• Title/Summary/Keyword: composition gradient

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Radial Distribution Proximate Composition and Minerals within Naked Barley Kernel (쌀보리 입자내의 일반성분 및 무기질의 분포)

  • Park, Sung-Hee;Kim, Kwan;Kim, Sung-Kon;Park, Yang-Kyun
    • Applied Biological Chemistry
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    • v.32 no.4
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    • pp.441-443
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    • 1989
  • The major kernels$(7{\sim}10\;mesh)$ of naked barley were pearled to give an average yield for each pearling of about 5% flour, with 70% of the naked barley left as residual kernel. The contents of protein, fat and ash were in the highest in the fraction of 1,2 and 3, respectively. These fractions contained 1, 4 times of protein, 3.16 times of fat and 3.08 times of ash more than those values of original kernel. Residual kernels contained 62% of protein, 38% of fat and 35% of ash in the original kernel. Among minerals, the content of Ca, Na, Fe and Mn were in the highest in fraction 1 ; P, Mg and Zn in fraction 2 ; and K and Cu in fraction 3. Concentrations of these minerals were the lowest in the residual kernel. Magnesium showed the deepest concentration gradient, while iron was evenly distributed within the kernel.

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The analysis of columnar to equiaxed dendritic transition during alloy solidification (합금응고시 주상정으로부터 등축정 수지상으로의 천이에 관한 해석)

  • 김신우
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.187-192
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    • 1998
  • Generally the solidified microstructures of materials consist of the columnar and equiaxed dendritic regions, and many theoretical studies about columnar-to-equiaxed transition have been done because that is closely related to the mechanical and physical properties of products. In this study, the modified equation based on the Hunt's analytical columnar-to-equiaxed transition condition which was derived from heterogeneous nucleation and grain growth in front of the columnar dendrite tip under directional solidification, was obtained applying the growth-velocity-dependent distribution coefficient and liquidus slope to Hunt's. The effects of the number of nucleation sites, nucleation temperature, alloy composition, growth velocity and liquid temperature gradient on the transition for Al-Cu alloys have been investigated.

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Growth of Superconductor YBa2Cu3O7-x Single Crystal by Flux Method (Flux법에 의한 초전도체 YBa2Cu3O7-x 단결정 육성)

  • 오근호;김호건;명중재
    • Journal of the Korean Ceramic Society
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    • v.27 no.1
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    • pp.48-54
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    • 1990
  • YBa2Cu3O7-x(=YBCO) single crystals were grown by flux method and the growing process of crystals was investigated. YBCO and 3BaO-7CuO composition powders were mixed by the ratio of 25 : 75(wt%), and the mixtures were melted at 105$0^{\circ}C$ in a electric furnace with no temperature-gradient. Then the melt was cooled at a rate 2-1$0^{\circ}C$/h in the above furnace. YBCO single crystal plate with average size of $1.5\times$2.0$\times$0.1㎣ were obtained in the cavities between crucible and solidified ingot, and the single crystals were oriented to <001> direction. The ingots of flux parts were analyzed by XRD and EDS for the purpose of presuming the growing process of the crystals. It was assumed that the divorced eutectic reaction, by which YBCO crystals were grown first and then BaCuO2 and CuO crystals, occured in the case of cooling rate faster than 2$^{\circ}C$/h. When the cooling rate was 2$^{\circ}C$/h, it was assumed that quasi-equilibrium eutectic reaction occured, so that YBCO, BaCuO2 and CuO crystals were grown at the same time.

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Biofilms and their Activity in Granular Activated Carbons Established in a Drinking Water Treatment Plant (정수장 활성탄 여과지의 생물막과 그 활성도)

