• Analytical Science and Technology
• /
• v.37 no.4
• /
• pp.230-238
• /
• 2024

This study evaluates a method for quantifying selenium (Se) concentration in soil using inductively coupled plasma mass spectrometry (ICP-MS), with oxygen as a reaction gas. This approach addresses the challenge of detecting low levels of Se in complex soil matrices and aims to effectively minimize interference problems typically associated with argon plasma in traditional ICP-MS analyses. The analytical method utilizes conditions optimized for minimizing spectral interference and were validated by linearity, accuracy, precision, limit of detection (LOD), and limit of quantification (LOQ). The method demonstrated good linearity, high accuracy (90-97 %), and remarkable sensitivity, achieving detection and quantification limits of 0.15 ㎍/kg and 0.44 ㎍/kg, respectively. Developed analysis method for Se in soil was applied to field samples in the different regions of South Korea and Se concentration ranged from 0.11 to 0.52 mg/kg. Correlation analysis between Se concentration and soil properties showed that Se concentration was significantly correlated with cation exchange capacity (CEC) and available phosphorus among other soil properties.

• Journal of the Society of Naval Architects of Korea
• /
• v.42 no.2 s.140
• /
• pp.159-164
• /
• 2005

Monostatic RCS analysis of complex structures has been done with a combined method of physical and geometric optics, commonly applied to high frequency electromagnetic backscattering problems. In the analysis, the complex structure is modeled as a number of flat surfaces and the RCS of whole structure is calculated by summing RCS of each surface, which can be obtained from an analytical solution of flat surface phase integral derived from physical optics. The reflected and hidden surfaces are searched by an object precision method based on adaptive triangular beam method, which can take account for effects of multiple reflections and polarizations of electromagnetic wave. The validity of the presented RCS analysis method has been verified by comparing with exact solutions and measured data for various structures.

• Analytical Science and Technology
• /
• v.31 no.4
• /
• pp.171-178
• /
• 2018

Recently, for successful lactation, many breastfeeding mothers seek various products, including herbal medicine, dietary supplements, and prescribed medicines, to improve milk production. As demand for galactogogues grows, it is highly possible that pharmaceutical galactogogues may be adulterated with illegal products to maximize their efficacy. For continuous control and supervision of illegal products, we developed and validated a simple and sensitive LC-MS/MS method capable of simultaneously determining five galactogogues. Chromatographic separation was conducted using an Agilent Poroshell $120SB-C_{18}$ column with a mobile phase consisting of 20 mM ammonium formate (pH 5.4) and 100 % acetonitrile. The total run time was 13 min per analyte. The proposed method was performed according to the guidelines of the International Conference of Harmonization and it produced reliable results. This method showed high sensitivity and specificity, with a limit of detection (LOD) and limit of quantitation (LOQ) of 0.01-0.82 ng/mL and 0.02-2.45 ng/mL, respectively, for the solid- and liquid-type samples. Specificity was evaluated by analyzing matrix-blank samples spiked with the target compounds at LOQ levels, which provided a good separation of all peaks without interference. Additionally, the repeatability and intermediate precision were typically <15 %, whereas the recovery was 80-120 % of the values obtained using blank samples. Thus, we concluded that this method could be used for the identification and quantification of galactogogues in food or herbal products.

• Analytical Science and Technology
• /
• v.32 no.2
• /
• pp.35-47
• /
• 2019

In this study, high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) was employed to detect 26 antidiabetic compounds in adulterated dietary supplements using a simple, selective method. The work presented herein may help prevent incidents related to food adulteration and restrict the illegal food market. The best separation was obtained on a Shiseido Capcell Pak(R) C18 MG-II ($2.0mm{\times}100mm$, $3{\mu}m$), which improved the peak shape and MS detection sensitivity of the target compounds. A gradient elution system composed of 0.1 % (v/v) formic acid in distilled water and methanol at a flow rate of 0.3 mL/min for 18 min was utilized. A triple quadrupole mass spectrometer with an electrospray ionization source operated in the positive or negative mode was employed as the detector. The developed method was validated as follows: specificity was confirmed in the multiple reaction monitoring mode using the precursor and product ion pairs. For solid samples, LOD ranged from 0.16 to 20.00 ng/mL and LOQ ranged from 0.50 to 60.00 ng/mL, and for liquid samples, LOD ranged from 0.16 to 20.00 ng/mL and LOQ ranged from 0.50 to 60.00 ng/mL. Satisfactory linearity was obtained from calibration curves, with $R^2$ > 0.99. Both intra and inter-day precision were less than 13.19 %. Accuracies ranged from 80.69 to 118.81 % (intra/inter-day), with a stability of less than 14.88 %. Mean recovery was found to be 80.6-119.0 % and less than 13.4 % RSD. Using the validated method, glibenclamide and pioglitazone were simultaneously determined in one capsule at concentrations of 1.52 and 0.53 mg (per capsule), respectively.

• The Journal of the Korea Contents Association
• /
• v.13 no.2
• /
• pp.505-511
• /
• 2013

A new boundary treatment technique which can be applied to axi-symmetric topography with inclined bottom was developed. Although the finite element method is good for complex geometry, there is no proper boundary treatment when a boundary is not a vertical section because the water depth at the coastline becomes zero. In this study, we developed a new boundary treatment for inclined bottom using the analytical solution for long wave. To develope a model, the mild-slope equation was used and then, a computational domain is divided into an analytical region and a numerical region. By combining a numerical and an analytical solutions, a complete solution was obtained. The developed solution was validated by comparing with a previous analytical solution.

