• Title/Summary/Keyword: coating method

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Preparation of low refractive index $SiO_xF_y$ optical thin films by ion beam assisted deposition (이온빔보조증착으로 제작한 저굴절률 $SiO_xF_y$ 광학박막의 특성 연구)

  • 이필주;황보창권
    • Korean Journal of Optics and Photonics
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    • v.9 no.3
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    • pp.162-167
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    • 1998
  • $SiO_xF_y$ optical thin films of lower refractive indices than glass substrates were fabricated by the CF$_4$ ion beam assisted deposition method and the optical, structural and chemical properties of them were investigated. Refractive index of $SiO_xF_y$ films was varied from 1.455 to 1.394 by decreasing the anode voltage or from 1.462 to 1.430 by increasing the current density of end-Hall ion source. FT-IR and XPS analyses show that as the F concentration increases, the Si-O bond at $1080m^{-1}$ shifts to higher wavenumber, the OH bonds are reduced drastically, and the fluorine atoms at the air-film interface are desorbed out by reacting with $H_2O$ in the atmosphere. $SiO_xF_y$ thin films are amorphous by the XRD analysis and have the compressive stress below 0.3 GPa. As an application of $SiO_xF_y$ thin films a two-layer antireflection coating was fabricated using a $SiO_xF_y$ film as a low refractive index layer and a Si film as an absorbing one.

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Gas Permeation Characteristics of Silica Membrane Prepared by Ultrasonic Spray Pyrolysis (초음파 분무 열분해법에 의해 합성한 실리카 막의 기체 투과 특성)

  • Lee Kew-Ho;Youn Min-Young;Park Sang-Jin;Lee Dong-Wook;Sea Bongkuk
    • Membrane Journal
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    • v.15 no.2
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    • pp.105-113
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    • 2005
  • Silica membranes were prepared on a porous metal sheet by ultrasonic spray pyrolysis method for gas separation at high temperatures. In order to improve the permselectivity, silica was deposited in the sol-gel derived $silica/\gamma-alumina$ intermediate layer by pyrolysis of tetraethyl orthosilicate (TEOS) at 873 K. The pyrolysis with forced cross flow through the porous wall of the support was very effective in plugging mesopores, Knudsen diffusion regime, that were left unplugged in the membranes. At permeation temperature of 523 K, the silica/alumina composite membrane showed $H_2/N_2$ and water/methanol selectivity as high as 17 and 16, respectively, by molecular sieve effect.

Understanding the Foreign Tech-Trend of Artificial Skin by the Analysis of Patents (특허정보분석을 통한 해외 인공피부 기술동향)

  • 이상필;강종석;이영무
    • Membrane Journal
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    • v.14 no.2
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    • pp.85-98
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    • 2004
  • The situation of technology Predominance and the distribution of core technology were visually mapped thorough the investigation of technical trend during 20 years, which was provided with the analysis of patent information for the artificial skin. Therefore, it was expected that technology mapping by means of multilateral analysis method allowed a good grasp of current technology trend of the artificial skin and the subdivision into nation and a field of research presents the direction of R&D. In the early R&D stage of artificial skin, the preparation technology of filters implantable into the living body including nursing devices, bandages, and dressings or absorbent pads (A6IF-002/10) was on the rise in research field of artificial skin until 1980's. And then the materials technology for coating prostheses (A6l L-027/00)was leading the core technology of artificial skin. Also, Nowadays the fusion technology connected the material technology with the cultivation technology of undifferentiated human or animal cells/tissues including culture media (C l2N-005/00, C 12N-005/06) was highlighted all over the world.

A Study of the Influence of Negative Skin Friction on Single Piles from Consolidation Analyses (압밀해석을 통한 부마찰이 작용하는 단독말뚝의 거동분석)

  • Lee, Cheolju
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.2
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    • pp.29-36
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    • 2009
  • A series of two-dimensional (2D) finite element analyses have been performed to study the behaviour of single piles in consolidating ground. The analysis was conducted based on coupled analyses by considering changes of pore water pressure in the clay. In the analyses the soil slippage at the pile and the soil interface has been included. The method widely used in practice somewhat overestimates dragload by about 25% compared to the rigorous numerical analysis since partial mobilization of skin friction near neutral plane and reductions in the vertical soil stress is not incorporated. When soil slip develops at most of the pile length at the pile-soil interface during consolidation, further increases in dragload is not significant. Application of coating on the pile surface can reduce dragload and pile settlement substantially, but under an axial load on the pile head very large pile settlement can be developed unless pile tip is located to a stiff bearing layer.

