• Clean Technology
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• v.16 no.3
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• pp.182-190
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• 2010

The feasibility of clean technology to minimize the $CO_2$ emission by recycling and reuse the waste materials and energy have been studied for the cement industry. A life cycle assessment (LCA) was performed for an alternative raw material-supply method to use the molted slag as the major raw material in the cement clinker manufacturing. Using this new method, a 60% of $CO_2$ could be reduced that comes out during the decarboxylation from the cement rotary kiln. The energy-efficiency improvement and the alternative energy methods that had been determined in our previous study through the environmental assessment of cement industry were applied to the study for the reduction of $CO_2$ emission. The natural gas, one of the fossil fuels, was also used as the first choice to get the result at the earliest time by the most economic and the most efficient green technology and to switch into the carbon neutral energy consumption pattern.

• The KSFM Journal of Fluid Machinery
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• v.14 no.2
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• pp.41-46
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• 2011

This study investigated the changes in performance and operating characteristics of an F-class gas turbine according to the change of working fluid from air to carbon dioxide. The revised gas turbine is the topping cycle of the semi-closed oxy-fuel combustion combined cycle. With the same turbine inlet temperature, the $CO_2$ gas turbine is expected to produce about 85% more power. The main contributor is the greater compressor mass flow and the added oxygen flow for the combustion. Compressor pressure ratio increases about 50%. However, the gas turbine efficiency reduces about 10 %. Modulation of inlet guide vane to reduce the compressor inlet mass flow, the major purpose of which is to reduce the compressor inlet Mach number, was also performed.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.11a
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• pp.149-150
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• 2011

Recently, Goverment's Energy-saving policy in Korea as 'Green Growth' is very remarkable effort. By intensive poliicies, the private is encouraged to participate in policy. Especially, it is very important in the field of architecture and we have to work for construction of law system. However, these efforts of the government buildings for energy efficiency in use stage is as mandatory system that may occur in the construction phase and the enviromental impact of greenhouse gas reductions is not affected. For this reason, Assess the amount of the energy consumption and CO₂ emissioont of Government Buildings in 2010 ordered by PPS(Public Procurement Service) in the construction phase and suggest to recognize the need for legal restrictions.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.17 no.5
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• pp.410-417
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• 2005

The cooling performance of a transcritical $CO_{2}$ cycle varies significantly with a variation of refrigerant charge amount. In this study, the performance of the $CO_{2}$ system was measured and analyzed by varying refrigerant charge amount at a standard test condition. Besides, the losses of the major components in the $CO_{2}$ system were estimated by evaluating entropy generation with refrigerant charge amount. The losses in the expansion device and the gascooler show the major portion of the total loss. For undercharging conditions, the expansion loss dominates the overall system performance, while the gascooler loss increases significantly with an increase of refrigerant charge amount.

• Bulletin of the Korean Chemical Society
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• v.27 no.2
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• pp.255-265
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• 2006

The oxidation of hydrazobenzene by molecular oxygen in the polar solvent methanol is catalysed by a Schiff's base complex Co(3MeOsalen) which is a synthetic oxygen carrier. The products are trans-azobenzene and water. The rate of the reaction has been studied spectrophotometrically and the rate law established. A mechanism involving a ternary complex of catalyst, hydrazobenzene and molecular oxygen has been proposed. The kinetic studies show that a ternary complex $CoL{\cdot}H_2AB{\cdot}O_2$ is involved in the rate determining step. The reactions are summarised in a catalytic cycle. The kinetic data suggest that a ternary complex involving Co(3MeOsalen), triphenyl-phosphine and molecular oxygen is catalytically acive species but at higher triphenylphosphine concentrations the catalyst becomes inactive. The destruction of the catalytic activity could be due to the catalyst becoming coordinated with triphenyl phosphine at both z axis sites of the complex e.g. Co (3MeOsalen)$(PPh_3)_2$.

