• Title/Summary/Keyword: co-cycle

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A Study on the V22Ti16Zr16Ni39X7(X=Cr, Co, Fe, Mn, Al) Metal Hydride Electrodes (V22Ti16Zr16Ni39X7(X=Cr, Co, Fe, Mn, Al) 금속수소화물전극에 관한 연구)

  • Kim, Jeong-Seon;Cho, Won-Il;Cho, Byung-Won;Yun, Kyung-Suk;Kim, Sang-Joo
    • Transactions of the Korean hydrogen and new energy society
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    • v.5 no.1
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    • pp.1-8
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    • 1994
  • Lattice structure, hydrogen absorption characteristics, discharge capacity and cycle life of $V_{22}Ti_{16}Zr_{16}Ni_{39}X_7$(X= Cr, Co, Fe, Mn, Al) alloys were investigated. The matrix phases of these alloys were the C14 Laves phase. Chromium-containing alloy had a vanadium-rich phase in addition to the Laves phase. The chromium, maganese, or aluminum-containing alloys had lower hydrogen equilibrium pressure and larger hydrogen absorption content than the cobalt or iron-containing alloys. The discharge capacities of these alloys were 270~330mAh/g. The discharge capacity according to the alloying element X decreased in the order of Mn>Cr>Co, Al)Fe. The charge/discharge cycle lives of the chromium, cobalt or iron-containing alloys were longer than those of maganese or aluminum-containing alloys due to the lower vanadium dissolution rate.

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Comparisons of Performance in CO2 Systems with Operating Conditions (운전조건 변화에 따른 이산화탄소 냉방시스템들의 성능 비교)

  • Bae, Kyung-Jin;Shin, Eun-Sung;Cho, Hong-Hyun
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.1484-1490
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    • 2009
  • Since the cooling performance of a $CO_2$ cooling cycle is varied significantly with a variation of refrigerant charge amount and outdoor temperature, the reliability of $CO_2$ system is down. In this study, the performance characteristics of three kinds of $CO_2$ systems were measured and analyzed by varying refrigerant charge amount and outdoor temperature so as to study the characteristics of variation with cycle option. The applied system options are the single-stage compression(1C-1E) system, two-stage compression with 1-EEV(2C-1E) system, and two-stage compression with 2-EEV(2C-2E) system. The performances of two-stage compression with 2-EEV system were less sensitive than those of other systems and the system operated safely and steadily for wide charge amount. The performance of the two-stage compression with 1-EEV(2C-1E) system was the most sensitive to the charge amount, and that of the single-stage compression(1C-1E) system varied a lot with outdoor temperature.

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Evaluation of Environment Imapcts on TiN-ZrCo Composites Hydrogen Seperation by Material Life Cycle Assessment (TiN-ZrCo 복합수소 분리막의 제조와 환경성 평가)

  • KIM, MINGYEOM;AHN, JOONGWOO;HONG, TAEWHAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.6
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    • pp.627-634
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    • 2017
  • In this study, Material life cycle evaluation was performed to analyze the environmental impact characteristics of TiN-ZrCo membrane manufacturting process. Gabi was used as software. The Eco-Indicator 99 methodology was used to evaluate the 11 impact categories and the 10 impact categories using the CML 2001 methodology. Precursor TiN was synthesized by sol-gel method and zirconium was coated by ball mill method. The metallurgical, physical and thermodynamic characteristics of the membranes were analyzed by using Scanning Electron Microscope (SEM), Energy Dispersive X-ray (EDS), X-ray Diffraction (XRD), Thermo Gravimetry/Differential Thermal Analysis (TG/DTA), Brunauer, Emmett, Teller (BET) and Gas Chromatograph System (GP). As a result of the characterization and normalization, the environmental impacts of each category of impacts were GWP 100 years with the highest environmental impact of 99.9%.

Utility-Connected Solar Power Conditioner Using Edge-Resonant Soft Switching Duty Cycle Sinewave Modulated Inverter Link

  • Ogura, Koki;Chandhaket, Srawouth;Nakaoka, Mutsuo;Terai, Haruo;Sumiyoshi, Shinichiro;Kitaizumi, Takeshi;Omori, Hideki
    • Journal of Power Electronics
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    • v.2 no.3
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    • pp.181-188
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    • 2002
  • The utility interfaced sinewave modulation Inverter for the solar photovoltaic power conditioner with a high frequency transformer is presented for residential applications. As compared with the conventional full-bridge hard switching slnewave PWM inverter with a high frequency link, the simplest single-ended edge-resonant soft switching sinewave inverter with a sinewave duty cycle pulse control scheme is implemented, resulting in size and weight reduction, low cost and high efficiency This paper presents a prototype system of the sinewave zero voltage soft switching sinewave inverter for solar power conditioner, along with its operating principle and unique features. In addition to these, this paper discusses a control implementation to deliver high quality output current. Major design of each component and the power loss analysis under actual power processing is also discussed and evaluated from an experimental point of view A newly developed utility-connected sinewave power conditioning circuit which achieves 92.5% efficiency under 4kW output is demonstrated.

