• 제목/요약/키워드: complex particle

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An Investigation on the Emission Characteristics of Heavy-duty Vehicles using CNG and Diesel Fuel According to the Various Driving Cycles (다양한 주행모드에 따른 천연가스(CNG) 및 경유 사용 대형자동차의 배출가스 특성에 관한 연구)

  • Kim, Hyungjun;Eom, Myungdo;Kim, Jeongsoo
    • Transactions of the Korean hydrogen and new energy society
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    • 제23권6호
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    • pp.634-639
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    • 2012
  • The contribution levels of emissions from the heavy-duty vehicles have been continuously increased. Among the exhaust emissions, NOx (nitric oxides) have a ratio of 73.2% and particle matters have a proportion of 61.8% in the heavy-duty vehicles. Also, natural gas vehicles have the 78.9% of total registered local buses in Korea. Therefore, the investigation on emission characteristics of heavy-duty vehicles using CNG and diesel fuel according to the various driving cycles was carried out in this study. In order to analyze the emission characteristics, the five kinds of buses by using CNG and diesel fuels with a after-treatment devices (DPF, p-DPF) was used and five test driving schedules were applied for analysis of emission characteristics in a chassis dynamometer. To analyze the exhaust emission, the exhaust emission and PM analyzers were used. From this study, it is revealed that diesel buses with after-treatment had reduced emission of CO, HC, PM but NOx. Also, NMHC emission of CNG bus have a higher level and NOx level was similar with diesel buses. In addition, emissions in NIER06 with slow average speed shows lowest levels compared to other test modes.

Photocatalytic and Antipathogenic Effects of TiO2/CuxO (1 (TiO2/CuxO (1)

  • Cho, Sungwoo;Lee, Yong-Im;Kim, Lee-Han;Jung, Dongwoon
    • Journal of the Korean Chemical Society
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    • 제57권4호
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    • pp.483-488
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    • 2013
  • Copper oxide (CuO) was synthesized from $CuCl_2$ by solution method. Anatase $TiO_2$ particle was dispersed into the solution before preparing CuO, so that $TiO_2$/CuO heterojunction was created through the nucleation of CuO onto the $TiO_2$ surface. Some amount of CuO was reduced to $Cu_2O$ by treating glucose into the solution, thereby preparing $TiO_2/Cu_xO$ complex. The obtained $TiO_2/Cu_xO$ complex showed advanced phtocatalytic activity under the sun light compared with the P-25 sample. In addition, the the $TiO_2/Cu_xO$ complex showed excellent antipathogenic effect.

Synthesis of (Ni,Mg)Al2O4 Ceramic Nano Pigment by a Polymerized Complex Method (착체중합법을 이용한 (Ni,Mg)Al2O4 Cyan 나노 무기안료 합성)

  • Son, Bo-Ram;Yoon, Dea-Ho;Han, Kyu-Sung;Cho, Woo-Suk;Hwang, Kwang-Taek;Kim, Jin-Ho
    • Journal of the Korean Ceramic Society
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    • 제50권3호
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    • pp.195-200
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    • 2013
  • Here, we report preparation of cyan ceramic nano-pigment for inkjet printing and the Ni substitutional effects on the cyan color. $MgAl_2O_4$ was selected as the crystalline host network for the synthesis of nickel-based cyan ceramic nano-pigments. Various compositions of $Ni_xMg_{1-x}Al_2O_4$ ($0{\leq}x{\leq}1$) powders were prepared using the polymerized complex method. The powder was then preheated at $400^{\circ}C$ for 5 h and finally calcined at $1000^{\circ}C$ for 5 h. XRD patterns of $Ni_xMg_{1-x}Al_2O_4$ showed a single phase of the spinel structure in all the compositions. The particle sizes ranged from 20 to 50 nm in TEM observations. The characteristics of the color tones of $Ni_xMg_{1-x}Al_2O_4$ were analyzed by UV-Visible spectroscopy and CIE $L^*a^*b^*$ measurement. CIE $L^*a^*b^*$ measurement results indicate that the pigment color changes from light cyan to deep cyan due to the decrease of the $a^*$ and $b^*$ values with an increase of an Ni substitutional amount. In addition, the thermal stability and the binding nature of $Ni_xMg_{1-x}Al_2O_4$ are also discussed using TG-DSC and FT-IR results respectively.

