• Title/Summary/Keyword: concentration ratio

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Physicochemical Characteristics of Groundwater Salinization in the eastern aea of Cheju Island (제주도 동부지역 지하수의 염수화와 이화학적 특성)

  • Oh, Youn-Keun;Kim, Kyung-Hoo;Ryu, Seong-Pil
    • Journal of Environmental Science International
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    • v.9 no.3
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    • pp.253-259
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    • 2000
  • The purpose of this study is to investigate the physicochemical characteristics of salinization of groundwater at the estern area of Cheju island. For this purpose, the major ions of groundwater, spring water are analyzed. The concentration of $Cl^-$ and Na^++K^+$/ contained in the groundwater at near the coastline are higher than those at inland area away from the coastline. The water quality components of groundwater observed at this area can be classified into 4 types such as Na-Cl, $HCO_3, Na-Cl-HCO_3$ and Ca-HCO$_3$. The concentration ratio of $SO_4^1 to Cl^- is 0.1354(R^2=0.972)$ at this area. This value is very similar with Dittomer's ratio of 0.13. For Na^+, K^+, and Mg^{2+}/ versus Cl^-$, their ratios also show a significant relationship between sea water and groundwater in this area. From the chloride-bicarbonate ratio, it can be estimated that the intrusion distance of seawater from coastline to inland area is 2.8km at Onpyung-Nansan, Sangdo and Pyungdae areas, and 5.4km at Kosung-Susan area. The mixing ratio between seawater and fresh water by the intrusion of seawater is decreased with the distance toward inland from coastline. This ratio(fresh water : seawater) is 80:20 in spring water adjacent the coastlines, Onpyung area and 99.8:0.2 in the well at No.3 of Susan located at inland away from the coastline. The concentration of $Na^+$ observed at field is 25~45% lower than that theoretically calculated by this mixing ratio. Based on the data of EC, the equipotential line of 500$\mu$mhos/cm is located at 4~5km poing at Kosung-Susan area and 2.5km point at the other area. The equation of correlation between $Cl^-$ concentration and EC values is $Cl^-$=0.1927EC-16.683 for the area lower than 500 $\mu$mhos/cm and $Cl^-$=0.2773EC for the area beyond 500 $\mu$mhos/cm.

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Effect of Ni/Fe Ion Concentration Ratio on Fuel Cladding Crud Deposition (핵연료 피복관 부식생성물 부착에 관한 Ni/Fe 이온 농도비의 영향)

  • Baek, S.H.;Kim, U.C.;Shim, H.S.;Lim, K.S.;Hur, D.H.
    • Corrosion Science and Technology
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    • v.13 no.4
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    • pp.145-151
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    • 2014
  • The objectives of this study are to investigate the effect of the concentration ratios of Ni and Fe ions on crud deposition onto the fuel cladding surface in the simulated primary environments of a pressurized water reactor. Crud deposition tests were conducted in the Ni and Fe concentration ratios of 20:20 ppm, 39:1 ppm and 1:39 ppm at $325^{\circ}C$ for 14 days. In the case of the same Ni and Fe ion ratio (20:20), nickel ferrite with a polyhedral shape was formed. Nickel oxide deposits with a needle shape were formed in the condition of high Ni to Fe ion ratio (39:1), While polyhedral iron oxide and needle-like nickel oxide formed in the condition of low Ni to Fe ion ratio (1:39). The amount of deposits increased, when Fe oxides were formed. This indicates that Fe rich oxides stimulated Ni oxide deposition.

Comparison of Dissolved Air and Micro-Bubble Concentration by a Micro-Bubble Generating Pump (미세기포 발생 펌프에서 생성되는 기포농도와 용존공기농도의 비교)

  • Lee, Chang-Han;Ahn, Kab-Hwan
    • Journal of Environmental Science International
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    • v.23 no.11
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    • pp.1835-1842
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    • 2014
  • The goal of this study was to evaluate micro-bubble concentration ($C_{air}$) in water by air/water ratio (A/W ratio) with a micro-bubble generating pump. The estimation of micro-bubble concentration is based on the balance of inlet/outlet air and water flow rate. On net A/W ratio to be generated micro-bubble, we found that the obtained the $C_{air}$ are shown as a function of discharge pressure ($P_g$) of the micro-bubble generating pump. The correlation of the $C_{air}$ and the $P_g$ ($C_{air}=3.261P_g-1.754$) was adequately described by the least square methods with a high correlation coefficient (r = 0.9459) and calculated values fit the experimental data quite well. The $C_{air}$ was lower than theoretical dissolved air concentration ($C_{aq}$) calculated by Henry's law. The $C_{air}$ for being operated the micro-bubble generating pump was 6.75 - 39.53 mL/L, however, we found that the optimum of the $C_{air}$ to generate micro-bubble was the range from 10 to 12 mL/L.

