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Halogen Etching of Si(100)-2x1 : Dependence on Vacancy Creation and Surface Concentration

  • Nakayama, Koji
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.146-146
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    • 2000
  • We have studied the etching of Si(100)-2xl by Cl and Br, using scanning tunneling microscopy to obtain morphological information that can be related to reaction and desorption pathways. Clean surfaces were exposed to molecular halogens at room temperature to produce well-defined chemisorption structures for coverages in the range 0.2-1.0 ML. Heating to 750-750 K induced etching by thermal desorpton. Analysis of the halogen concentration before and after heating indicated that the rates of desorption for SICl2 or SiBr2 were greatest for intermediate coverages and that etching was suppressed as saturation was reached. Hence, desorption is not simply proportional to the concentration of species that can form adsorbed precursors SiX2(a). Instead, it is directly coupled to the creation of monomer vacancies adjacent to the SiX2 (a) unit because this increases the lifetime of the excited state and increases the likelihood of its desorption. Increasing the surface concentration of halogens reduces the rate of vacancy formation. We show that these rates are also affected by a re-dimerization process in the high temperature Br-stabilized Si(100)-3xl reconstruction that increases the likelihood of siBr2(a) formation and enhances its desorption. I will also discuss recent result for F etching on Si(100)-2xl.

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Effect of an Urban Thermal Environment on the Air Quality in Two Cities

  • Lee, Kwi-Ok;Lee, Hwa-Woon;Lee, Hyun-Ju;Park, Jong-Kil;Jung, Woo-Sik
    • Asian Journal of Atmospheric Environment
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    • v.5 no.1
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    • pp.29-40
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    • 2011
  • In this study, the effects of an urban thermal environment on air quality were investigated using hourly surface weather observation data and air quality data over six summers from 2000 to 2005 in two cities on the Korean Peninsula. One, the city of Daegu, is representative of basin topography and the other, the city of Busan, represents a coastal area. It is known that the characteristics of an urban thermal environment are represented as an "urban heat island". Here, we focus on the nighttime urban thermal environment, which is called a "tropical night", during the summer. On tropical nights in Busan, the temperature and cloud cover levels were higher than on non-tropical nights. Wind speed did not appear to make a difference even on a tropical night. However, the frequency of southwestern winds from the sea was higher during tropical nights. The prevailing southwest winds in all areas meant an inflow of air from the sea. So at most of the air quality stations, the ozone concentration during tropical nights was lower than during non-tropical nights. In Daegu, the tropical nights had higher temperatures and cloud covers. Despite these higher temperatures, the ozone concentration during the tropical nights was lower than that on non-tropical nights at most of the air quality stations. This feature was caused by low irradiance, which in turn caused an increased cloud cover. Wind speed was stronger during the tropical nights and dispersed the air pollutants. These meteorological characteristics of the tropical nights reduced ozone concentrations in the Daegu Basin.

Application of response surface methodology in pes/speek blend NF membrane for dyeing solution treatment

  • Lau, W.J.;Ismail, A.F.
    • Membrane and Water Treatment
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    • v.1 no.1
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    • pp.49-60
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    • 2010
  • In this study, response surface methodology (RSM) was performed in NF membrane process to evaluate the separation efficiency of membrane in the removal of salt and reactive dye by varying different variables such as pressure, temperature, pH, dye concentration and salt concentration. The significant level of both the main effects and the interaction were observed by analysis of variance (ANOVA) approach. Based on the statistical analysis, the results have provided valuable information on the relationship between these variables and the performances of membrane. The rejection of salt was found to be greatly influenced by pressure, pH and salt concentration whereas the dye rejection was relatively constant in between 96.22 and 99.43% regardless of the changes in the variables. The water flux on the other hand was found to be affected by the pressure and salt concentration. It is also found that the model predictions were in good agreement with the experimental data, indicating the validity of these models in predicting membrane performances prior to the real filtration process.