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Effect of Boron Carbide on the Morphology of SiC Conversion Layer of Graphite Substrate formed by Chemical Vapor Reaction (화학기상반응으로 흑연 위에 만든 SiC 반응층의 모양에 미치는 보론 카바이드의 영향)

  • Hong, Hyun-Jung;Riu, Doh-Hyung;Cho, Kwang-Youn;Kong, Eun-Bae;Shin, Dong-Geun;Shin, Dae-Kyu;Lee, Jae-Sung
    • Journal of the Korean Ceramic Society
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    • v.44 no.8
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    • pp.445-450
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    • 2007
  • A conversion layer of SiC was fabricated on the graphite substrate by a chemical vapor reaction method in order to enhance the oxidation resistance of graphite. The effect of boron carbide containing powder bed on the morphology of SiC conversion layer was investigated during the chemical vapor reaction of graphite with the reactive silicon-source at $1650^{\circ}C\;and\;1700^{\circ}C$ for 1 h. The presence of boron species enhanced the conversion of graphite into SiC, and altered the morphology of the conversion layer significantly as well. A continuous and thick SiC conversion layer was formed only when the boron source was used with the other silicon compounds. The boron is deemed to increase the diffusion of SiOx in SiC/C system.

Macroscopic Wear Behavior of C/C and C/C-SiC Composites Coated with Hafnium Carbide

  • Lee, Kee Sung;Sihn, Ihn Cheol;Lim, Byung-Joo;Lim, Kwang Hyun
    • Journal of the Korean Ceramic Society
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    • v.52 no.6
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    • pp.429-434
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    • 2015
  • This study investigates the macroscopic wear behaviors of C/C and C/C-SiC composites coated with hafnium carbide (HfC). To improve the wear resistance of C/C composites, low-pressure chemical vapor deposition (LPCVD) was used to obtain HfC coating. The CVD coatings were deposited at various deposition temperatures of 1300, 1400, and $1500^{\circ}C$. The effect of the substrate material (the C/C substrate, the C/C-CVR substrate, or the C/C-SiC substrate deposited by LSI) was also studied to improve the wear resistance. The experiment used the ball-on-disk method, with a tungsten carbide (WC) ball utilized as an indenter to evaluate the wear behavior. The HfC coatings were found to effectively improve the wear resistance of C/C and C/C-SiC composites, compared with the case of a non-coated C/C composite. The former showed lower friction coefficients and almost no wear loss during the wear test because of the presence of hard coatings. The wear scar width was relatively narrower for the C/C and C/C-SiC composites with hafnium coatings. Wear behavior was found to critically depend on the deposition temperature and the material. Thus, the HfC-coated C/C-SiC composites fabricated at deposition temperatures of $1500^{\circ}C$ showed the best wear resistance, a lower friction coefficient, and almost no loss during the wear test.

Fabrication and microstructure of the Fe doped $TiO_{2}$ composite membranes with ultrafine pores (미세기공을 가지는 철이 첨가된 티타니아 복합여과막 제조 및 미세구조)

  • Dong-Sik Bae;Kyong-Sop Han;Sang-Hael Choi
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.3
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    • pp.463-470
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    • 1996
  • Ceramic membrane consisting of an ${\alpha}-Al_{2}O_{3}$ support and Fe doped $TiO_{2}$ top layer was prepared by the sol-gel method. The supported Fe doped $TiO_{2}$ top layer was made by dip coating the support in a mixed sol. The microstructure of the composite membranes was studied by SEM after calcination at $550~850^{\circ}C$. After sintering at $650^{\circ}C$ for 1 hr., the average particle diameter of the Fe doped $TiO_{2}$ top layer was ~40 nm. The supported Fe doped $TiO_{2}$ composite membranes exhibited much higher heat resistance than the $TiO_{2}$ membrane. The Fe doped $TiO_{2}$ composite membrane retained a crack-free microstructure and narrow particle size distribution even after calcination up to $650^{\circ}C$.

