• Bulletin of the Korean Chemical Society
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• 제24권10호
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• pp.1495-1500
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• 2003

Equilibria and applications of a synergistic extraction were studied for the determination of a trace lithium by using thenoyltrifluoroacetone (TTA) and trioctylphosphine oxide (TOPO) as ligands. Several equations were derived for the extraction of lithium into m-xylene as a phase of Li-TTA·mTOPO adduct. Distribution coefficients and extraction constant were determined together with a stability constant of the adduct. The adduct was quantitatively extracted from the basic solution of higher than pH 9 by shaking for 30 minutes. m-Xylene was selected as an optimum solvent by comparing the extraction efficiency among several kinds of organic solvents. The stability constant (${\Beta}_2$) for Li-TTA/2TOPO was 150 times higher than Li-TTA/TOPO. The distribution coefficient of Li-TTA/2TOPO into m-xylene was 9.12 and the logarithmic extraction constant (log $K_{ex}$) was 6.76. Trace lithium of sub-ppm level in seawater samples could be determined under modified conditions and a detection limit equivalent to 3 times standard deviation for background absorption was 0.42 ng/mL.

• 한국물환경학회지
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• 제16권4호
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• pp.421-430
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• 2000

To study the distribution and the behavior of trace metals in Kwangyang Bay, surface water samples were collected four times from August 1997 to May 1998 and were analyzed for trace metals (Cd, Co, Cu, Fe, Ni, Pb, Zn) by Atomic Absorption Spectrometer and Inductively Coupled Plasma Mass Spectrometer. Dissolved Co and Fe concentrations were comparatively high near the Seomjin River mouth. Particulate trace metal contents were relatively high near the Sueochun River mouth and near the Yeochun industrial complex. Distribution coefficients ($K_d$; $Lkg^1$) between dissolved and particulate phases of Fe, Pb, Co, Zn, Ni, Cu and Cd were $1.67{\times}10^8$, $1.37{\times}10^6$, $7.25{\times}10^5$, $4.43{\times}10^5$, $1.39{\times}10^5$, $9.1{\times}10^4$ and $1.8{\times}10^4$, respectively. In Kwangyang Bay, particulate trace-metal concentrations were as high as dissolved ones and showed seasonal and geographic variations.

• 한국수산과학회지
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• 제46권5호
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• pp.638-648
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• 2013

To understand the geochemical characteristics of intertidal sediment in a semi-enclosed bay, we measured various geochemical parameters, including grain size, ignition loss (IL), chemical oxygen demand (COD), acid volatile sulfide (AVS), and trace metals (Al, Fe, Cu, Pb, Zn, Cd, Hg, and As), in intertidal sediment from three bays (Deukryang Bay, Yeoja Bay, and Gamak Bay) in the southern region of Jeollanam Province. The intertidal sediment in Deukryang Bay consisted of various sedimentary types, such as sand, gravelly muddy sand, mud, and silt, whereas the intertidal sediments in Yeoja and Gamak Bays were composed mainly of mud. The concentrations of IL, COD, AVS and trace metals in the intertidal sediments of the three study regions were relatively high near areas affected by input of stream waters and/or shellfish farming waste. The concentrations of organic matter and trace metals in Gamak Bay were much higher than those in Deukryang and Yeoja Bays, which appears to be due to the influence of anthropogenic pollutants, originating from the city and the industrial complex near Gamak Bay. The evaluation results of organic matter and metal pollution using the sediment quality guidelines showed that the intertidal sediments in the three study regions were not polluted in terms of organic matter and trace metals. In future, sustainable management for sources of organic matter and trace metal is necessary to conserve a healthy benthic ecosystem in intertidal sediments.

• 암석학회지
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• 제2권1호
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• pp.41-52
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• 1993

We report adventages of employing MgO as a differentiation index for the Namwon granitic complex. It is shown to be much more sensitive than the usual Harker index. The complex can be divided into two groups on the basis of $TiO_2$/MgO ratio. The low $TiO_2$/MgO group consists of hornblende biotite tonalite-granodiorite, porphyritic hornblende biotite granodiorite (PHBGd) and part of biotite granite (loBG). PHBGd shows its own distinct variation in the low group. This group is characterized in most cases by the presence of hornblende, even if it occurs as a trace amount. The high $TiO_2$/MgO group consists of part of biotite granite (hiBG) and two mica granite. The major element differences between rock types are also apparent in biotite chemistry. These chemical data indicate that at least two distinct origins of magma are rquired for the complex. Two kinds of biotite granite revealed in this study show distinct geographic distribution, suggesting that a new geologic map should be made.

