• Title/Summary/Keyword: coal waste

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The utilization of waste seashell for high temperature desulfurization

  • Kim, Young-Sik;Kim, Taek-Geun;Sim, Eon-Bong;Seo, Jeong-Min
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2005.12a
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    • pp.66-71
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    • 2005
  • The waste seashells were used for the removal of hydrogen sulfide from a hot gas stream. The sulphidation of waste seashells with $H_2S$ was studied in a thermogravimetric analyzer at temperature between 600 and 800$^{\circ}C$. The desulfurization performance of the waste seashell sorbents was experimentally tested in a fixed bed reactor system. Sulfidation experiments performed under reaction conditions similar to those at the exit of a coal gasifier showed that preparation procedure and technique, the type and the amount of seashell, and the size of the seashell affect the $H_2S$ removal capacity of the sorbents. The pore structure of fresh and sulfided seashell sorbents was analyzed using mercury porosimetry, nitrogen adsorption, and scanning electron microscopy.

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Reaction of $H_2S$ with Sorbents of Waste Seashell

  • Kim, Young-Sik;Kim, Taek-Gyun;Lee, Yong-Du;Shim, Eon-Bong;Jung, Jong-Hyeon
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2005.06a
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    • pp.378-380
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    • 2005
  • The waste seashells were used for the removal of hydrogen sulfide from a hot gas stream, The sulphidation of waste seashells with H$_2$S was studied in a thermogravimetric analyzer at temperature between 600 and 800${\circ}$C . The desulfurization performance of the waste seashell sorbents was experimentally tested in a fixed bed reactor system. Sulfidation experiments performed under reaction conditions similar to those at the exit of a coal gasifier showed that preparation procedure and technique, the type and the amount of seashell, and the size of the seashell affect the H2S removal capacity of the sorbents. The pore structure of fresh and sulfided seashell sorbents was analyzed using mercury porosimetry, nitrogen adsorption, and scanning electron microscopy.

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Study of manufacturing of portland cement and sulfuric acid from waste gypsum and the utilization of anthracite coal other than cokes as reaction promotor (폐석고로부터 시멘트와 유산제조 및 기반응촉진제 탄소의 무연탄 대체에 관한 연구)

  • Lee Suk Woo
    • Cement
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    • s.30
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    • pp.44-50
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    • 1969
  • To manufacture portland cement and sulfuric acid from gypsum has long been established in Europe. As sulfur, more Precisely sulfuric acid, is getting around shortage, it boosts hunt for alternate sources and for new fertilizer process. As the result, all

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Review of the 21th Energy (21세기의 에너지에 관한 고찰)

  • Lee, Hyun-Hwa
    • Journal of the Korean Professional Engineers Association
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    • v.39 no.5 s.188
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    • pp.20-24
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    • 2006
  • The energy of 97% consumed by our country depends on it's import from foreign market. This article covers hydrogen, fuel-cell, coal liquefaction gasification energy, and solar, wind, photovoltaic, hydro power, ocean, waste, geothermal, bio energy that is renewable energy, and so on, which are new-generation energy sources, increasing the concern on new & renewable source of enenrgy in future.

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Development of Sulfated Oyster Shell-Based Solidifying Agent for Flowable Backfill Material (황산처리 굴패각을 이용한 유동성 뒷채움용 고화재 개발)

  • Wang, Xue;Kim, Sung Bae;Kim, Chang-Joon
    • Clean Technology
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    • v.24 no.4
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    • pp.315-322
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    • 2018
  • Industrial use of waste oyster shells is limited because of requiring excessive energy for converting natural oyster shells in the form of calcium carbonate ($CaCO_3$) into calcium oxide (CaO) for this purpose. This study aimed to develop energy-saving process for producing solidifying agent using waste oyster shells for backfill materials. It was suggested that oyster shells were converted to calcium sulfates which were mixed with sodium hydroxide solution and red clay, forming solid specimen. The optimal concentrations of sulfuric acid for sulfation of oyster shell and sodium hydroxide to generate calcium hydroxide ($Ca(OH)_2$), were determined. Unconfined compressive strength of solid specimen increased with increasing the content of solidifying agent while it increased also with increasing ratio of natural oyster shells to coal ash. The result clearly demonstrates that solidifying agent consisting of sulfuric acid-treated oyster shell, coal ash, and sodium hydroxide solution, can be effectively utilized for preparing backfill materials using natural oyster shell and coal ash. Sulfuric acid-treated oyster shell-based solidifying agent has not been previously developed and will contribute to broaden industrial application of waste oyster shells.

Priority Assessment for Remediation of Heavy Metals Closed/Abandoned Mine Areas Using Pollution Indexes

  • Kim Hee-Joung;Yang Jae-E.;Park Byung-Kil;Kong Sung-Ho;Lee Jai-Young;Jun Sang-Ho
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.183-193
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    • 2006
  • Several metalliferous and coal mines, including Seojin and Okdong located at the Kangwon province, were abandoned or closed since 1989 due to the mining industry promotion policy and thus disposed an enormous amount of mining wastes without a proper treatment facilities, resulting in water and soil pollution in the downstream areas. However, no quantitative assessment was made on soil and water pollution by the transport of mining wastes such as acid mine drainage, mine tailing, and rocky waste. In this research, total and fractional concentrations of heavy metals in mining wastes were analyzed and accordingly the degree of water and soil pollutions in the stream area were quantitatively assessed employing the several pollution indices. Concentrations of Ni, Cd, and Pb in soils near the abandoned coal mine areas were 1,240.0, 25.0 and 1,093.0 mg/kg, respectively, and these concentrations were higher than those in soils near the closed metalliferous mine areas. Also Cu concentrations in soils near the tailing dams were about 1967 mg/kg, which is considered as very polluted level. Results demonstrated that soil at the abandoned mine areas were highly contaminated by AMO, tailing, and effluents of the mining wastes. Therefore, a prompt countermeasure on the mining waste treatment and remediation of the codntaminated water and soil should be made to the abandoned or closed metalliferous and coal mines located at the abandoned mine area.

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