• 제목/요약/키워드: concentration dependence

검색결과 546건 처리시간 0.028초

품종별 감자 전분 호화액의 리올로지 특성 (Rheological Properties of Various Gelatinized Potato Starch Pastes)

  • 정란희;김경애
    • 한국식품조리과학회지
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    • 제7권3호
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    • pp.1-6
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    • 1991
  • 분질 감자인 남작, 중간질 감자인 세풍과 수미 및 점질 감자인 대지마로부터 전분을 분리하여 품종별로 가열 호화액에 대한 리올로지 특성을 비교하였다. 3~7%의 감자 전분 호화액은 항복응력이 존재하는 의가소성을 나타내었고 전분 농도가 증가함에 따라 점조도 지수값이 증가하였다. 점조도 지수의 대수값과 농도의 관계는 전분 농도 5%에서 기울기가 서로 다른 직선 관계를 나타내었고, 점조도 지수의 농도 의존성과 항복응력의 농도 의존성은 세풍 전분이 가장 높았다. 가열 호화액은 온도가 증가할수록 점조도 지수값이 감소하였고 남작전분은 $50^{\circ}C$에서, 세풍, 수미 및 대지마 전분은 $60^{\circ}C$에서 기울기가 서로 다른 직선 관계를 나타내었으며, 활성화 에너지는 세풍 전분이 3.97 ㎉l/㏖로 다른 전분보다 높게 나타나 온도 의존성이 가장 컸다.

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팔라듐 코팅된 편광 유지 광섬유를 이용한 편광 상이 배치 구조 기반 광섬유 수소 센서의 개발 (Development of Optical Fiber Hydrogen Sensor Based on Polarization-Diversity Loop Configuration Using Pd-Coated Polarization-Maintaining Fiber)

  • 노태규;김영호;이용욱
    • 조명전기설비학회논문지
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    • 제27권3호
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    • pp.1-6
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    • 2013
  • In this study, we propose a fiber-optic hydrogen sensor using a polarization-diversity loop configuration composed of a polarization beam splitter, two quarter-wave plates, and a polarization-maintaining fiber coated with palladium whose thickness is ~400nm. One transmission dip of the output interference spectrum of the proposed sensor, chosen as a sensor indicator, was observed to spectrally shift with the increase of the hydrogen concentration, and the sensing indicator showed a wavelength shift of ~2.48nm at a hydrogen concentration of 4%. Except for a hydrogen concentration of 4%, the response time of the proposed sensor was measured as less than 12.5s and did not show significant dependence on the hydrogen concentration. In particular, the proposed fiber hydrogen sensor is more durable and highly resistant to external stress applied on a transverse axis of an optical fiber, compared with other hydrogen sensors based on side-polished fibers or fiber gratings.

Halogen Etching of Si(100)-2x1 : Dependence on Vacancy Creation and Surface Concentration

  • Nakayama, Koji
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2000년도 제18회 학술발표회 논문개요집
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    • pp.146-146
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    • 2000
  • We have studied the etching of Si(100)-2xl by Cl and Br, using scanning tunneling microscopy to obtain morphological information that can be related to reaction and desorption pathways. Clean surfaces were exposed to molecular halogens at room temperature to produce well-defined chemisorption structures for coverages in the range 0.2-1.0 ML. Heating to 750-750 K induced etching by thermal desorpton. Analysis of the halogen concentration before and after heating indicated that the rates of desorption for SICl2 or SiBr2 were greatest for intermediate coverages and that etching was suppressed as saturation was reached. Hence, desorption is not simply proportional to the concentration of species that can form adsorbed precursors SiX2(a). Instead, it is directly coupled to the creation of monomer vacancies adjacent to the SiX2 (a) unit because this increases the lifetime of the excited state and increases the likelihood of its desorption. Increasing the surface concentration of halogens reduces the rate of vacancy formation. We show that these rates are also affected by a re-dimerization process in the high temperature Br-stabilized Si(100)-3xl reconstruction that increases the likelihood of siBr2(a) formation and enhances its desorption. I will also discuss recent result for F etching on Si(100)-2xl.

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Aggregation Prodesses of Hydrophobically Modified Polythylene Oxide

  • 백기욱;김범성;김응렬;손대원
    • Bulletin of the Korean Chemical Society
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    • 제21권6호
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    • pp.623-627
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    • 2000
  • Aggregation of hydrophobically end-capped poly(ethylene oxide)s: HEURs, denoted as $C_8$$EO_{380}$$C_8$, $C_12$$CO_{600}$$C_{12}$, and $C_{18}$$EO_{860}$$C_{18}$,are described using static fluorescence, dynamic light scattering, and atomic force microscope (AFM) techniques. The CAC (critical aggregation concentration) was determined by com-paring two fluorescent peaks which were influenced by the polarity of the probe dye molecules, pyrene. The aggregation occurs in concentrations higher than 10 g/L of $C_8$$EO_{380}$$C_8$ and the CAC decreases by increasing the side chain length. The dynamic light scattering experiment shows fast mode and slow mode decays, and both are diffusive. The fast mode does not depend on the concentration, but the slow mode shows concentration dependence influenced by the formation of an aggregated structure. The hydrophobic end groups effect more dominantly than the main chains for the formation of HEUR micelles. By increasing the concentration, the HEUR micelles change their structure from spheres to rodlike micelles, and finally make fused structures, which were visualized with atomic force microscopy.

