• Clean Technology
• /
• 제20권4호
• /
• pp.367-374
• /
• 2014

Several experiments have been done to investigate the removal of hydrogen sulfide ($H_2S$) synthetic gas from biogas streams by means of chemical absorption and chemical reaction with 0.1-1 M Fe/EDTA solution. The roles of Fe/EDTA were studied to enhance the removal efficiency of hydrogen sulfide because of oxidizing by chelate. The motivation of this investigation is first to explore the feasibility of enhancing the toxic gas treatment in the biogas facility. The biogas purification strategy affords many advantages. For instance, the process can be performed under mild environmental conditions and at low temperature, and it removes hydrogen sulfide selectively. The end product of separation is elemental sulfur, which is a stable material that can be easily disposed with minor potential for further pollution. As the Fe-EDTA concentration increased, the conversion rate of hydrogen sulfide increased because of the high stability of Fe-EDTA complex. pH as an important environmental factor was 9.0 for the stability of chemical complex in the oxidation of hydrogen sulfide.

• Convergence Security Journal
• /
• 제11권5호
• /
• pp.31-40
• /
• 2011

As new technologies emerge and threats become increasingly complex and unpredictable, security professionals who are living in the age of information face an increasingly complex array of challenges. In recent, virtually all organizations with physical and IT assets protect those assets in a variety of methods. There are physical systems to protect facilities and their contents from unlawful trespassing. It is important to note that the integration of physical and IT security is to be required: When done correctly, the integration starts with laws, strategies, policies and procedures. Integration of physical and IT security systems is done not for its own sake but in support of security policies and procedures. Significant security improvements can be made by integrating physical and IT security management without necessarily integrating physical and logical electronic security systems. Up to now, the private security industries of the Republic of Korea have been operated and developed by the separation of physical security and industrial security. However, considering the fast changing security environments, physical security companies should turn their attention to security convergence field to cope with the new trends in the security matters. At the same time, governmental supports on the improvement of various laws, regulations and policies in such a way to meet the realistic needs of the industries should be followed.

• Proceedings of the Korean Institute of Resources Recycling Conference
• /
• 한국자원리싸이클링학회 2006년도 춘계임시총회 및 제27회 학술발표대회
• /
• pp.78-85
• /
• 2006

In textile industries, waste effluent containing zinc is generated during the manufacture of rayon yarn from the wood pulp or cotton linters. Due to the strict environmental regulations and the presence of toxic metallic and other constituents, the discharge of industrial effluents in the sewage or disposal of solid sludge as landfill is restricted. Before recycling of zinc as zinc sulphate solution to the spinning-bath of the rayon manufacturing plant the zinc sulphate solution must be free from calcium, which is deleterious to the process as gypsum precipitates with the increase in concentration and forms scale in the bath. In the present work an attempt has been made to develop a process following solvent extraction technique using thiophosphinic extractants, Cyanex 272 and 302 modified with isodecanol and diluted in kerosene to recover zinc from rayon effluent. Various process parameters viz. extraction of zinc from different concentration of solution, distribution ratio, selective extraction, O/A ratio on extraction and stripping from the loaded organic, complex formation in the organic phase etc. have been studied to see the feasibility of the process. The extractant Cyanex 302 has been found selective for the recovery of 99.99% of zinc from the effluent above equilibrium pH 3.4 maintaining the O/A ratio of 1/30 leaving all the calcium in the raffinate. It selectively extracted zinc in the form of complex $[R_{2}Zn.3RH]_{org}$ and retained all the calcium in the aqueous raffinate. The zinc from the loaded Cyanex 302 can be stripped with 10% sulphuric acid at even O/A ratio of 10 without affecting the stripping efficiency. The stripped solution thus obtained could be recycled in the spinning bath of the rayon plant. The raffinate obtained after the recovery of zinc could be disposed safely without affacting environment.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• 제29권4호
• /
• pp.485-494
• /
• 2005