Prediction and Comparison for the N-Nitrosodimethylamine(NDMA) Formation (N-Nitrosodimethylamine(NDMA) 생성에 관한 예측과 비교 연구)

  • Kim, Jong-O;Kim, Dong-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.4
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    • pp.402-406
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    • 2006
  • N-Nitrosodimethylamine(NDMA) formation was studied as a function of chloramine concentration at a fixed dimethylamine (DMA) concentration of 0.05 mM at pH 7 and 8. Regression equations were developed by molar ratio of chloramine to DMA. The NDMA formation was dependent on molar ratio(chloramine/DMA) and was different when the ratio is less or greater than 1. The formation of NDMA increased with increasing chloramine concentration and a linear correlation was examined between NDMA concentration and the ratio on a log scale. The developed regression was applied to previously reported data and relative errors ranged from -79 to 163%. Regression equations could provide a potential tool to predict NDMA formation for a simple and quick estimation in water supply systems.

The Decomposition of Leaf Litters of Some Tree Species in Temperate Deciduous Forest in Korea II. Changes in Nutrient Content During Litter Decomposition

  • Yang, Keum-Chul;Shim, Jae-Kuk
    • The Korean Journal of Ecology
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    • v.26 no.6
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    • pp.313-319
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    • 2003
  • Dry weight loss and nutrient release from leaf litter for six tree species were studied using litter bag methods. The litter bags were incubated for f6 months on the forest floor in temperate deciduous forest in Mt. Cheonma, located at the middle part of Korean Peninsula. The changes in nutrient content and the rate of dry weight loss in leaf litter varied with litter types. The litter of Pinus densiflora showed the lowest rate of mass loss (k=0.33), nitrogen concentration (0.89%) and ash concentration (2.50%), while showed the highest C/N ratio (63.40). On the other hand, the litter of Acer pseudo-sieboldianum showed the fastest rate of mass loss (k=0.82), the highest nitrogen concentration (1.11%), and the lowest C/N ratio (49.40). During the decomposition, nitrogen, phosphorus and calcium in the leaf litters showed relatively slow decreasing pattern compared to other elements (carbon, potassium, magnesium, manganese and sodium), but potassium and sodium decreased at early stage of the decomposition for all leaf litters. Differences in annual decomposition rates of litter among species were consistent with the particular chemical characteristics of their leaf litters. The initial concentration of nitrogen was positively correlated with litter decomposition rate for six species, while litter decomposition rate of six species was negatively correlated with C:N ratio of initial leaf litters.

The Characteristics of Various Stress in Cohesionless Soil with the Rammed Aggregate Pier (짧은 쇄석다짐말뚝(RAP)이 설치된 사질토지반의 응력변화 특성)

  • Chun, Byung-Sik;Kim, Kyung-Min;Kim, Jun-Ho
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.03a
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    • pp.1108-1117
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    • 2005
  • RAP(rammed aggregate pier) method which is intermediate foundation of deep and shallow foundation is used to improve the ground with high compaction energy. This method is widely spread around the world, but there are few examples and systemic researches for failure mechanism and bearing capacity of this method are not organized yet. In this paper, soil laboratory tests were carried out to evaluate the applicability of RAP method as the foundation of a structure. And the bearing capacity and the failure mechanism of RAP method were studied with respect to various relative densities(35%, 65%, 90%), diameters(45mm, 60mm) and lengths(20cm, 30cm, 40cm). As results, stress concentration ratio decreased as diameter of RAP was increasing or length of RAP was decreased or relative density was decreased. however these results were not always constant. because systematic interaction between relative density and diameter and length of RAP can affect stress concentration ratio, more studies on stress concentration ratio are needed throughout laboratory and field tests.

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Dye removal from water using emulsion liquid membrane: Effect of alkane solvents on efficiency

