• Applied Chemistry for Engineering
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• v.18 no.5
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• pp.495-500
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• 2007

The inside wall of a coal gasifier is lined with refractory, and the corrosion of the refractory is an important factor affecting the refractory lifetime and the replacement period. This paper examines the changes in microstructure of a chromia refractory due to chemical reactions with slag having varying amounts of $Fe_2O_3$. Slag samples were prepared by adding $Fe_2O_3$ to KIDECO slag, and static corrosion experiments were carried out at $1550^{\circ}C$. The layer of $(Fe,Cr)_3O_4$ formation and the depth of Fe depletion in the infiltrating slag were determined. In addition, FactSage equilibrium calculations were carried out in order to determine the conditions of formation, and to compare with the experimental observations. In the sample exposed to KIDECO slag, which has about 10 wt% $Fe_2O_3$, the formation of $(Fe,Cr)_3O_4$ was not observed. As the $Fe_2O_3$ concentration in slag increased, $(Fe,Cr)_3O_4$ formation and Fe depletion depth increased. Increasing $Fe_2O_3$ concentration also made the slag/refractory interface indistinguishable. Equilibrium calculations predicted that higher $Fe_2O_3$ concentrations favor chromite formation at gasification temperatures. The chromite formation was most favorable when the amount of $Cr_2O_3$ was limited, as in the case of dissolved $Cr_2O_3$ in slag. When the concentration of $Fe_2O_3$ in slag was less than 20%, the formation of chromite was least favorable in the system with equal amounts of slag and refractory.

• 한국연소학회:학술대회논문집
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• 2015.12a
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• pp.93-96
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• 2015

Commercial coal gasifiers typically use entrained flow type reactors, but have unique features in terms of reactor shape, gasifying agent, coal feeding type, ash/slag discharge, and reaction stages. The MHI gasifier is characterized as air-blow dry-feed entrained reactor, which incorporates a short combustion stage at the bottom and a tall gasification stage above. This study investigates the flow and reaction characteristics inside a MHI gasifier by using computational fluid dynamics (CFD) in order to understand its design and operation features. For its pilot-scale system at 200 ton/day capacity, the distribution of coal and air supply between the two reaction stages was varied. It was found that the syngas composition and carbon conversion rate were not significantly influenced by the changes in the distribution of coal and air supply. However, the temperature, velocity and flow pattern changed sensitively to the changes in the distribution of coal and air supply. The results suggest that one key factor to determine the operational ranges of coal and air supply would be the temperature and flow pattern along the narrower wall between the two reaction stages.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.147-148
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• 2012

The syngas produced from coal gasification is cooled down for gas cleaning by a syngas cooler that produces steam. Due to the presence of fly slag in the syngas, erosion, slagging and corrosion especially in the upper part of the syngas cooler may cause major operational problems. This study investigates the flow, heat transfer and particle behaviors in the syngas cooler of a 300MWe IGCC plant by using computational fluid dynamics. For various operational loads and geometry, the gas and particle flows directly impinged on the wall opposite to the syngas inlet, which may lead to erosion of the membrane wall. In the evaporate channels inside the syngas cololr, the particle flows were concentrated more on the outer channel where slagging becomes more serious. The heat transfer to the wall was mainly by convection which was larger on the side wall below the inlet level.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.05a
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• pp.56-57
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• 2018

This study is a fundamental consideration for using CGS from the IGCC as a fine aggregate for concrete. For the review, the physical properties and hazardous materials content of KS F 2527 were considered. The results showed that KS F 2527 standard was generally satisfied, making it possible to confirm the possibility that it is a fine metal considering its physical properties and hazardous materials content characteristics.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.05a
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• pp.138-139
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• 2018

This study is a basic review of the basic characteristics of mortar as a result of the use of concrete as a fine aggregate for CGS(coal gasification slag) generated from the IGCC(integrated gasification combined cycle). The analysis shows that CGS and crushed sand + seal sand mix is the best combination of CGS combined with about 75 % of CGS based on the effects of promoting liquidity and strength. This is expected to be a positive factor in securing the strength and flexibility of concrete given the optimal mix of CGS, and may also contribute to the improvement of quality.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.04a
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• pp.192-193
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• 2022

In this study, concrete durability was reviewed before CGS, a by-product generated from IGCC, was used as a fine aggregate for concrete. The characteristics of concrete and effect on carbonization according to the type of pre-mixed cement and the CGS substitution rate were analyzed. As a result of the analysis, the depth of carbonation according to the pre-mixed cement types increased by up to 52%, and the carbonation resistance tended to be similar overall when CGS was used as a fine aggregate.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.05a
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• pp.114-115
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• 2021

The research team conducted a series of studies to use CGS as fine aggregate for concrete. In this paper, through the adiabatic temperature rising test, CGS' hydration heating performance and its usability as a mass concrete hydration heating agent were reviewed. According to the analysis, the maximum temperature of the mix of OPC 100 was 53.7℃, and the temperature of CGS 50% was 45.2℃, which was 8.5℃ lower than the OPC 100.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.11a
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• pp.120-121
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• 2021

This study examines the performance of the pre-treatment process system to use CGS, a by-product generated in IGCC, as a concrete fine aggregate for construction materials, on the quality of CGS fine aggregate. As a result of the analysis, it is judged that the quality of fine aggregates of CGS can be improved at both density, absorption rate, and 0.08mm body passage amount after the hydroelectric screening process using water as a medium during the pretreatment process. It is believed that it can be used as basic data for national standard certification of CGS fine aggregates in the future.

• International Journal of Concrete Structures and Materials
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• v.9 no.3
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• pp.283-294
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• 2015

In the present study, a porous concrete with alkali activated slag (AAS) and coal bottom ash was developed and the effect of carbonation on the physical property, microstructural characteristic, and heavy metal leaching behavior of the porous concrete were investigated. Independent variables, such as the type of the alkali activator and binder, the amount of paste, and $CO_2$ concentration, were considered. The experimental test results showed that the measured void ratio and compressive strength of the carbonated porous concrete exceeded minimum level stated in ACI 522 for general porous concrete. A new quantitative TG analysis for evaluating $CO_2$ uptake in AAS was proposed, and the result showed that the $CO_2$ uptake in AAS paste was approximately twice as high as that in OPC paste. The leached concentrations of heavy metals from carbonated porous concrete were below the relevant environmental criteria.

• Journal of Energy Engineering
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• v.27 no.2
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• pp.55-60
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• 2018

In this study investigated the Controlled Low Strength Materials using coal ash and steel slag(KR slag) as the main material in the thermal power plant classified as waste resource. Bottom ash and KR slag are mixed at a ratio of 7: 3 to expand the use of industrial by-products through carbonate($CO_2$-fixation) reactions and inhibit the exudation of heavy metals. The results showed that the water content increased as the content of bottom ash increased. It was confirmed that as the powder content increased, the bleeding ratio decreased. Also, as the content of one kind of ordinary portland cement (OPC) decreased, activation of hydration reaction decreased and compressive strength decreased. However, when the mixed composition is appropriately adjusted, the compressive strength of 2.0 MPa required for the controlled low-strength material can be satisfied.