• Title/Summary/Keyword: co-agent

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Curing Kinetics of TDI/PTMEG-based Urethane Prepolymers Depending on the Amount of Curing Agent and Curing Temperatures by DSC and Real Time FT-IR Spectroscopy

  • Kim, Se Mi;Park, Hee Jung;Kim, Seon Hong;Lee, Eun Ju;Lee, Kee Yoon
    • Elastomers and Composites
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    • v.52 no.4
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    • pp.266-271
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    • 2017
  • This study describes the influence of the amount of curing agent and curing temperature on the kinetics of polyurethane elastomers. The urethane prepolymer series was prepared by reacting toluene diisocyanate with polytetramethylene ether glycol at $80^{\circ}C$ for 1 h, and 4,4'-methylene bis(2-chloroaniline) was used as the curing agent. The ratio of the amine group of the curing agent to the isocyanate group of the urethane prepolymer was controlled from 0.85 to 1.05 at curing temperatures ranging from 80 to $120^{\circ}C$. The curing rate of the urethane prepolymer was monitored by observing the change in heat flow during the curing process using differential scanning calorimetry (DSC). As either the content of curing agent or the curing temperature was higher, the conversion rate to the polyurethane elastomer was high. The DSC results were compared with those obtained from using real-time FT-IR.

Effects of Coal Fly Ash as a Bulking Agent under Co-composting with Swine Manure and Saw Dust

  • Lee, Chang Hoon;Park, Seong Jin;Kim, Myung Sook;Yun, Sun Kang;Sonn, Yeon Kyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.5
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    • pp.356-361
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    • 2014
  • The coal fly ash (CFA) may be utilized as an extender for organic waste composting at the same time fully expected to solve all industrial waste disposal and sawdust tribe. The main objective in this study was to evaluate the effect of CFA addition as a bulking agent for swine manure composting. To determine the suitable addition rate of CFA as a bulking agent, 0, 10, 20 and 30% of saw dust were mixed with 30, 20, 10 and 0% of coal fly ash, respectively. Compost quality for swine manure composting was to evaluate temperature, pH, C/N ratio, and phytotoxicity as germination index. Stability of compost increased with increasing levels of CFA as bulking agent during swine manure composting due to the high alkaline materials including CFA. C to N ratio in treatment added CFA was higher than that of the control without CFA. After finishing composting, germination index of lettuce and cabbage in swine manure compost added 10% of CFA was similar to the control, all the heavy metal contents were far below the stipulated standard for organic farming. These results indicated tahr coal fly ash as bulking agents might be alternative materials to save saw dust and apply industrial products for swine manure composting.

Neutral Sizing of Linerboard Using Fast Cure Type AKD (급속경화형 AKD를 이용한 라이너지의 중성 사이징)

  • Lee Hak-Lae;Seo Man-Seok;Shin Jong-Ho;Youn Hye-Jung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.1 s.113
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    • pp.1-8
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    • 2006
  • To overcome troubles in strength and process of linerboard caused by raw materials, a neutral sizing which is usual in fine paper making can be considered. A new sizing agent is necessary to show good performance in a system with high conductivity and COD. In this study, fast cure type AKD was examined as a new sizing agent and compared with conventional AKD. The effects of fixing agent addition and drying condition were also investigated. Fast cure type AKD which has a higher cationicity showed better sizing degree than conventional AKD in spite of low addition level and no curing treatment. And when fixing agent of sufficient amount was added, sizing degree was improved for both AKDs. High cationicity is a crucial factor for neutral sizing of linerboard for obtaining fast and stable sizing degree. Drying with temperature over $100^{\circ}$ was desirable for developing sizing degree.