  • Ghaemi, Negin;Darabi, Farzaneh;Falsafi, Monireh
    • Membrane and Water Treatment
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    • v.10 no.5
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    • pp.361-372
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    • 2019
  • Effect of different alkane based solvents on the stability of emulsion liquid membrane was investigated using normal alkanes (n-hexane, n-heptane, n-octane and n-decane) under various operating parameters of surfactant concentration, emulsification time, internal phase concentration, volume ratio of internal phase to organic phase, volume ratio of emulsion phase to external phase and stirring speed. Results of stability revealed that emulsion liquid membrane containing n-octane as solvent and span-80 (5 % (w/w)) as emulsifying agent presented the highest amount of emulsion stability (the lowest breakage) compared with other solvents; however, operating parameters (surfactant concentration (5% (w/w)), emulsification time (6 min), internal phase concentration (0.05 M), volume ratio of internal phase to organic phase (1/1), volume ratio of emulsion phase to external phase (1/5) and stirring speed (300 rpm)) were also influential on improving the stability (about 0.2% breakage) and on achieving the most stable emulsion. The membrane with the highest stability was employed to extract acridine orange with various concentrations (10, 20 and 40 ppm) from water. The emulsion liquid membrane prepared with n-octane as the best solvent almost removed 99.5% of acridine orange from water. Also, the prepared liquid membrane eliminated completely (100%) other cationic dyes (methylene blue, methyl violet and crystal violet) from water demonstrating the efficacy of prepared emulsion liquid membrane in treatment of dye polluted waters.

The Effect of Combination Ratio of Dye Concentration on Black Dyeing Property of PET Fabric (분산염료의 농도조합이 PET 섬유의 Black 염색성에 미치는 영향)

  • Lee, Jeong-Jin;Kim, Hye-Rim;Jang, Hye-Gyeong
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.10a
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    • pp.13-14
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    • 2008
  • In black dyeing of PET fabric, high concentrations of disperse dyes of three primary color are generally used, which leads low exhaustion level of dye and discharge of a large amount of unfixed dye into dyehouse effluent. In this study, the effect of combination ratio of dye concentration, liquor ratio, and dyeing pH on dyeing and color property of black dyed PET fabric was investigated.

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Effect of Catholyte to Anolyte Amount Ratio on the Electrodialysis Cell Performance for HI Concentration (Anolyte와 Catholyte의 비율에 따른 HI 농축 전기투석 셀의 성능변화)

  • Kim, Chang-Hee;Cho, Won-Chul;Kang, Kyoung-Soo;Park, Chu-Sik;Bae, Ki-Kwang
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.6
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    • pp.507-512
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    • 2010
  • The effect of catholyte to anolyte amount ratio on the electrodialysis cell performance for HI concentration was investigated. For this purpose, the electrodialysis cell was assembled with Nafion 117 as PEM membrane and activated carbon fiber cloth as electrodes. The initial amount of catholyte was 310 g and that of anolyte varied from 1 to 3 of amount ratio. The calculated electro motive force (EMF) increased with time and the increment enhanced as the amount ratio of catholyte to anolyte decreased. The mole ratios of HI to $H_2O$ (HI molarity) in catholyte were almost the same and exceeded pseudo-azeotropic composition for all amount ratios after 2 h operation. The HI molarity continuously increased with time for 10 h operation. The mole ratio of $I_2$ to HI decreased in catholyte but increased in anolyte. The increment of mole ratio of $I_2$ to HI in anolyte rose as the amount ratio of catholyte to anolyte decreased. In case of 1:1 amount ratio, the cell operation was stopped for the safety at approximately 6 h operation, since the mole ratio of $I_2$ to HI reached solubility limit. The cell voltage of the electrodialysis cell increased with time and the rate of increase was high at low amount ratio. This suggests that the amount ratio of catholyte to anolyte not only crucially influences the cell voltage, but also cell operation condition.

A study on the parameters for biodegradable characteristics of sewage discharged intermittently (부정기적 발생 오수의 유기물 생분해도 특성 parameter 산정에 관한 연구)

  • Han, Gee-Bong;Lee, Young-Sin
    • Journal of the Korea Organic Resources Recycling Association
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    • v.22 no.3
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    • pp.41-52
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    • 2014
  • In this study, to estimate the biodegradability of sewage discharged intermittently, field scale sampling and analysis was conducted and the results were obtained as follows. According to results of the biodegradability of sewage discharged intermittently, average concentration of TCODcr is 325.5mg/L and ratio of TCOD fraction resulted 100%. Also, average concentration of SCODcr resulted 135.9mg/L and ratio of TCOD fraction resulted 41.8%. Average concentration of Ss showed 74.1mg/L and ratio of TCOD fraction resulted 22.8%. Average concentration of $S_I$ was analyzed to be 61.8mg/L and ratio of TCOD fraction was calculated to 19.0%. Xs which is particulate matter was analyzed to show 27.8mg/L and ratio of TCOD fraction also showed 8.5%. Average concentration of $X_H$ is 103.4mg/L and ratio of TCOD fraction resulted 31.8%. Inert particulate matter showed that average concentration of $X_I$ is 58.5mg/L and ratio of TCOD fraction resulted 18.0%. Accordingly, dissolved biodegradable organic matter showed the ratio of 41.8%, and readily biodegradable matter among this showed 22.8%. Thus intermittent inflow is expected to have less effect with regards equalization by organic loading rate of influent.