• Tribology and Lubricants
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• v.34 no.6
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• pp.209-216
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• 2018

Sapphire is a substrate material that is widely used in optical and electronic devices. However, the processing of sapphire into a substrate takes a long time owing to its high hardness and chemical inertness. In order to process the sapphire ingot into a substrate, ingot growth, multiwire sawing, lapping, and polishing are required. The lap grinding process using pellets is known as one of the ways to improve the efficiency of sapphire substrate processing. The lap grinding process ensures high processing efficiency while utilizing two-body abrasion, unlike the lapping process which utilizes three-body abrasion by particles. However, the lap grinding process has a high material removal rate (MRR), while its weakness is in obtaining the required surface roughness for the final polishing process. In this study, we examine the effects of free abrasives in lap grinding on the material removal characteristics of sapphire substrate. Before conducting the lap grinding experiments, it was confirmed that the addition of free abrasives changed the friction force through the pin-on-disk wear test. The MRR and roughness reduction rate are experimentally studied to verify the effects of free abrasive concentration on deionized water. The addition of free abrasives (colloidal silica) in the lap grinding process can improve surface roughness by three-body abrasion along with two-body abrasion by diamond grits.

• Journal of the Korean Institute of Rural Architecture
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• v.21 no.2
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• pp.35-42
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• 2019

There are 17,427 reservoirs in Korea, of which about 96% were built before the mid 1980s. Therefore, aging is severe and reinforcement are necessary. In addition, aged reservoirs, which are more than 50 years old, account for 70% of the total. Therefore, there is a problem such as the collapse of the reservoir and the decrease of the storage capacity due to progress of aging with time. The grouting method using cement is mainly used as maintenance and reinforcement method of old reservoir. However, the grouting method using cement has engineering and environmental problems. In order to solve the engineering and environmental problems of cement grouting method, an eco-friendly grouting material was developed that mixes circular resource grouting binder, high molar ratio sodium silicate and colloidal silica. The engineering and environmental properties of the developed injection materials were evaluated by conducting gel time, homo-gel strength, sea water resistance test and environmental stability evaluation. Also, examined the possibility of replacing OPC existing aged reservoir reinforcement methods. As a result, it was found out that it was better than the conventional cement method in terms of engineering and environment. However, since this study is the result of laboratory test, it is necessary of verify the application at field of aged reservoir.

• Membrane and Water Treatment
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• v.13 no.1
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• pp.39-49
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• 2022

Seawater desalination is doubtlessly a viable option to supply fresh drinking water. Nevertheless, RO (reverse osmosis) desalination plants in specific areas may be intermittently operated to match the imbalance between water demand and supply. Although a handful of works have been done on other membrane systems, few studies have attempted to mitigate fouling in intermittent RO systems. Accordingly, the objectives of this paper were to examine the effect of the intermittent operation on RO fouling; and to compare four intermittent operation modes including feed solution recirculation, membrane storage in the feed solution, deionized water (DI) recirculation, and membrane storage in DI water. Results showed that intermittent operation reduced RO fouling under several conditions. However, the extents of fouling mitigation were different depending on the feed conditions, foulant types, and membrane lay-up methods. When the feed solution was recirculated during the lay-up, the restoration of the flux was less significant than that by the feed solution feed-up. The use of deionized water during the lay-up was effective to restore flux, especially when the feed solution contains scale-forming salts (CaSO₄) and/or colloidal silica.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.4A
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• pp.603-609
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• 2008

The recycled aggregates which were produced from the waste concretes have the disadvantages of inferior properties for natural aggregate. Therefore, in order to reuse the recycled aggregate it must be solved to improve the quality of recycled aggregate. In this study, the quality of recycled aggregate was improved by the surface treatment method using the colloidal silica solution. And, in order to examine the possibility of reusing the surface coated recycled aggregate in constructing concrete structures, we studied the mechanical properties and durability of the concrete using the surface coated recycled aggregates and the other concrete.

