• Bulletin of the Korean Chemical Society
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• v.26 no.10
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• pp.1529-1532
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• 2005

A simple and cost effective method for separation and preconcentration of Ag(I) at the $10^{-7}\;mol\;L^{-1}$ level in the environmental and mineral samples is present. The method is based on the flotation of Ag(I)-iodide complex as an ion-associate with ferroin in pH of 4 from a large volume of an aqueous solution (500 mL) using nheptane. The floated layer was then dissolved in dimethylsulfoxide (DMSO) for the subsequent spectrophotometric determination. Beer's law was obeyed over a range of 2.0 ${\times}$ $10^{-7}$-4.0 ${\times}$ $10^{-6}$ mol $L^{-1}$ with the apparent molar absorptivity of 2.67 ${\times}$ $10^5$ L $mol^{-1}\;cm^{-1}$. The detection limit (n = 5) was 4 ${\times}$ $10^{-8}$ mol $L^{-1}$, and RSD (n = 5) obtained for 2.0 ${\times}$ $10^{-6}$ mol $L^{-1}$ of Ag(I) was 2.2%. The interference effects of a number of elements was studied and found that only $Hg^{2+}$ at low concentration, and $Pb^{2+}$, $Cd^{2+}$, $Cu^{2+}$, and $Fe^{3+}$ ions at moderately high concentrations were interfered. To overcome on these interference effects, the solution was treated with EDTA at a buffering pH of 4 and passed through a column containing Amberlite IR-120 ionexchanger resin, just before the flotation process. The proposed method was applied to determine of Ag(I) in a synthetic waste water, a photographic washing sample and a geological sample and the results was compared with those obtained from the flame atomic absorption spectrometry. The results were satisfactorily comparable with together, so that the applicability of the proposed method was confirmed in encountering with the real samples.

• Resources Recycling
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• v.8 no.4
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• pp.11-19
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• 1999

Fly ash generated from (he pulverized coal power plant have caused the serious ocean pollution due to the disposal in the ash pond, the life reduction of a power plant and the waste of re-utilizable resource The research to reuse the unburned carbon and mineral composing of the ash has been progressed. In this study. the physical and chemical characteristics of high grade ash and unburned carbon particles obtained from countercurrent column flotation are investigated. The cleaned ash of the less 0,5% loss on Ignition(LOI) in carbon content is a spherical sphere and 39.8${\mu}m$ in size of MMD(Mass Median Diameter). 2.22 $m^2/g$ of specific area. The morphology of high LOI carbon particles is a amorphousness, 76.6 ${\mu}m$ of particle size and 15.2 $m^2/g$ of specific The high grade cleaned ash and the high LOI ash have some difference in the light of physical. chemical and morphological characteristics

• 한국생물공학회:학술대회논문집
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• 2000.11a
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• pp.741-744
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• 2000

The removal of colours from aqueous solution and/or dispersions has been studied by dispersed-air flotation, in a semi-batch column. Two colours were used for the experiments: Basic Yellow 28 (basic) and Direct Orange 31 (basic). All two were effectively removed by flotation within 8 min. Sodium dodecyl sulfate, sodium oleate and amines were found to be effective as collectors in the removal of colour, which was found to be related to the pH of the solution and the amount of collector added to it, with high collector dosages causing the process to become pH-independent.

• Resources Recycling
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• v.9 no.6
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• pp.36-44
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• 2000

Fly ash was composed of the unburned carbon and mineral particles. The former was able to attach on the bubbles, while the latter was not. Therefore, it was possible to separate the unburned carbon and the mineral from fly ash using the froth flotation process. This study was carried out to evaluate the separation efficiency as a function of the ny ash particle properties in the column flotation. Separation efficiency was analyzed for various size fraction of -38 fm,38~125 fm and 1125 W, and for various fly ash samples containing 7, 11, and 20 wt% unburned carbon. For the size fractions of -38 fm containing 7 wt% unburned carbon, separation efficiency was 86ft, whereas separation efficiency was found to be 74% for the size fraction of +125$\mu\textrm{m}$ containing 20 wt% unburned carbon. The results indicated that separation efficiency increased with the decrease in the particle size and the unburned carbon content of the fly ash.

• Journal of Navigation and Port Research
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• v.32 no.9
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• pp.705-709
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• 2008

In the sea various methods have been conducted to capture wave energy which include the use of pendulums, pneumatic devices, etc. Floating devices, such as a cavity resonance device take advantages of both the water motion and the wave induced motions of the floating body itself. The wave energy converter is known commercially as the WAGB(Wave Activated Generator Buoy) and is used in some commercially available buoys to power navigation aids such as lights and horns. This wave energy converter consists of a circular flotation body which contains a vertical water column that has free communication with the sea. A theoretical analysis of this power generated by a pneumatic type wave energy converter is performed and the results obtained from the analysis are used for a real wave energy converter buoy. This paper is shown to have an optimum value for which maximum power is obtained at a given resonant wave period Also, the length of the internal water column corresponds to that of the water mass in the water column. If designed properly, wave energy converter can take advantage not only of the cavity resonance, but also qf the heaving motion of the buoy. Finally, simulation is performed with a LabVIEW program and the simulation results are applied to a wave energy simulator for modifying design data for a wave energy converter.

