• Title/Summary/Keyword: compound metal

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A Study on Properties of semiconducting paste on metal insert molded in Epoxy compound (에폭시 절연물 매입금구 반도전 접착제 코팅에 따른 특성 연구)

  • Kim, Su-Youn;Ha, Young-Gil;Lee, Sang-Jin;Kim, Young-Seong;Park, Wan-Ki;Kim, Seong-Jin
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1645-1647
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    • 1999
  • Epoxy compound has been used as insulation material in electrical equipment because of its properties 1) Nowadays, becoming higher voltage system, the properties of interface between epoxy and its metal insert become more important. In this paper, we suggest two types semiconducting paste. One is epoxy type and the other is olephine type. After sprayed the semiconducting paste on metal insert sanded, we procedure the test one is the adhesion strength test, the other is electrical breakdown strength test. So we knew that the epoxy type paste became more higher adhesion strength than olephine type paste because of its homogeneity at the interfaces. And at the breakdown strength test, olephine type paste became less higher than epoxy type paste because of its volatility. So in this study, we suggest the optimum interface condition by adjusting the semiconducting paste and surface roughness.

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Ex-situ Reductive Dechlorination of Carbon Tetrachloride by Iron Sulfide in Batch Reactor

  • Choi, Kyung-Hoon;Lee, Woo-Jin
    • Environmental Engineering Research
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    • v.13 no.4
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    • pp.177-183
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    • 2008
  • Ex-situ reductive dechlorination of carbon tetrachloride (CT) by iron sulfide in a batch reactor was characterized in this study. Reactor scaled-up by 3.5 L was used to investigate the effect of reductant concentration on removal efficiency and process optimization for ex-situ degradation. The experiment was conducted by using both liquid-phase and gas-phase volume at pH 8.5 in anaerobic condition. For 1 mM of initial CT concentration, the removal of the target compound was 98.9% at 6.0 g/L iron sulfide. Process optimization for ex-situ treatment was performed by checking the effect of transition metal and mixing time on synthesizing iron sulfide solution, and by determining of the regeneration time. The effect of Co(II) as transition metal was shown that the reaction rate was slightly improved but the improvement was not that outstanding. The result of determination on the regeneration time indicated that regenerating reductant capacity after $1^{st}$ treatment of target compound was needed. Due to the high removal rates of CT, ex-situ reductive dechlorination in batch reactor can be used for basic treatment for the chlorinated compounds.

Synthesis of 1,1,3,4-Tetramethyl-1-sila-2,4-Cyclopentadiene

  • Joo, Wan-Chul;Hwang, Hae-Sook;Hong, Jang-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.6 no.6
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    • pp.348-350
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    • 1985
  • The compound 1,1,3,4-tetramethyl-1-sila-3-cyclopentene was obtained through the reaction of 2,3-dimethylbutadiene and dichlorodimethyl-silane in THF in the presence of sodium metal. After the bromination of this compound at $0^{\circ}C$ for 2 hrs and dehydrobromination by using a base, we prepared 1.1.3.4-tetramethyl-1-sila-2,4-cyclopentadiene, Which could undergo dimerization. The identification has been done by using $^1H-,^{13}C-$ and C/H-Correlation two dimensional nmr spectroscopies.

Genetic Characteristics of Arsenic Compounds-Resistant Bacteria Isolated from Stream Water (하천에서 분리한 비소 내성세균의 유전적 특성)

  • 정미경;이호자
    • Korean Journal of Microbiology
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    • v.29 no.1
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    • pp.63-68
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    • 1991
  • Several arsenic compound-resistant bacteria were isolated from Jung-Rang stream. The isolates, D-3, D-12, and D-14 were characterized phenotypically and genetically, and identified as Serratia liquefaciens, Klebsiella oxytoca, and Klebsiella pneumoniae, respectively. A plasmid of 67kb was found in Klebsiella oxytoca D-12 and designated as pMH12. Transfer of this plasmid from D-12 to E. coli HB101 was occurred, and the resulting transconjugant strains expressed the same level of heavy metal resistance as the donor strain. The physical presence of this plasmid in transconjugant was detected with agarose gel electrophoresis. Arsenite-sensitive derivatives of isolate D-12 were obtained with Mitomycin C treatment which cured pMH12. Antibiotics and heavy metal resistances were also examined to be used as a proper marker for the isolates in gene cloning. Isolate D-12 has resistance to several heavy metal ions such as $Cd^{2+}$ , $Zn^{2+}$ and $Hg^{ 2+}$ Also, all the other arsenite resistant isolates showed resistance to several heavy metal ions and antibiotics.