• Korean Chemical Engineering Research
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• v.50 no.2
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• pp.371-378
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• 2012

Hydrophilic silica nanoparticles (SNPs) were treated by using 3-glycidoxypropyltrimethoxy silane (GPTMS) and then they were blended with polyurethane-urea (PUU) emulsions to obtain SNPs/PUU nanocomposite films. Thermo-mechanical properties of the nanocomposite films were investigated by varying the grafted amount of GPTMS onto SNPs and the contents of SNPs in the PUU matrix. The thermo-mechanical properties of the nanocomposite films were also compared in terms of the dispersibility of SNPs in the PUU matrix and thermal curing of the GPTMS-grafted SNPs. The maximum amount of grafted GPTMS was $1.99{\times}10^{-6}\;mol/m^2$, and which covered ca. 53% of the total SNP surface area. $^{29}Si$ CP/MAS NMR analyses with the deconvolution of peaks revealed the details of polycondensation degree and patterns of GPTMS in the surface modification of SNPs. The surface modification did not significantly affect colloidal stability of the SNPs in aqueous medium; however, the hydrophobic modification of SNPs offered a favorable effect on the dispersibility of SNPs in the PUU matrix as well as better thermal stability. XRD patterns revealed that GPTMS-grafted SNPs broadened the reduced the characteristic peak of polyol in PUU matrix. The composite films became rigid and less flexible as the SNP content increased from 5 wt.% to 20 wt.%. Particularly, Young's modulus and tensile modulus significantly increased after the thermal curing reaction of the epoxy groups in the SNPs.

• Korean Chemical Engineering Research
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• v.51 no.4
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• pp.443-454
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• 2013

Various metal ions (transition and base metals) incorporated MCM-41 catalysts can be synthesized using colloidal and soluble silica with non-sodium involved process. Transition metal ion-typically $V^{5+}$, $Co^{2+}$, and $Ni^{2+}$-incorporated MCM-41 catalysts were synthesized by isomorphous substitution of Si ions in the framework. Each incorporated metal ion created a single species in the silica framework, single-site solid catalyst, showing a substantial stability in reduction and catalytic activity. Radius of pore curvature effect was investigated with Co-MCM-41 by temperature programmed reduction (TPR). The size of metallic Co clusters, sub-nanometer, could be controlled by a proper reduction treatment of Co-MCM-41 having different pore size and the initial pH adjustment of the Co-MCM-41 synthesis solution. These small metallic clusters showed a high stability under a harsh reaction condition without serious migration, resulting from a direct anchoring of small metallic clusters to the partially or unreduced metal ions on the surface. After a complete reduction, partial occlusion of the metallic cluster surface by amorphous silica stabilized the particles against aggregations. As a probe reaction of particle size sensitivity, carbon single wall nanotubes (SWNT) were synthesized using Co-MCM-41. A metallic cluster stability test was performed by CO methanation using Co- and Ni-MCM-41. Methanol and methane partial oxidations were carried out with V-MCM-41, and the radius of pore curvature effect on the catalytic activity was investigated.

• Economic and Environmental Geology
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• v.35 no.3
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• pp.203-210
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• 2002

In order to elucidate the growth mechanism of sulfide chimney formed as a result of seafloor hydrothermal mineralization, we carried out the mineralogical and fluid inclusion studies on the inactive, sulfide- and silica-rich chimney which has been recovered from a hydrothermal field in the Cleft segment of the Juan de Fuca Ridge. According to previous studies, many active and inactive vents are present in the Cleft segment. The sulfide- and silica-rich chimney is composed of amorphous silica, pyrite, sphalerite and wurtzite with minor amounts of chalcopyrite and marcasite. The interior part of the chimney is highly porous and represents a flow channel. Open spaces within chimneys are typically coated with colloform layers of amorphous silica. The FeS content of Zn-sulfides varies widely from 13.9 to 34.3 mole% with Fe-rich core and Fe-poor rims. This variation possibly reflects the change of physicochemical characteristics of hydrothermal fluids. Chemical and mineralogical compositions of the each growth zone are also varied, possibly due to a thermal gradient. Based on the microthermometric measurements of liquid-rich, two-phase inclusions in amorphous silica that was precipitated in the late stage of mineralization, minimum trapping temperatures are estimated to be about 1140 to 145$^{\circ}$C with the salinities between 3.2 and 4.8 wt.% NaCI equiv. Although the actual fluid temperatures of the vent are not available, this study suggests that the lowtemperature conditions were predominant during the mineralization in the hydrothermal field at Cleft segment. Comparing with the previously reported chimney types, the morphology, colloform texture, bulk chemistry, and a characteristic mineral assemblage (pyrite + marcasite + wurtzite + amorphous silica) of this chimney indicate that the chimney have been formed from a relatively low-temperature (<250$^{\circ}$C) hydrothermal fluid that was changed by sluggish fluid flow and conductive cooling.

