• Title/Summary/Keyword: combustion products

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A Study on the Mechanical Properties of Polymer Repair-Mortars with CFBC Ash (순환유동층 보일러애시를 활용한 폴리머 보수 모르타르의 역학적 특성에 대한 연구)

  • Kang, Yong Hak;Lim, Gwi Hwan;Shin, Dong Cheol;Choi, Young Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.5
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    • pp.127-132
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    • 2018
  • The amount of generated Circulating Fluidized Bed Combustion ash (CFBC ash) is annually increasing, but most CFBC ash has been landfilled and discarded due to the limited utilization. The major chemical compositions of CFBC ash are $SiO_2$, CaO and $CaSO_4$, which could form hydration products by reacting with water as self-cementing property such as cement. The purpose of the this study is to derive the optimal mix proportions to improve polymer-modified mortar with the use of CFBC ash which has the self-cementing property. In order to develop polymer-modified mortar, three mix proportions were determined, and fundamental properties for the mixtures were obtained. As a result, the optimal mixture containing 10 percent of silica fume, 1.0 percent of polymer and 3.5 percent of expansive additives were proposed in this study.

Numerical Study of Chemical Reaction for Liquid Rocket Propellant Using Equilibrium Constant (평형상수를 이용한 액체로켓 추진제의 화학반응 수치연구)

  • Jang, Yo Han;Lee, Kyun Ho
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.44 no.4
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    • pp.333-342
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    • 2016
  • Liquid rocket propulsion is a system that produces required thrust for satellites and space launch vehicles by using chemical reactions of a liquid fuel and a liquid oxidizer. Monomethylhydrazine/dinitrogen tetroxide, liquid hydrogen/liquid oxygen and RP-1/liquid oxygen are typical combinations of liquid propellants commonly used for the liquid rocket propulsion system. The objective of the present study is to investigate useful design and performance data of liquid rocket engine by conducting a numerical analysis of thermochemical reactions of liquid rocket propellants. For this, final products and chemical compositions of three liquid propellant combinations are calculated using equilibrium constants of major elementary equilibrium reactions when reactants remain in chemical equilibrium state after combustion process. In addition, flame temperature and specific impulse are estimated.

Reaction Parameters on the Reactivity in the Preparation of B4C by SHS (자전연소합성법에 의한 B4C분말의 제조에 있어 반응성에 대한 반응변수의 고찰)

  • Shin, Chang-Yun;Yun, Ki-Seok;Park, Yeong-Cheol;Hayk, Nersisyan;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.42 no.1
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    • pp.22-27
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    • 2005
  • The preparation of B4C by SHS in $B_{2}O_{3}-Mg-C$ system was investigated in this study. In the preparation of B4C, the effect on reactivity and reaction products of the initial pressure of inert gas in reactor, the content of Mg and C in mixture was investigated. The minimum initial pressure of inert gas in reactor for SHS reaction in this system was 25 atm, and as the pressure increased, the concentration of unreacted Mg decreased and combustion temperature increased. At the initial inert gas pressure in reactor of 25 atm, the optimum composition for the preparation of pure B4C was $2B_{2}O_{3}+6.3Mg +0.94C$. The B4C synthesized in this condition had an irregular shape and the particle size of $1\~3{\mu}m$.

The $SO_2$ effect on NOx removal by Corona Shower System (코로나 샤워 시스템을 이용한 NOx제거에서 $SO_2$의 영향)