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C-V Characteristics of The MOS Devices by Using different Gate Metals (게이트 금속 변화에 의한 MOS 소자의 C-V 특성)

  • 최현식;서용진;유석빈;장의구
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1988.10a
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    • pp.95-97
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    • 1988
  • The instability of MOS devices is mainly caused by the oxide charges, and as the need to develop the gate metal grows researches for various new metal gate have been performed, and in these researches, the difference work function existing between the metal and the semiconductor should be considered. Here int his paper, the device is made by the sputtering and the LPCVD method using pure Al, compound metal. poly-si, as a gate metal, the result of the research was shown that the work function difference from using different gate metals effects on the flatband voltage shift. This means we can infer that the threshold voltage adjustment is possible by using different gate metals and this whole mechanism makes the devices behavior more stable.

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Selective Metal Ion Sensing of Bipyridine-Bisterpyridine containing Fluorescent Dyes (다중 피리딘 구조를 가지는 형광염료의 금속 이온 반응성에 대한 연구)

  • Zo, Hye Jin;Kim, Arong;Jeong, Sooyeon;Park, Jong S.
    • Textile Coloration and Finishing
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    • v.25 no.4
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    • pp.254-261
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    • 2013
  • In this study, we synthesized a new fluorescent polypyridyl dye 2 containing a 2,2'-bipyridine in the center and two 2,2':6',2"-terpyridines at both ends. When exposed to various metal ions, the dye 2 showed selective fluorescence responses. In the presence of $Cu^{2+}$ and $Ni^{2+}$, it exhibited a highly effective fluorescence quenching, leading to large $K_{sv}$ values of up to $10^5$. In response to most other metal ions including $Al^{3+}$, in contrast, its fluorescence changes little, showing a small Ksv value at $10^2$. Meanwhile, the compound 2 revealed a differentiated fluorescence response to $Zn^{2+}$, which is evidenced by a large red shift of > 100 nm. Such a red shift from the ion binding is attributed to the planarization of the bipyridyl unit extending the effective conjugation length in conjunction. A polypyridyl compound will find important usefulness in chemosensor application due to its selective binding to metal ions. Subsequent research concerned with modified derivatives is currently going on, as a way to provide high solubility even after metal-complexing.

Carbonization and Activation Behaviors of Metal Containing Carbon Fibers (금속함유 탄소섬유의 탄화 및 활성화 거동)

  • Young Ok CHOI;Kap Seung YANG
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.98-100
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    • 2003
  • The efficiency of the adsorption of adsorbents depends on both pore size and shape. In other to adsorb hydrated ion in application of electric double layer capacitor (EDLC), mesopore is necessary[1,2]. Tamai et al.[3] reported that an increased portion of mesopore was introduced through addition of metal or organometallic compound in the precursor and following activation of the carbon fibers with steam. (omitted)

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Microstructural study of polycrystalline films prepared by Ni vapor induced crystallization

  • Ahn, Kyung-Min;Lee, Kye-Ung;Ahn, Byung-Tae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.715-717
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    • 2006
  • $NiCl_2$ vapor was introduced into conventional furnace to conduct vapor-induced crystallization (VIC) process. We made the metal chloride atmosphere by sublimating the $NiCl_2$ compound. The $NiCl_2$ atmosphere enhanced the crystallization of amorphous silicon thin films. As the result, polycrystalline Si film with large grain size and low metal contamination has been obtained.

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Band Electronic Structure Study of Compound $(ET)_2ICl_2$ in Two Structural Modifications

  • Kang Dae Bok
    • Bulletin of the Korean Chemical Society
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    • v.15 no.6
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    • pp.428-432
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    • 1994
  • The crystals of ${\beta}-and\;{\beta}'-(ET)_2ICl_2$ have a modified structure of organic superconductor ${\beta}(ET)_2I_3$. These salts possess strictly different physical properties : the ${\beta}$ phase is a metal but the ${\beta}'$ phase is a semiconductor. Our band electronic structure calculations show that the ${\beta}$ phase is somewhat anisotropic 2D metal and the ${\beta}'$ phase with the 1D character in electronic structure is magnetic insulating, in good agreement with experimental indications.