• Title/Summary/Keyword: coating properties

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Degradation Characteristics of Filament-Winding-Laminated Composites Under Accelerated Environmental Test (필라멘트 와인딩 복합적층재의 환경가속 노화시험 평가)

  • Kim, Duck-Jae;Yun, Young-Ju;Choi, Nak-Sam
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.31 no.3 s.258
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    • pp.295-303
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    • 2007
  • Degradation behaviors of filament-winded composites have been evaluated under the accelerated environmental test of high temperature, water immersion and thermal impact conditions. Two kinds of laminated composites coated by an urethane resin have been used: carbon-fiber reinforced epoxy(T700/Epon-826, CFRP) and glass-fiber reinforced phenolic (E-glass/phenolic, GFRP). For tensile strength of $0^{\circ}$ composites, CFRP showed little degradation while GFRP did high reduction by 25% under the influence of high temperature and water However for water-immersed $90^{\circ}$ composites tensile strength of both CFRP and GFRP showed high reduction. Bending strength and modulus of $90^{\circ}$ composites were largely reduced in water-immersion as well as high temperature environment. Urethane coating on the composite surface improved the bending properties by 20%, however hardly showed such improvement for water-immersed $90^{\circ}$ composites. In case of shear strength and modulus, both CFRP and GFRP showed high reduction by water-Immersion test but did a slight increase by high temperature and thermal impact conditions.

Comparative Study on Ejection Phenomena of Droplets from EHD Jet by Hydrophobic Coating of Nozzle (노즐의 소수성 코팅에 의한 EHD 제트의 액적 토출 현상 비교 연구)

  • Kim, Yong-Jae;Choi, Jae-Yong;Son, Sang-Uk;Ahn, Ki-Cheol;Keum, Hyun-Joon;Lee, Suk-Han;Byun, Do-Young;Ko, Han-Seo
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1742-1746
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    • 2008
  • An EHD (Electro-Hydro-Dynamic) jet for electrostatic inkjet head shows advantages to print micro-size patterns using various inks because it can generate sub-micron droplets and can use highly viscous inks. Thus, many researchers in industrial fields are concerned about the EHD jet in these days. Since the basic principle of the EHD jet is to form a droplet from an apex of meniscus at the end of the nozzle, the ejection mechanism can be changed by the shape of the meniscus. The stable ejection of the droplet is greatly affected by the shape of the meniscus which is also influenced by surface characteristics of the nozzle, electric potential and ink properties. Experiments have been performed using the nozzles with hydrophilic and hydrophobic coatings in this study. The hydrophobic nozzle forms the stable droplets in wider range of the electric potential than the hydrophilic nozzle does.

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Damage Detection and Suppression in Composites Using Smart Technologies

  • Takeda, Nobuo
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.26-36
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    • 2001
  • Smart sensors and actuators have recently been developed. In this study, first, small-diameter fiber Bragg grating (FBG) sensors developed by the author, whose cladding and polyimide coating diameters were 40 and $52{\mu}m$, respectively, were embedded inside a laminate without resin-rich regions around sensors and the deterioration of mechanical properties of the composite laminate. The small-diameter FBG sensor was embedded in $0^{\circ}$ ply of a CFRP laminate for the detection of transverse cracks in $90^{\circ}$ ply of the laminate. The reflection spectra from the FBG sensor were measured at various tensile stresses. The spectrum became broad and had some peaks with an increase of the transverse crack density. Furthermore, the theoretical calculation reproduced the change in the spectrum very well. These results show that the small-diameter FBG sensors have a potential to detect the occurrence of transverse cracks through the change in the form of the spectrum, and to evaluate the transverse crack density quantitatively by the spectrum width. On the other hand, shape memory alloy (SMA) films were used to suppress the initiation and growth of transverse cracks in CFRP laminates. Pre-strained SMA films were embedded between laminas in CFRP laminates and then heated to introduce the recovery stress in SMA films and compressive stresses in the weakest plies ($90^{\circ}$ ply). The effects of recovery stresses are demonstrated in the experiments and well predicted using the shear-lag analysis and the nonlinear constitutive equation of SMA films.