• Resources Recycling
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• v.19 no.2
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• pp.35-44
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• 2010

As the competition of acquiring foreign resources of advanced countries and developing countries intensifies, South Korea which imports most of the mineral resources, started to re-develop domestic mines for molybdenite ore, in order to secure stable natural resources and decrease foreign currency expense. In this study, as a result of performing XRD and composite analysis on Dongwon NMC's (the sole producer of molybdenite ore in Korea) final concentrate(Mo 50.4%), Quartz, Grossular and Hedenbergite exists as impurities and size analysis showed that in relative coarse particle range of 60~140 mesh was formed with high grade over 57% Mo. Also, a test was performed to confirm the possibilities of increasing the grade and recovery of Dong won NMC's final ore. As a result, Mo 58.6% ($MoS_2$ 97.83%) was obtained with 87.47% recovery at a condition of 15 minutes grinding time, Kerosene as collector 0.1 l/ton, AF as Frother 65 7.2 l/ton, wash water of 630 ml/min and air flow rate of 1,197 ml/min.

• Journal of Industrial Technology
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• v.10
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• pp.83-88
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• 1990

The samples used for this work were low grade c1ay($Fe_2O_3$ : 2.90%, $TiO_2$ : 1.65%) produced from Youngsan-po district, and for the iron-bearing impurities removal having a bad influence on Kaoline sample was carried out column floatatoin using Oleic acid, Potassium oleat, Aero 840 promotor, Aero 870 promotor and Keroseneas collectors. For removal of the iron-vearing impurities from the kaoline, investigated first chemical composition size distribution of Kaoline sample, also performanced a basic study on pulp density, collector and pH change on a sort of frother. The flotation separation of impurities from kaoline can be achieved by using both oleic acid and Aero 840 promotor as collectors within narrow acid limits(pH 2-3). Pine oil was more effective frother than MIBC with olelic acid as aa collector.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1995.11a
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• pp.42-49
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• 1995

석유에너지의 고갈을 앞두고 석탄에너지의 활용연구가 우리나라에서도 광범위하게 연구되어 왔다. 현재 국내에서 석탄(무연탄과 유연탄)은 발전용으로 대량 사용되고 있으며 이중에서 유연탄은 전량 수입에 의존하고 있다. 지리적으로 중국과 접하고 있는 우리나라의 경우 중국의 석탄 사용은 피할 수 없는 현실이며 지금도 상당량을 중국에서 수입하고 있다. 현재까지 우리나라에서는 비교적 저회분, 저유황분의 석탄만을 중국에서 수입하고 있다. 그러나 중국에서 점차 저유황탄의 생산이 줄어들고 있는 점을 감안할 때 앞으로는 고회분, 고유황탄의 수입이 필연적일 것으로 생각된다. 그러나 이 경우 우리는 SOx발생에 의한 환경오염에 대한 대비책이 있어야 하며 이와 관련하여 석탄전처리(Coal Cleaning)기술은 매우 중요하다.

• Journal of Korean Society on Water Environment
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• v.25 no.3
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• pp.386-393
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• 2009

This study was carried out to assess water quality and to introduce the management measures for water quality improvement with the collected data from 87 agricultural reservoirs in Han river watershed. According to the water quality criteria (WQC) for lake based on the COD, TP, TN and chl.a concentration, 18, 16, 4 and 19 of 87 reservoirs exceed class IV, respectively. Based on the trophic state index (TSI) with chl.a concentration, 51 of selected reservoirs appeared to be eutrophic. Phosphorus was limiting nutrient on algal growth in 58 reservoirs. TP, chl.a and COD concentration in 23 of 49 agricultural reservoirs with chl.a concentration ${\geq}25{\mu}g/L$ and eutrophic exceed class IV by WQC. Also, the mean depth in 21 of 23 reservoirs was below 5m. Our results suggest that advanced wastewater treatment and crop land control in watershed of reservoirs with TP concentration ${\geq}0.1mg/L$ would be a effective tool to improve water quality. Dredging would to be effective measure in reservoirs with mean depth < 5 m and relatively old age. In reservoirs with chl.a concentration ${\geq}50{\mu}g/L$, application of technique such dissolved air flotation (DAF) and P inactivation be effective to improve water quality by removing particulate matters in water column. The management measure to control inflow such as sedimentation basin, Pre-dam and diversion would to be application in reservoirs with shallow depth, while large watershed and surface area.

• Resources Recycling
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• v.8 no.5
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• pp.51-58
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• 1999

The sbdy iwestlgaled ihc propa-ties of Lhe dust\ulcorner rrom fe~~oallomya ~~ufacturTeh. e chemical composition, cornpasitlon material, p d c l e sire md shapes of the bulk dust, sired dust and magnetically separated durl were mvesligaled. As the re\ulcornerulL, we suppose that the dust from &gh Carbon Fenama~~gunesMc anuiact~vingP rocess is not sufiicient as solulce material of Mn because of ale low Mn canlenl (13.5%) and complicaled composition mate~ial. The dust from Bug F!lter or AOD Proccss is mi~inlym ade up of 0.2-2 pm Mn30, (Hausmam~iu)p iutlde in spherical shape and thc Mn content is 63.190.The dust from Cooler of AOD Process is inninly made up of coarse Ca(O1-Or)zM. n,FeyO,, SiO, and fine Mn30d.