For the extensive investigation of local heat/mass transfer on the near-tip surface of turbine blade, experiments were conducted in a low speed stationary annular cascade. The turbine test section has a single stage composed of sixteen guide vanes and blades. The chord length and the height of the tested blade are 150 mm and about 125 mm, respectively. The blade has flat tip geometry and the mean tip clearance is about $2.5{\%}$ of the blade chord. Detailed mass transfer coefficient on the blade near-tip surface was obtained using a naphthalene sublimation technique. The inlet flow Reynolds number based on chord length and incoming flow velocity is changed from $1.0{\times}10^{5}\;to\;2.3{\times}10^{5}.$ Extremely complex heat transfer characteristics are observed on the blade surface due, to complicated flow patterns, such as flow acceleration, laminarization, transition, separation bubble and tip leakage flow. Especially, the suction side surface of the blade has higher heat/mass transfer coefficients and more complex distribution than the pressure side surface, which is related to the leakage flow. For all the tested Reynolds numbers, the heat/mass transfer characteristics on the turbine blade are the similar. The overall averaged $Sh_{c}$ values are proportional to $Re_{c}^{0.5}$ on the stagnation region and the laminar flow region such as the pressure side surface. However, since the flow is fully turbulent in the near-tip region, the heat/mass transfer coefficients are proportional to $Re_{c}^{0.8}.$

• Bulletin of the Korean Chemical Society
• /
• 제16권9호
• /
• pp.819-823
• /
• 1995

Thin films of two kinds of Prussian Blue (PB)-modified, using iron(Ⅲ) complex instead of conventional FeCl3, were prepared on a gold substrate and these films were able to be electrochemically reduced in potassium nitrate solution. In case of PB-modified films prepared from Fe(Ⅲ)-ethylenediamine-N,N'-diacetic acid (FeEN3+)/K3Fe(CN)6 solution, the mid-peak potential was 0.156 V in 0.1 M KNO3 and it was found that potassium ion migrates into or out of the film during the electrolysis. These films were shown to be electrochromic. These films exhibited smaller peak separation than those formed from Fe(Ⅲ)-tartaric acid (FeTA3+)/K3Fe(CN)6 system. The diffusion coefficient of Fe(CN)63-/4- redox couple, evaluated using the fabricated Au rotating disc electrode(rde) previously reported, was in good agreement with the existing data. Two experimental procedures, including the voltammetry at relatively low scan rates and the rde study, have been used in order to characterize the electrode kinetics. The electrode kinetics of some redox couples (FeEN2+-FeEN3+ and FeTA2+-FeTA3+) on both PB-modified thin films and bare Au electrode were studied using a Au rde. In all cases the rate constants of electron transfer obtained with the PB-modified film electrodes were only slightly less than those obtained for the same reaction on bare Au disc electrodes. The conductivities, as determined from the slopes of the i-V curves for a ca. 1 mm sample for dried PB-modified potassium-rich and deficient bulk samples pressed between graphite electrodes, were 6.21 × 10-7 and 2.03 × 10-7(Ω·cm)-1, respectively.

• Korean Journal of Metals and Materials
• /
• 제46권4호
• /
• pp.257-266
• /
• 2008

AHydrogen induced cracking (HIC) was phenomenologically studied in terms of the effect of nonmetallic inclusions and hot rolling process parameters. By comparing the level of non-metallic inclusions in two different kinds of commercial grade steels having different HIC resistance, the role of non-metallic inclusions in HIC occurrence was investigated. Change in inclusion morphology and distribution during hot rolling was also studied throughout slab, rolling at austenite recrystallization region (roughing mill; RM) and rolling at austenite non-recrystallization region (finish mill; FM). In addition, the contribution of RM and FM parameters to HIC was investigated from the standpoint of change in inclusion morphology during hot rolling processes. As a result, HIC was closely related to the separation of large complex inclusion during hot rolling process. Large complex inclusions originated from the improper Ca treatment, after which equilibrium composition of slag should have resulted in eutectoid composition. By controlling the equilibrium slag composition equivalent to eutectoid one, HIC resistance could be improved due to the reduced size of inclusions. In addition, change in reduction/pass in RM had an effect on HIC resistance of steels while that in FM did not. Increase in the reduction/pass in the latter stage of RM improved HIC resistance of steels by enhancing the void enclosure around inclusions.