THE EFFECT OF VARIOUS DESENSITIZING AGENTS ON RETENTION AND FITNESS OF CEMENTED CROWNS WITH ZINC PHOSPHATE CEMENT (수 종의 지각 과민 완화제가 인산 아연 시멘트 사용시 주조관의 유지력 및 적합도에 미치는 영향)

  • Oh Se-Wook;Lee Ho-Yong
    • The Journal of Korean Academy of Prosthodontics
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    • v.32 no.2
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    • pp.181-194
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    • 1994
  • The purpose of this study was to compare the retention and fitness of crown treated with various desensitizing agents on natural teeth. Varnish, dentin primer, bonding agent and potassium oxalate treated groups and control group with no treatment were used. The retention test was executed with the Instron test machine(Instron Co.,U.S.A.) on 24 hours after cementation with zinc phosphate cement. After retention test, the teeth and crowns were washed and recemented. The cemented crowns were embedded in clear resin and sectioned with a diamond saw. The occlusal and marginal fitnesses, were measured indirectly with a stereomicroscopic photographs. The result of this study were obtained as follows : 1. The retention of control group was higher than any other desensitizing agent treated group. 2. The differences of retention among varnish, dentin primer, bonding agent and potassium oxalate treated groups were not statistically significant. 3. There were no statistically significant difference in fitness at occlusal surface and margin among control, varnish, dentin primer, bonding agent and potassium oxalate treated groups. According to these results, desensitizing agents used to protect the pulp from irritation of luting agents may adversely affect the retention of castings. Therefore, desensitizing agents should be used in limited areas carefully.

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Roles of Phosphoric Acid in Slurry for Cu and TaN CMP

  • Kim, Sang-Yong;Lim, Jong-Heun;Yu, Chong-Hee;Kim, Nam-Hoon;Chang, Eui-Goo
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.2
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    • pp.1-4
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    • 2003
  • The purpose of this study was to investigate the characteristics of slurry including phosphoric acid for chemical-mechanical planarization of copper and tantalum nitride. In general, the slurry for copper CMP consists of alumina or colloidal silica as an abrasive, organic acid as a complexing agent, an oxidizing agent, a film forming agent, a pH control agent and additives. Hydrogen peroxide (H$_2$O$_2$) is the material that is used as an oxidizing agent in copper CMP. But, the hydrogen peroxide needs some stabilizers to prevent decomposition. We evaluated phosphoric acid (H$_3$PO$_4$) as a stabilizer of the hydrogen peroxide as well as an accelerator of the tantalum nitride CMP process. We also estimated dispersion stability and zeta potential of the abrasive with the contents of phosphoric acid. An acceleration of the tantalum nitride CMP was verified through the electrochemical test. This approach may be useful for the development of the 2$\^$nd/ step copper CMP slurry and hydrogen peroxide stability.

Effects of Hydroxide and Silicate ions on the Plasma Electrolytic Oxidation of AZ31 Mg Alloy (AZ31 마그네슘 합금의 플라즈마전해산화 피막 형성에 미치는 수산화 이온 및 규산 이온의 영향)

  • Moon, Sungmo;Yang, Cheolnam;Na, Sangjo
    • Journal of the Korean institute of surface engineering
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    • v.47 no.4
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    • pp.147-154
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    • 2014
  • Formation behavior of PEO (Plasma Electrolytic Oxidation) films on AZ31 Mg alloy was studied in aqueous solutions containing various concentrations of hydroxide ion ($OH^-$) and silicate ion ($SiO_3{^{2-}}$) by voltage-time curves, and corrosion resistance of the PEO film-covered specimen was investigated by immersion test in 0.5 M NaCl solution. From the analyses of the voltage-time curves, it is suggested that two different types of anions are essentially needed for the formation of PEO films on AZ31 Mg alloy: film formation agent and local film breakdown agent. $SiO_3{^{2-}}$ ion acts only as a film formation agent but $OH^-$ ion acts not only as a film formation agent but also film breakdown agent. The PEO films prepared on AZ31 Mg alloy in alkaline silicate solution showed very good corrosion resistance without any pitting or filiform corrosions up to 480 h of immersion in 0.5 M NaCl.