Life cycle greenhouse-gas emissions from urban area with low impact development (LID)

  • Kim, Dongwook;Park, Taehyung;Hyun, Kyounghak;Lee, Woojin
    • Advances in environmental research
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    • v.2 no.4
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    • pp.279-290
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    • 2013
  • In this study, a comprehensive model developed to estimate greenhouse gas (GHG) emissions from urban area with low impact development (LID) and its integrated management practices (IMPs). The model was applied to the actual urban area in Asan Tangjeong district (ATD) as a case study. A rainwater tank (1200 ton) among various LID IMPs generated the highest amount of GHG emissions ($3.77{\times}10^5kgCO_2eq$) and led to the utmost reducing effect ($1.49{\times}10^3kgCO_2eq/year$). In the urban area with LID IMPs, annually $1.95{\times}104kgCO_2eq$ of avoided GHG emissions were generated by a reducing effect (e.g., tap water substitution and vegetation $CO_2$ absorption) for a payback period of 162 years. A sensitivity analysis was carried out to quantitatively evaluate the significance of the factors on the overall GHG emissions in ATD, and suggested to plant alternative vegetation on LID IMPs.

Thermal and Flow Analysis of Organic Rankine Cycle System Pipe Line for 250 kW Grade Waste Gas Heat Recovery (250kW급 폐열회수 시스템용 유기랭킨사이클 배관 열유동해석에 관한 연구)

  • Kim, Kyoung Su;Bang, Se Kyoung;Seo, In Ho;Lee, Sang Yun;Yi, Chung Seob
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.18 no.4
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    • pp.26-33
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    • 2019
  • This study is a thermal and flow analysis of Organic Rankine Cycle (ORC) pipe line for 250 kW grade waste gas heat recovery. We attempted to obtain the boundary condition data through the process design of the ORC, which can produce an electric power of 250 kW through the recovery of waste heat. Then, we conducted a simulation by using STAR-CCM+ to verify the model for the pipe line stream of the 250 kW class waste heat recovery system. Based on the results of the thermal and flow analyses of each pipe line applied to the ORC system, we gained the following conclusion. The pressure was relatively increased at the pipe outside the refracted part due to the pipe shape. Moreover, the heat transfer amount of the refrigerant gas line is relatively higher than that of the liquid line.

Estimating carbon dioxide uptake in wetland ecosystems of Tumen River Basin using eddy covariance flux data (에디 공분산 기반의 플럭스 타워 관측자료를 이용한 두만강 유역 습지 생태계 CO2 흡수량 분석)

  • Chen, Pengshen;Zhao, Shuqing;Cui, Guishan;Lee, Dongkun
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.27 no.3
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    • pp.67-74
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    • 2024
  • In the context of rapid temperature rise in mid-to-high latitude regions, cold region wetlands have become a hotspot for current wetland carbon cycle research due to their high sensitivity to climate change. Strengthening the monitoring of CO2 fluxes in wetland ecosystems is of great practical significance for clarifying the carbon balance of wetlands and maintaining the ecological balance of wetland ecosystems in China's high latitude regions. In this study, the carbon flux (NEE, Net ecosystem exchange; GPP, Gross Primary Production; RECO, Ecosystem response) of Jingxin Wetland was monitored by eddy correlation method from August 2021 to March 2024.2022-2023 shows CO2 sinks, absorbing 349.4 g C·m-2·yr-1 annually. The correlation analysis showed that Ta, VPD and PPFD were the main environmental factors affecting CO2 flux in Jingxin wetland.

Estimation of Carbon Emission and LCA (Life Cycle Assessment) from Soybean (Glycine max L.) Production System (콩의 생산과정에서 발생하는 탄소배출량 산정 및 전과정평가)

