• Title/Summary/Keyword: coefficient-based method

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Multi-variable and Multi-site Calibration and Validation of SWAT for the Gap River Catchment (갑천유역을 대상으로 SWAT 모형의 다 변수 및 다 지점 검.보정)

  • Kim, Jeong-Kon;Son, Kyong-Ho;Noh, Jun-Woo;Jang, Chang-Lae;Ko, Ick-Hwan
    • Journal of Korea Water Resources Association
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    • v.39 no.10 s.171
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    • pp.867-880
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    • 2006
  • Hydrological models with many parameters and complex model structures require a powerful and detailed model calibration/validation scheme. In this study, we proposed a multi-variable and multi-site calibration and validation framework for the Soil Water Assessment Tool (SWAT) model applied in the Gap-cheon catchment located downstream of the Geum river basin. The sensitivity analysis conducted before main calibration helped understand various hydrological processes and the characteristics of subcatchments by identifying sensitive parameters in the model. In addition, the model's parameters were estimated based on existing data prior to calibration in order to increase the validity of model. The Nash-Sutcliffe coefficients and correlation coefficient were used to estimate compare model output with the observed streamflow data: $R_{eff}\;and\;R^2$ ranged 0.41-0.84 and 0.5-0.86, respectively, at the Heuduck station. Model reproduced baseflow estimated using recursive digital filter except for 2-5% overestimation at the Sindae and Boksu stations. Model also reproduced the temporal variability and fluctuation magnitude of observed groundwater levels with $R^2$ of 0.71 except for certain periods. Therefore, it was concluded that the use of multi-variable and multi-site method provided high confidence for the structure and estimated parameter values of the model.

Data Qualification of Optical Emission Spectroscopy Spectra in Resist/Nitride/Oxide Etch: Coupon vs. Whole Wafer Etching

  • Kang, Dong-Hyun;Pak, Soo-Kyung;Park, George O.;Hong, Sang-Jeen
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.433-433
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    • 2012
  • As the requirement in patterning geometry continuously shrinks down, the termination of etch process at the exact time became crucial for the success in nano patterning technology. By virtue of real-time optical emission spectroscopy (OES), etch end point detection (EPD) technique continuously develops; however, it also faced with difficulty in low open ratio etching, typically in self aligned contact (SAC) and one cylinder contact (OCS), because of very small amount of optical emission from by-product gas species in the bulk plasma glow discharge. In developing etching process, one may observe that coupon test is being performed. It consumes costs and time for preparing the patterned sample wafers every test in priority, so the coupon wafer test instead of the whole patterned wafer is beneficial for testing and developing etch process condition. We also can observe that etch open area is varied with the number of coupons on a dummy wafer. However, this can be a misleading in OES study. If the coupon wafer test are monitored using OES, we can conjecture the endpoint by experienced method, but considering by data, the materials for residual area by being etched open area are needed to consider. In this research, we compare and analysis the OES data for coupon wafer test results for monitoring about the conditions that the areas except the patterns on the coupon wafers for real-time process monitoring. In this research, we compared two cases, first one is etching the coupon wafers attached on the carrier wafer that is covered by the photoresist, and other case is etching the coupon wafers on the chuck. For comparing the emission intensity, we chose the four chemical species (SiF2, N2, CO, CN), and for comparing the etched profile, measured by scanning electron microscope (SEM). In addition, we adopted the Dynamic Time Warping (DTW) algorithm for analyzing the chose OES data patterns, and analysis the covariance and coefficient for statistical method. After the result, coupon wafers are over-etched for without carrier wafer groups, while with carrier wafer groups are under-etched. And the CN emission intensity has significant difference compare with OES raw data. Based on these results, it necessary to reasonable analysis of the OES data to adopt the pre-data processing and algorithms, and the result will influence the reliability for relation of coupon wafer test and whole wafer test.