• Bulletin of the Korean Chemical Society
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• 제21권11호
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• pp.1090-1094
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• 2000

A reaction between germanium (Ge) and the ligand, o-chlorophenylfluorone (o-CPF) has been carried out. The reaction sensitive at pH 4.5 in the presence of triton x-100 was selective in the presence of EDTA. The spectral correction technique was ap plied to the analysis of the reaction instead of single wavelength spectrophotometry because the absorption of excess of o-CPF was not negligible. An updated determination of the properties of the Ge(IV)-o-CPF complex is given, which involved the complex ratio, stepwise absorptivity and stability constant of the complex. In present work, the results show that the complex $Ge(o-CPF)_3was$ formed and its cumulative stability constant was 1.09 ${\times}$1016 . For sample analysis, the detection limit of germanium was 0.01 mg/L, and the recoveries were between 96.4% and 102%, with relative standard deviations of less than 6.5%.

• 한국정보과학회논문지:컴퓨팅의 실제 및 레터
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• 제9권2호
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• pp.166-181
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• 2003

최근 인터넷의 급속한 성장으로 Web TV, PDA 및 Web phone과 같은 장치들이 인터넷에 연결되기 시작하고 있다. 그러나, 이러한 장치들은 복잡한 실시간 응용 시스템을 지원하기 위해 RTOS와 같은 실시간 운영체제가 필요로 하게 되었으며, 특히, 내장형 인터넷 응용 시스템을 개발하기 위한 디버거 등과 같은 적절한 도구들의 부족으로 개발하는데 어려움을 겪고 있다. 이에, 본 논문에서는 Qplus-T 실시간 운영 체제 내장형 시스템을 위한 새로운 트레이스포인트 디버깅 도구를 제안하다. 이 도구는 타이밍 트레이스포인트들을 이용하여 실시간 응용 소프트웨어의 디버깅을 쉽게 한다. 전통적인 브레이크포인트 디버거에 비해, 이 트레이스포인트 디버거는 온라인 및 오프라인 분석을 위해 응용 프로그램의 데이터를 동적으로 수집하고 기록하는 기능을 제공한다. 그리고, 응용프로그램의 실행을 멈추거나 원래의 실행 속도에 참견이 거의 없이 실행중인 응용프로그램의 변수들에 새로운 값을 할당해 보기 위한 수단으로도 제공된다. 본 논문에서 제시하는 트레이스포인트 디버거는 Qplus-T 인터넷 응용프로그램과 같은 타겟 실시간 응용 프로그램에 수많은 모니터링 트레이스포인트들을 추가하기 위한 효과적인 방법을 제공하며, 실행 중에 응용프로 그램의 행위를 모니터하고 분석하기 위한 트레이스포인트를 설정할 수 있다. 또한, RTL(Real-Time Logic) 표현을 이용하여 타이밍 문제를 명세화하고 검출할 수 있어 기존 트레이스포인트 디버거와는 다르다.

• 암석학회지
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• 제2권2호
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• pp.130-138
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• 1993

주로 연대측정이 어려운 변성최적암류로 이루어진 선캠브리아의 경기육괴에 대해 정량적 연대측정 방법을 개발하기 위하여 대리암에 대한 연대측정법의 적용 가능성에 대해 연구하였다. 이 지역의 대리암은 대부분 규산염 광물을 함유하고 있으므로 염산을 사용한 선별용해 실험을 하였다. 미량원소 분석결과 Zr과 Rb은 거의 대부분 잔류물에 함유되어 있으며 U도 염산용해 부분보다는 잔류물에 많이 포함되어 있음을 알 수 있었다. 또한 Pb, Sr, Sm, Nd은 양쪽에 비슷하게 포함되며 Th은 다소 복잡한 양상을 보인다. 선별용해에 의한 Sr 동위원소 분석시에는 Sr 동위원소비가 높은 규산염 광물의 영향을 쉽게 영향을 받기 때문에 많은 주의와 연구가 요구된다. 탄산염 광물로만 구성된 순수한 대리암 시료를 골라 여러 조각으로 나눈 후 각각에 대해 분석된 Pb 동위원소비로부터 연대를 구하는 방법이 Sr 동위원소 분석에 의한 연대측정보다 성공 가능성이 높은 연대측정법으로 판단된다.

