• Title/Summary/Keyword: co-agent

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Formaldehyde Free Cross-linking Agents Based on Maleic Anhydride Copolymers

  • Yoon, Kee-Jong;Woo, Jong-Hyung;Seo, Young-Sam
    • Fibers and Polymers
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    • v.4 no.4
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    • pp.182-187
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    • 2003
  • Low molecular weight copolymers of maleic anhydride and vinyl acetate were prepared to develop formaldehyde free cross-linking agents. Since lower molecular weight is favorable for efficient penetration of the finishing agent into the cotton fibers in the padding process, the concentration of the initiator, chain transfer agent and the monomer ratios were varied to obtain copolymers of low molecular weights. The prepared polymers were characterized by GPC, $^1{H-NMR}$, FTIR, DSC and TGA. Copolymers of molecular weights of 2 000 to 10 000 were obtained and it was found that the most efficient method of controlling the molecular weight was by varying the monomer ratios. Poly(maleic anhydride-co-vinyl acetate) did not dissolve in water, but the maleic anhydride residue hydrolyzed within a few minutes to form poly(maleic acid-co-vinyl acetate) and dissolved in water. However, the maleic acid units undergo dehydration to form anhydride groups on heating above ${160}^{\circ}C$ to some extent even in the absence of catalysts. The possibility of using the copolymers as durable press finishing agent for cotton fabric was investigated. Lower molecular weight poly(maleic anhydride-co-vinyl acetate) copolymers were more efficient in introducing crease resistance, which appears to be due to the more efficient penetration of the cross-linking agent into cotton fabrics. The wrinkle recovery angles of cotton fabrics treated with poly(maleic anhydride-co-vinyl acetate) copolymers were slightly lower than those treated with DMDHEU and were higher when higher curing temperatures or higher concentrations of copolymer were used, and when catalyst, $NaH_2$$PO_2$, was added. The strength retention of the poly(maleic anhydride-co-vinyl acetate) treated cotton fabrics was excellent.

CO2 Suppression Characteristics of the Nitrogen-diluted Methane Counterflow Non-premixed Flame (질소로 희석된 대향류 메탄 비예혼합화염에서 CO2에 의한 소화특성)

  • Lee, Ho-Hyun;Oh, Chang Bo;Hwang, Cheol Hong
    • Journal of the Korean Society of Safety
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    • v.28 no.2
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    • pp.42-48
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    • 2013
  • The $CO_2$ suppression characteristics and flame structure of nitrogen-diluted methane counterflow non-premixed flame were studied experimentally and numerically. To mimic a situation where combustion product gases are entrained into a compartment fire, fuel stream was diluted with $N_2$. A gas-phase suppression agent, $CO_2$, was diluted in the air-stream to investigate the suppression characteristics by the agent. For numerical simulation, an one-dimensional OPPDIF code was used for comparison with experimental results. An optically-thin radiation model(OTM) was adopted to consider radiation effects on the suppression characteristics. It was confirmed experimentally and numerically that suppression limit decreased with increasing nitrogen mole fraction in the fuel stream. A turning point was found only when a radiation heat loss was considered and the extinguishing concentration for turning point was differently predicted compared to the experiment result. Critical extinguishing concentration when neglecting radiation heat loss was also differently predicted compared with the experimental result.

Effect of Co-agent on Cure, Mechanical Properties of NBR Compounds in Peroxide System

  • Seo, Eun Ho;Kim, Gi Hong;Kim, Do Young;Lee, Dong Won;Seo, Kwan Ho
    • Elastomers and Composites
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    • v.52 no.3
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    • pp.187-193
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    • 2017
  • In this study, the effect of the cure, mechanical properties, and oil resistance of NBR (acrylonitrile-butadiene rubber)/peroxide compounds were investigated for various co-agents. NBR compounds were characterized using a swelling test, a rheometer (MDR), and a compression set test. Mechanical properties were tested with original compounds, heated in air and exposed to the ASTM No.1, IRM 903 oil. NBR compounds were prepared using peroxide as the crosslinking agent. Trimethylolpropane trimethacrylate (TMPTMA), triallyl isocyanurate (TAIC), and 1,2-polybutadiene (HVPBD) were used as co-agents. The NBR compounds containing TMPTMA and HVPBD lowered the scorch time, while the addition of TAIC did not significantly change the scorch time. NBR compounds containing TMPTMA increased the crosslinking density, while the addition of TAIC and HVPBD lowered the crosslinking density. Moreover, the addition of TMPTMA improved the oil resistance of the NBR compound.

