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Fabrication Process and Characterization of Sonic Polymer-Metal Composite Actuators by Electroless Plating of Platinum (백금의 무 전해 도금에 의한 이온성 고분자-금속 복합물 액추에이터의 제작 공정 및 특성 측정)

  • Cha, Seung-Eun;Park, Jeong-Ho;Lee, Seung-Gi
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.9
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    • pp.455-463
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    • 2002
  • Ionic Polymer metal composite(IPMC), one of new actuation materials of EAPs is fabricated by electroless plating of platinum on both sides of the perfluorosulfonic acid film or Nafion film and its electromechanical characteristics are investigated. The IPMC strip bends towards anode under electrical field. As the number of plating cycle increases, the distance between plated platinum electrodes on both sides of Nafion membrane decreases and also the displacement is almost inversely proportional to the number of plating. The displacement of IPMC strip depends on voltage magnitude and applied signal frequency and its maximum deformation is observed at a critical frequency, resonant frequency. Low pressure sandblasting is used for surface treatment of Nafion membrane and at 8 times of plating cycle produced actuator with high displacement performance. For more efficiency of fabricated IPMC, it is useful to add one or two surface developing step which is the second reduction process using hydrazine.

Prediction of strength development of fly ash and silica fume ternary composite concrete using artificial neural network (인공신경망을 이용한 플라이애시 및 실리카 흄 복합 콘크리트의 압축강도 예측)

  • Fan, Wei-Jie;Choi, Young-Ji;Wang, Xiao-Yong
    • Journal of Industrial Technology
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    • v.41 no.1
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    • pp.1-6
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    • 2021
  • Fly ash and silica fume belong to industry by-products that can be used to produce concrete. This study shows the model of a neural network to evaluate the strength development of blended concrete containing fly ash and silica fume. The neural network model has four input parameters, such as fly ash replacement content, silica fume replacement content, water/binder ratio, and ages. Strength is the output variable of neural network. Based on the backpropagation algorithm, the values of elements in the hidden layer of neural network are determined. The number of neurons in the hidden layer is confirmed based on trial calculations. We find (1) neural network can give a reasonable evaluation of the strength development of composite concrete. Neural network can reflect the improvement of strength due to silica fume additions and can consider the reductions of strength as water/binder increases. (2) When the number of neurons in the hidden layer is five, the prediction results show more accuracy than four neurons in the hidden layer. Moreover, five neurons in the hidden layer can reproduce the strength crossover between fly ash concrete and plain concrete. Summarily, the neural network-based model is valuable for design sustainable composite concrete containing silica fume and fly ash.

Characteristics of Workers' Exposure to Aerosolized Particles during the Production of Carbon Nanotube-enabled Composites (탄소나노튜브 복합체 취급 작업자의 공기 중 입자상 물질 노출 특성)

  • Kwon, Jiwoon;Kim, Sungho;Jang, Miyeon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.30 no.1
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    • pp.1-9
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    • 2020
  • Objectives: The purpose of this case study is to assess workers' exposure to carbon nanotubes(CNTs) and characterize particles aerosolized during the process of producing CNT-enabled polytetrafuoroethylene(PTFE) composites at a worksite in Korea. Methods: Personal breathing zone and area samples were collected for determining respirable concentrations of elemental carbon(EC) using NIOSH(National Institute for Occupational Safety and Health) Method 5040. Personal exposure to nano-sized particles was measured as the number concentration and mean diameter using personal ultrafine particle monitors. The number concentration by particle size was measured using optical particle sizers(OPS) and scanning mobility particle sizers(SMPS). Transmission electron microscopy (TEM) area samples were collected on TEM grids and analyzed to characterize the size, morphology, and chemistry of the particles. Results: Respirable EC concentrations ranged from 0.04 to 0.24 ㎍/㎥, which were below 23% of the exposure limit recommended by NIOSH and lower than background concentrations. Number concentrations by particle size measured using OPS and SMPS were not noticeably elevated during CNT-PTFE composite work. Instant increase of number concentrations of nano-sized particles was observed during manual sanding of CNT-PTFE composites. Both number concentrations and mean diameters did not show a statistically significant difference between workers handing CNT-added and not-added materials. TEM analyses revealed the emission of free-standing CNTs and CNT-PTFE aggregate particles from the powder supply task and composite particles embedded with CNTs from the computer numerical control(CNC) machining task with more than tens of micrometers in diameter. No free-standing CNT particles were observed from the CNC machining task. Conclusions: Significant worker exposure to respirable CNTs was not found, but the aerosolization of CNTs and CNT-embedded composite particles were observed during handing of CNT-PTFE powders and CNC machining of CNT-PTFE composites. Considering the limited knowledge on the toxicity of CNTs and CNT composite particles to date, it seems prudent to take a precautionary approach for the protection of workers' health.

