• Journal of Microbiology and Biotechnology
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• 제20권10호
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• pp.1436-1439
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• 2010

Many studies have clarified that poly(${\gamma}$-glutamic acid) (PGA) increases the solubility of $Ca^{2+}$, suggesting that PGA enhances calcium absorption in the small intestine. However, there has been no report on the specific interaction between PGA and $Ca^{2+}$ in water. We studied the aqueous solution properties of PGA calcium salt (PGA-Ca complex). The chelating ability and binding strength of PGA for $Ca^{2+}$ were evaluated. The PGA-Ca complex was soluble in water, in contrast to the insolubility of poly(acrylic acid) (PAA) calcium salt, and the chelating ability of PGA for $Ca^{2+}$ was almost the same as that of PAA. The globular conformation of the PGA-Ca complex in water was estimated by SEC and viscosity measurements. The chelation ability of PGA for $Ca^{2+}$ was examined by $^1H$ NMR. The present study showing the characteristics of the PGA-Ca complex will provide useful information about the calcium absorption by PGA in vivo.

• Macromolecular Research
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• 제14권3호
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• pp.267-271
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• 2006

Polyelectrolyte complex films were prepared with two compounds, chitosan and poly(ethylene glycol)-monosuccinate, using a casting in order to synthesize a polyelectrolyte complex film with various mole ratios of chitosan and poly(ethylene glycol)-monosuccinate. The solution properties of isolated PEC were investigated for the effects of FTIR, pH value, Brookfield viscosity and cell viability assay using MTT staining. The PEC films were evaluated for mechanical properties by typical stress-strain curve, far thermal properties by DSC and TGA and for surface morphology Properties by SEM. Furthermore, the surface resistance, moisture regain and water content of the films were characterized. The solution properties were affected by several factors including the chitosan content in the PEC, the mixing ratio of PEG and chitosan, and pH. Several PEC in acidic conditions exhibited film formation under appropriate conditions of mixing ratio and chitosan concentration in the mixing process. These PEC films were found to have sufficiently flexible and stable properties due to their hydrophilic structure, which was farmed by the oppositely charged interaction between PEG-MS and chitosan matrix. The results showed the potential applicability of chitosan and poly(ethylene glycol)-monosuccinate films as a biocompatible polymer.

• Bulletin of the Korean Chemical Society
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• 제7권3호
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• pp.238-240
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• 1986

Complex formations between syndiotactic poly(methacrylic acid) (st-PMAA) and poly(N-vinyl pyrrolidone) (PVP), and that between st-PMAA and polyethyleneoxide (PEO) through hydrogen bonding were studied by viscometry and potentiometry. Reduced viscosity (${\eta}_{red}$) was measured at various mole fraction of PVP or PEO with respect to a constant amount of st-PMAA. Observation shows a sharp minimum at the 1:1 mole ratio of st-PMAA:PVP or st-PMAA:PEO, which shows that the complexation becomes optimal and the complex has a compact structure in this ratio. Variation of pH also supports this conclusion. This is the case of the system of st-PMAA and PVP in water as well as in DMF. Also the complexation is much enhanced when the molecular weight of PVP is high. Meanwhile, the system of st-PMAA and PEO shows a little different behavior, i.e., this system does not form the complex in DMF and does only in water. It is because the interaction st-PMAA with PEO is weaker than that with PVP.

• 전기학회논문지
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• 제60권5호
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• pp.1030-1035
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• 2011

The remote control of mobile robot is widely used to perform dangerous and complex tasks such as underwater exploration and cleaning of nuclear reactor. For this purpose, the obstacle avoidance process will proceed to ensure a safe drive. In this paper, we tested that mobile robot drive in which replaced a pipe with a box. After we measured the distance around the obstacle through a sensor of robot, we got the information that changed haptic force from the distance of the obstacle.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2002년도 학술대회지
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• pp.791-794
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• 2002

Cavity is inevitably included in automobile vehicle configuration. The complex unsteady flow and sound waves generated by the cavity are very important issues because of the involved fluid dynamics and the practical importance in the field of aerodynamics. The LES method used is a conventional one with Smagorinsky eddy-viscosity model and the computational grid is small enough to be handled by workstation-level computers. LES can successfully simulate of cavity noise analysis.

