• Journal of the Korean Chemical Society
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• v.34 no.6
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• pp.582-592
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• 1990

Retention behavior of lanthanide-$\alpha$HiBA complexes was studied on the cation exchanger (LC-18 coated with $C_{20}H_{41}SO_4^-$). An equation predicting retention of lanthanides in isocratic or gradient elution with sodium ion and $\alpha$-HiBA concentration was derived from ion exchange equilibria of metal-ligand complex system, respectively. The relations between log k' and log [Na$^+$] /log [$\alpha$-HiBA) showed non-linearity in isocratic elution. In gradient elution a good linearity between log k' vs log R was obtained. The values of slopes (log k / log R) gave good agreements between calculation and experiment. Individual capacity factors ($k'_{Ln}^{3+}, k'_{LnL}^{2+}, k'{LnL2+}) and stability constant (${\beta}_1$, ${\beta}_2$, ${\beta}_3$) of lanthanide-$\alpha$HiBA complexes were calculated by the non-linear least square fittings using the retention equation. The correlation coefficients of lanthanides were shown better than 0.9996 between experiment and calculation.

• Computers and Concrete
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• v.6 no.1
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• pp.41-57
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• 2009

This paper presents the details of a novel external prestressing technique for strengthening of concrete members. In the proposed technique, transfer of external force is in shear mode on the end block thus creating a complex stress distribution and the required transverse prestressing force is lesser compared to conventional techniques. Steel brackets are provided on either side of the end block for transferring external prestressing force and these are connected to the anchor blocks by expansion type anchor bolts. In order to validate the technique, an experimental investigation has been carried out on post-tensioned end blocks. Performance of the end blocks have been studied for design, cracking and ultimate loads. Slip and slope of steel bracket have been recorded at various stages during the experiment. Finite element analysis has been carried out by simulating the test conditions and the responses have been compared. From the analysis, it has been observed that the computed slope and slip of the steel bracket are in good agreement with the corresponding experimental observations. A simplified analytical model has been proposed to compute load-deformation of the loaded steel bracket with respect to the end block. Yield and ultimate loads have been arrived at based on force/moment equilibrium equations at critical sections. Deformation analysis has been carried out based on the assumption that the ratio of axial deformation to vertical deformation of anchor bolt would follow the same ratio at the corresponding forces such as yield and ultimate. It is observed that the computed forces, slip and slopes are in good agreement with the corresponding experimental observations.

• Korean Journal of Agricultural and Forest Meteorology
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• v.11 no.1
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• pp.13-18
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• 2009

Accurate solar radiation data are critical to evaluate major physiological responses of plants. For most upland crops and orchard plants growing in complex terrain, however, it is not easy for farmers or agronomists to access solar irradiance data. Here we suggest a simple method using a sun-slope geometry based topographical coefficient to estimate daily solar irradiance on any sloping surfaces from global solar radiation measured at a nearby weather station. An hourly solar irradiance ratio ($W_i$) between sloping and horizontal surface is defined as multiplication of the relative solar intensity($k_i$) and the slope irradiance ratio($r_i$) at an hourly interval. The $k_i$ is the ratio of hourly solar radiation to the 24 hour cumulative radiation on a horizontal surface under clear sky conditions. The $r_i$ is the ratio of clear sky radiation on a given slope to that on a horizontal reference. Daily coefficient for slope correction is simply the sum of $W_i$ on each date. We calculated daily solar irradiance at 8 side slope locations circumventing a cone-shaped parasitic volcano(c.a., 570m diameter for the bottom circle and 90m bottom-to-top height) by multiplying these coefficients to the global solar radiation measured horizontally. Comparison with the measured slope irradiance from April 2007 to March 2008 resulted in the root mean square error(RMSE) of $1.61MJ\;m^{-2}$ for the whole period but the RMSE for April to October(i.e., major cropping season in Korea) was much lower and satisfied the 5% error tolerance for radiation measurement. The RMSE was smallest in October regardless of slope aspect, and the aspect dependent variation of RMSE was greatest in November. Annual variation in RMSE was greatest on north and south facing slopes, followed by southwest, southeast, and northwest slopes in decreasing order. Once the coefficients are prepared, global solar radiation data from nearby stations can be easily converted to the solar irradiance map at landscape scales with the operational reliability in cropping season.

