• 한국염색가공학회지
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• 제12권2호
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• pp.96-102
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• 2000

For the effective treatment of dyeing-complex wastewater, the most effective chemical coagulation method was studied. For the chemical coagulation of dyeing-complex wastewater, polyferric sulfate, $4Al_2(SO_4)_3$, PAC, ferrous sulfate, ferric sulfate, $FeCl_2$ and lime were used. It was investigated that polyferric sulfate was the most efficient coagulant. The optimal conditions and results for polyferric sulfate include the followings. When initial $COD_{Mn}$ concentration was 600mg/L, the optimal initial pH, dosage of coagulant, dosage of lime and PAA for $COD_{Mn}$ removal efficiency were 5, 1,200mg/L, 500mg/L and lmg/L, respectively. The optimal dosage of polyferric sulfate was increased proportionally to the influent $COD_{Mn}$ concentration.

• 상하수도학회지
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• 제26권5호
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• pp.713-721
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• 2012

강이나 호수로 유입되는 인(P)이 종종 부영양화의 가장 큰 제한요소로 작용한다. 그런데 하수처리장의 방류수가 자연수계에 인의 중요한 공급처로 작용하는 경우가 많기 때문에 하수처리장의 최종 처리수에서 인의 제거가 요구된다. 하수에서 인을 제거할 수 있는 많은 기술 중에서, 활성 칼슘-황토의 복합체를 이용한 흡착기술을 연구하였다. 칼슘을 황토에 첨가하여 인의 흡착 용량과 흡착강도를 증가시켰다. 칼슘을 첨가한 황토를 최적 온도로 밝혀진 $400^{\circ}C$의 고온에서 활성화시켰다. $400^{\circ}C$ 미만에서 활성화시킨 칼슘-황토는 하수처리 공정의 활성칼슘-황토 복합체를 이용한 처리조에 적용하기엔 강도가 부족하였다. 반면 $400^{\circ}C$ 초과 온도에서 활성화시킨 칼슘-황토 복합체는 복합체 표면이 유리화되어 흡착용량이 감소하였다. 활성칼슘-황토 복합체는 표면에 충분한 기공이 발달하지 못하여 인의 흡착용량에 한계는 있으나 칼슘을 첨가하였기 때문에 흡착강도는 높았다. 활성칼슘-황토는 입자형 복합체로 만들어졌다. 제조된 복합체를 흡착칼럼에 채워 하수처리공정에 적용하였다. 활성칼슘-황토의 복합체를 충진한 칼럼을 파일롯트 플랜트에 적용한 결과 0.5 mg/l의 인의 농도를 0.1 mg/l로 낮출 수 있었고, 이온성 인을 4개월의 운전기간 동안 완전하게 흡착시켜 제거할 수 있었다.

• 한국농공학회지
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• 제39권5호
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• pp.97-108
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• 1997

Natural wastewater treatment systems using the constructed wetland system were evaluated for the wastewater from the industrial complex in rural areas. For the treatment of wastewater from the industrial complex in rural area, a pilot plant of the constructed wetland system was installed at Baeksuk agri-industrial complex in ChunahnCity, Chunchungnam-Do. The experiment with this pilot plants was performed for 1996 and 1997. Results of the study were summarized as follows. For the BOD and COD, when the pollutant loading of them was about 1 3.8g/$m^2$. day (the concentration was l24.0mg/${\ell}$) arid 24.4g/$m^2$.day(the concentration was 220.Omg/${\ell}$), the removal rate of them was high, 90.2% and 93.4%, respectively. For the SS, the effluent concentration was consistently lower than the water quality standard even though the influent concentration varied significantly, which showed that SS was removed by the system effectively which consist of soil and plants. For the T-N and T-P, when the influent pollutant loading of them were moderately high, 2.8g/$m^2$.day to 7.4g/$m^2$. day(concentration 25.0mg/${\ell}$ to 49.7mg/${\ell}$) for T-N and 1.0g/$m^2$.day to 2.6g /$m^2$.day(concentration 8.6mg/${\ell}$ to 14.7mg/${\ell}$) for T-P, the removal rate of them were 86.5% and 94.0%, respectively. The removal rate by the flow distance increased rapidly in the first 4m from the inlet zone, and gradually there after. The width of system was 2m. Overall, the result showed that constructed wetland system is a feasible alternative for the treatment of wastewater from industrial complex in rural areas. Compared to existing systems, this system is quite competitive because it requires low capital cost, almost no energy and maintenance, and therefore, very cost effective.

• 한국환경보건학회지
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• 제32권5호
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• pp.446-450
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• 2006

In order to treat the wastewater containing organic compound, pre-treatment system connected with MSP(molecular separation process) was investigated. With the aim of selecting an optimum process of Fenton's oxidation, removal efficiency of each process in the optimum reaction condition was recommended. The $Fe/H_{2}O_{2}$(ferric sulfate to hydrogen peroxide)reagent is referred to as the Fenton's regent, which produces hydroxyl radicals by the interaction of Fe with $H_{2}O_{2}$. The powerful oxidizing ability and extreme kinetic reactively of the hydroxyl radical was well established. Increasing dosage of $Fe/H_{2}O_{2}$ increased removal efficiency as molar ratio of $Fe/H_{2}O_{2}$ between 0.2 and 2.5. Optimum dosage of molar ratio was 1. The removal efficiency for reaction condition was increased as pH decreased when the molar ratio of $Fe/H_{2}O_{2}$ was 1.7. Fenton's oxidation was most efficient in the reaction time 35 min for complex wastewater. Also, coagulation aid experiments using kaolin resulted in 3% of kaolin dosage.