• Proceedings of the KIEE Conference
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• 2003.07c
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• pp.1722-1725
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• 2003

절연물에 가해지는 열화 중에서 열 사이클(Thermal cycle) 열화를 모사하기 위하여, 대형 터빈 발전기 수냉각 고정자 권선용 바를 대상으로 IEEE Std 1310 규격에 따라 200 사이클의 열 사이클 열화 시험을 수행하였다. 바에 대한 절연 특성을 분석하기 위하여 시험 수행 전후의 Tan ${\delta}$ 및 Tip-up(%, ${\Delta}$ Tan ${\delta}$), 부분방전의 최대 방전량 등을 측정하였고 또한 바를 절단하여 절연물 내의 박리와 도체와 절연물 간의 분리 등을 점검하였다. 최종적으로는 절연파괴 시험을 수행하여 절연파괴 강도를 측정하였다. 시험 결과 초기 절연 특성상의 현저한 변화는 없었으며 양호한 특성을 보였다.

• Bulletin of the Korean Chemical Society
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• v.10 no.1
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• pp.102-103
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• 1989

Four coordinated rhodium(Ⅰ) complexes, Rh($ClO_4$)(CO)$(PPh_3)_2$ and [$Rh(CO)(PPh_3)_3$]$ClO_4$(2) catalyze the iosmerization of allylic alcohols to the corresponding carbonyl compounds at room temperature under nitrogen. The isomerization is faster with 2 than with 1, which is understood in terms of relative ease of the last step of the catalytic cycle, the reductive elimination of enol. Relative rates of the isomerization with 1 and 2 for different allylic alcohols are also explained by the relative ease of the enol elimination step in part. The first step of the catalytic cycle, the complex formation of the allylic alcohol through the ${\pi}-system$ of the olefinic group of the allylic alcohol and the following step, formation of hydridoallyl complex also seem to affect the overall rate of the isomerization.

• Journal of the Korean Wood Science and Technology
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• v.42 no.1
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• pp.1-12
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• 2014

This study carried out life cycle assessment for evaluating environmental impacts of timber Arch-Truss bridge by using domestic Pinus rigida Miller glued-laminated timber throughout life cycle such as extraction, manufacturing, transportation, construction, use, dismantlement, transportation of waste, disposal and recycling. The life cycle GHG (GreenHouse Gas) emissions of the target bridge are 192.56 ton $CO_2$ eq. in 50 years. Especially, the life cycle GHG emissions of concrete used in the target bridge are 82.84 ton $CO_2$ eq. which accounts for 53.02% of the GWP (Global Warming Potential) in extraction and manufacturing stages. The target bridge is constructed of $116.57m^3$ of domestic Pinus rigida Miller glued-laminated timber and used timber has stored 104.72 ton $CO_2$. If an effect of carbon storage in timber is applied to the total GHG emissions of the target bridge, the GHG emissions can be reduced by 54.38%. In the case of substitution effect, if domestic Pinus rigida Miller glued-laminated timber replaces steel manufactures used in other bridge which has the same structure and life span as the target bridge, the GHG emissions in extraction and manufacturing stages can be reduced by 10.26% to 23.91%.

• Journal of Korean Society of Water and Wastewater
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• v.26 no.2
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• pp.303-312
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• 2012

Water supply and sewerage systems are the large-scale urban infrastructure ejecting large amount of environmental load over the life-cycle. Therefore, it is important not only to optimize in the aspect of economical superiority and process efficiency but also to consider earth scale environmental impact. This study aimed to suggest the establishment of life cycle management(LCM) system as an integrated management solution in urban water supply and sewerage systems. As a result, the methodology for LCM system consisting of life cycle assessment(LCA), life cycle cost(LCC), life cycle $CO_{2}(LCCO_{2})$ and life cycle energy(LCE) was developed. Also, several case studies using the latest statistics data of water supply and sewerage systems were carried out to investigate the field applicability of LCM.

• Proceedings of the Korean Nuclear Society Conference
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• 2001.05a
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• pp.142-142
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• 2001