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Statistical Characteristics of the Non-tidal Components Data in Korean Coasts (한반도 연안 비조석 성분자료의 통계적 특성)

  • Cho, Hong-Yeon;Jeong, Shin-Taek;Yoon, Jong-Tae;Kim, Chang-Il
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.18 no.2
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    • pp.112-123
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    • 2006
  • Double-peak normal distribution function was suggested as the probability density function of the non-tidal components (NTC) data in Korean coastal zone. Frequency distribution analysis of the NTC data was carried out using hourly tidal elevation data of the ten tidal gauging stations, i.e., Incheon, Gunsan, Mokpo, Jeju, Yeosu, Masan, Gadeokdo, Busan, Pohang, and Sokcho which were served through the Internet Homepage by the National Ocean Research Institute. NTC data is defined as the difference between the measured tidal elevation data and the astronomical tidal elevation data using 64 tidal constituents information. Based on the RMS error and R2 value comparison analysis, it was found that this suggested function as the probability density function of the NTC data was found to be more appropriate than the normal distribution function. The parameters of the double-peak function were estimated optimally using Levenberg-Marquardt method which was modified from the Newton method. The standard deviation and skewness coefficient were highly correlated with the non-tidal constants of the tidal gauging stations except Mokpo, Jeju and Sokcho stations.

Reference evapotranspiration estimates based on meteorological variables over Korean agro-climatic zones for rice field (남한지역의 논 농업기후지대에 대한 기상자료 기반의 기준 증발산량 추정)

  • Jung, Myung-Pyo;Hur, Jina;Shim, Kyo-Moon;Kim, Yongseok;Kang, Kee-Kyung;Choi, Soon-Kun;Lee, Byeong-Tae
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.21 no.4
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    • pp.229-237
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    • 2019
  • This study was conducted to estimate annual reference evapotranspiration (ET0) for the agro-climatic zones for rice paddy fields in South Korea between 1980 and 2015. The daily ET0 was estimated by applying the Penman-Monteith method to meteorological data from 61 weather stations provided by Korean Meteorological Administration (KMA). The average of annual ET0 from 1980 to 2015 was 1334.1±33.89 mm. The ET0 was the highest at the Southern Coastal Zone due to their higher air temperature and lower relative humidity. The ET0 had significantly increased with 2.81 mm/yr for the whole zones over 36 years. However, the change rate of it was different among agro-climatic zones. The annual ET0 highly increased in central zones and eastern coastal zones. In terms of correlation coefficient, the temporal change of the annual ET0 was closely related to variations of four meteorological factors (i.e., mean, minimum temperatures, sunshine duration, and relative humidity). The results demonstrated that whole Korean agro-climatic zones have been undergoing a significant change in the annual ET0 for the last 36 years. Understanding the spatial pattern and the long-term variation of the annual ET0 associated with global warming would be useful to improve crop and water resource managements at each agro-climatic zone of South Korea.

Establishment of Pre-Harvest Residue Limits (PHRLs) of Fluopicolide and Metrafenone in Cherry Tomato (Lycopersicon esculentum Mill.) (방울토마토(Lycopersicon esculentum Mill.) 생산단계에서 Fluopicolide 및 Metrafenone의 잔류허용기준 설정)

  • Hur, Kyung Jin;Woo, Min Ji;Kim, Ji Yoon;Saravanan, Manoharan;Kwon, Chan-Hyeok;Son, Yong Wook;Hur, Jang Hyun
    • Korean Journal of Environmental Agriculture
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    • v.34 no.4
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    • pp.328-335
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    • 2015
  • BACKGROUND: The present investigation was aimed to predict the pre-harvest residue limits (PHRLs) of the fluopicolide and metrafenone on cherry tomato and to estimate their half-life and characteristics of the residues.METHODS AND RESULTS: Pesticides were treated once on cherry tomato in field 1 and 2 under the standard application rate. The samples were collected 7 times at the end of 0(2 hours after pesticides spaying), 1, 2, 3, 5, 7 and 10 days before harvest. Residues of fluopicolide and metrafenone were analyzed by the LC-MS/MS. In this study, the method limit of quantification (MLOQ) for both fluopicolide and metrafenone in cherry tomato was found to be 0.005 mg kg-1. Their recovery levels were 92.7∼94.8% and 82.6∼88.0%, shown with coefficient of variation of less than 10%. Half-life of fluopicolide and metrafenone in field 1 and 2 were found to be 15.0 days and 12.8 days, 18.9 days and 21.5 days, respectively.CONCLUSION: Based on the results, this study shows the level of PHRL on cherry tomato is 0.27 mg/kg for fluopicolide and 2.29 mg/kg for metrafenone at 10 days before harvesting. The present study indicates the residues of both pesticides on cherry tomato will be below maximum residue limit (MRL) at harvest.