RNAi Suppression of RPN12a Decreases the Expression of Type-A ARRs, Negative Regulators of Cytokinin Signaling Pathway, in Arabidopsis

  • Ryu, Moon Young;Cho, Seok Keun;Kim, Woo Taek
    • Molecules and Cells
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    • 제28권4호
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    • pp.375-382
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    • 2009
  • The 26S proteasome is a 2-MDa complex with a central role in protein turn over. The 26S proteasome is comprised of one 20S core particle and two 19S regulatory particles (RPs). The RPN12a protein, a non-ATPase subunit of the 19S RP, was previously shown to be involved in cytokinin signaling in Arabidopsis. To further investigate cellular roles of RPN12a, RNAi transgenic plants of RPN12a were constructed. As expected, the 35S:RNAi-RPN12a plants showed cytokinin signaling defective phenotypes, including abnormal formation of leaves and inflorescences. Furthermore, RNAi knock-down transgenic plants exhibited additional unique phenotypes, including concave and heart-shape cotyledons, triple cotyledons, irregular and clustered guard cells, and defects in phyllotaxy, all of which are typical for defective cytokinin signaling. We next examined the mRNA level of cytokinin signaling components, including type-A ARRs, type-B ARRs, and CRFs. The expression of type-A ARRs, encoding negative regulators of cytokinin signaling, was markedly reduced in 35S:RNAi-RPN12a transgenic plants relative to that in wild type plants, while type-B ARRs and CRFs were unaffected. Our results also indicate that in vivo stability of the ARR5 protein, a negative regulator of cytokinin signaling, is mediated by the 26S proteasome complex. These results suggest that RPN12a participates in feedback inhibitory mechanism of cytokinin signaling through modulation of the abundance of ARR5 protein in Arabidopsis.

Needham's grand question: its accurate answer and the mathematical principles of Chinese natural philosophy and medicine

  • Chang, Shyang
    • CELLMED
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    • 제5권2호
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    • pp.9.1-9.14
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    • 2015
  • The so-called "Needham's Grand Question" (NGQ) can be formulated as why modern science was developed in Europe despite the earlier successes of science and technology in ancient China. Numerous answers have been proposed. In this review, it will be pointed out that traditional Chinese natural philosophy (TCNP) and traditional Chinese medicine (TCM) are in fact dealing with problems of highly complex dynamical systems of Nature and human beings. Due to the lack of mathematical machinery in dealing with such complex phenomena, a holistic approach was taken by ancient Chinese instead. It was very successful for the first eighteen centuries. In the recent three centuries, however, the reductionist and mechanistic viewpoints of Western natural philosophy, sciences, and medicine have been prevalent all over the world up to now. The main obstacle in preventing the advancement of TCM, TCNP and its sciences is actually the lacking of proper mathematical tools in dealing with complex dynamical systems. Fortunately, the tools are now available and a "chaotic wave theory of fractal continuum" has been proposed recently. To give the theory an operational meaning, three basic laws of TCNP are outlined. These three laws of wave/field interactions contrast readily with those of Newton's particle collisions. Via the proposed three laws, TCM, TCNP and its sciences can be unified under the same principles. Finally, an answer to NGQ can be accurately given. It is hoped that this review will help promoting a genuine understanding of natural philosophy, sciences, and medicine in an ecumenical way.

Effect of Aging Time of AlO(OH) Gel Precipitated by Hydrolysis of Aluminum Sulfate on Crystal Growth of the Flaky α-Al2O3 (황산알루미늄의 가수분해에 의해 석출된 AlO(OH) 겔의 숙성시간이 판상 α-Al2O3의 결정성장에 미치는 영향)

  • Choe, Dong-Uk;Park, Byung-Ki;Suh, Jeong-Kwon;Lee, Jung-Min
    • Journal of the Korean Ceramic Society
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    • 제43권9호
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    • pp.575-581
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    • 2006
  • To precipitate the complex gel of flux and aluminum hydroxides gel, aqueous solution of the mixture of $Na_2CO_3\;and\;Na_2PO_4{\cdot}12H_2O$ was added with stirring in aqueous solution of the mixture of $Al_2(SO_4)_3{\cdot}14{\sim}18H_2O,\;Na_2SO_4$, and then the complex gel was aged in $0{\sim}30h\;at\;90^{\circ}C$. As aging time passed, the aluminum hydroxides was grown into the acicular AlO(OH) gel. Also, aging time had an effect on physical properties of the AlO(OH) gel and on crystal growth of the flaky ${\alpha}-Al_2O_3$ prepared by molten-salt precipitation. In this study, the complex gel was crystallized in temperature range of $400{\sim}1,200^{\circ}C$ after drying at $110^{\circ}C$, and then it was investigated to effect of aging time on precipitation temperature, size, thickness, morphology and particle size distribution of the flaky ${\alpha}-Al_2O_3$ crystal. As aging time passed, the flaky a${\alpha}-Al_2O_3$ crystal showed a tendency toward an increase in size and thickness as result from an increase in BET surface area and pore volume of the acicular AlO(OH) gel.