• Journal of the korean society of oceanography
• /
• 제39권3호
• /
• pp.163-171
• /
• 2004

Sequences of the large subunit ribosomal (LSD) rDNA D1-D2 region of Alexandrium catenella(=A. sp. cf. catenella) and A. tamarense isolates, which were collected along the Korea coasts, were analyzed to understand their phylogenetic relationships and geographical distributions. All A. catenella and A. tamarense isolates belonged to the A. tamarense/catenella/fundyense complex and were grouped with the North American and temperate Asian ribotypes, respectively, regardless of the presence or absence of a ventral pore in the first apical plate. A consistent and peculiar characteristic that differentiated the Alexandrium isolates was amplification of a second PCR product with a lower molecular weight in addition to the predicted one; ten A. catenella isolates belonging to the temperate Asian ribotype yielded this additional PCR product. Sequence alignment revealed that the shorter PCR product resulted from an unusual large deletion of 87 bp in the LSD rDNA D1 domain. The North American and temperate Asian ribotypes were prevalent along the Korean coasts without geographical separation. Given the high genetic homogeneity among widely distributed Alexandrium populations, each ribotype appeared to be pandemic rather than to constitute a distinct regional population.

• Journal of Institute of Control, Robotics and Systems
• /
• 제20권2호
• /
• pp.143-148
• /
• 2014

Conventional wireless power transfer methods based on coupled magnetic fields need a complex winding structure on the surface of the energy transfer and shows poor efficiency near metal objects due to the eddy current effect. In this study, to mitigate these problems, we investigate an electric field-coupled power transmission system, which is less prone to metal object problems and EMI. Because of the fundamental physical limit in the size of link capacitances, a half-bridge converter with an impedance matching transformer is proposed and the design procedure is derived to provide a soft-switching scheme. Hardware implementation shows that the proposed scheme with a pair of 10cm by 10cm copper plate can power a 1.4W USB FAN in a separation of 0.2mm by using insulating paper when driven by 227 kHz gate pulse.

• Tribology and Lubricants
• /
• 제28권1호
• /
• pp.33-37
• /
• 2012

Automotive wheel bearing grease helps to reduce stresses and prevent wear of wheel bearings. But it is easily contaminated by water and other contaminants. Previously, our research group reported the change of grease physical properties such as dropping point, work penetration and oxidation work stability, water washout characteristics, leakage tendency, oil separation, evaporation loss and rust protection by water contamination. In this paper, we analyzed the physical characteristics of grease such as lubricity, viscosity and total acid number to investigate the mechanism of thickener decomposition. In water contaminated grease, the total acid number and wear scar were increased, the viscosity was decreased due to the decomposition of lithium complex thickener.

• Korean Institute of Interior Design Journal
• /
• 제21권1호
• /
• pp.195-202
• /
• 2012

This study aimed to analyze the types and characteristics of space forms according to performance types in the space of performing arts centers through the cases of modern performing arts centers. As for the space forms according to the performance forms, the performing arts centers devoted to dramas made a small space or turned into multi-purpose ones entering the modern days. Added to the proscenium, the main stage, was the back stage for the stage background. The area of the stage and auditorium grew similar with some kind of separation between the stage and audience. The concert halls have close relationships with the audience and their stage contacts the auditorium on many sections. The stage space is smaller than the auditorium and usually either the complex or entry type. In the opera theater, they commonly create a space for social gathering in addition to the main stage of proscenium, back stage, side stage and auditorium. They're also distinct from other performing centers for having an orchestra pit between the stage and audience. The stage is twice as big as the auditorium and the separate type. In today's performing arts centers, the sizes of the stage and auditorium can vary widely, and the performances of many different genres are put to multiple purposes.