DA-7911, rhenium-188 ($Re^{188}$) tin colloid. as a strong candidate agent for radiation synovectomy

  • Shin, Chang-Yell;Jung, Mi-Young;Lee, In-Ki;Son, Mi-Won;Kim, Soon-Hoe;Kim, Won-Bae
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.252-252
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    • 2002
  • Radiation synovectomy is an useful alternative treatment to rheumatoid arthritis and Re$\^$188/ is suggested as an ideal radiopharmaceutical agents because beta ray (2.1 MeV) emitted from Re$\^$188/ is appropriate for synovial cell ablation and gamma ray (155 KeV) is ideal for dosimetry. Its' ideal particle size (2-5 mm) was achieved by conjugation with tin-colloid, In this study, we investigated the toxicity, stability and biodistribution to evaluate the suitability of DA-7911 as a synovectomy agent. (omitted)

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3D-QSAR Study of Competitive Inhibitor for Acethylcholine Esterase (AChE) Nerve Agent Toxicity

  • San Juan, Amor A.;Cho, Seung-Joo
    • Molecular & Cellular Toxicology
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    • v.2 no.3
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    • pp.216-221
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    • 2006
  • The cholinesterase-inhibiting organophosphorous (OP) compounds known as nerve agents are highly toxic. The principal toxic mechanism of OP compounds is the inhibition of acethylcholine esterase (AChE) by phosphorylation of its catalytic site. The reversible competitive inhibition of AChE may prevent the subsequent OP intoxication. In this study, three-dimensional quantitative structure-activity relationship (3D-QSAR) was performed to investigate the relationship between the 29 compounds with structural diversity and their bioactivities against AChE. In particular, predictive models were constructed using the comparative molecular field analysis (CoMFA) and comparative molecular similarity indices analysis (CoMSIA). The results indicate reasonable model for CoMFA ($q^{2}=0.453,\;r^{2}=0.697$) and CoMSIA ($q^{2}=0.518,\;r^{2}=0.696$). The presence of steric and hydophobic group at naphtyl moiety of the model may lead to the design of improved competitive inhibitors for organophosphorous intoxication.

Solidification of sludge by reactive amendment agent (반응성 고화제를 이용한 슬러지 고형화 방안)

  • Koh, Yong-Kook
    • Proceedings of the Korean Geotechical Society Conference
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    • 2004.03b
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    • pp.869-872
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    • 2004
  • A study on the solidification of sludge by reactive amendment agent was carried out in this paper. The reactive amendment agent used in this study is mainly composed of inorganic solidification agent and reactive adsorptive material. The reactive agent has a function of soil-cement-agent solidification and harmlessness of contaminant in waste. The reactive agent is environmentally friendly material to the surrounding environment. In this study, a series of tests and experiments including unconfined compressive strength, permeability, pH test, constituent analysis, leaching test were carried out to analyse engineering and environmental characteristics of solidified sludge treated reactive agent. The result of this research shows that the solidified sludge treated reactive agent is increased in strength and decreased in contaminant concentration.