  • Lee, Ji-Young;Kim, Se-Jun;Chung, Ik-Sang;Joh, Gyeong-Je
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.6
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    • pp.661-674
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    • 2010
  • Bacterial biomass and its activity were measured in two kinds of granular activated carbon (GAC), the experimental and existing biofiltration system in a drinking water plant. The bacterial biomass was around 210 to 250 nmol P/g WW with phospholipid concentration at acclimation of ozonation treatment. The phospholipid biomass shows more or less a declining gradient along filter depth and no clear seasonality in its values. On the other hand, the microbial activity of [$^3H$]-thymidine and [$^{14}C$]-acetate incorporation within cells increased significantly along the filter depth, showing the difference of three fold between the upper and bottom layer. These factors support the different microbial composition or metabolic activity along the depth of GAC column. Turnover rates, the rate of bacterial biomass and production of biofilm, ranged from 0.26 /hr to 0.37 /hr, indicating a highly rapid recovery itself at amature state. In the non-ozonation treatment, the bacterial biomass was lower than in the ozonation and biological activity also declined towards the filter depth. The biomass levels during cessation of ozonation in the existing GAC filters were 68% of the actively ozonated state.

MERCURY-INDUCED ALTERATIONS OF CHLOROPHYLL a FLUORESCENCE KINETICS IN ISOLATED BARLEY (Hordeum vulgare L. cv. ALBORI) CHLOROPLASTS

  • Chun, Hyun-Sik;Lee, Choon-Hwan;Lee, Chin-Bum
    • Journal of Photoscience
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    • v.1 no.1
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    • pp.47-52
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    • 1994
  • Effects of HgCl$_2$-treatment on electron transport, chlorophyll a fluorescence and its quenching were studied using isolated barley (Hordeum vulgare L. cv. Albori) chloroplasts. Depending on the concentration of HgCI$_2$, photosynthetic oxygen-evolving activities of photosystem II (PS II) were greatly inhibited, whereas those of photosystem I (PS I) were slightly decreased. The inhibitory effects of HgCl$_2$ on the oxygen-evolving activity was partially restored by the addition of hydroxyamine, suggesting the primary inhibition site by HgCl$_2$2-treatment is close to the oxidizing site of PS tl associated with water-splitting complex. Addition of 50 $\mu$M HgCI$_2$ decreased both photochemical and nonphotochemical quenching of chlorophyll fluorescence. Especially, energy dependent quenching (qE) was completely disappeared by HgCl$_2$-treatment as observed by NH$_4$CI treatment. In the presence of HgCI$_2$, F'o level during illumination was also increased. These results suggest that pH gradient across thylakoid membrane can not be formed in the presence of 0 $\mu$M HgCl$_2$. In addition, antenna pigment composition might be altered by HgCl$_2$-treatment.

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A study on the change of microstructural and mechanical properties by the long-term thermal aging of dissimilar metal welds in nuclear power plants (원전 이종금속 용접부의 장기 열적 시효에 따른 미세조직 및 기계적 특성변화에 관한 고찰)

  • Choi, Kyoung Joon;Yoo, Seung Chang;Kim, Ji Hyun
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.10 no.1
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    • pp.82-89
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    • 2014
  • In this study, the metallurgical analysis and mechanical property measurement have been performed to investigate the effect of long-term thermal aging on the microstructural evolution in the fusion boundary region between weld metal and low alloy steel in dissimilar metal welds. A representative dissimilar weld mock-up made of Alloy 690-Alloy 152-A533 Gr. B was fabricated and aged at $450^{\circ}C$ for 2,750 hours. The microstructural characterization was conducted mainly near in a weld root region by using optical microscopy, scanning electron microscopy, transmission electron microscopy. And the mechanical properties were measured with Vickers microhardness test and nanoindentation method. A steep gradient was shown in the chemical composition profile across the interface between A533 Gr. B and Alloy 152. Type-II boundaries were found in weld side of DMW and the hardness was the highest at the narrow zone between Type-II boundary and fusion boundary.

An Experimental Study on Relationship Between Global Equivalence Ratio and Fire Characteristics in Full-Scale Compartment Fires (실제 규모의 구획화재에서 총괄당량비와 화재특성의 상관관계에 관한 실험적 연구)