  • Park, Jae-Yoon;Kim, Ick-Kewn;Lee, Jae-Dong;Kim, Jong-Dal;Lee, Duck-Chool;Chang, J.S.
    • Proceedings of the KIEE Conference
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    • 1998.07e
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    • pp.1794-1796
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    • 1998
  • In this study, the $SO_2$ addition effect on NOx removal has been conducted from a combustion flue gases by the do corona discharge-activated radical shower systems. The simulated flue gases were consisted of NO-O_2-$N_2$, NO-$CO_2-N_2-O_2$ and $NO-SO_2-CO_2-Na-O_2$([NO]o:200ppm and $[SO_2]o$:800ppm). The injection gases used as radical source gases were $NH_3$-Ar-air. $SO_2$ and NOx removal efficiency and the other by-products were measured by Fourier Transform Infrared(FTIR) as well as $SO_2$. NOx and $NO_2$ gas detectors. By-product aerosol particles were also observed by Condensation Nucleation Particle Counter(CNPC) and SEM images after sampling. The results showed that asignificant aerosol Particle formation was observed during a removal operation in corona radical shower systems. The NOx removal efficiency significantly increased with increasing applied voltage and $NH_3$ molecule ratio. The $SO_2$ removal efficiency was not significantly effected by applied voltage and slightly increased with increasing $NH_3$ molecule ratio. The NOx removal efficiency for NO-$SO_2-CO_2-N_2-O_2$ was better than that for NO-$CO_2-N_2-O_2$.

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A Study on Ventilation Effects on Smoke Behavior in Rescue Station for Tunnel Fires (철도터널 화재시 구난역 내의 연기거동에 미치는 배연효과에 관한 연구)

  • Jang, Won-Cheol;Kim, Dong-Woon;Lee, Seong-Hyuk;Ryou, Hong-Sun
    • Journal of the Korean Society for Railway
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    • v.11 no.3
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    • pp.294-299
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    • 2008
  • The present study investigates the ventilation effects on smoke spreading with the rescue stations. Experiments for tunnel fires were carried out for n-heptane pool em at different fire locations, and the heat release rates (HRR) were obtained by addition, using the commercial code (FLUENT), the present article presents numerical results for smoke behavior in railway tunnels with rescue station, and it uses the MVHS (Modified Volumetric Heat Source) model for estimation of combustion products resulting from the fire source determined from the HRR measurement. As a result, it is found that smoke propagation is prevented successfully by the fire doors located inside the cross-passages and especially, the smoke behavior in the accident tunnel can be controlled through the ventilation system because of substantial change in smoke flow direction in the cross-passages.

An Experimental Study on the Mechanical Properties of Porous Concrete Using Coal Ash and Polymer (석탄재 및 고분자화합물을 이용한 포러스콘크리트의 역학적 특성에 관한 실험적 연구)

  • Lee, Byung-Jae;Park, Seong-Bum;Lee, Jun;Jang, Young-Il;Cho, Kwang-Yun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.901-904
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    • 2008
  • Immense quantities of coal combustion by-products are produced every year, and only a small fraction of them are currently utilized. Therefore, this study investigated and analyzed the applications of porous concrete for the efficient utilization of bottom ash. This study examines on application of polymer to improve strength properties of porous concrete using coal-ash. As the results, when the mixing ratio of bottom ash increases, void ratio and coefficient of permeability of porous concrete increases, but its strength decreases. Also, as the mixing ratio of polymer increases, its void ratio and coefficient of permeability decreases. When specific amount of polymer is mixed, we can find its strength properties are improved.

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Coal gasification with High Temperature Steam (고온(高溫) 수증기(水蒸氣)를 이용한 석탄(石炭) 가스화)

  • Yun, Jin-Han;Kim, Woo-Hyun;Keel, Sang-In;Min, Tai-Jin;Roh, Seon-Ah
    • Resources Recycling
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    • v.16 no.6
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    • pp.28-33
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    • 2007
  • Coal is the most abundant energy source and deposited in every area of world. Combustion process with lower efficiency has been mainly used. Therefore, implementation of more efficient technologies, involving gasification, combined cycles and fuel cells, would be a key issue in the plans for more efficient power generation. In these technologies, gasification has been studied for decades. However, coal gasification to high value combustible gas such as hydrogen and carbon monoxide is focused again due to high oil price. The gaseous product, called syngas, can be effectively utilized in a variety of ways ranging from electricity production to chemical industry (as feedstock). In this study, coal gasification with ultra high temperature steam has been performed. The effect of steam/carbon ratio on the produced gas concentrations, gasification rate and additional products like tar, ammonia and cyan compounds has been determined.