Determination of ethyl carbamate in maesil wine by alcohol content and ratio of maesil (Prunus mume) during ripening period (알코올 농도 및 담금비에 따른 숙성 기간별 매실주의 에틸카바메이트 함량조사)

  • Kim, Nan-Young;Eom, Mi-Na;Do, Young-Sook;Kim, Jung-Beom;Kang, Suk-Ho;Yoon, Mi-Hye;Lee, Jong-Bok
    • Food Science and Preservation
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    • v.20 no.3
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    • pp.429-434
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    • 2013
  • This study was designed to investigate the formation of ethyl carbamate (EC) during the ripening of Maesil with sugar and Soju (19.5~35% alcohol contents) using a homemade method. Maesil, sugar and Soju were purchased at ordinary market in June of 2012. The preparation of sample for analysis was conducted by method of Henry et al. The analysis of GC/MS was used SIM mode (m/z 89, 74, 62). Quantification was performed in terms of the 62 ion and was based on an internal standard procedure. Good linearity was obtained with a regression coefficient ($r^2$ = 0.993). Low detection limits (LOD) was achieved 4.31 ug/kg and recovery for alcohol was 74.8%. During 90 days, fermentation with sugar was not detected EC (under LOQ). 15 days ripened Maesil wine contained EC between non detected~32.7 ug/kg and 90 days ripened Maesil wine was 19.7~87.4 ug/kg. Higher proportion of Maesil and Soju increased EC contents. EC levels were increased 32.7 ug/kg to 87.4 ug/kg in the ratio of Maesil to 35% alcohol-Soju (1:1). In the ratio of Maesil to 35% alcohol-Soju (1:3) was increased non detected to 69.7 ug/kg. After 90 days, Maesil wine was filtered Maesil through a seive and ripened by 180 days to investigate the formation of EC compared with non filtered. Treatment of filtered, EC contents was much higher level compared with non filtered. Therefore, this result showed that alcohol contents contribute to increase EC formation more than Maesil.

Estimation of the Periodic Extremes of Minimum Air Temperature Using January Mean of Daily Minimum Air Temperature in Korea (1월 일최저기온 평균을 이용한 한국의 재현기간별 일 최저기온 극값 예측)

  • Moon, Kyung Hwan;Son, In Chang;Seo, Hyeong Ho;Choi, Kyung San
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.14 no.4
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    • pp.155-160
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    • 2012
  • This study was conducted to develop a practical method for estimating the extremes of minimum air temperature with given return-period based on the frequency distribution of daily minimum air temperature in January. Daily temperature data were collected from 61 meteorological observatories country-wide from 1961 to 2010. Most of daily minimum temperature in January could be represented by a normal-distribution, so it is possible to predict stochastically the lowest temperature by the mean and standard deviation. We developed a quadratic function to estimate standard deviation in terms of daily minimum temperature in January. Also, we introduced a coefficient which can be used to predict an extreme of minimum temperature with mean and standard deviation, and is dependent on return-periods. Using this method, we were able to reproduce the past 30-year extremes with an error of 1.1 on average and 5.3 in the worst case.

A Study on the Correlation with the Degree of Compaction and the Penetration Depth Using the Portable Penetration Meter at Field Test (휴대용 다짐도 측정기의 현장실험을 통한 다짐도와 관입깊이 상관성 연구)

  • Park, Geoun Hyun
    • Journal of the Korean GEO-environmental Society
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    • v.19 no.11
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    • pp.5-14
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    • 2018
  • Worldwide, soil compaction work is one of the most important activities that are carried out on civil engineering works sites. Compaction work, particularly in the area of road construction, is considered to be important, as poor compaction work is closely related with poor construction even after a construction is complete. Currently, the plate bearing test or the sand cone method relative to the unit weight of soil test are commonly used to measure the degree of compaction, but as these require a great deal of time, equipment and manpower, it is difficult to secure economic efficiency. The method that is used to measure the degree of compaction according to the penetration depth achieved by free fall objects through gravity is the Free-Fall Penetration Test (FFPT), which uses a so-called "portable compaction measuring meter (PCMM)." In this study, the degree of compaction was measured and a penetration depth graph was developed after the field test using the portable compaction measuring meter. The coefficient of determination was 0.963 at a drop height of 10 cm, showing the highest level of accuracy. Both horizontal axis and longitudinal axis were developed in a decimal form of graph, and the range of allowable error was ${\pm}1.28mm$ based on the penetration depth. The portable compaction measuring meter makes it possible to measure the degree of compaction simply, quickly and accurately in the field, which will ensure economic efficiency and facilitate the process management.

