• 대한화학회지
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• 제7권2호
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• pp.128-132
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• 1963

A study has been made on the applicability of gas-liquid partition chromatography to the qualitative and quantitative analysis of complex mixture of gaseous hydrocarbons. While phthalate columns are widely used for this $purpose^9$, they separates neither saturated hydrocarbons from the unsaturated nor n-butane from isobutene or butene-1, therefore combined columns such as phthalate and dimethylsulfolane have been used for the perfect separation of gaseous hydrocarbons. It is shown by this study, however, that hydrocarbons having $C_1$ through $C_4$ can be separated with a 2-meters tetraethyleneglycol dimethylether column except ethane from ethylene, and trans-from cis-2-butene especially operated at $15^{\circ}C$$ using helium as the carrier gas. The column effluents were in order of methane, (ethane, ethylene), propane, propylene, isobutane, n-butane, isobutylene, butene-1, (trans-& cis-2-butene, isopentane), (butadiene-1, 3, n-pentane). Two kinds of liquified petroleum gases in market are analysed qualitatively and quantitatively. The results indicate that use of this 2-meters TEGDE column permits the separation and identification of all the commonly encountered aliphatic gaseous hydrocarbons.

• 대한기계학회논문집B
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• 제36권3호
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• pp.315-324
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• 2012

본 연구는 가연성 기체로서 에틸렌-공기 혼합물로 채워져 있는 관에서 장애물과 굽은 관에 의한 지형적 효과에 따라 변화하는 충격파와 화염의 상호 작용, 화염 가속, 연소폭발천이 현상을 수치적으로 살펴보았다. 여기서 사용되는 모델은 지배방정식으로 Navier-Stokes 방정식과 경계조건 처리 방법으로 ghost fluid 기법을 사용하였으며 지형적 영향을 달리한 여러 모델링을 통하여 화염과 강한 충격파의 충돌에 의한 열점 생성과 화염 전파의 지연 혹은 가속 현상을 확인하였다. 추가적으로 평균 화학적 에너지 발생률이 대략 20 MJ/($g{\bullet}s$)에서 폭굉으로 천이한다는 사실을 확인하였다. 그리고 동일 위치 열점 생성에도 불구하고 폭굉의 발생 시기가 반응물의 부재와 화염면 전방의 온도와 압력 차에 의해 지연될 수 있음을 확인하였다.

• Bulletin of the Korean Chemical Society
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• 제35권1호
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• pp.147-150
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• 2014

Copper ink has been prepared by mixing copper(II) formate and 2-ethyl-1-hexylammonium bicarbonate (EHABC) to overcome some weak points such as aggregation and degradation of copper nano-type ink. Ink was coated on glass substrate and calcined at $110^{\circ}C$ to $150^{\circ}C$ to generate electrically conductive copper film under two different atmospheres such as nitrogen gas and gaseous mixture of formic acid and methanol. The lowest resistivity of $1.88{\mu}{\Omega}{\cdot}cm$ of copper film was obtained at $150^{\circ}C$ in gaseous formic acid condition. The long-term resistivity shows to increase from $1.88{\mu}{\Omega}{\cdot}cm$ to $2.61{\mu}{\Omega}{\cdot}cm$ after one month.

• Bulletin of the Korean Chemical Society
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• 제30권7호
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• pp.1563-1566
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• 2009

One-dimensional aluminum nitride (AlN) nanostructures were synthesized by calcining an Al(OH)(succinate) complex, which contained a very small amount of iron as a catalyst, under a mixed gas flow of nitrogen and CO (1 vol%). The complex decomposed into a homogeneous mixture of alumina and carbon at the molecular level, resulting in the lowering of the formation temperature of the AlN nanostructures. The morphology of the nanostructures such as nanocone, nanoneedle, nanowire, and nanobamboo was controlled by varying the reaction conditions, including the reaction atmosphere, reaction temperature, duration time, and ramping rate. Iron droplets were observed on the tips of the AlN nanostructures, strongly supporting that the nanostructures grow through the vapor-liquid-solid mechanism. The variation in the morphology of the nanostructures was well explained in terms of the relationship between the diffusion rate of AlN vapor into the iron droplets and the growth rate of the nanostructures.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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• pp.85-87
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• 2012

We present a numerical investigation on gaseous (ethylene-air mixture) detonation in the elastoplastical metal tubes to understand the wall effects associated with the developing detonation instability. The acoustic disturbances originating from the rapidly expanding tube walls reach the detonating flame surface, thereby causing flame distortions and total energy losses. The compressible Navier-Stokes equations with equation of state for gas and elasto-plastic deformation field equations for inert tubes are solved simultaneously to understand the complex multi-material interaction in the rapidly expanding gas pipe. In order to track governing variables across the material interface, we use the hybrid particle level-set and ghost fluid methods to precisely estimate the interfacial quantities. Features observed from the deforming (thin) tube show substantially different behavior when a detonation propagates in the rigid (thick) tube with no acoustically responding wall conditions.