PARAMETRIC INVESTIGATIONS ON THE DOUBLE DIFFUSIVE CONVECTION IN TRIANGULAR CAVITY

  • Kwon, SunJoo;Oh, SeYoung;Yun, Jae Heon;Chung, Sei-Young
    • 충청수학회지
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    • 제20권4호
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    • pp.419-432
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    • 2007
  • Double-diffusive convection inside a triangular porous cavity is studied numerically. Galerkin finite element method is adopted to derive the discrete form of the governing differential equations. The first-order backward Euler scheme is used for temporal discretization with the second-order Adams-Bashforth scheme for the convection terms in the energy and species conservation equations. The Boussinesq-Oberbeck approximation is used to calculate the density dependence on the temperature and concentration fields. A parametric study is performed with the Lewis number, the Rayleigh number, the buoyancy ratio, and the shape of the triangle. The effect of gravity orientation is considered also. Results obtained include the flow, temperature, and concentration fields. The differences induced by varying physical parameters are analyzed and discussed. It is found that the heat transfer rate is sensitive to the shape of the triangles. For the given geometries, buoyancy ratio and Rayleigh numbers are the dominating parameters controlling the heat transfer.

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$NaBH_4$ 수용액 분해 수소 발생용 최적 촉매 개발 (Development of an Catalyst for Hydrolysis of Aqueous Sodium Borohydride Solution)

  • 양태현;;이원용;김창수
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2005년도 춘계학술대회
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    • pp.296-298
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    • 2005
  • Hydrogen generation by the hydrolysis of aqueous sodium borohydride $(NaBH_4)$ solutions was studied using IRA-400 anion resin dispersed Pt. Ru catalysts and Lithium Cobalt oxide $(LiCoO_2)$ supported Pt, Ru and PtRu catalysts. The performance of the $LiCoO_2$ supported catalysts is better than the ion exchange resin dispersed catalysts. There is a marked concentration dependence on the performance of the $LiCoO_2$ supported catalysts and the hydrogen generation rate goes down if the borohydride concentration is increased beyond $10\%$. The efficiency of PtRu- $LiCoO_2$ is almost double that of either Ru-$LiCoO_2$ or Pt-$LiCoO_2$ for $NaBH_4$ concentrations up to $10\%$.

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Dissolution of Protons in Oxides

  • Norby, Truls
    • The Korean Journal of Ceramics
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    • 제4권2호
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    • pp.128-135
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    • 1998
  • The paper gives a brief introduction to protonic defects and their chemistry, thermodynamics and transport in oxides. The temperature dependence of the equilibrium concentration of protons is illustrated and compared for different acceptor-doped oxides. The difficulties of saturating as well as emptying the oxides of protons are discussed. In order to illustrate the possibility of lattice relaxation of defects, a conceptual study is made of a case where the enthalpy of dissolution of protons(water) at the cost of oxygen vacancies is assumed dependent on the concentration of vacancies. It is shown how this changes the behavior of hydration curves vs temperature and water vapour pressure. finally, a discussion is given on the water uptake in heavily oxygen deficient oxides; how water uptake may affect order-disorder in the oxygen sublattice and eventually lead to defective, disordered or ordered oxyhydroxides or hydroxides of potential interest as intermediate temperature proton conductions.

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레이저 유도 열화학 습식에칭을 이용한 티타늄 미세구조물 제조 (Laser-induced Thermochemical Wet Etching of Titanium for Fabrication of Microstructures)

  • 신용산;손승우;정성호
    • 한국정밀공학회지
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    • 제21권4호
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    • pp.32-38
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    • 2004
  • Laser-induced thermochemical wet etching of titanium in phosphoric acid has been investigated to examine the feasibility of this method fur fabrication of microstructures. Cutting, drilling, and milling of titanium foil were carried out while examining the influence of process parameters on etch width, etch depth, and edge straightness. Laser power, scanning speed of workpiece, and etchant concentration were chosen as major process parameters influencing on temperature distribution and reaction rate. Etch width increased almost linearly with laser power showing little dependence on scanning speed while etch depth showed wide variation with both laser power and scanning speed. A well-defined etch profile with good surface quality was obtained at high concentration condition. Fabrication of a hole, micro cantilever beam, and rectangular slot with dimension of tess than 100${\mu}{\textrm}{m}$ has been demonstrated.

Stress distribution on the real corrosion surface of the orthotropic steel bridge deck

  • Kainuma, Shigenobu;Jeong, Young-Soo;Ahn, Jin-Hee
    • Steel and Composite Structures
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    • 제18권6호
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    • pp.1479-1492
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    • 2015
  • This study evaluated the localized stress condition of the real corroded deck surface of an orthotropic steel bridge because severe corrosion damage on the deck surface and fatigue cracking were reported. Thus, a three-dimensional finite element (FE) analysis model was created based on measurements of the corroded orthotropic steel deck surface to examine the stress level dependence on the corrosion condition. Based on the FE analysis results, it could be confirmed that a high stress concentration and irregular stress distribution can develop on the deck surface. The stress level was also increased by approximately 1.3-1.5 times as a result of the irregular corroded surface. It was concluded that this stress concentration could increase the possibility of fatigue cracking in the deck surface because of the surface roughness of the orthotropic steel bridge deck.

γ -valley에서 산란의 종류에 따른 전자의 홀 인수 (Hall Factor of Electrons in γ -valley due to Various Scatterings)

  • 서헌교;박일수;전상국
    • 한국전기전자재료학회논문지
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    • 제15권8호
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    • pp.658-663
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    • 2002
  • Hall factor of electrons in $\Gamma$-valley is calculated as functions of temperature, impurity concentration, and nonparabolicity of conduction valleys by taking into account the current density obtained from the Boltzmann transport equation. The dependence of the Hall factor on the temperature is clearly shown in the case of the optical phonon scattering and that on the impurity concentration is obvious in the case of the ionized impurity scattering. As the nonparabolicity of the conduction band increases, the Hall factor due to the acoustic or optic phonon scattering increases, whereas that due to the ionized impurity scattering decreases. The change of the Hall factor can be analysed in terms of the dispersion of relaxation time.