• Title/Summary/Keyword: complex analysis

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Inclusion Selectivity of the Cyanocadmate Host Complex with Piperazine Ligand for Aromatic Guest Molecules; Benzene, Toluene, Ethylbenzene and Xylene Isomers (Piperazine 리간드를 가진 시아노카드뮴 호스트 착물의 방향족 게스트 분자에 대한 포접선택성)

  • Kim, Chong-Hyeak;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.16 no.4
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    • pp.333-338
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    • 2003
  • Inclusion selectivity of a three-dimensional piperazine-ligated cyanocadmate host complex, $[Cd_x(CN)_{2x}\{HN(CH_2CH_2)_2NH\}_y]{\cdot}zG$, has been investigated for benzene (B), toluene (T), ethylbenzene (E), o- (O), m- (M), and p-xylene (P) isomers as the aromatic guest molecules. From the binary, ternary and quarternary guest mixtures of E and xylene isomer (X), the order of inclusion selectivity in the host complex is O>E>P>M. From the binary to quinary BTX mixtures, the order of preference in the complex is seen to be B>T>O${\gg}$P>M.

Complex Discrete Systems Graph Simulation

  • Kadirova, Delovar;Kadirova, Aziza
    • Journal of Multimedia Information System
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    • v.2 no.3
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    • pp.263-274
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    • 2015
  • The subject of this work is the complex discrete systems simulation special features with the aid of dynamic graph models. The proposed simulation technique allows to determine the ways for tasks solutions in terms of discrete systems analysis and synthesis of various complication: one-dimensional and multidimensional, steady and unstable, with the pulse elements abnormal operating mode and others. Often complex control systems analysis and synthesis task solutions, via classical approach comes out to be insolvent, because of the computational problems. The application of graph models allows to perform clear and strict characterization and computer procedures automation. The optimal controls synthesis algorithm presented in this paper, transferring the discrete system from target initial state to target final state within the minimum time, allows to consider the zero initial conditions systems, with the initial potential energy, with the control actions limitations and complex pulse elements operating mode.

A Study on the exterior pedestrian passages evaluation through case studies of multi-family housing complex (공동주택단지 사례분석을 통한 외부보행로 평가 연구)

  • Kim, Sung Yong;Park, Jung Eun;Lee, Hyo-Won
    • KIEAE Journal
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    • v.8 no.1
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    • pp.61-70
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    • 2008
  • This paper is focused on studying a pedestrian passage that forms exterior space of the housing unit on diverse prerequisites and convenience of residential environment regards to plans for Multi-family Housing Complex. The paper explores the actual usage of a pedestrian passage installed in Multi-family Housing Complex and examine whether the nature-friendly space that includes the exterior pedestrian passage of the housing unit is being applied variously on a pedestrian passage. In order to obtain an analysis of the current status on case study unit, the study has prepared an analyzing tool for the environment in use for the exterior pedestrian passage and was able to construction problematic points by applying the obtained data. Thanks for the analysis, a comprehensive evaluation on the plans for the pedestrian passage was implemented through correlation with a green tract of land, living space and the exterior pedestrian passage installed in Multi-family Housing Complex.

Development on a Transmission Unit for a Plug Type Passenger Door (플러그 방식 승객용 출입문의 변속장치 개발)

  • 김연수;홍재성;박성혁;이관섭;백영남
    • Journal of the Korean Society for Railway
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    • v.4 no.2
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    • pp.55-61
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    • 2001
  • Since the plug type passenger door has two modes of motion, a power transmission unit must be capable of plug-in or plug-out mode, and sliding mode. Complex planetary gear train is proposed, which is composed of two 2K-H, I type planetary gear units. For the proposed complex planetary gear train, ranges of addendum modification coefficients which would not lead to interferences are analyzed, and optimal addendum modification coefficients among these ranges which generate the maximum efficiency are presented. Based on the results of analysis on interferences, efficiencies and torque ratios, the specifications for the complex planetary gear train were determined. It has been shown by tests of the complex planetary gear train manufactured that the gear train worked well with good agreements of analysis.