• Mass Spectrometry Letters
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• 제14권2호
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• pp.25-35
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• 2023

Plants are a traditional source of many chemicals used as biochemical, flavors, food, color, and pharmaceuticals in various countries, especially India. Most herbal medicines and their derivatives are often made from crude extracts containing a complex mixture of various phytochemical chemical components (secondary metabolites of the plants). This study aimed to identify bioactive compounds from the different parts of the plant from the ethanolic extract of Gymnema sylvestre, Senna auriculata, and Cissus quadrangularis (leaves, flower, stem) by gas chromatography-mass spectroscopy (GC-MS). The gas chromatography - mass spectrometry analysis revealed the presence of various compounds like 3,4-dimethylcyclohexanol, hexanoic acid, D-mannose, and N-decanoic acid. Hence, the Gymnema sylvestre, Senna auriculata, and Cissus quadrangularis may have chemopreventive, anti-cancer, anti-microbial activity, antioxidant, anti-diabetic activity, anti-inflammatory, and antifungal due to the presence of secondary metabolites in the ethanolic extract. These phytochemicals are supported for traditional use in a variety of diseases.

• 한국음향학회지
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• 제8권1호
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• pp.23-30
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• 1989

기포 혼합 유체 내에서의 압력파의 전파 현상을 수치해석으로 연구한다. 혼합 유체 영역을 지배하는 지배 방정식을 heuristic 한 방법으로 유도하고 기포 내부 영역에는 열전달 효과를 고려할 수 있도록 에너지 방정식을 도입한다. 기포 내부의 비등온 조건은 특히 기포가 고진폭을 가지고 진동할 때 매우 중요하다. 기포 역학 방정식으로서 Keller 방정식이 채택, 변형되어 기포 외부와 내부의 coupling을 맺어준다. 실제 문제로서 충격관내 충격파의 전파 현상을 수치해석 방법으로 해석한 결과가 Noordzij 및 van Wijngaarden 의 실험 결과와 거의 일치한다. 그러나 그들에 의해 설명된 충격파 구조의 변화 원인은 가스와 액체 간의 상대 운동인데 이는 본 모델에서 고려되지 않았기 때문에 가스와 액체 간의 열전달에 의해 충격파의 구조가 변화된다고 보는 것이 타당하다.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 1998년도 춘계학술대회논문집; 용평리조트 타워콘도, 21-22 May 1998
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• pp.492-497
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• 1998

Thermoacoustic oscillation is a significant problem in cylindrical-type combustors such as common internal combustion engines, industrial furnaces, gas turbine, etc. This kind of low frequency oscillation can give rise to serious troubles such as the destruction of system or producing of a strong noise. Accurate numerical simulation of thermoacoustic phenomena is a complex and challenging problem. Especially, considering the reaction of mixture intensifies the difficulty of analysis. Like as other simulations of the aerodynamics and aeroacoustics, direct computation of thermoacoustic phenomena requires that the Navier-Stokes equations be solved using accurate numerical differentiation and time-marching schemes, with non-reflecting boundary conditions. In this study,, numerical approach aims at qualitative analysis and efficient prediction of problem, not at the development of an accurate scheme. Overally speaking, numerical prediction is reasonably matched with experimental result.

• 반도체디스플레이기술학회지
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• 제19권4호
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• pp.121-125
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• 2020

With miniaturization of semiconductor, the manufacturing process become more complex, and undetected small changes in the state of the equipment have unexpectedly changed the process results. Fault detection classification (FDC) system that conducts more active data analysis is feasible to achieve more precise manufacturing process control with advanced machine learning method. However, applying machine learning, especially in supervised learning criteria, requires an arduous data labeling process for the construction of machine learning data. In this paper, we propose a semi-supervised learning to minimize the data labeling work for the data preprocessing. We employed equipment status variable identification (SVID) data and optical emission spectroscopy data (OES) in silicon etch with SF6/O2/Ar gas mixture, and the result shows as high as 95.2% of labeling accuracy with the suggested semi-supervised learning algorithm.

• 해양환경안전학회:학술대회논문집
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• 해양환경안전학회 2006년도 춘계학술발표회
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• pp.85-92
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• 2006

모든 원유(crude oil) 와 연료유(refined petroleum) 는 서로 구별되는 개별 탄화수소 특성을 가지고 있다. 원유의 경우 산지별로 고유한 특성을 지니고 있으며, 연료유의 경우 같은 유종이라 할지라도 그 원료가 되는 원유의 특성, 또는 생산공정, 생산시기 등에서 차이점이 발생하고 생산시기가 동일한 통일유종의 기름이더라도 선박의 연료탱크 내에 남아있는 잔류물과의 혼합 등에 의해 구별될 수 있는 특징을 가지게 된다. 유지문기법(oil fingerprint method)은 이러한 특성을 이용하여 해상유출유의 오염원을 밝히기 위한 감식 분석기법을 말한다. 현재의 유용한 유지문기법으로는 기체크로마토그래피 (GC)를 이용한 포화탄화수소류 방향족탄화수소류 황화합물 패턴분석방법과 적외선분광광도계(IR)를 이용한 적외선스펙트럼 측정방법 그리고 형광분광광도계(FL)를 이용한 방향족탄화수소류 스펙트럽분석방법 둥이 있으며 GC/MS를 이용한 EICs(Extracted Ion Chromatograms) 패턴분석방법이 있다.