Identification and Concentration of Airborne Microbes in Food Manufacturing Plants (식품제조공장 내 공중부유미생물 오염도와 오염진균동정)

  • Gwak, Hyun-Jung;Lee, Hun-June;Lee, Sang-Ho;Na, Hye-Jin
    • Journal of Food Hygiene and Safety
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    • v.26 no.4
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    • pp.361-365
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    • 2011
  • To evaluate the indoor air quality of food manufacturing plants, the presence of viable bacteria and fungi was assessed in the indoor air of the facilities at which 9 food items were manufactured. Air samples were collected from the general zone, low clean zone and clean zone of each factory with an air sampler, in combination with plate counts agar using for bacteria, and dichloran-glycerol agar for fungi. The samples were incubated at $25^{\circ}C$ for 4 to 7 days. After culture, the colony forming units (CFU) on each plate were counted and corrected with a positive hole conversion table. The average concentration of bacteria was $2.2{\times}10^3\;CFU/m^3$ in the general zone, $1.2{\times}10^3\;CFU/m^3$ in the low clean zone and $7.3{\times}10^2\;CFU/m^3$ in the clean zone. The average concentration of fungal microbes was $2.5{\times}10^3\;CFU/m^3$ in the general zone, $2.6{\times}10^3\;CFU/m^3$ in the low clean zone, and $2.0{\times}10^2\;CFU/m^3$ in the clean zone. No meaningful differences were detected between the general zone and the low clean zone, but the clean zone had significantly lower concentrations than the other zones. Additionally, the identification of the fungi was performed according to morphological method using a giant culture and slide culture. The fungi were identified as belonging to 18 genera, and the genera Cladosporium(33%), Penicillium(29%) and Aspergillus(26%), predominated. Aspergillus isolates were identified to species level, and A. ochraceus, a mycotoxigenic species, was identified. As part of the effort to control the quality of the indoor air of food manufacturing plants, our results show that continued studies are clearly warranted.

Air Quality Modeling of Ozone Concentration According to the Roughness Length on the Complex Terrain (복잡지형에서의 지표면 거칠기에 따른 오존 농도 수치모의)

  • Choi, Hyun-Jung;Lee, Hwa-Woon;Sung, Kyoung-Hee
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.4
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    • pp.430-439
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    • 2007
  • The objective of this work is the air quality modeling according to the practical roughness length using the building information as surface boundary conditions. As accurate wind and temperature field are required to produce realistic urban air quality modeling, comparative simulations by various roughness length are discussed. The prognostic meteorological fields and air quality field over complex areas of Seoul, Korea are generated by the PSU/NCAR mesoscale model (MM5) and the Third Generation Community Multi-scale Air Quality Modeling System (Models-3/CMAQ), respectively. The simulated $O_3$ concentration on complex terrain and their interactions with the weak synoptic flow had relatively strong effects by the roughness length. A comparison of the three meteorological fields of respective roughness length reveals substantial localized differences in surface temperature and wind folds. Under these conditions, the ascended mixing height and weakened wind speed at night which induced the stable boundary stronger, and the difference of simulated $O_3$ concentration is $2{\sim}6\;ppb$.

A study on the optical properties of PLT thin films with varying the La concentration by using the transmission spectrum (투과곡선을 이용한 La 농도에 따른 PLT 박막의 광학적 특성에 관한 연구)

  • 강성준;윤석민;윤영섭
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.34D no.5
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    • pp.22-31
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    • 1997
  • We have measured the optical properties, thickness, and energy band gap of the P $b_{1-x}$/100/L $a_{x}$100/ $Ti_{1-}$0.25x/100/ $O_{3}$ (PLT(x)) thin film prepared by the sol-gel method with varying the La concentration, x, fyom 15 nto 33 mol%. We have obtained the values from the tranmission spectrum and employed the envelope method in anayzing the spectrum. We have also performed the simulation of the transmission spectrum on the PC (personal computer) to verify the accuracy of the values 15 to 33mol%, the refractive index (at .lambda.=632.8nm) increases from 2.39 to 2.44. The extinction coefficient does not depend on the la concentration but mainly on te wavelength, and has the values between 0.2 and 0.5 at the wavelength shorter than 330nm and between 0.001 and 0.008 at the wavelength longer than 700nm. The energy band gap of the PLT (x) thin film has been obtained on the assumption of the direct band-to-band transition. It decreases from 3.28 to 3.17eV as the La concentration increases from 15 to 33 mol%. The thickness of the PLT(x) thin film has been also obtained in high accuracy by the envelope method..