  • So, Kyu-Ho;Lee, Gil-Zae;Kim, Gun-Yeob;Jeong, Hyun-Cheol;Ryu, Jong-Hee;Park, Jung-Ah;Lee, Deog-Bae
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.6
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    • pp.898-903
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    • 2010
  • This study was carried out to estimate carbon emission using LCA (Life Cycle Assessment) and to establish LCI (Life Cycle Inventory) database of soybean production system. Based on collecting the data for operating LCI, it was shown that input of organic fertilizer was value of 3.10E+00 kg $kg^{-1}$ soybean and it of mineral fertilizer was 4.57E-01 kg $kg^{-1}$ soybean for soybean cultivation. It was the highest value among input for soybean production. And direct field emission was 1.48E-01 kg $kg^{-1}$ soybean during soybean cropping. The result of LCI analysis focussed on greenhouse gas (GHG) was showed that carbon footprint was 3.36E+00 kg $CO_2$-eq $kg^{-1}$ soybean. Especially $CO_2$ for 71% of the GHG emission. Also of the GHG emission $CH_4$, and $N_2O$ were estimated to be 18% and 11%, respectively. It might be due to emit from mainly fertilizer production (92%) and soybean cultivation (7%) for soybean production system. $N_2O$ was emitted from soybean cropping for 67% of the GHG emission. In $CO_2$-eq. value, $CO_2$ and $N_2O$ were 2.36E+00 kg $CO_2$-eq. $kg^{-1}$ soybean and 3.50E-01 kg $CO_2$-eq. $kg^{-1}$ soybean, respectively. With LCIA (Life Cycle Impact Assessment) for soybean production system, it was observed that the process of fertilizer production might be contributed to approximately 90% of GWP (global warming potential). Characterization value of GWP was 3.36E+00 kg $CO_2$-eq $kg^{-1}$.

Evaluations for Representativeness of Light-Duty Diesel Vehicles' Fuel-based Emission Factors on Vehicle Operating Conditions (연료 소비량에 기반한 소형 경유차 대기오염물질 배출계수의 운전조건별 대표성 평가)

  • Lee, Taewoo;Kwon, Sangil;Son, Jihwan;Kim, Jiyoung;Jeon, Sangzin;Kim, Jeongsoo;Choi, Kwangho
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.6
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    • pp.745-756
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    • 2013
  • The purpose of this study is to evaluate representativeness of fuel-based emission factors. Twelve light-duty diesel vehicles which meet Euro-3 to 5 legislative emission limits were selected for emission tests. Second-by-second modal emission rates of vehicles were measured on a standard laboratory chassis dynamometer system. An off-cycle driving cycle was developed as a representative Korean real-world on-road driving cycle. Fuel-based emission factors were developed for short trip segments that involved in the selected driving cycle. Each segment was defined to have unit travel distance, which is 1 km, and characterized by its average speed and Relative Positive Acceleration (RPA). Fuel-based $NO_x$ emission factors demonstrate relatively good representativeness in terms of vehicle operation conditions. $NO_x$ emission factors are estimated to be within ${\pm}20%$ of area-wide emission factor under more than 40% of total driving situations. This result implies that the fuel-based $NO_x$ emission factor could be practically implemented into the on-road emission management strategies, such as a remote sensing device (RSD). High emitting vehicles as well as high emitting operating conditions heavily affect on the mean values and distributions of CO and THC emission factors. Few high emitting conditions are pulling up the mean value and biasing the distributions, which weaken representativeness of fuel-based CO and THC emission factors.

Effect of Welding Thermal Cycle on Microstructure and Pitting Corrosion Property of Multi-pass Weldment of Super-duplex Stainless Steel (슈퍼 듀플렉스 스테인리스강 다층용접부의 미세조직 및 공식(Pitting Corrosion)에 미치는 용접열사이클의 영향)

  • Nam, Seong-Kil;Park, Se-Jin;Na, Hye-Sung;Kang, Chung-Yun
    • Journal of Welding and Joining
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    • v.28 no.4
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    • pp.18-25
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    • 2010
  • Super-duplex stainless steels (SDSS) have a good balance of mechanical property and corrosion resistance when they consist of approximately equal amount of austenite and ferrite. The SDSS needs to avoid the detrimental phases such as sigma(${\sigma}$), chi(${\chi}$), secondary austenite(${\gamma}2$), chromium carbide & nitride and to maintain the ratio of ferrite & austenite phase as well known. However, the effects of the subsequent weld thermal cycle were seldom experimentally studied on the micro-structural variation of weldment & pitting corrosion property. Therefore, the present study investigated the effect of the subsequent thermal cycle on the change of weld microstructure and pitting corrosion property at $40^{\circ}C$. The thermal history of root side was measured experimentally and the change of microstructure of weld root & the weight loss by pitting corrosion test were observed as a function of the thermal cycle of each weld layer. The ferrite contents of root weld were reduced with the subsequent weld thermal cycles. The pitting corrosion was occurred in the weld root region in case of the all pitted specimen & in the middle weld layer in some cases. And the weight loss by pitting corrosion was increased in proportional to the time exposed at high temperature of the root weld and also by the decrease of ferrite content. The subsequent weld thermal cycles destroy the phase balance of ferrite & austenite at the root weld. Conclusively, It is thought that as the more subsequent welds were added, the more the phase balance of ferrite & austenite was deviated from equality, therefore the pitting corrosion property was deteriorated by galvanic effect of the two phases and the increase of 2nd phases & grain boundary energy.