• The Journal of Engineering Geology
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• v.23 no.2
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• pp.149-160
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• 2013

Volcanic activity commonly creates a highly complicated volcanic complex due to the admixture of lava flow and sedimentation of volcanic ash. The Song-Gok site is composed of volcanic rocks that collapsed at the lower part of the slope, in combination with several discontinuities in and around a fault. The results of projection analysis indicated the possibility of plane, wedge, and toppling failure in the failure section. The results of discontinuity modeling using the Distinct Element Method (DEM) revealed a total displacement of 207 mm and a joint shear displacement of 114 mm. The yield surface zone was verified at the fault plane of the failure section. In geotechnical terms, volcanic rock slopes are characteristically vulnerable to failure because of differential weathering among the various rock types, the effect of groundwater based on the permeability of the rocks, and the presence of systematic joints generated by the cooling and contraction of lava. When considering the stability of a volcanic rock slope, it is necessary to consider data such as the geological features of the rock, as obtained through detailed geological survey, and variations in discontinuities and rock blocks.

• Korean Journal of Agricultural and Forest Meteorology
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• v.17 no.4
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• pp.317-325
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• 2015

An adequate downscaling of synoptic forecasts is a prerequisite for improved agrometeorological service to rural areas in South Korea where complex terrains and small farms are common. In this study, geospatial schemes based on topoclimatology were used to scale down the Korea Meteorological Administration (KMA) temperature forecasts to the local scale (~30 m) across a rural catchment. Then, using these schemes, local temperatures were estimated at 14 validation sites at 0600 and 1500 LST in 2013/2014 and were compared with the observations. The estimation errors were substantially reduced for both 0600 and 1500 LST temperatures when compared against the uncorrected KMA products. The improvement was most notable at low lying locations for the 0600 temperature and at the locations on west- and south-facing slopes for the 1500 LST temperature. Using the downscaled real-time temperature data, a pilot service has started to provide the field-specific weather information tailored to meet the requirements of small-scale farms. For example, the service system makes a daily outlook on the phenology of crop species grown in a given field using the field-specific temperature data. When the temperature forecast is given for next morning, a frost risk index is calculated according to a known relationship of phenology and frost injury. If the calculated index is higher than a pre-defined threshold, a warning is issued and delivered to the grower's cellular phone with relevant countermeasures to help protect crops against frost damage.

• Korean Journal of Agricultural and Forest Meteorology
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• v.10 no.1
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• pp.25-31
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• 2008

Information on daily maximum air temperature is important in predicting the status of plants and insects, but the uneven and sparse distribution of weather stations prohibits timely access to the data in regions with complex topography. Since cumulative solar irradiance plays a critical role in determining daily maximum temperature on any sloping surfaces, derivation of a quantitative relationship between cumulative solar irradiance and the resultant daily maximum temperature is a prerequisite to development of such estimation models. Air temperatures at 8 sideslope locations with similar elevation and slope angle but aspect, circumventing a cone-shaped, grass-covered parasitic volcano (c.a., 570 m diameter for the bottom circle and 90m bottom-to-top height), were measured from June to December in 2007. Daily maximum temperatures from each location were compared with the average of 8 locations (assumed to be the temperature measured at a "horizontal reference" position). The temperature deviation at all locations increased with the day of year (or sun elevation) from summer solstice to winter solstice. Averaged over the entire period, the south facing location was warmer by $1^{\circ}C$ in daily maximum temperature than "horizontal reference" and the north facing location was cooler by $0.8^{\circ}C$ than the reference, resulting in the year round average south-north temperature difference of $1.8^{\circ}C$. In November, both south and north facing slopes showed the greatest deviation of $+2.0^{\circ}C$ and $-1.3^{\circ}C$, respectively in daily maximum temperature at monthly scale. On a daily scale, the greatest deviation was +3.8 and $2.7^{\circ}C$ at the south and north slope, respectively. The cumulative solar irradiance (on the slope for 4 hours from 11:00 to 15:00 TST) explained >60% of the variance in daily maximum temperature deviations among 8 locations, suggesting a feasibility of developing an estimation model for daily maximum temperature over complex topography at landscape scales.