• Journal of the Earthquake Engineering Society of Korea
• /
• v.17 no.3
• /
• pp.143-150
• /
• 2013

The paper introduces Multi-Platform Analysis (MPA) for the seismic performance of a structure controlled by Magneto-Rheological (MR) dampers and presents analytical assessment of the effect of MR damper when taking into account nonlinear behavior of the structure. This paper introduces the MR Damper Plugin that can facilitate communication between MATLAB/Simulink and a finite element analysis tool in order to account for more complex inelastic behavior of the structure with MR dampers. The MPA method using the developed MR Damper Plugin is validated with experimental results from the real-time hybrid simulation. By utilizing the proposed MPA method, the three-story RC structure controlled by MR dampers is more realistically modeled and its performance under seismic loads is investigated. It is concluded that MR damper designed for a linear structure is not effective in a nonlinear structure and can overestimate the effect of MR damper. This work is expected to overcome difficulties in the analytical assessment of structural control strategies for complex and nonlinear structures by obtaining more reliable results.

• Analytical Science and Technology
• /
• v.9 no.2
• /
• pp.139-144
• /
• 1996

The spectrophotometric determination method of scandium with eriochrome cyanine R(ECR) and the composition ratio of the complex were investigated in the presence of surfactants. The absorbance increase and red shift of maximum adsorption wavelength of Sc(III)-ECR complex were observed in cetyltrimethylammonium bromide (CTMAB), but those changes were not observed in the sodium dodecyl sulfate(SDS) and Triton X-100. A volume of 5ml of $1{\times}10^{-3}M$ ECR and 10ml of $2{\times}10^{-4}M$ CTMAB are necessary for the determination of $1{\times}10^{-7}{\sim}3.0{\times}10^{-6}M$ Sc(III) at pH 6.5. The apparent molar absorption coefficient of the Sc(III)-ECR-CTMAB, temary complex at 610nm is $5.6{\times}10^5mol^{-1}cm^{-1}L$ and its detection limit is $1.0{\times}10^{-7}M$. The binary complex composition of Sc(III)-ECR is 1:2 and the ternary complex composition of Sc(III)-ECR-CTMAB is 1:3:1.

• The korean journal of orthodontics
• /
• v.18 no.2
• /
• pp.343-366
• /
• 1988

Craniofacial complex is influenced by numerical skeletal elements. Though the analysis of growth change has been done by various analytical methods, it was dependent on any method of registration and superimposition, based on reference plane and reference point. However, the craniofacial growth is composed of a number of local growth elements. Therefore, it will be necessary to use a clinically useful method for estimating craniofacial skeletal growth independently. The author analysed longitudinal cephalometric roentgenogram of 15 Korean males and 15 Korean females aged from 6 to 12 years by the finite element method and results were as follows : 1. The finite element method for craniofacial skeletal complex and soft tissue made it possible to analyze the independent local growth. 2. Regression equations from the value of each strain will make it possible to predict the craniofacial growth. 3. The growth of anterior cranial base was different from that of other facial bone. 4. The growth of posterior cranial base influenced the growth of upper pharyngeal region, midfacial region, maxilla and posterior region of mandible. 5. The growth of maxillary complex was vertical rather than horizontal. 6. The growth direction of ramus, mandibular body, alveolar bone was various. 7. The relation between hard tissue and soft tissue by finite element method was variant.

• 제어로봇시스템학회:학술대회논문집
• /
• 2005.06a
• /
• pp.377-382
• /
• 2005

This paper presents a new method for the attitude control of planar space robots. In order to control highly constrained non-linear system such as a 3D space robot, the analytical formulation for the system with complex dynamics and effective control methodology based on the formulation, are not always obtainable. In the proposed method, correspondingly, a non-analytical but effective self-organizing modeling method for controlling a highly constrained system is proposed based on a polynomial data mining algorithm. In order to control the attitude of a planar space robot, it is well known to require inputs characterized by a special pattern in time series with a non-deterministic length. In order to correspond to this type of control paradigm, we adopt the Model Predictive Control (MPC) scheme where the length of the non-deterministic horizon is determined based on implementation cost and control performance. The optimal solution to finding the size of the input pattern is found by a solving two-stage programming problem.

• Proceedings of the KIEE Conference
• /
• 2007.07a
• /
• pp.1027-1028
• /
• 2007

In this paper, the variation of air-gap field intensity caused by the slot-opening in interior permanent magnet (IPM) motor is investigated, which is for predicting the instantaneous magnetic field more preciously in analytical method further. It is different with the approach of dealing the slot-opening effect on the air-gap field distribution with the "relative permeance" function in surface permanent magnet (SPM) motor. The prediction of the air-gap field in IPM motor is much more complex than SPM motor. In this study, an approximate estimation method is adopted based on analyzing the changing of flux path in both the IPM rotor part and stator part, and in additional an analytical function defined as "relative pole-arc" is built. The finite element method(FEM) is used for confirming the slot-opening effect on the field prediction.