Bioequivalence of Tagamet Tablet to Sinil CIMETIDINE Tablet (cimetidine 400 mg) (타가메트정 400 mg에 대한 신일시메티딘정 400 mg의 생물학적동등성시험)

  • Yoon, Mi-Kyeong;Lee, Byoung-Moo;Lee, Sung-Jae;Kim, Sun-Kyu;Lee, Jae-Hwi;Choi, Young-Wook
    • Journal of Pharmaceutical Investigation
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    • v.34 no.6
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    • pp.521-527
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    • 2004
  • Cimetidine is a histamine $H_2-receptor$ antagonist, used for the treatment of endoscopically or radiographically comfirmed duodenal ulcer, pathologic GI hypersecretory conditions, and active, benign and gastric ulcer. Simple method for determining cimetidine in human plasma has been developed and validated. The analytical procedure for cimetidine showed a linear relationship in the concentration ranges from $0.05\;to\;5\;{\mu}g/ml$. Coefficient of variance (CV, %) for intraday and interday validation and relative error (RE, %) were less than ${\pm}15%$. Based on this analytical method, the bioequivalence of two cimetidine 400 mg tablets, reference (Tagamet 400 mg) and test drug (Sinil CIMETIDINE 400 mg) was evaluated according to the guidelines set by the Korea Food and Drug Administration (KFDA). Release of cimetidine from the tablets in vitro was tested using KP VIII Apparatus II with various dissolution media (pH 1.2, 4.0, 6.8 buffer solutions and water). Twenty-four healthy volunteers, $21.38{\pm}1.86$ years in age and $68.71{\pm}8.68\;kg$ in body weight, were divided into two groups and a randomized $2{\times}2$ cross-over study was performed. After oral administration of a tablet containing 400 mg of cimetidine, blood samples were taken at predetermined time intervals and concentrations of cimetidine in plasma were determined using HPLC equipped with UV detector. The dissolution profiles of the two tablet formulations were very similar at all dissolution media. In addition, pharmacokinetic parameters such as $AUC_t$ and $C_{max}$ were calculated and ANOVA was employed for the statistical analysis of parameters. The results were revealed that the differences in $AUC_t$ and $C_{max}$ between the two tablets were 4.17 % and 0.97% respectively. At 90% confidence intervals, the differences in these parameters were also within ${\pm}20%$. All of the above mentioned parameters have met the criteria of KFDA guidelines for bioequivalence, indicating that the test drug tablet (Sinil CIMETIDINE tablet) is bioequivalent to Tagamet 400 mg tablet.

Fatigue Analysis based on Kriging for Flaperon Joint of Tilt Rotor Type Aircraft (틸트 로터형 항공기의 플랩퍼론 연결부에 대한 크리깅 기반 피로해석)

  • Park, Young-Chul;Jang, Byoung-Uk;Im, Jong-Bin;Lee, Jung-Jin;Lee, Soo-Yong;Park, Jung-Sun
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.36 no.6
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    • pp.541-549
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    • 2008
  • The fatigue analysis is performed to avoid structural failure in aerospace structures under repeated loads. In this paper, the fatigue life is estimated for the design of tilt rotor UAV. First of all, the fatigue load spectrum for tilt rotor UAV is generated. Fatigue analysis is done for the flaperon joint which may have FCL(fracture critical location). Tilt rotor UAV operates at two modes: helicopter mode such as taking off and landing; fixed wing mode like cruising. To make overall fatigue load spectrum, FELIX is used for helicopter mode and TWIST is used for fixed wing mode. The other hand, the Kriging meta model is used to get S-N regression curve for whole range of material life when S-N test data are analyzed. And then, the second order of S-N curve is accomplished by the least square method. In addition, the coefficient of determination method is used to ensure how accuracy it has. Finally, the fatigue life of flaperon joint is compared with that obtained by MSC. Fatigue.