• The Journal of the Acoustical Society of Korea
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• 제21권1E호
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• pp.42-48
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• 2002

In this paper, a computer simulation method is presented far the dynamic analysis of a hydraulic engine mount system. The hydraulic engine mount system controls the damping characteristics using the viscosity of fluid flow. The complex stiffnesses of the main rubber for the hydraulic engine mount system are computed using a finite element analysis. The equations of motion considering the parameters of the hydraulic engine mount system are derived. To investigate the effects of the hydraulic engine mount system, the computer simulation running over a typical rough road is carried out using a vehicle dynamic model. These results are compared with those of the conventional rubber mount system.

• 소음진동
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• 제9권1호
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• pp.42-48
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• 1999

In this paper, a computer simulation method for dynamic analysis of the hydraulic engine mount system is proposed. The hydraulic engine mount system controls the damping characteristics using the viscosity of fluid flow The complex stiffness of the main rubber of the hydraulic engine mount system is computed by finite element analysis for the viscoelastic materials and hydro-static elements. A numerical analysis method is presented to solve nonlinear equations of the hydraulic engine mount system. which is composed of an engine mass, fluid in inertia track and a vertical inertia force of reciprocating mass in the engine. Also. dynamic properties of the hydraulic engine mount system are analyzed in the frequency domain. Effects of the hydraulic engine mount system running over the rough road are investigated using a vehicle dynamic model. These results are compared with those of the rubber mount system.

• Carbon letters
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• 제10권2호
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• pp.109-113
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• 2009

Various silanes, amino silane, vinyl silane, TESPD, and ZS (TESPD/zinc soap complex), are added into chlorinated isobutylene-isoprene copolymer (CIIR)/soft clay/carbon black (CB). The vulcanization characteristics, the processability, and the mechanical properties are measured. In soft clay/CB filled CIIR system, there are no significant changes in Mooney viscosity among compounds. Vinyl silane added compound shows a low extrusion torque. All the silane added compounds shows an increased modulus. The mechanical properties are significantly increased when the S2 is added into CIIR/soft clay/CB compounds.

• Korea-Australia Rheology Journal
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• 제20권3호
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• pp.117-125
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• 2008

Viscoelastic instabilities are of fundamental importance to understanding the physics of complex fluids and of practical importance to materials processing and fluid characterization. Significant progress has been made over the past 15 years in understanding instabilities in viscoelastic flows with curved streamlines and is reviewed here. Taylor-Couette flow, torsional flow between a cone and plate, and torsional flow between parallel plates have received special attention due to both the basic significance of these flows and their critical role in rheometry. First, we review the criteria for determining when these flows become unstable due to elasticity in the absence of inertia, and discuss the generalization of these criteria to more complex flows with curved streamlines. Then, focusing on experiments and simulations in the Taylor-Couette problem, we review how thermal sensitivity (i.e., the dependence of fluid viscosity and elasticity on temperature) and inertia affect the stability of viscoelastic flows. Finally, we conclude with some general thoughts on unresolved issues and remaining challenges related to viscoelastic instabilities.

• 한국식품조리과학회지
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• 제8권3호
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• pp.255-263
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• 1992

Pasting characteristics and amylose-surfactant complex forming ability of sweet potato starch were investigated after defatting and the addition of surfactants, such as SSL (sodium steamyl-2-lactylate) Dimodan (mono/di glyceride) and SE (sucrose ester) with different concentrations. All starch granules were smooth and round, there were no damages to starch granules after defatting and surfactant addition. amylose content of surfactant added stach decreased and me order of decrease was SSL, SE and Dimodan. The cornplex forming ability of SE added starch increased according to increasing HLB value. As surfactants concentration increased, amylose complex formig ability increased. In case of gelatinization patterns by amylograph, the initial pasting temperature of surfactant added starches was higher than mat of untreated or defatted starches, but viscosity at each temperature were all decreased. Soluble carbohydrate and leached amylose of starches increased at increasing temperature, those of surfactant added starches decreased at each temperature in the order of SSL, SE and Dimodan.