  • Hwang, Cheol-Hong;Park, Chung-Hwa;Ko, Gwon Hyun;Lock, Andrew
    • Journal of the Korean Society of Combustion
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    • v.15 no.3
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    • pp.32-39
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    • 2010
  • An experimental study was conducted to investigate the relationship between global equivalence ratio(GER) and fire characteristics in an ISO 9705 room. Heptane fuel was burned with different fuel flow rates and doorway widths in order to force the room to be placed in different GER conditions. It was observed that after the onset of under-ventilated fire conditions, temperature and unburned fuel components such as CO and soot increased with increasing heat release rate (HRR), regardless of the doorway width. From the analysis of local mixture fraction, it was reconfirmed that the inclusion of soot production in the product composition was very important to predict accurately the chemical conditions inside the compartment, particularly for the under-ventilated fire conditions. In addition, the local equivalence ratio (LER) was directly proportional to the GER with a unit gradient regardless of doorway width when the soot production was included in the chemical products. This finding provided an important potential that the GER could be used to correlate the local thermal and chemical environment measured at the upper layer of a full-scale enclosure when soot was included.

Ecological responses of natural and planted forests to thinning in southeastern Korea: a chronosequence study

  • Cho, Yong-Chan;Pee, Jung-Hun;Kim, Gyeong-Soon;Koo, Bon-Yoel;Cho, Hyun-Je;Lee, Chang-Seok
    • Journal of Ecology and Environment
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    • v.34 no.4
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    • pp.347-355
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    • 2011
  • Effects of forest thinning on community level properties have not been understood yet in Korea. We investigated regeneration patterns and trajectories after a disturbance by applying a chronosequence approach. Light availability, litter and woody debris cover, and species composition were determined for twenty 50 m line-transect samples representing a disturbance duration gradient (within 11 years). Environmental factors such as light availability and coverage of woody debris and litter changed abruptly after thinning and then returned to the pre-disturbance state. Although species richness was gained at shrub and ground layer in a limited way in both forests, cover of various functional types revealed diversity in their responses. Notably, Alnus firma stands exhibited a larger increment of cover in woody plants. Ordination analysis revealed different regeneration trajectories between natural and planted stands. Based on ordination analysis, rehabilitated stands showed movement to alternative states compared with natural ones, reflecting lower resilience to perturbation (i.e., lower stability). Our results suggest that community resilience to artificial thinning depends on properties of the dominant species. But to get more explanatory ecological information, longer-term static observations are required.

Single Crystalline InxGa1-xAs Nanowires on Si (111) via VLS Method (VLS 방법을 이용한 단결정 InxGa1-xAs 나노와이어 성장과 조성비 변화에 대한 특성측정)

  • Shin, Hyun Wook;Shin, Jae Cheol;Choe, Jeong-Woo
    • Journal of the Korean Vacuum Society
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    • v.22 no.2
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    • pp.105-110
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    • 2013
  • Single crystalline $In_xGa_{1-x}As$ nanowires are grown on Si (111) substrate via Vapor-Liquid-Solid growth mode using metal-organic chemical vapor deposition. The ternary nanowires have been grown with various growth conditions and examined by electron microscopy. The alloy compositions of the nanowires has been investigated using Energy-dispersive X-ray spectroscopy. We have found that the composition gradient of the nanowire becomes larger with growth temperature and V/III ratio.

Effect of Concentration of Ionic Liquids on Resolution of Nucleotides in Reversed-phase Liquid Chromatography

  • Hua, Jin Chun;Polyakova, Yulia;Row, Kyung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.28 no.4
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    • pp.601-606
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    • 2007
  • The chromatographic behaviors of nucleotides (inosine 5'-monophosphate, uridine 5'-monophosphate, guanosine 5'-monophosphate, and thymine monophosphate disodium salts) on a C18 column were studied with different types of ionic liquids (ILs) as additives for the mobile phase in reversed-phase liquid chromatography (RPLC). Three ILs, 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF4]), 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIm][BF4]), and 1-ethyl-3-methylimidazolium methylsulfate ([EMIm][MS]), were used. Eluents were composed of water and methanol (90/10%, vol) with the addition of 0.5-13.0 mM of ILs. The effects of the concentration of ILs on retention and separation were investigated and discussed. The results showed that the addition of ILs affects the retention and resolution of the tested compounds. Use of 13.0 mM of [BMIm][BF4] as the eluent modifier resulted in a baseline separation of nucleotides without requiring gradient elution. This study demonstrates that ILs can be potentially applied as a mobile phase modifier in RPLC.