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Photodegradation of Volatile Organic Compound (VOC) Through Pure TiO2 and V-Doped TiO2 Coated Glasses

  • Moon, Jiyeon;Kim, Seonmin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.425.2-425.2
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    • 2014
  • $TiO_2$ possesses great photocatalytic properties but absorbs only UV light owing to high band gap energy (Eg = 3.2 eV). By narrowing the band gap through doping a metal ion, the photocatalytic activity can be enhanced in condition of the light of a higher than 365 nm wavelength. Main purpose for this study is to evaluate the activities of metal doped $TiO_2$ for degrading the volatile organic compounds (VOCs); p-xylene is chosen in the VOC removal test. Vanadium is selected in this study because an ionic radius of vanadium is almost the same as titanium ion and vanadium can be easily doped into $TiO_2$. V-doped $TiO_2$ was synthesized by sol-gel methods and compared with pure $TiO_2$. Pure TiO2 powder and V-doped $TiO_2$ powder were coated on glasses by spray coating method. UV-Visible spectrophotometer was used for the measurement of the band gap changes. VOC concentration degradation level was tested with using various UV light sources in an enclosed chamber. Catalytic activities of prepared samples were evaluated based on the experimental results and compared with coated pure $TiO_2$ sample.

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Development of MEMS based Piezoelectric Inkjet Print Head and Its Applications

  • Shin, Seung-Joo;Lee, Hwa-Sun;Lee, Tae-Kyung;Kim, Sung-Jin
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.20.2-20.2
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    • 2010
  • Recently inkjet printing technology has been developed in the areas of low cost fabrication in environmentally friendly manufacturing processes. Although inkjet printing requires the interdisciplinary researches including development of materials, manufacturing processes and printing equipment and peripherals, manufacturing a printhead is still core of inkjet technology. In this study, a piezoelectric driven DOD (drop on demand) inkjet printhead has been fabricated on three layers of the silicon wafer in MEMS Technology because of its chemical resistance to industrial inks, strong mechanical properties and dimensional accuracy to meet the drop volume uniformity in printed electronics and display industries. The flow passage, filter and nozzles are precisely etched on the layers of the silicon wafers and assembled through silicon fusion bonding without additional adhesives. The piezoelectric is screen-printed on the top the pressure chamber and the nozzle plate surface is treated with non-wetting coating for jetting fluids. Printheads with nozzle number of 16 to 256 have been developed to get the drop volume range from 5 pL to 80 pL in various industrial applications. Currently our printheads are successfully utilized to fabricating color-filters and PI alignment layers in LCD Flat Panel Display and legend marking for PCB in Samsung Electronics.

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The Fabrication of Ferroelectric PZT thin films by Sol-Gel Processing (졸-겔법에 의한 강유전성 PZT 박막의 제작)

  • Lee, B.S.;Chung, M.Y.;You, D.H.;Kim, Y.U.;Lee, S.H.;Lee, N.H.;Ji, S.H.;Park, S.H.;Lee, D.C.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05c
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    • pp.93-96
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    • 2002
  • In this study, PZT thin films were fabricated using sol-gel processing onto Si/$SiO_2$/Ti/Pt substrates. PZT sol with different Zr/Ti ratio(20/80, 30/70, 40/60, 52/48) were prepared, respectively. The films were fabricated by using the spin-coating method on substrates. The films were heat treated at $450^{\circ}C$, $650^{\circ}C$ by rapid thermal annealing(RTA). The preferred orientation of the PZT thin films were observed by X-ray diffraction(XRD), and Scanning electron microscopy(SEM). All of the resulting PZT thin films were crystallized with perovskite phase. The fine crystallinity of the films were fabricated. Also, we found that the ferroelectric properties from the dielectric constant of the PZT thin films were over 600 degrees, P-E hysteresis constant. And the leakage current densities of films were lower than $10^{-8}A/cm^2$. It is concluded that the PZT thin films by sol-gel process to be convinced of application for ferroelectric memory device.