Inhibitory effect on Streptococcus mutans and mechanical properties of the chitosan containing composite resin

  • Kim, Ji-Sun;Shin, Dong-Hoon
    • Restorative Dentistry and Endodontics
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    • v.38 no.1
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    • pp.36-42
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    • 2013
  • Objectives: This study evaluated the antibacterial effect and mechanical properties of composite resins ($L_{CR}$, $M_{CR}$, $H_{CR}$) incorporating chitosan with three different molecular weights (L, Low; M, Medium; H, High). Materials and Methods: Streptococcus (S). mutans 100 mL and each chitosan powder were inoculated in sterilized 10 mL Brain-Heart Infusion (BHI) solution, and was centrifuged for 12 hr. Absorbance of the supernatent was measured at $OD_{660}$ to estimate the antibacterial activities of chitosan. After S. mutans was inoculated in the disc shaped chitosan-containing composite resins, the disc was cleansed with BHI and diluted with serial dilution method. S. mutans was spread on Mitis-salivarius bacitracin agar. After then, colony forming unit (CFU) was measured to verify the inhibitory effect on S. mutans biofilm. To ascertain the effect on the mechanical properties of composite resin, 3-point bending and Vickers hardness tests were done after 1 and 3 wk water storage, respectively. Using 2-way analysis of variance (ANOVA) and Scheffe test, statistical analysis was done with 95% significance level. Results: All chitosan powder showed inhibition effect against S. mutans. CFU number in chitosan-containing composite resins was smaller than that of control resin without chitosan. The chitosan containing composite resins did not show any significant difference in flexural strength and Vickers hardness in comparison with the control resin. However, the composite resin, $M_{CR}$ showed a slightly decreased flexural strength and the maximum load than those of control and the other composite resins $H_{CR}$ and $L_{CR}$. Conclusions: $L_{CR}$ and $H_{CR}$ would be recommended as a feasible antibacterial restorative due to its antibacterial nature and mechanical properties.

Synthesis and Photocatalytic Activity of Ag Spot-coated TiO2-SrO Composite Powders (나노 Ag spot-coated TiO2-SrO 복합분체의 합성과 광촉매 활성 평가)

  • Han, Jae-Kil;Kim, Hyeong-Chul;Hong, Won-Seok;Choi, Sung-Chang
    • Korean Journal of Materials Research
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    • v.18 no.7
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    • pp.389-393
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    • 2008
  • Nano-sized $TiO_2$-60 wt% SrO composite powders were synthesized by a sol-gel method using titanium isopropoxide and $Sr(OH)_2\;{\cdot}\;8H_2O$ as precursors. 3, -5, -7 wt%Ag spot-coated $TiO_2$-60 wt% SrO composite powders were synthesized by a Ag electroless deposition method using $TiO_2$-60 wt% SrO composite powders calcined at $1050^{\circ}C$, which mainly exhibited the $SrTiO_3$phase. However, a small number of rutile $TiO_2$, $Sr_2TiO_4$ and $SrO_2$ phases were also detected. In the Ag spot-coated powders synthesized by electroless deposition, nano-sized particles about 5-25 nm in diameter adhered to the $TiO_2$-60 wt% SrO composite powders. The photocatalytic activity of Ag spot-coated $TiO_2$-SrO and $TiO_2$-SrO composite powders for degradation of phenol showed that all of $TiO_2$-SrO composite powders were highly active under UV light irradiation. 7 wt%Ag spot-coated $TiO_2$-60wt.%SrO composite powders had a relatively higher photocatalytic activity than did $TiO_2$-SrO composite powders under visible light.