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Annual Energy Performance Evaluation of Zero Energy House Using Metering Data (실측데이터를 이용한 에너지제로주택의 연간 에너지성능평가)

  • Lim, Hee-Won;Yoon, Jong-Ho;Shin, U-Cheul
    • KIEAE Journal
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    • v.16 no.3
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    • pp.113-119
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    • 2016
  • Purpose: In this study, we evaluate the annual energy performance of the detached house which was designed with the aim of zero energy. Method: The experimental house which was constructed in Gonju Chungnam in 2013, is the single family detached house of light weight wood frame with $100m^2$ of heating area. Thermal transmittance of roof (by ISO 10211) and building external walls are designed as $0.10W/m^2K$ and $0.14W/m^2$ respectively and low-e coating vacuum window glazing with PVC frame was installed. Also grid connected PV system and natural-circulation solar water heater was applied and 6kWp capacity of photovoltaic module was installed in pitched roof and $5m^2$ of solar collector in vertical wall facing the south. We analyzed the 2014 annual data of the detached house in which residents were actually living, measured though web-based remote monitoring system. Result: First, as a result, total annual energy consumption and energy production (PV generation and solar hot water) are 7,919kWh and 7,689kWh respectively and the rate of energy independence is 97.1% which is almost close to the zero energy. Second, plug load and hot water of energy consumption by category showed the highest numbers each with 33% and 31%, with following space heating 24%, electric cooker 8%, lighting 3% in order. Hot water supply is relatively higher than space heating because high insulation makes it decreased.

Fabrication and Performance Evaluation of Zinc Oxide Varistors for the Arresters used for Station System (발변전소 피뢰기용 산화아연소자의 제작 및 성능평가)

  • Cho, Han-Goo;Han, Se-Won;Kim, Suk-Soo;Yoon, Han-Soo;Lee, Un-Yong;O, Cheol-Gyu;Yu, Kun-Yang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.636-639
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    • 2004
  • This paper presents the fabrication and performance evaluation of zinc oxide varistors for the arresters used for station system. ZnO varistors were fabricated with typical ceramic production methods and the structural and electrical characteristics were investigated. All varistors exhibited high density, which were in the range of $5.41{\sim}5.49g/cm^3$. In the electrical properties the reference voltage increased in the range of $4.410{\sim}5.250kV$ with increasing their thickness and the residual voltage exhibited the same trends as the reference voltage. In the long duration current impulse withstand test, E-2 and F-1 samples failed in the two and four shots, respectively, but E-1 and F-2 samples survived 18 shots during the test. Before and after this test, the variation ratio of residual voltage of E-1 and F-2 samples were -0.34% and 0.05%, respectively, which were in the acceptance range of 5%. According to the results of tests, it is thought that if the fabrication process such as insulating coating, sintering condition, and soldering method is improved, these ZnO varistors would be possible to apply to the station class arresters in the new future.

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A Study on Adhesion and Electro-optical Properties of ITO Films deposited on Flexible PET Substrates with $SiO_2$ Buffer Layer (PET 기판 위해 $SiO_2$ 버퍼층 도입에 따른 IT 박막의 접착 및 전기적.광학적 특성 연구)

  • Kang, Ja-Youn;Kim, Dong-Won;Yun, Hwan-Jun;Park, Kwang-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.316-316
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    • 2008
  • Using an evaporation method, $SiO_2$ was deposited as a buffer layer between a flexible PET substrate and a ITO film deposited by DC magnetron sputtering and electro-optical properties were investigated with thickness variance of $SiO_2$ layers. After coating a $SiO_2$ layer and a ITO film, the ITO/$SiO_2$/PET was heated up to $200^{\circ}C$ and the resistivity and the transmittance were measured by hall effect measurement system and UV/VIS/NIR spectroscopy. As a result of depositing a $SiO_2$ buffer layer, the resistivity increased and the transmittance and adhesion property were enhanced than ITO films with no buffer layers and the resistivity was lowered as $SiO_2$ thickness increased from 50 $\AA$ to 100 $\AA$. It was found that the transmittance was independent of annealing temperature variance in $150^{\circ}C{\sim}200^{\circ}C$ and the resistivity decreased as the temperature increased and especially decreasing rate of the resistivity was higher as the buffer layer thickness was thinner. So under optimized depositing of $SiO_2$ buffer layers and post-annealing of ITO/$SiO_2$/PET, ITO films with enhanced adhesion, electro-optical properties can obtained.

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