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Indoor Air-Conditioning System in building Using Lower Power Wireless Sensor Network (저전력 무선센서 네트워크를 이용한 빌딩 내 환경공조 시스템)

  • Lee, Seung-Chul;Chung, Wan-Young
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2007.06a
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    • pp.397-400
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    • 2007
  • Indoor air-conditioning system(IAS) using wireless sensor network serves to reduce the amount of pollution entering the room from outside and also the pollution that is generated indoor. Small-size and lower power wireless sensor node and sensor interface board was designed for indoor air-conditioning system in buildings of offices and industrial establishments. Many sensor nodes forms Ad-hoc network topology using simple forwarding routing to transmit polluting gas concentration data from different rooms to the indoor air-conditioning system. Sensor node analyzes pollution concentration in the each room and air-conditioning system performs to air-distribution and air-inhalation according to room's pollution by regulating the fan of indoor air-conditioning system. To reduce power consumption electrochemical gas sensor was used in the design. Thus the designed system can optimize state of indoor environment. Graphic user interface displays node sate, gas concentration and temperature of each room.

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Analysis of CO2 Distribution Properties Using GOSAT : a Case Study of North-East Asia (GOSAT을 활용한 이산화탄소 분포 특성 분석 : 동북아시아를 사례로)

  • Choi, Jin Ho;Um, Jung Sup
    • Journal of Korean Society for Geospatial Information Science
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    • v.21 no.2
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    • pp.85-92
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    • 2013
  • This study determined the spatial distribution characteristics of carbon dioxide in Northeast Asia, connecting land coverage and vegetation index that have influence on concentration and distribution of carbon dioxide measured by GOSAT with GIS spatial analysis method. The results visibly showed that the spatial distribution of carbon dioxide had different patterns in dependent on the present status of land use in its surrounding area. Such high concentration of carbon dioxide was formed in developed sites like cities while forest areas showed low concentration of it. We also found that there were relatively high negative(-) correlations between carbon dioxide and vegetation, in statistically significant level. It is expected to be used as a basic data for establishing measures to reduce greenhouse gas in the future.

A Study on the Influential Factors of Intention to Continued Use of e-Learning (이러닝의 특성과 유용성이 지속적 이용의도에 미치는 영향에 관한 연구)

  • Kwon, Sun-Dong;Yun, Suk-Ja
    • Journal of Information Technology Applications and Management
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    • v.17 no.1
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    • pp.35-54
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    • 2010
  • Why does e-Learning service for individuals remain in the early development stage? To find the answers of this question, we adopted usefulness and intention to continued use as dependent variables based on technology acceptance model and inferred convenience, cost-effectiveness, social presence, interactivity, concentration, and procrastination as independent variables based on literature review and interview with e-Learning users. Convenience and cost-effectiveness of e-Learning tend to enhance usefulness and/or intention to continued use, while lack of social presence, interactivity, and concentration of e-Learning and academic procrastination tend to hinder usefulness and/or intention to continued use. To prove this research model, we used a data set collected from the survey. The respondents of survey were the undergraduate students who used voluntarily e-Learning. Data analysis was conducted using 275 respondents by partial least square. The analysis result of causal relation indicated that convenience and cost-effectiveness influenced both usefulness and intention to continued use, and that cost-effectiveness and concentration influenced only intention to continued use. But, interactivity and procrastination did not influence usefulness and intention to continued use.

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Vitamin C Intake and Serum Leverls in Smoking College Students (흡연대학생의 비타민 C 섭취량과 혈청수준)

  • 박정아
    • Journal of Nutrition and Health
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    • v.29 no.1
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    • pp.122-133
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    • 1996
  • As ciarette smoking adversely affects vitamin C metabolism in humans, smokers need substantially more vitamin C intake than do non-smokers to achieve similar serum vitamin C concentration. To provide the basic information currently available for the determination of vitamin C requirement for Korean smokers, we investigated the differences the serum vitamin C values between smokers(n=53) and non-smokers(n=62) in relation to their intake of the vitamin through diet in 115 male college students, who had not been using vitamin C supplements. Dietary intakes of vitamin C were determined by a 24-hour recall, and serum vitamin C was determined using the 2, 4-dinitrophenylhydrazine method. The mean vitamin C intakes of smokers and non-smokers were consuming less than 75% of the Koeran RDA for vitamin c in their diet. Smokers consumed yellow and green leafy vegetables more often (P=0.02) and fresh fruits less often(P=0.006) than non-smokers. The mean serum vitamin C concentration of smokers consuming the same amounts of vitamine C as non-smokers, 64.3 umol/1, were 20% lower than for non-smokers, 80.1 umol/l(P<0.05). The risk of low serum vitamin C concentration (LoC) among smokers were 3.8% compared with 1.6% in non-smokers, and the odd ratio for LoC risk was 2.43. There were no correlations between dietary and serum vitamin C for smokers and non-smokers. It was concluded that smokers might require at least 20% more vitamin C to reach the same concentration comparable to non-smokers.

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