanocomposites, focusing on bioengineering applications such as polyaniline (PANI), poly(3,4-ethylenedioxythiophene) or PEDOT, polypyrrole (Ppy), and carbon nanotubes and graphene.

• Journal of Magnetics
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• 제2권4호
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• pp.123-125
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• 1997

We have studied a series of I2-doped poly [2-buthoxy-5-methoxy-1, 4-phenylenevinylene] (PBMPV) conducting polymers by means of electron paramagnetic resonance (EPR) measurements. In this work, the EPR linewidth and spin density were obtained from the EPR intensity and studied as a function of the degree of doping.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2003년도 봄 학술발표회 논문집
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• pp.303-304
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• 2003

Conducting polymers show several unique features, wherein electrical and optical properties change drastically during electrochemical reaction. By making use of these phenomena, several electronic devices have been fabricated, for instance, electrochromic displays, rechargeable batteries and electroplasticity memory devices. Electromechanical actuators using conducting polymers have been proposed by Baughman et. al [1]. (omitted)

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1998년도 가을 학술발표회논문집
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• pp.219-222
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• 1998

Polyaniline (PANI) has emerged as one of the most promising conducting polymers of the many types of conducting polymers in that it is soluble and therefore processable in the conducting form, and it is both environmentally and thermally stable together with high conductivity when it is doped by functionalized protonic acids like camphorsulfonic acid (CSA) and dodecylbenzenesulfonic acid (DBSA). (omitted)

• E2M - 전기 전자와 첨단 소재
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• 제8권6호
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• pp.795-805
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• 1995

A novel thin film processing technique has been developed for the fabrication of ultrathin films of conducting polymers with molecular-level control over thickness and multilayer architecture. This new self-assembly process opens up vast possibilities in applications which require large area, ultrathin films of conducting polymers and more importantly in applications that can take advantage of the unique interactions achievable in the complex, supermolecular architectures of multilayer films.

• 한국전기전자재료학회논문지
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• 제15권2호
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• pp.153-161
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• 2002

Stable polyaniline-dodecylbenzenesulfonic acid(PANI-DBSA) fully dissolved in toluene was obtained by a direct one-step emulsion polymerization technique. By using the proper molar ratio of APS/aniline monomer and DBSA/aniline monomer, the highest conductivity(7 S/cm) of PANI was obtained. The UV-Vis absorption spectrum of PANI confirmed PANI is emeraldine salt form. PANI/styrene polymers (polystyrene and styrene-butadiene copolymer) blends were prepared by mixing PANI solution with polymers in toluene. These blends exhibited the conductivity of 10$\^$-4/-10$\^$-3/ S/cm at 1 wt. % of PANI content. The mechanical property of conducting blend was decreased and TGA thermograms of conducting blends were similar to that of PANI. It had been checked that the flatness of coating layers of conducting blends decreased with increasing conducting components. It was also found that the morphology of blends was setting closer to that of PANI at higher conducting component contents.

• Advances in materials Research
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• 제3권2호
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• pp.117-128
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• 2014

Processable conducting polyaniline derivative with free amine functional groups was successfully synthesized from the monomer o-phenylenediamine in aqueous hydrochloric acid medium using ammonium persulfate as an oxidative initiator. The synthesized poly(o-phenylenediamine) (PoPD) in critical condition was found to be completely soluble in common organic solvents like dimethyl sulfoxide, N,N-dimethyl formamide etc. From the intrinsic viscosity measurement, the optimum condition for the polymerization was established. The polymer was characterized by ultraviolet visible spectroscopy, Fourier transform infrared spectroscopy, proton magnetic resonance spectroscopy ($^1HNMR$) and thermogravimetric (TGA) analyses. The weight average molecular weights of the synthesized polymers were determined by the dynamic light scattering (DLS) method. From the spectroscopic analysis the structure was found to resemble that of polyaniline derivative with free amine functional groups attached to ortho/meta position in the phenyl ring. However, very little ladder unit was also present with in the polymer chain. The moderate thermal stability of the synthesized polymer could be found from the TGA analysis. The average DC conductivity of $2.8{\times}10^{-4}S/cm$ was observed for the synthesized polymer pellet after doping with hydrochloric acid.

• Carbon letters
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• 제12권1호
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• pp.48-52
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• 2011

The conducting polymer-coated multi-walled carbon nanotubes (MWCNTs) were prepared by template polymerization of aniline and pyrrole on the surface of MWCNTs in order to develop the novel electromagnetic interference (EMI) shielding materials. The conducting polymer phases formed on the surface of MWCNTs were confirmed by field emission-scanning electron microscopy and field emission-transmission electron microscopy. Both permittivity and permeability were significantly improved for the conducting polymer-coated MWCNTs due to the intrinsic electrical properties of MWCNTs and the conducting properties of coated polymers. The electromagnetic waves were effectively absorbed based on the permittivity nature of conducting polymer and MWCNTs preventing the secondary interference from reflecting the electromagnetic waves. The highly improved EMI shielding efficiency was also obtained for the conducting polymer-coated MWCNTs showing the synergistic effects by combining MWCNTs and the conducting polymers.