• Analytical Science and Technology
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• v.6 no.5
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• pp.471-477
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• 1993

The novel macrocylic ligand {(4, 5):(13, 14)-dibenzo-6, 9, 12-trioxa-3, 15, 21, -triazabicyclo [15. 3. 1]heneicosa-(1, 17, 19)(18, 20, 21) triene: HDBPDA} was synthesized, and protonable constants of the ligand and the complex stability constants with alkali metals alkaline earth metals were determined. We evaluated the resolution factor(${\Delta}$) from equation that inducing from stability constants(pK). Also, this ligand was grafted on chloromethylated styrene-divinyl benzene(Merrifield resin) for HDBPDA, ion exchanger. Alkali and alkaline earth metal ions were separated using water by the column chromatography with this ion exchanger. Selectivity(${\alpha}$) and resolution(Rs) of alkali and alkaline earth metal ions were measured from the elution curves chromatogram. The selectivity and resolution values of the various ions calculated from the elution curves were compared with those abtained from pK values. The results were in a good agreement between tow methods. Ion exchange capacity of the resin were determined using the alkali and alkaline earth metal ions and pH dependence of capacity was also discussed.

• Applied Chemistry for Engineering
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• v.9 no.2
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• pp.232-237
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• 1998

This study was carried out to find the optimal operating conditions for separation of residual uranium from the simulated radwaste solution containing 19 elements, and to evaluate the validity of the process. The selected process was based on the solvent extraction with TBP(tributyl phosphate). As an extractor, two miniature mixer-settlers with a total of 18 stages were used. Extraction yield of U, Np and Tc was about 99.2%. 32.1%, and 99.9%, respectively. The other elements were coextracted in the range of 1~4%. Extraction yield of U exceeded those of the previous work performed with batch system, which resulted in the low extractability of U (about 80%) according to the coexisting element such as Nd and Fe. It was due to the characteristics of multi-stage extractor. On the other hand, low extractability of Np was caused by various oxidation states in the nitric acid medium. In the case of Tc, its high extractability may be attributed to the complex formation with Zr and U, which is not well proved yet. All elements extracted with TBP were stripped into aqueous phase more than 99% by 0.01M $HNO_3$. From the results, this process has no problem with respect to in the same step was required, because Np was distributed in the raffinate and U product, respectively.

• Journal of the Korean Geotechnical Society
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• v.27 no.5
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• pp.85-92
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• 2011

The dynamic behavior of piles becomes very complex due to soil-pile dynamic interaction, soil non-linearity, resonance phenomena of soil-pile system and so on. Therefore, the proper numerical simulation of the pile behavior needs much effort and calculation time. In this research, a new modeling method, which can be applied to the conventional finite difference analysis program FLAC 3D, was developed to reduce the calculation time. The soil domain in this method is divided into a near-field region and a far-field region, which is not influenced by the soil-pile dynamic interaction. Then, the ground motion of the far-field is applied to the boundaries of the near-field instead of modeling the far-field region as finite meshes. In addition, the soil non-linearity behavior is modeled by using the hysteretic damping model, which determines the soil tangent modulus as a function of shear strain and the interface element was applied to simulate the separation and slip between the soil and pile. The proposed method reduced the calculation time by as much as one third compared with a usual modeling method and maintained the accuracy of the calculated results. The calculated results by the proposed method showed a good agreement with the prototype pile behavior, which was obtained by applying a similitude law to the 1-g shaking table test results.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.13 no.2
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• pp.173-182
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• 1993

This paper presents an algorithm to derive the representative unit hydrograph for the real environment of a watershed. For a given watershed, the conventional methods give several different unit hydrographs by storm events. In this study the LP model is somewhat modified based on the previous study by Mays et also as follows: the objective function is designed to minimize the sum of weighted residuals. An additional constraint of moving average is added to prevent the unit hydrograph from the occurence of oscillation which was not active in Mays's paper. Configuration of rainfall matrix was improved to reduce its dimension in accordance with Diskin's review point. In spite of the superiority of LP approach in terms of representativeness, all the methods were very sensitive to the validity of baseflow separation and rainfall-loss. Several methods of the separations for rainfall excesses and direct runoffs were applied and no preferred methods were identified. This is the matter of judgement considering catchment and rainfall characteristics. This algorithm was applied to a real watershed of the Wi stream in the Nak-dong river. Compared with the IHP results by conventional methods, this optimized representative unit hydrograph demonstrated relatively smaller and shorter values in terms of the peak discharge and the basin lag respectively, and the oscillation of its falling limb successfully eliminated owing to the additional constraints of moving averages.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.18 no.9
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• pp.1248-1256
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• 1993