Experimental Study of the Blowoff Flame Phenomena Due to Changes of Balcony Length (발코니 길이변화에 의한 화염분출성상의 실험적 고찰)

  • Kim, Hoe-Cheon;Sohn, Jang-Yeul;Park, Hyung-Ju
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.19 no.3
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    • pp.235-244
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    • 2007
  • In the case of the fire outburst within a partitioned space, it can disappear inside it through smoldering process if the fire cannot obtain sufficient imflammability. On the contrary, if it obtains it, the fire is not restricted within the room, spreading to the higher levels beyond outside windows and the compartment room. The method to prevent the fire spread through windows is considered to build a balcony or equip with sprinkler facilities. This case study is to identify which effects and controlibility a balcony brings about on the spread of fire through a full scale model experiment. In order to understand the effects of fire spread on the upper levels of the room on fire by changing the length of balcony, the temperature was measured, radiant heat was investigated, and products of combustion were analyzed. The result showed that when fire occured, longer length of the balcony, which linked to the outside wall of the apartments, led to the blocking of the fire spread, lower level of radiant heat, and significantly less transfer of toxic gases, and the driving force of the outburst of flame was identified as the attractive force due to the turbulence of uncombusted gases, which exist on the upper level of the outbursting flame.

Experimental Study on Smoke Production and Smoke Generation in Thermoplastic Resins Based on PP, PMMA, and PVC (열가소성 수지(PP, PMMA, PVC)의 연기생성 및 발생에 관한 실험적 연구)

  • Hwang, Euy-Hong;Choi, Don-Mook
    • Fire Science and Engineering
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    • v.34 no.3
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    • pp.1-7
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    • 2020
  • Due to the complexity and large size of buildings, plastic resin is widely used as a building material. Accordingly, the occurrence of fires caused by plastics is increasing. Due to the nature of plastic resin fires, the amount of damage to properties and human life caused by combustion products such as smoke are large, and these damages are related to smoke production and smoke generation. Therefore, this study reviews smoke measurement methods and laws on domestic buildings and fire services. Experiments were conducted based on three smoke-related test standards (ISO 5660-1, ISO 12136, ASTM E 662). The experiment results indicate a total smoke production and generation by PP, PVC, and PMMA of 43.27, 32.83, and 12.33 ㎡, and 27.855, 9.599, and 6.975 g, respectively.

A Study of Coal Gasification Process Modeling (석탄가스화 공정 모델링에 관한 연구)

  • Lee, Joong-Won;Kim, Mi-Yeong;Chi, Jun-Hwa;Kim, Si-Moon;Park, Se-Ik
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.5
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    • pp.425-434
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    • 2010
  • Integrated gasification combined cycle (IGCC) is an efficient and environment-friendly power generation system which is capable of burning low-ranked coals and other renewable resources such as biofuels, petcokes and residues. In this study some process modeling on a conceptual entrained flow gasifier was conducted using the ASPEN Plus process simulator. This model is composed of three major steps; initial coal pyrolysis, combustion of volatile components, and gasification of char particles. One of the purposes of this study is to develop an effective and versatile simulation model applicable to numerous configurations of coal gasification systems. Our model does not depend on the hypothesis of chemical equilibrium as it can trace the exact reaction kinetics and incorporate the residence time calculation of solid particles in the reactors. Comparisons with previously reported models and experimental results also showed that the predictions by our model were pretty reasonable in estimating the products and the conditions of gasification processes. Verification of the accuracy of our model was mainly based upon how closely it predicts the syngas composition in the gasifier outlet. Lastly the effects of change oxygen are studied by sensitivity analysis using the developed model.