Structural and Mechanistic Insights into the Tropism of Epstein-Barr Virus

  • Mohl, Britta S.;Chen, Jia;Sathiyamoorthy, Karthik;Jardetzky, Theodore S.;Longnecker, Richard
    • Molecules and Cells
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    • 제39권4호
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    • pp.286-291
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    • 2016
  • Epstein-Barr virus (EBV) is the prototypical ${\gamma}$-herpesvirus and an obligate human pathogen that infects mainly epithelial cells and B cells, which can result in malignancies. EBV infects these target cells by fusing with the viral and cellular lipid bilayer membranes using multiple viral factors and host receptor(s) thus exhibiting a unique complexity in its entry machinery. To enter epithelial cells, EBV requires minimally the conserved core fusion machinery comprised of the glycoproteins gH/gL acting as the receptor-binding complex and gB as the fusogen. EBV can enter B cells using gp42, which binds tightly to gH/gL and interacts with host HLA class II, activating fusion. Previously, we published the individual crystal structures of EBV entry factors, such as gH/gL and gp42, the EBV/host receptor complex, gp42/HLA-DR1, and the fusion protein EBV gB in a postfusion conformation, which allowed us to identify structural determinants and regions critical for receptor-binding and membrane fusion. Recently, we reported different low resolution models of the EBV B cell entry triggering complex (gHgL/gp42/HLA class II) in "open" and "closed" states based on negative-stain single particle electron microscopy, which provide further mechanistic insights. This review summarizes the current knowledge of these key players in EBV entry and how their structures impact receptor-binding and the triggering of gB-mediated fusion.

Particle Removal on Buffing Process After Copper CMP (구리 CMP 후 버핑 공정을 이용한 연마 입자 제거)

  • Shin, Woon-Ki;Park, Sun-Joon;Lee, Hyun-Seop;Jeong, Moon-Ki;Lee, Young-Kyun;Lee, Ho-Jun;Kim, Young-Min;Cho, Han-Chul;Joo, Suk-Bae;Jeong, Hae-Do
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • 제24권1호
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    • pp.17-21
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    • 2011
  • Copper (Cu) had been attractive material due to its superior properties comparing to other metals such as aluminum or tungsten and considered as the best metal which can replace them as an interconnect metal in integrated circuits. CMP (Chemical Mechanical Polishing) technology enabled the production of excellent local and global planarization of microelectronic materials, which allow high resolution of photolithography process. Cu CMP is a complex removal process performed by chemical reaction and mechanical abrasion, which can make defects of its own such as a scratch, particle and dishing. The abrasive particles remain on the Cu surface, and become contaminations to make device yield and performance deteriorate. To remove the particle, buffing cleaning method used in post-CMP cleaning and buffing is the one of the most effective physical cleaning process. AE(Acoustic Emission) sensor was used to detect dynamic friction during the buffing process. When polishing is started, the sensor starts to be loaded and produces an electrical charge that is directly proportional to the applied force. Cleaning efficiency of Cu surface were measured by FE-SEM and AFM during the buffing process. The experimental result showed that particles removed with buffing process, it is possible to detect the particle removal efficiency through obtained signal by the AE sensor.

Welding Fume and Others from Welding Processes

  • Yoon, Chung-Sik
    • Journal of Environmental Health Sciences
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    • 제30권4호
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    • pp.320-328
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    • 2004
  • A number of health hazards are generated in welding processes. In this paper, the characteristics of fumes and some other hazardous agents in welding are reviewed. Fumes in welding are generated by complex mechanism like physical ejection of particles, oxidation-enhanced vaporization, vaporization-condensation-oxidation, and spatter contribution. Fume generation rates could be described as a power function in a given process. Most of fume constituents was originated from consumables rather than base metal. The mass distribution for the welding fumes is unimodal and very small to penetrate respiratory system. So, almost fractions of fumes are classified into the respirable particulate mass. Total chromium contents in FCAW were similar to those from SMAW whereas hexavalent chromium concentrations in fume were similar to those produced from MIG welding fume. Hexavalent chromium was mostly soluble which was similar to the characteristic solubility of fume hexavalent chromium from SMAW.

Direct Calculation Method for Excited-state Diffusion-influenced Reversible Reactions with an External Field

  • Reigh, Shang Yik;Kim, Hyo-Joon
    • Bulletin of the Korean Chemical Society
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    • 제33권3호
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    • pp.1015-1019
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    • 2012
  • The direct calculation method is generalized to the excited-state diffusion-influenced reversible reaction of a neutral and a charged particle under an external field with two different lifetimes and quenching in three dimensions. The present method provides an alternative way to calculate the binding probability density functions and the survival probabilities from the corresponding irreversible results. The solutions are obtained as the series solutions by the diagonal approximation due to the anisotropy of the unidirectional external field. The numerical results are found to be in good agreement with those of the previous study [S. Y. Reigh et al. J. Chem. Phys. 132, 164112 (2010)] within a weak field limit. The solutions of two approaches show qualitatively the same overall behavior including the power laws at long times.