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Spectrophotometric Investigation of Germanium Complex Solution with o-Chlorophenylfluorone and Determination of Trace Amounts of Germanium

  • Hong-Wen Gao;Wei-Guo Liu
    • Bulletin of the Korean Chemical Society
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    • v.21 no.11
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    • pp.1090-1094
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    • 2000
  • A reaction between germanium (Ge) and the ligand, o-chlorophenylfluorone (o-CPF) has been carried out. The reaction sensitive at pH 4.5 in the presence of triton x-100 was selective in the presence of EDTA. The spectral correction technique was ap plied to the analysis of the reaction instead of single wavelength spectrophotometry because the absorption of excess of o-CPF was not negligible. An updated determination of the properties of the Ge(IV)-o-CPF complex is given, which involved the complex ratio, stepwise absorptivity and stability constant of the complex. In present work, the results show that the complex $Ge(o-CPF)_3was$ formed and its cumulative stability constant was 1.09 ${\times}$1016 . For sample analysis, the detection limit of germanium was 0.01 mg/L, and the recoveries were between 96.4% and 102%, with relative standard deviations of less than 6.5%.

The Analysis of Communication Invigorating Element in the Play Spaces of Apartments - Focused on the Cases in Suncheon City - (아파트 놀이공간의 커뮤니케이션 활성화 요소 분석 - 전라남도 순천시 사례를 중심으로 -)

  • Yun, Yeo-Ran;Moon, Jeong-Min
    • Journal of the Korean housing association
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    • v.26 no.3
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    • pp.25-32
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    • 2015
  • Apartment complex has become the major residental type of the urban structure. apartment complex has started to equip various subsidiary welfare facilities recently. environmental planning for play space has especially been important due to the growing attention over children's emotional development. In this study, arrangement types for play spaces in apartments to invigorate communication had been analyzed focusing on physical environment. based on previous studies, the arrangement of subsidiary welfare facilities can be categorized into dispersal type, concentrative type, affiliated type, and affiliated concentration type, and the elements to invigorate communication consist of circulative elements which contain location of play space and affiliated facility, visual elements which contain visual openness, and social elements which draw arrangement types of benches. the result of the analysis devide the arrangement type into concentrative type, affiliated type, and affiliated concentration type. referring to the location of play space, the first, if it is situated outside of apartment complex, theme-centered play space can be equipped to invigorate communication, the second, if it is situated in the center of the complex or outside of the apartment complex, low fence can be applied for free sight, and the last, straight type of bench arrangement should be used in big scale play space, aspectant type and gazebo type of the arrangement can be situated only outside of complex. This research could serve as a baseline of physical environment analysis to invigorate communication for play space in apartment complex.

Application of Substructure Synthesis Method for Analysis of Acoustic System (음향계의 해석을 위한 부분구조합성법의 적용)

  • 오재응;고상철;조용구
    • Journal of KSNVE
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    • v.7 no.5
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    • pp.737-746
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    • 1997
  • The substructure synthesis method is used for making it easy to analyze vibration systems generally in vibration field. In the past, this method has been to be used mainly because of shortage of computer memory and CPU time. But recently this method is used for analyzing complex structure or identifying the characteristics of systems precisely. The purpose of this study is to develop acoustic substructure synthesis method that can be applied to acoustic modal analysis of complex acoustic systems. Acoustic modal analysis method to be introduced here is a method that analyze acoustic natural mode shape of the complex acoustic system by the principle of CMS(component mode synthesis method). This paper describes the acoustic modal analysis of the acoustic finite element model of simple expansion pipe by acoustic substructure synthesis method. The resutls of acoustic modal analysis analyzed by Acoustic substructure synthesis method and the results by FEM(finite element method) shows good agreement.