The propagation and delay properties in opical fiber are particularly attractive because digital signal processing and conventional analog signal processing techniques such as those using surface acoustic wave devices are limited In their usefulness for signal bandwidth exceeding one or two GHz, although they are very effective at lower frequencies. Since an accurate, low loss and short time delay elements can be obtained by using such an optical fiber, optical signal precessing has attracted much attention for high speed and broad-band signal precessing in particular channel separation filtering for optical FDM signals. In this paper, we consider a coherent optical lattice filter, which uses coherent light sources and consists of directional couplers and optical fiber delay elemnts. The optical fiber fitters are more restricted than the usual digital filters. The reasons are as follows. 1) the coupling coefficients of directional couplers are restricted to the number between 0 and 1. 2) optical signal E(complex amplitude) is divided into J If-$\boxUl$ and J L/7$\div$$\boxUl$ at the directional coupler. Considering these restrictions and in this case all the coupling coefficients of summing and branching elements are set to be equal, we have given design formulae for optical lattice filter, which make the best use of optical signal energy.

• Journal of the Korean Society for Marine Environment & Energy
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• v.12 no.3
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• pp.165-172
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• 2009

A set of equations for description of transformation of harmonic waves is proposed here. Velocity potential function and separation of variables are introduced for the derivation. The continuity equation is in a vertical plane is integrated through the water so that a horizontal one-dimensional wave equation is produced. The new equation composed of the complex velocity potential function, further be modified into. A set up of equations composed of the wave amplitude and wave phase gradient. The horizontally one-dimensional equations on the wave amplitude and wave phase gradient are the first and second-order ordinary differential equations. They are solved in a one-way marching manner starting from a side where boundary values are supplied, i.e. the wave amplitude, the wave amplitude gradient, and the wave phase gradient. Simple spatially-centered finite difference schemes are adopted for the present set of equations. The equations set is applied to three test cases, Booij's inclined plane slope profile, Massel's smooth bed profile, and Bragg's wavy bed profile. The present equations set is satisfactorily verified against existing theories including Massel's modified mild-slope equation, Berkhoff's mild-slope equation, and the full linear equation.

• Journal of Korean Tunnelling and Underground Space Association
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• v.20 no.4
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• pp.657-669
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• 2018

In recent years, the development of complex urban areas has become saturated and much attention has been focused on the development of underground space, and deep excavation is frequently performed in order to increase the utilization of underground space due to the enlargement of buildings and the high rise of buildings. Therefore, in this study, we tried to understand the behavior of the braced wall and the behavior of the tunnel adjacent to the wall according to the stiffness of the wall and the distance between the tunnel and wall. As a result of the study, the deformation of the braced wall tended to decrease with increasing the stiffness of the wall, and the axial force acting on the struts was also different according to the stiffness of braced wall. When the stiffness of the braced wall is small (2 mm), the point at which the axial force of the braces maximizes is near 0.3H of the wall. When the stiffness of the braced wall is large (5 mm), the axial force is maximum at around 0.7H of the wall. Also, the tunnel convergence occurred more clearly when the separation distance from the braced wall was closer, the stiffness of the wall was smaller, and the tunnel convergence was concentrated to the lower right part. The ground settlement due to the excavation of the ground tended to decrease as the distance between tunnel and braced wall was closer to that of the tunnel, which is considered to be influenced by the stiffness of the tunnel.