• 한국주거학회논문집
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• 제12권3호
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• pp.1-12
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• 2001

The purpose of this study was to investigate the outdoor space of the recent built apartment complex in Ulsan and to provide the basic information for planning and apartment outdoor space. Multiple methods were utilized such as questionnaire, observation, behavior-mapping, and photography. The sample consisted of 382 residents living in four apartment complex in Ulsan. data were analyzed by frequency and percentage using SPSS PC+. The observation was performed in seven outdoor space, i.e., green area, road area, exercise area, play area, parking area, and approach area. According to the findings of this study, residents did not actively involve in outdoor activities and seldom use the outdoor space. Various changes and erosions were observed as a trace, especially near fence and grass area because of unplanned location of entrances. Finally this study suggested several planning guidelines for outdoor space in apartment complex.

• 한국광물학회지
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• 제11권1호
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• pp.20-31
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• 1998

Adsorption of metal elements onto illite and halloysite was investigated at $25^{\circ}C$ using pollutant water collected from the gold-bearing metal mine. Incipient solution of pH 3.19 was reacted with clay minerals as a function of time: 10 minute, 30 minute, 1 hour, 12 hour, 24 hour, 1 day, 2 day, 1 week, and 2 week. Twenty-seven cations and six anions from solutions were analyzed by AAs (atomic absorption spectrometer), ICP(induced-coupled plasma), and IC (ion chromatography). Speciation and saturation index of solutions were calculated by WATEQ4F and MINTEQA2 codes, indicating that most of metal ions exist as free ions and that there is little difference in chemical species and relative abundances between initial solution and reacted solutions. The adsorption results showed that the adsorption extent of elements varies depending on mineral types and reaction time. As for illite, adsorption after 1 hour-reaction occurs in the order of As>Pb>Ge>Li>Co, Pb, Cr, Ba>Cs for trace elements and Fe>K>Na>Mn>Al>Ca>Si for major elements, respectively. As for halloysite, adsorption after 1 hour-reaction occurs in the order of Cu>Pb>Li>Ge>Cr>Zn>As>Ba>Ti>Cd>Co for trace elements and Fe>K>Mn>Ca>Al>Na>Si for major elements, respectively. After 2 week-reaction, the adsorption occurs in the order of Cu>As>Zn>Li>Ge>Co>Ti>Ba>Ni>Pb>Cr>Cd>Se for trace elements and Fe>K>Mn>Al, Mg>Ca>Na, Si for major elements, respectively. No significant adsorption as well as selectivity was found for anions. Although halloysite has a 1:1 layer structure, its capacity of adsorption is greater than that of illite with 2:1 structure, probably due to its peculiar mineralogical characteristics. According to FTIR (Fourier transform infrared spectroscopy) results, there was no shift in the OH-stretching bond for illite, but the ν1 bond at 3695 cm-1 for halloysite was found to be stronger. In the viewpoint of adsorption, illite is characterized by an inner-sphere complex, whereas halloysite by an outer-sphere complex, respectively. Initial ion activity and dissociation constant of metal elements are regarded as the main factors that control the adsorption behaviors in a natural system containing multicomponents at the acidic condition.

• 지구물리와물리탐사
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• 제2권1호
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• pp.33-42
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• 1999

천연가스 저류층의 부존 특성을 파악하는데 주로 이용되고 있는 AVO 및 복소분석법을 파쇄대와 같은 지반환경의 주요 불연속면에 적용하는데 그 초점을 두었다. 연구에 이용된 시험자료는 수평 파쇄구조에 대하여 일반화된 맥스웰체 근사법을 적용한 점탄성매질에서의 수치모형자료이다. 수평 파쇄구조에 대한 AVO분석에서 반사 P파의 특성은 지하매질의 음향 임피던스 차이와 기하학적 계수인 오프셋에 따라 다양하게 나타나며 구배중합 단면도 및 오프셋조절 중합단면도에서 효과적으로 해석되는데, 입사각이 커질수록 진폭이 감쇠되는 특성을 보인다. 중합자료에 대한 복소트레이스 플롯(순간진폭, 순간주파수, 순간위상)에서 파쇄대의 상$\cdot$하부 경계는 강한 진폭과 동일한 위상으로 특징 지워지며, 파쇄대 구간 및 직하부는 저주파 특성을 보인다. 파쇄대와 주위 매질의 Q-대비에 따라 다르게 나타나는 진폭감쇠와 파형분산은 역 Q-필터링으로 효과적으로 보상되었다.