• Korean Journal of Agricultural and Forest Meteorology
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• v.26 no.3
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• pp.161-173
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• 2024

In South Korea, 50-65% of the annual precipitation is concentrated during the summer monsoon season, which is called Changma. In 2023, extreme precipitation was observed during Changma period, and was recorded the highest amount in southern part of Korea. Extreme precipitation in forest region is one of significant factors related to the landslide. Therefore, accurate monitoring and understanding of precipitation patterns are crucial for preventing the landslide disasters in Changma period. This study investigated the precipitation patterns including precipitation intensity, duration, and total amount in mountainous and non-mountainous regions during the Changma period using dataset observed from the Korea Forest Service's Automatic Mountain Meteorology Observation Station (AMOS) and the Korea Meteorological Administration (KMA). Precipitation map produced from the Modified Korean-Parameter elevation Regressions an Independent Slopes Model (MK-PRISM) was also used to verify precipitation patterns in areas affected by landslides in Gyeongsangbuk-do province. The results used from precipitation observations revealed that the total amount of precipitation was greater at elevations such as mountainous regions. In particular, extreme precipitation events such as precipitation duration exceeding 50 hours with amount of over 300 mm and heavy rainfalls of over 30 mm/hr occurred at landslide areas including Mungyeong, Bonghwa, and Yeongju in Gyeongsangbuk-do province. Total amount of precipitation produced by MK-PRISM in these areas during Changma period were more than double compared with 30 years mean values obtained from KMA. The results conducted in this study indicate that it is essential to establish the thresolds considering recent precipitation patterns to effectively prepare and prevent for landslide disasters.

• Applied Chemistry for Engineering
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• v.26 no.3
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• pp.336-340
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• 2015

Three different types of polycarbonate (PC)/graphene oxide (GO) composites using diphenyl carbonate as a monomer were fabricated by melt polymerization. Those were the PC/GO composite (PC/GO) using a twin extruder, in-situ PC/GO composite (PC/GO-cat.) using a catalyst, and in-situ PC/GO composite (PC/GO-COCl) using a GO-COCl treated by -COCl, Chemical structures of the composites were confirmed by C-H and C=O stretching peak at $3000cm^{-1}$ and $1750cm^{-1}$, respectively. The slope for the storage (G') versus loss (G") modulus plot decreased with an increase in the heterogeneous property of polymer melts. So we can check the GO dispersion of the PC/GO composites using by the slop for G'-G" plot. According to the G'- G" slopes for three different types of PC/GO composites, GO was well dispersed within PC matrix in case of PC/GO and PC/GO-cat.. It was also confirmed by atomic force microscope (AFM) photos. One of the reasons for the poor GO dispersion of PC/GO-COCl is branching and crosslinking processes occurred during polymerization, which was further confirmed by a plot for the complex modulus versus phase difference.

• Journal of Korea Water Resources Association
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• v.44 no.10
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• pp.819-830
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• 2011

The multi-slope MUSCL, proposed by T. Buffard and S. Clain, determines slopes of conserved variables at each edge of a cell in the linear reconstructions of data. In this study, the second order accurate numerical model was developed according to the multi-slope MUSCL to solve the shallow water equations on the unstructured grids. The HLLL scheme of approximate Riemann solvers was used to calculate fluxes. For the review of the applicability of the developed model, the results of the model were compared to the 'isolated building test' and the 'model city flooding experiment' conducted as part of the IMPACT (Investigation of extreMe flood Processes And unCerTainty) project in Europe. There were limitations to predict abrupt rising of water depths by the resistance of model buildings and water depths at the specific locations among the buildings. But they were identified as the same problems also revealed in results of the other models to the same experiment. On the more refined meshes to the 'model city flooding experiment' simulated results showed good agreement with measurements. It was verified that the developed model simulated well the complex phenomena such as a dam-break problem and the urban inundation by flash floods.

• Journal of the Korean Geotechnical Society
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• v.30 no.4
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• pp.35-45
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• 2014

Limit equilibrium methods of slope stability analysis have been widely adopted mainly due to their simplicity and applicability. However, the conventional methods may not give reliable and convincing results for various geological conditions such as nonhomogeneous and anisotropic soils. Also, they do not take into account soil slope history nor the initial state of stress, for example excavation or fill placement. In contrast to the limit equilibrium analysis, the analysis of deformation and stress distribution by finite element method can deal with the complex loading sequence and the growth of inelastic zone with time. This paper proposes a technique to determine the critical slip surface as well as to calculate the factor of safety for shallow failure on partially saturated soil slope. Based on the effective stress field in finite element analysis, all stresses are estimated at each Gaussian point of elements. The search strategy for a noncircular critical slip surface along weak points is appropriate for rainfall-induced shallow slope failure. The change of unit weight by seepage force has an effect on the horizontal and vertical displacements on the soil slope. The Drucker-Prager failure criterion was adopted for stress-strain relation to calculate coupling hydraulic and mechanical behavior of the partially saturated soil slope.