• Analytical Science and Technology
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• v.25 no.2
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• pp.152-157
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• 2012

Currently, many types of compound preparations are being used but the quality control guidelines for their use are lacking. In case of single compound drug, the quality control methods are specified in the pharmacopeia. However, there is no method to simultaneously analyze compound preparations. In this study, a simple validated analytical method for HPLC separation of chlorquinaldol and promestriene is introduced. Validation was divided into categories including linearity, precision, accuracy (recovery) and system suitability. The contents of the products which are on the market were monitored using the validated analytical method and the robustness of the analytical method was tested by conducting an inter-laboratory validation.

• Membrane Journal
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• v.16 no.4
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• pp.294-302
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• 2006

Silver polymer electrolytes are very promising membrane materials for the separation of olefin/paraffn mixtures. Olefin molecules are known to be transported through reversible complex formation with silver ions entrapped iii polymer matrix. However, they have poor long-term stability, which is very important fur the industrial application; the selectivity through the membrane decreases gradually with time mostly due to the reduction of silver ions ($Ag^+$) into silver nanoparticles ($Ag^0$). In this study, the stability of silver polymer electrolyte was investigated for poly(vinyl pyrrolidone) (PVP) and $AgBF_4$ system containing a surfactant, i.e. $C_{18}H_{35}(OCH_2CH_2)_{20}OH$ (Brij98) as a stabilizer. The reduction behavior of silver ions to silver nanoparticles in PVP was also investigated by atomic force microscopy (AFM) and UV-visible spectroscopy. It was found that the growth of silver nanoparticles was slower and selectivity of polymer electrolyte for propylene in propylene/propane was maintained longer time when Brij98 was added as a stabilizer.

• Proceedings of the Mineralogical Society of Korea Conference
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• 2003.05a
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• pp.54-54
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• 2003

The metasedimentary rocks together with various granitoids are the main constituents in Taebaeksan gneiss complex, northern Yeongnam Massif. Chemical compositions of sedimentary rocks may reflect the nature of the provenance and could be crucial for understanding the evolution of early continental crust. Previous workers have suggested that the provenance and tectonic studies based on the geochemistry of sediments are applicable to the Precambrian samples. In this study we analyzed the major, trace and REE elements of metasedimentary rocks to understand their provenance and tectonic setting during sedimentation. The overall geochemical characteristics of metasedimentary rocks are similar to those of average shale of the post-Archean. Major element chemistry indicates mature and sorted nature of the sediments. The degree of weathering in the source rocks the is not uniform, as inferred from a large scatter in chemical indices of weathering (CIW). The immobile trace elements such as Th, Sc, and REE can be used to discriminate various sedimentary processes. The Th/sc ratios (0.9 - 4.4) are larger than those of the upper crust and average shale, suggesting that the felsic source predominates. The contents of Ni and Cr and the variations in the ratio of compatible to incompatible elements are similar to the average post-Archean shale. Uniform chondrite-normalized REE pattern with the LREE enrichment (LaN/SmN = 4.9 ${\pm}$ 0.4) and slight negative Eu anomalies (Eu/Eu$\^$*/ = 0.7 ${\pm}$ 0.1) also support this observation. The presence of negative Eu anomaly indicates that intracrustal igneous processes involving plagioclase separation have affected the provenance rocks. The LREE enrichment implies the major role of felsic rocks in source rocks. The eNd (1.9 Ga) values of metasediment rocks vary from 9.4 to 6.7, corresponding to TDM of 2.9 - 2.7 Ga. On the other hand, the 147Sm/144Nd ratios are 0.1079 - 0.1101, corresponding to typical tettigenous sediments. The geochemical features of metasedimentary rocks such as high abundances of large ion lithophile elements, high ratios of Th/Sc and La/Sm, commonly high Th/U ratios, negative Eu anomalies, and negative eNd, suggest a provenance consisting virtually entirely of recycled upper continental crust in passive margin environment. Tectonic discrimination diagrams based upon major element compositions also support this suggestion. In conjunction with igneous activity and metamorphism in the convergent margin setting at 1.8 - 1. 9 Ga, the transition from passive margin to active margin characterize the Paleoproterozoic crustal evolution in northern Yeongnam Massif.