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A study on the Preparation Methods of the Immobilized Encapsulation PVA-media for Wastewater Treatment (포괄고정화 PVA-gel의 물리적 특성 연구)

  • Lee, Eun-Woo;Chang, In-Soung;Chung, Son-Young;Nam, Byeong-Uk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.6 no.2
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    • pp.116-121
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    • 2005
  • Immobilization technique by PVA encapsulation is an effective alternative for wastewater treatment. However little information is available about the effect of PVA characteristics on physical properties as an encapsulation media. This study aims at investigating the effect of the preparation methods of PVA and filler addition to media on the solubility of PVA. The solubility decreased as the freezing temperature decreased and the vacuum-drying was applied. Addition of the PAC (Powered Activated Carbon) and organoclay decreased the solubility of the PVA gels. Organoclay was more effective for lowering the solubility about 25% than the PAC. Nitrification with the PVA-coating media was less sufficient than with the polyurethane media due to the mass transfer restriction for oxygen and nutrients.

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The study on preparation of $Sr_xBa_{1-x}$ $Nb_2O_6$ piezoelectric Thin Film of tungsten-bronze type by Metal Organic Decomposition Process and their properties (MOD 공법을 이용한 텅스텐 브론즈구조의 $Sr_x Ba_{1-x}$ $Nb_2O_6$ 압전 박막의 제조 및 특성 연구)

  • Kim, Kwang-Sik;Kim, Kyoung-Won;Jang, Gun-Ik;Ur, Soon-Chul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.248-249
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    • 2005
  • The tungsten bronze type of strontium barium niobate(SBN) thin film was synthesized by metal organic decomposion method for SBN stock solution and the SBN thin film process were deposited by spin-coating process on Pt-deposited si-wafer(100) by magnetron sputtering system. The thickness of SBN thin film was 150$\sim$200 nm and were optimized for rpm of spin-coater system. The structural variation of SBN thin film was studied by TG-DTA and XRD. The deposited SBN stock solution on annealing at $400\sim800^{\circ}C$ a pure tungsten bronze SBN phase and the corresponding average grain size about 500$\sim$1000 nm influenced by annealing temperature.

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Effect of Process Parameters on Deposition Characteristics in Fabrication of Coated Tools (코팅공구의 제조에서 공정인자가 증착특성에 미치는 영향)

  • 김종희
    • Journal of Surface Science and Engineering
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    • v.28 no.6
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    • pp.368-375
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    • 1995
  • Thermal CVD method is in general used for the fabrication of TiC/$Al_2O_3$-coated carbide tools. The growth of TiC layer and the coating morphology depended on the chemical composition of the hard metal substrate on which the tool properties were strongly influenced. TiC-coated layer was grown by the diffusion of carbon from the substrate, whereas the growth of $Al_2O_3$ layer was unrelated to the composition of substrate. In the nitride hard coatings of Zr, Nb and Mo metals deposited on high speed steel substrate by magnetron sputtering, the reactivity of the metal elements was decreased with increasing group number in one period of the periodic system. The hard material films exhibited the highest adhesion with the chemical composition of stoichiometry or substoichiometry. The critical load as a measure of adhesion was evaluated using scratch tester. The CVD tools indicated the values of 80 and 40N in the coated layers with proper bonding to the substrate and with $\eta$ phase of 1$\mu\textrm{m}$ in the interface respectively, but the nitride films prepared by sputtering of PVD showed only the values between 10 and 20N.

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Development of Evaluation Method for Drug Release Propreties in Drug Eluting Stent (약물방출스텐트의 약물 방출 특성 평가 방법 개발)

  • Song, J.M.;Baek, H.;Lee, S.Y.;Jang, D.H.;Seo, M.Y.;Park, G.J.;Maeng, Eun-Ho
    • Journal of Biomedical Engineering Research
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    • v.34 no.2
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    • pp.69-72
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    • 2013
  • The goal of this study is to develop test method for evaluating the drug eluting properties of drug eluting stents (DES). PBS and the detergent solutions, presented by each DES manufacturer, were used for drug release of DES coated with paclitaxel, zotarolimus and everolimus. The drugs which are coating DES were not released by PBS but released by the detergent solutions, finally paclitaxel 83.38%, zotarolimus 103.85% and everolimus 115.78%. It seems that the use of the detergents is necessary in order to release the drugs because those drugs are extremely hydrophobic. In conclusion, using of detergent solutions presented by each manufacturer were suitable for evaluating the drug eluting property of drug eluting stent.