• Bulletin of the Korean Chemical Society
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• 제25권12호
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• pp.1877-1880
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• 2004

The simple and convenient determination of trace Hg(II) with its 2-mercaptobenzothiazole (MBT) complex in cetyltrimethylammonium bromide (CTAB) media has been studied. The UV-visible spectrum of Hg(II)-MBT complex in CTAB media had a good sensitivity and reproducibility. The Hg(II)-MBT complex in CTAB solution was very stable at pH 10.0 and could be quantitatively complexed if MBT were added to the sample solution more than 10 equivalent of Hg(II). The optimum concentration of CTAB was 0.001%. The calibration curve of Hg(II)-MBT complex with good linearity ($R^2$ = 0.9985) was obtained at the concentration range between $1.0{\times}10^-7$ and $1.0{\times}10^-5$ M in 0.001% CTAB media. The detection limit was $3.1{\times}10^-8$ M (6.2 ng m$L^{-1}$). Hg(II) in the synthetic samples and in the wastewater of the university's wastewater tank and the industrial wastewater tank could also be determined. Based on the experimental results, this proposed technique could be applied to the simple and convenient determination of trace Hg(II) in real samples.

• 청정기술
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• 제17권2호
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• pp.175-180
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• 2011

생태산업단지의 산업 공생망 구성을 위한 다중척도 의사결정 전략을 개발하고 이를 여수산업단지의 산/염기성 폐수 중화망 설계에 적용하였다. 산(또는 염기)성 폐수는 화학산업에서 공통적으로 나오며, 다른 곳에서 나온 염기(또는 산)성 폐수를 자체적으로 중화할 수 있는 원료가 될 수 있다. 따라서 산/염기성 폐수가 대량으로 발생되는 석유화학산업단지에서 대규모의 산업 공생망을 구축할 수 있는 가능성을 지나고 있다. 본 연구에서는 산/염기성 폐수의 상호 중화를 위한 물질 흐름 모델을 구성하고, 여기에 다중척도의사결정 전략을 적용하여 최적이며 대등한 다수의 산업 공생망 후보를 설계하고 이들의 성능을 비교 분석하였다.

• 상하수도학회지
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• 제27권2호
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• pp.165-175
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• 2013

This study aims to analysis correlation in septic tank and sewer pipe between odor substances and complex odor. For the analysis, convert odor substances to odor intensity, and estimate the effect of odor substances on complex odor. As a result, both Hydrogen sulfide and Methyl mercaptane of specified offensive odor substances accounted for 29 percent of the effect of odor substances on complex odor. Hydrogen sulfide and Methyl mercaptane are major cause of odor from septic tank and sewer pipe. The result of this study is suggested to be used as a preliminary data for research on analysis complex odor and odor substances.

• Bulletin of the Korean Chemical Society
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• 제24권10호
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• pp.1444-1448
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• 2003

The microsurface adsorption - spectral correction (MSASC) technique has been applied to the interaction of indigo carmine (IC) with cetyltrimethylammonium bromide (CTAB). The aggregation of IC on CTAB obeys Langmuir isothermal adsorption. The results show that both the monomer complex $IC{\cdot}CTAB$ and the micellar complex $(IC{\cdot}CTAB)_{78}$ were formed. The binding constant of the monomer complex was calculated to be $K_{IC{\cdot}CTAB}$ = 2.20 ${\times}10^5L{\cdot}mol^{-1}$, and the molar absorptivity of the micellar complex was calculated to be ${\varepsilon}_{(IC{\cdot}CTAB)78}\;^{560nm}$ = 8.58 ${\times}10^5L{\cdot}mol^{-1}{\cdot}cm^{-1}$. The aggregation was applied to the determination of cationic surfactant in wastewater.

• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2002년도 생물공학의 동향 (X)
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• pp.359-360
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• 2002

1. TPA 제거능이 우수한 미생물을 개발하였으며 동정 결과 Corynebacterium sp. 로 판단되며 Corynebacterium sp. YT-14로 명명하였다. 2. TPA 제거를 위한 Corynebacterium sp. YT-14의 최적 배양온도는 $35^{\circ}C$ 였고, 최적 초기 pH는 pH 10이었다. 3. Stirred loop bioreator에 Corynebacterium sp. YT-14를 배양한 후 감량가공폐수와 종합염색폐수를 회분식으로 처리한 결과 감량가공폐수에서 처리 7일 후 TPA 제거효율이 85.4% 였으며, 종합염색폐수에서는 처리 3일 후 TPA가 검출되지 않았다.

• 한국지반환경공학회 논문집
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• 제16권3호
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• pp.35-39
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• 2015

Dowex 21K XLT 수지를 이용하여 산업폐수 내에 존재하는 금과 납-시안 착화합물에 대한 연속흡착 및 회수 특성을 조사하였다. 충전층에 충진된 Dowex 21K XLT 수지는 0.5mL/min의 유입유속에서 금-시안 착화합물을 520 bed volume까지 95% 이상 연속적으로 제거할 수 있지만, 납-시안 착화합물은 전혀 제거할 수 없었다. Dowex 21K XLT 수지에 흡착된 금-시안 착화합물은 HCl과 Acetone을 7:3의 비율로 섞은 혼합액을 탈착제로 이용하였을 때, 8 bed volume 내에서 96% 탈착되어졌다. 또한 두 번 재사용된 Dowex 21K XLT 수지의 금-시안 착화합물에 대한 bed volume이 490을 유지하여 향후 금 이온을 포함하고 있는 산업폐수 처리공정에 충분히 적용될 수 있을 것으로 판단된다.