• Applied Chemistry for Engineering
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• v.16 no.6
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• pp.737-741
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• 2005

In this study, the effect of copper content on the NO removal efficiency by Cu/MCM-41 has been investigated. MCM-41 was prepared by hydrothermal synthesis using a gel mixture of colloidal silica solution and cetyltrimethylammonium. Cu/MCM-41 was manufactured with copper content (5, 10, 20, and 40%) in Cu(II) acetylacetonate. The surface properties of MCM-41 were investigated by using pH, XRD, and FT-IR analyses. $N_2/77K$ adsorption isotherm characteristics, including the specific surface area and micropore volume were studied by BET's equation and Boer's t-plot methods. NO removal efficiency was confirmed by gas chromatography technique. From the experimental results, the MCM-41 was analyzed to have the surface functional groups of Si-OH and Si-O-Si and the characteristic diffraction lines (100), (110), (200), and (210) corresponding to a hexagonal arrangement structure. The copper content supported on MCM-41 appeared to increase the NO removal efficiency in spite of decreasing the specific surface areas or micropore volumes. Consequently, it was found that the copper content in Cu/MCM-41 played an important role in improving the NO removal efficiency, which was mainly attributed to the catalytic reactions.

• Journal of the Korean Chemical Society
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• v.47 no.6
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• pp.619-624
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• 2003

The $Gd_{1.9-x}Li_{0.1}Eu_xO_3$ (x=0.02, 0.05, 0.08, and 0.12) powders (${\thickapprox}1{\mu}m$) synthesized by sol-gel method, whose surfaces are modified in a colloidal silica suspension (size of $SiO_2$ particles: ${\sim}30$ nm), have been fabricated to highly stable and effective luminescent films on the glass substrates. Thanks to the fused $SiO_2$ nano particles in the vicinity of the glass softening temperature (at around $700^{\circ}C$), $Gd_{1.9-x}Li_{0.1}Eu_xO_3$ powders are strongly attached onto the surface of glass substrate (>9H, pencil hardness tester). This simple and low-cost method to get $Gd_{1.9-x}Li_{0.1}Eu_xO_3$ phosphor films without any loss of luminescence brightness would promise for applications to display devices.

• Journal of the Korean Chemical Society
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• v.37 no.3
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• pp.317-326
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• 1993

The acid catalytic reactions of toluene with n-propylalcohol were investigated and the adsorption experiments of dialkylbenzene isomers were carried out at 100$^{\circ}C$ over modified HZSM-5 zeolites. ZSM-5 zeolite was synthesized by the hydrothermal reaction using 4-propylammonium ion, sodium aluminate and colloidal silica etc., and several zeolite catalysts, including H-, K-, Sr-, P-Mg-HZSM-5, H-Y and H-mordenite, were prepared by conventional methods. The main reaction products of toluene with n-propylalcohol over HZSM-5 catalyst include not only xylenes, propyltoluenes, but also ethyltoluenes and high para-selectivity among dialkylbenzene isomers was observed on P-Mg-HZSM-5 zeolite. The diffusion coefficients of various p-dialkylbenzenes are nearly the same, about 1 ${times}$ 10$^{-10}$ cm$^2$/sec and that of m-xylene was about one tenth of o-xylene. These reaction and adsorption characteristics were interpreted in the light of the shape-selectivity related to related to the zeolite pore structure and the zeolitic acidity.