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Fast Handoff Technique using Improved Cashing Agent and CoA Pool in Mobile IP (모바일 아이피에서 개선된 캐싱 에이전트와 CoA 풀을 사용한 빠른 핸드오프 기법)

  • Lee, Jang-Su;Kim, Sung-Chun
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.45 no.2
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    • pp.75-82
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    • 2008
  • Mobile IP was proposed to overcome identity problem of original IP address system caused by mobility of wireless mobile host. To complete its network handoff procedure, it must receive a mobile advertisement broadcasted by mobile agent. Generally, in a mobile IP system, mean time delay, 500ms, in a network handoff procedure is a critical problem of wireless service such as Voip, multimedia streaming. A caching agent caches a latest mobile advertisement, and replays it by receiving solicitation message from a mobile node finishing link layer detection. But, during the procedure of mobile registration, many packets from service provider to the mobile host would be lost and handoff time delay would be increased. In this thesis, we propose an unproved caching agent technique which can forward data packets while handoff procedure, and CoA pool for fast mobile IP registration.

Electroless Plating of Co-P Magnetic Films from Pyrophosphate Bath (피로인산염욕으로부터 Co-P자성막의 무전해 도금)

  • Jo Jung-San;Koh, Suck-Soo;Lee, Ju-Seong
    • Journal of the Korean institute of surface engineering
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    • v.19 no.4
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    • pp.140-148
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    • 1986
  • Using sodium pyrophoshate as complexing agent, the characteristics and the magnetic properties of the films deposited from electroless cobalt plating bath have been studied. The result obtained are as following; 1. It was found that the optimum bath compositions consisted of 0.1M cobalt sulfate, 0.2M sodium hypophosphite as reducing agent, 0.4M sodium pyrophosphate as complexing agent and 0.5M ammonium sulfate as buffer agent, whereas good operating conditions were the bath of pH 10.5 adjusted with ammonia and 70$^{\circ}C$ of bath temperature, respectively. 2. The coercive force and the squareness of magnetic films were increased with deposition from the low temperature bath. 3. The phosphorous content in Co-P films deposited from these bath was relatively higher than that from Brenner bath. It was assumed to be due to codeposition of phosphorous from the pyrophosphate anion in the solution.

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An Error Synchronization running on Gateway Software Stack based on CoAP (CoAP 기반 게이트웨이 소프트웨어 스택에서의 오류 동기화)

  • Ko, Eung-Nam
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.9 no.1
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    • pp.114-119
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    • 2016
  • The necessity of IoT(Internet of Things) and Multimedia CSCW is described, and error control for multimedia CSCW(Computer Supported Cooperated Works) based on CoAP stack is suggested. This paper describes an error synchronization running on gateway software stack based CoAP. This system consists of an CS_EDA, and CS_ESA. CS_EDA is an agent that detects an error for multimedia distance system based on gateway software stack based CoAP environment. CS_ESA is an agent that is an error synchronization system for multimedia distance control based on gateway software stack based CoAP environment. From the perspective of multimedia collaborative environment of gateway software stack based CoAP, an error application becomes another interactive presentation error is synchronized with participants engaged in a cooperative work.

High Pressure Leaching of Matte Converted from Cobalt Concentrate from Democratic Republic of the Congo (콩고산 코발트 정광으로부터 제조한 매트의 고온고압침출)

  • Kim, Gunha;Kang, Ga-hee;Kim, Sookyung;Sohn, Jeongsoo;Kwon, Kyungjung
    • Resources Recycling
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    • v.24 no.4
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    • pp.32-37
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    • 2015
  • Cobalt is abundant only in some countries including Democratic Republic of the Congo. It would be necessary to secure overseas Co ores and Co extraction technology. Two kinds of matte varying the sulfur content were manufactured by smelting reduction of Co concentrate containing ~8 wt% Co, ~19 wt% Cu, and ~3 wt% Fe. The amount of Co, Cu and Fe was concentrated to 19~21 wt%, 39~41 wt%, and 7~9 wt% respectively in the resulting matte. High-pressure leaching of matte was performed in an autoclave with considering the effect of oxidizing agent, $H_2SO_4$ concentration as a lixiviant, and the amount of sulfur added to the matte. An oxidizing agent (oxygen) is necessary to improve Co leaching efficiency enabling usage of a dilute $H_2SO_4$ leaching agent. An increase in $H_2SO_4$ concentration prevents selective leaching of Co, and the sulfur content in matte has a minor influence on the Co leaching efficiency.