• Journal of Korean Society of Water and Wastewater
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• v.33 no.2
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• pp.151-158
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• 2019

Objectives of this study were to identify the hotspot for displacement of the on-line water quality sensors, in order to detect illicit discharge of untreated wastewater. A total of twenty-six water quality parameters were measured in sewer networks of the industrial complex located in Daejeon city as a test-bed site of this study. For the water qualities measured on a daily basis by 2-hour interval, the self-organizing maps(SOMs), one of the artificial neural networks(ANNs), were applied to classify the catchments to the clusters in accordance with patterns of water qualities discharged, and to determine the hotspot for priority sensor allocation in the study. The results revealed that the catchments were classified into four clusters in terms of extent of water qualities, in which the grouping were validated by the Euclidean distance and Davies-Bouldin index. Of the on-line sensors, total organic carbon(TOC) sensor, selected to be suitable for organic pollutants monitoring, would be effective to be allocated in D and a part of E catchments. Pb sensor, of heavy metals, would be suitable to be displaced in A and a part of B catchments.

• Journal of Korean Society of Water and Wastewater
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• v.19 no.4
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• pp.455-461
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• 2005

This study was designed to investigate the fundamental aspects of a possible recovery of phosphorus strategy from wastewater by using the zirconium mesoporous structured materials as a new type of ion exchangers. Zirconium mesoporous structure material was synthesized by hydro-thermal synthesis. The synthesized zirconium mesoporous structure was examined by X-ray diffraction (XRD) and Transmission electron micrograph (TEM). From the results of XRD and TEM, it was found out that hexagonal mesoporous structure, pore size was about $47{\AA}$, was synthesized. Experimental results showed that the complex of zirconium sulfate tetrahydrate and surfactant micelles had very high ability for capture of phosphorus. The amount of phosphate ions exchanged into the solid was as great as 3.4mmol/g-ZS. And the ion exchange reaction was occurred between $PO_4{^{3-}}$ and $SO_4{^{2-}}$ and also between $PO_4{^{3-}}$ and $OH^-$. Therefore, it is possible to get the higher removal efficiency than other ion exchange media and adsorbent.

• Journal of Korean Society on Water Environment
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• v.21 no.1
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• pp.14-20
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• 2005

A feasibility study has been conducted regarding the application of waste coffee grounds as an adsorbent for the treatment of nickel ion containing wastewater. The major variables which considered to influence the adsorbability of nickel ion were its initial concentration, reaction temperature, pH, and coexisting ion. The specific surface area of coffee grounds used in the experiment was found to be ca. $39.67m^2/g$, which suggesting its potential applicability as an adsorbent due to its relatively high surface area. In the experimental conditions, more than 90% of the initial amount of nickel ion was shown to adsorb within 15 minutes and equilibrium in adsorption was attained after 3 hours. The adsorption behavior of nickel ion was well explained by Freundlich model and kinetics study showed that the adsorption reaction was second-order. Adsorption was reduced with temperature and its change of enthalpy in standard state was estimated to be -807.05 kJ/mol. Arrhenius equation was employed for the calculation of the activation energy of adsorption and nickel ion was observed to adsorb on coffee grounds exoentropically based on thermodynamic estimations. As pH rose, the adsorption of nickel ion was diminished presumably due to the formation of cuboidal complex with hydroxide ion and the coexistence of cadmium ion was found to decrease the amount of nickel ion adsorption, which was proportional to the concentration of cadmium ion.

• Korean Journal of Environmental Agriculture
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• v.29 no.4
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• pp.402-407
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• 2010

Zerovalent iron (ZVI) is one of the most commonly used metallic reducing agents for the treatment of toxic contaminants in wastewater. Traditional ZVIs are less effective than nanoscale ZVI (nZVI) due to prolonged reaction time. However, the reactivity can be significantly increased by reducing the size of ZVI particles to nanoscale. In this study, nZVI particles were synthesized under laboratory condition and their efficiency in removing hexavalent chromium (Cr(VI)) from aqueous solutions were compared with commercially available ZVI particles. The results showed that the synthesized nZVI particles (SnZVI) reduced >99% of Cr(VI) at the application rate of 0.2% (w/v), while commercial nZVI (CnZVI) particles resulted in 59.6% removal of Cr(VI) at the same application rate. Scanning electron micrographs (SEM) and energy dispersive spectra (EDS) of the nZVI particles revealed the formation of Fe-Cr hydroxide complex after reaction. Overall, the SnZVI particles can be used in treating chromium contaminated wastewater.

• International journal of advanced smart convergence
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• v.9 no.4
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• pp.16-25
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• 2020

The operation of a wastewater treatment plant (WWTP) is a complex task which requires to consider several aspects: adapting to always changing influent composition and volume, ensuring treated effluents quality complies with local regulations, ensuring dissolved oxygen levels in biological reaction tanks are sufficient to avoid anoxic conditions etc. all of it while minimizing usage of chemicals and power consumption. The traditional way of managing WWTPs consists in having employees on the field measure various parameters and make decisions based on their judgment and experience which holds various concerns such as the low frequency of data, errors in measurement and difficulty to analyze historical data to propose optimal solutions. In the case of activated sludge WWTPs, parts of the treatment process can be automated and controlled in order to satisfy various control objectives. The models developed by the International Water Association (IWA) have been extensively used worldwide in order to design and assess the performance of various control strategies. In this work, we propose to review most recent WWTP automation initiatives around the world and identify most currently used control parameters and control architectures. We then suggest a framework to select WWTP model, control parameters and control scheme in order to develop and benchmark control strategies for WWTP automation.