Research of Possibility of Carrageenan as DTP Pre-treatment Thickening Agent for Cellulosic Fabric (카라기난(Carrageenan)의 셀룰로오스 직물 DTP 전처리 호제로써의 가능성 연구)

  • Ki, Saetbyul;Seo, Hyeji;Hong, Jinpyo;Yoon, Seokhan;Shin, Kyung
    • Textile Coloration and Finishing
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    • v.27 no.4
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    • pp.318-326
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    • 2015
  • A pre-treatment process is essential for getting high quality of digital textile printing(DTP). In this study, we have studied three kinds of carrageenan polymer(k-, ${\lambda}$-, i-Carrageenan) as a pre-treatment thickening agent for the first time. Alginate polymer was also examined and its results were compared with that of the three kinds of carrageenan polymer. To confirm the performance of each thickening agent, we examined for a sharpness, color strength and fastness(washing, rub, light). The result showed that ${\lambda}$-Carrageenan has superior property in sharpness with low viscosity and i-Carrageenan was excellent in the color strength among the pre-treatment agents. Washing fastness to color change and staining for the all samples were 4 or 4-5 grade. Both dry and wet rubbing fastness of the samples were 4-5 grade. However, ${\lambda}$-Carrageenan coated sample has the lowest grade in light fastness. As a result, we found the possibility of carrageenan polymer as pre-treatment agent.

On Managing Mobility of Mobile Nodes using an Improved Mobile IP Regional Registration in Wireless Mobile Networks (무선 이동 망에서 개선된 Mobile IP 지역 위치등록을 이용한 이동 노드의 이동성 관리)

  • 한승진;이정현
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.41 no.3
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    • pp.47-54
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    • 2004
  • By using wireless terminal, the number of users who wish to use the multimedia service like the Internet as well as Short Message Services and voice service has increased dramatically over the last years. We propose the method that improves Mobile IPv4 (MIPv4) Regional Registration in wireless mobile networks to decrease traffic's transmission delay and message generation compared with an existing method We design the scheme in MIPv4 environments that a packet do not pass through the home agent transmitted from correspondent node to mobile node, if a mobile node moves to other mobility agent. Simulation results show that the proposed method significantly reduces the expenses for registration and delivering packet.

A Multiagent-Based Hybrid Power Control and Management of Distributed Power Sources

  • Yoon, Gi-Gab;Hong, Won-Pyo;Lee, Ki-Hong
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.25 no.8
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    • pp.70-81
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    • 2011
  • In this paper, a multi-agent control system for DC-coupled photovoltaic (PV), fuel cell (FC), ultracapacitor(UC) and battery hybrid power system is studied for commercial buildings & apartment buildings microgrid. In this proposed system, the PV system provides electric energy to the electrolyzer to produce hydrogen for future use and transfer to the load side, if possible. Whenever the PV system cannot completely meet load demands, the FC system provides power to meet the remaining load. A multi-agent system based-power management and control algorithm is proposed for the hybrid power system by taking into account the characteristics of each power source. The main works of this paper are hybridization of alternate energy sources with FC systems using long and short storage strategies to build the multi-agent control system with pragmatic design, and a dynamic model proposed for a PV/FC/UC/battery bank hybrid power generation system. A dynamic simulation model for the hybrid power system has been developed using Matlab/Simulink, SimPowerSystems and Stateflow. Simulation results are also presented to demonstrate the effectiveness of the proposed multi-agent control and management system for building microgrid.

The Effect of the Distance Between $CO_2$ Agent Nozzle and Wall ($CO_2$소화제 노즐과 벽간 거리의 영향)

  • Park Chan-Su
    • Fire Science and Engineering
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    • v.18 no.4
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    • pp.27-34
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    • 2004
  • We have conducted a numerical simulation under three-dimensional unsteady conditions in order to analyze the effect of flow and CO₂ mass transfer according to the distance between the CO₂ nozzle of CO₂ fire fighting system and the rear wall in a protection space. Flow fields and CO₂ concentration fields were measured. The different recirculation flow form and wall jet was developed according to increasing the distance between CO₂ nozzles and rear wall. In all the case, CO₂ mass transfer was generated toward the center of a protection space from each walls, but the CO₂ mass fraction of front and rear areas based on CO₂ nozzles showed higher or lower by increasing the distance between CO₂ nozzle and rear wall.