Optimal design of laminated composite plates to maximise fundamental frequency using MFD method

  • Topal, Umut;Uzman, Umit
    • Structural Engineering and Mechanics
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    • v.24 no.4
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    • pp.479-491
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    • 2006
  • This paper deals with optimal fibre orientations of symmetrically laminated fibre reinforced composite structures for maximising the fundamental frequency of small-amplitude. A set of fiber orientation angles in the layers are considered as design variable. The Modified Feasible Direction method is used in order to obtain the optimal designs. The effects of number of layers, boundary conditions, laminate thicknesses, aspect ratios and in-plane loads on the optimal designs are studied.

Statistical treatment of the effective modulus of woven composites (평직복합재료 등가물성치의 통계학적 분포 특성)

  • 우경식;서영욱
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.04a
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    • pp.59-62
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    • 2000
  • In this study, the distribution of the effective modulus was investigated statistically Plain weave structures were modeled with random stacking phase shift angles and the effective modulus was calculated by the unit cell analysis. The analysis results indicated that the effect of random phase shift angles was significant on the modulus distribution. As the number of layers increased, the coefficient of variation decreased and higher degree of homogeneity was attained.

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Impact Simulation of Automotive GMT Bumper (자동차용 유리섬유강화 매트 수지(GMT) 범퍼의 충돌성능 평가 수치모사)

  • 백승훈;문종근;정우식;김승조
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.137-140
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    • 2003
  • Impact of Automotive GMT(Glassfiber reinforced Mat Thermoplastic) Bumper for '5Mhp Barrier Test'was simulated using ls-dyna. The FE model consists of foam which is energy absorber, bumper beam and stay etc. Bumper intrusion and deflection was compared with the experimental results. Effects of uncertainty of material property and deviation of impact velocity were considered and results were compared with those of base design. Effects of number of integration points through th thickness was also investigated.

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Geometric Nonlinear Analysis of Underground Laminated Composite Pipes (기하학적 비선형을 고려한 지하매설 복합재료 파이프의 해석)

  • 김덕현;이인원;변문주
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1988.10a
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    • pp.30-35
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    • 1988
  • An analytical study was conducted using the Galerkin technique to determine the behaviour of thin fibre-reinforced and laminated composite pipes under soil pressure. Geometric nonlinearity and material linearity have been assumed. We assumed that vertical and lateral soil pressure are proportional to the depth and lateral displacement of the pipe respectively. And we also assumed that radial shear stress is negligible because the ratio of the thickness to the radius of pipe is very small. We, in this paper, discuss the effect of the number of layer, fiber orientation, and soil property.

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Electrical Conductivity of Polypyrrole/Copolyester Composite Films. 2. Composite Films Prepared from Copolyester-$FeCl_3$ Surface Absorption

  • Lee, Seong-Mo;Baik, Doo-Hyun
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.53-56
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    • 1998
  • Polypyrrole (PPy) is regarded as one of the most Promising intrinsically or naturally conductive polymer for practical applications due to its relatively high electrical conductivity, environmental stability and low toxicity. The typical PPy, which is insoluble and infusible, exhibits poor processability and lacks essential mechanical properties. A number of papers have concerned the efforts to overcome these drawbacks. (omitted)

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