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A Study on Possibility of Teaching Complex Numbers from Geometric Aspect (기하학적 측면에서 복소수의 지도가능성 고찰)

  • Lee, Dong-Hwan
    • Journal of Educational Research in Mathematics
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    • v.18 no.1
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    • pp.51-62
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    • 2008
  • In the 7th-curriculum, only basic arithmetics of complex numbers have been taught. They are taught formally like literal manipulations. This paper analyzes mathematically essential relations between algebra of complex numbers and plane geometry. Historical analysis is also performed to find effective methods of teaching complex numbers in school mathematics. As a result, we can integrates this analysis with school mathematics by help of Viete's operations on right triangles. We conclude that teaching geometric interpretation of complex numbers is possible in school mathematics.

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Synthesis, spectral, thermal, structural study and theoretical treatment of new complexes of mannich base with Ni(II) and study of cytotoxicity effect on (Hepa-2) cell line and antimicrobial activity

  • Omar H. Al-Obaidi
    • Analytical Science and Technology
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    • v.36 no.2
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    • pp.70-79
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    • 2023
  • The synthesis of the Mannich base as a ligand (L) N-(morpholino (phenyl) methyl) acetamide is the subject of this study. Elemental analyses, FT-IR spectra, UV-vis, 1H-NMR, and magnetic measurements were used to confirm the synthesis of the [Ni(L)2]Cl2 complex, thermal analysis (TG/DTG), atomic absorption, and scanning, and structurally explained as electron microscopy (SEM), and X-ray powder diffraction (XRD) methods. The melting point of the complex and its molar conductivity were also measured. The suggested geometries of the complexes formed have a tetrahedral structure, according to the data acquired using various techniques. Theoretical approaches to the complex formation have been investigated. For molecular mechanics and semi-empirical calculations, the HYPERCHEM6 program had been used. The effect of the novel Ni(II) complex on the cancer cell Hepa-2 (human hepatocellular ademocarcinoma), that is the human laryngeal cancer, was studied. It has been found that these ligand and complex have potent effects on the cancer cell. The antibacterial activity of the free ligand and its complex was evaluated against two kinds of human pathogenic bacteria. The first category is Gram-positive (Staphylococcus aureas, epiderimids), whereas the second group is Gram-negative (Psedamonas aeruginosa, Escherichia coli) (from the diffusion method). Finally, it was discovered that various chemicals had varied growth-inhibiting effects on bacteria.

Distribution and Exposure Characteristics of Pneumoconiosis Patients in Fuel Complexes (연료단지 진폐증 환자 분포현황 및 노출특성)

  • Jong-Hyeon Jung
    • Journal of Environmental Science International
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    • v.33 no.2
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    • pp.161-168
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    • 2024
  • This study was conducted to identify the pollutants generated by the fuel complex and to determine the health effects of the surrounding residents. In addition, based on the results of epidemiological surveys and health impact surveys of local residents, we analyze the distribution of patient groups and exposure characteristics according to the distance from the fuel complex boundary. Samples were collected from the briquette plant within the fuel complex and analyzed by SEM-EDXA, X-ray Fluorescence Spectrometer, and ICP. In addition, the distribution of patients and exposure characteristics were analyzed according to the distance from the fuel complex and yard boundaries. Analysis of briquette samples from the fuel complex showed that the average particle size was 10-30 ㎛, the shape was irregular, and SiO2 accounted for more than 50%. It is believed that silica, which causes pneumoconiosis, may have been scattered into the air. In particular, there was a large distribution of 5 ㎛ particles that affect respiratory diseases. According to the analysis of the residential addresses and distribution of pneumoconiosis cases, many pneumoconiosis cases were located in the area between 200 and 500 meters from the boundary of the fuel complex. In addition, 28 pneumoconiosis cases were identified as a result of the epidemiological survey and health impact survey at the fuel complex. In detail, there were 8 cases of occupational pneumoconiosis, 6 cases of environmental pneumoconiosis, and 14 cases of occupational and environmental pneumoconiosis. The confirmed pneumoconiosis cases were located between 0.3 and 1.1 kilometers from the fuel complex. It was found that environmental pollutants generated by the fuel complex adversely affect the health of local residents. In particular, there are many cases of pneumoconiosis in the area between 200 and 500 meters from the boundary of the fuel complex, and this distance is considered to be the direct and indirect impact zone of the briquette plant.