• Clean Technology
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• v.27 no.2
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• pp.168-173
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• 2021

The treatment of plated wastewater is subject to various and complex processes depending on the pH, heavy metal, and cyanide content of the wastewater. Alkali chlorine treatment using NaOCl is commonly used for cyanide treatment. However, if ammonia and cyanide are present simultaneously, NaOCl is consumed excessively to treat ammonia. To solve this problem, this study investigated 1) the consumption of NaOCl according to ammonia concentration in the alkaline chlorine method and 2) whether ferrate (VI) could selectively treat the cyanide. Experiments using simulated wastewater showed that the higher the ammonia concentration, the lower the cyanide removal rate, and the linear increase in NaOCl consumption according to the ammonia concentration. Removal of cyanide using ferrate (VI) confirmed the removal of cyanide regardless of ammonia concentration. Moreover, the removal rate of ammonia was low, so it was confirmed that the ferrate (VI) selectively eliminated the cyanide. The cyanide removal efficiency of ferrate (VI) was higher with lower pH and showed more than 99% regardless of the ferrate (VI) injection amount. The actual application to plated wastewater showed a high removal ratio of over 99% when the input mole ratio of ferrate (VI) and cyanide was 1:1, consistent with the molarity of the stoichiometry reaction method, which selectively removes cyanide from actual wastewater containing ammonia and other pollutants like the result of simulated wastewater.

• Journal of Korean Society of Water and Wastewater
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• v.10 no.1
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• pp.69-77
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• 1996

To evaluate the change of the groundwater flow and the water table response resulting from urbanization, two cases of the transient three-dimensional numerical simulations were performed. Variations of the groundwater flow system caused by withdrawals were analyzed. Two cases of infiltration rates were applied in this study to verify the water table changes. One is the rate under the circumstance during 1994 and the other is the revised rate. The numerical results from this study indicated that groundwater flow was influenced by human impacts. Groundwater flow has been concentrated to Taegu Textile Complex area where had large amount of pumping. Water table so far decreased -2.76m a year due to withdrawals. Water tables of many points were increased more than 30cm when the surface was reformed by infiltrating the rainfall. It was appeared that the improvement of surface to recharge the precipitation was very important to preserve and manage for the groundwater.

• Textile Coloration and Finishing
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• v.10 no.6
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• pp.42-48
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• 1998

For the effective operation of complex dyeing wastewater treatment plant, the biodegradability of various dyeing agents were investigated. For experiments in biodegradability, activated sludge from aeration tank of wastewater treatment plant was used. Biodegradability of dyeing agents were compared by measuring the $BOD_5/COD_{Cr}$ ratios and $BOD_5$ removal efficiency. $COD_{Cr}$. removal efficiency of dyeing agents was less than 80% , while $BOD_5$ removal efficiency was less than 60% after of days. Therefore, biodegradation by activated sludge were found very difficult. Judging from this, it is necessary to isolate strains biodegrading dyeing agents in order to operate activated sludge process safely.

• 한국연소학회:학술대회논문집
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• 2004.06a
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• pp.165-172
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• 2004

Co-incineration of coal and wastewater sludge was r;erfonn:rl in a O.lMWth bench scale circulating fluidized bed combustor(CFBC) Sludge was received from a wastewater treatment plant in a dye industrial complex in Busan. Metropolis. Moisture content of received sludge was 80%. Coal and sludge mixture was prepared with weight ratio of 90/10, 85/15 and 80/20. Co-combustion characteristics of the coal and sludge mixture demonstrated stable combustion conditions. Component analysis, incineration characteristics, boiler performance was measured before and after the test and application for commercial 59MWth CFBC boiler. The release of hazardous components such as $SO_2$ and Cl was suppressed by the presence of inherent minerals of Ca, Na, K in coal and sludge mixture. Pre-drying was not essential but it was recommended for the benefits of manageability of sludge.

• Journal of Korean Society of Water and Wastewater
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• v.11 no.2
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• pp.50-64
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• 1997

Life cycle assessment (LCA) on total sewage sludge treatment system from thickening to incineration and melting was performed for estimating global environmental impact as $CO_2$. In general, the life cycles of actual treatment facilities consist of construction, operation and dismantlement. In this study, the amount of $CO_2$ produced from both whole and each life cycle step of currently used unit sludge treatment processes were calculated by inventory analysis. In addition, in the all processes investigated in this study, individual $CO_2$ production unit (CPU), i.e. total produced $CO_2$ by treating a unit weight of sludge was also calculated. By using the CPU matrix of the unit processes, it was possible to simulate the $CO_2$ production for any type of complex-system as well as to trace a dominant cause of $CO_2$ production in each process. Four selected alternatives examined here, each involve the same disposal way but differ substantially in the $CO_2$ exhaust.