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Effect of different abrasive grain sizes of the diamond grinding wheel on the surface characteristics of GaN

  • Joo Hyung Lee;Seung Hoon Lee;Hee Ae Lee;Nuri Oh;Sung Chul Yi;Jae Hwa Park
    • Journal of Ceramic Processing Research
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    • v.23 no.4
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    • pp.436-442
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    • 2022
  • Gallium nitride (GaN) substrates were ground in two different grinding wheel abrasive sizes of 270 and 800-mesh, and thechange in surface morphologies of the substrates and the depth of subsurface damage (SSD) were observed. With the 800-meshgrinding wheel, the surface roughness (SR) and the depth of SSD of the sample tended to decrease, which was not the casewith the 270-mesh grinding wheel. In the X-ray rocking curve, the sample exhibited some compressive stress with the 270-meshgrinding wheel, but with the 800-mesh grinding wheel, it demonstrated the occurrence of tensile stresses in the sample and adecrease in full width at half maximum (FWHM), which confirms an improvement in the crystallinity. In the Raman spectra,the compressive stress of the 270-mesh grinding wheel and the tensile stress of the 800-mesh grinding wheel were confirmedthrough peak shifts. Photoluminescence (PL) spectra confirmed that the intensity ratio of the yellow luminescence increasedat the 800-mesh grinding wheel, and a blue shift occurred further. These results indicate that the SR and the depth of SSDwere proportional to the abrasive grain size of the grinding wheel. At the same time, the increase in PL intensity at specificpeak positions indicates that the stress stemming from the grinding process was concentrated at the crystal surface. The abovemechanism is illustrated in a schematic diagram, which confirms the possibility of improving the grinding efficiency andsubsequent polishing processes in future applications.

A Study on the Method of Teaching Korean Synonyms Using Online Corpora (온라인 코퍼스를 활용한 한국어 유의어 교수 방안 연구)

  • 전지은
    • Language Facts and Perspectives
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    • v.47
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    • pp.177-203
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    • 2019
  • The purpose of this study is to suggest the possibility of using online corpora for teaching synonyms in Korean. The research included how to develop the effective concordance learning materials for teaching synonyms in Korean using data driven learning(DDL). Because synonyms are similar in meaning and usage, even native speaker can not clearly explain the difference in synonyms. Furthermore, it is not easy to provide proper example sentences for each word, and it is a reality that the differentiation of the synonyms are not sufficiently provided in the Korean textbooks. In recent years, it has been claimed that DDL helps students produce vocabulary as well as comprehend vocabulary. Nevertheless, it is hard to find how the concordance materials should be made for them. In this study, we extract concordance examples from the various kinds of online corpora; written and spoken corpora, korean textbooks, newspapers. We presented how to make corpus-designed activities using concordance materials for teaching Korean synonyms. In order to examine the effects of DDL, five experimental lessons were given to a group of 15 advanced korean learners in the university and follow-up surveys(attitude-questionnaire) were conducted. This study is meaningful in that it proposed a new teaching method in Korean synonym education.

Compositional Variation of Arsenopyrites in Arsenic and Polymetallic Ores from the Ulsan Mine, Republic of Korea, and their Application to a Geothermometer (울산광산산(蔚山鑛山産) 유비철석(硫砒鐵石)의 조성변화(組成變化) 및 지질온도계(地質溫度計)에 대(對)한 적용(適用))

  • Choi, Seon-Gyu;Chung, Jae-Ill;Imai, Naoya
    • Economic and Environmental Geology
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    • v.19 no.3
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    • pp.199-218
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    • 1986
  • Arsenopyrite in arsenic and polymetallic ores from calcic Fe-W skarn deposit of the Ulsan mine, Republic of Korea, has been investigated by means of electron microprobe analysis and X-ray diffractometry. As a result, it is revealed that the Ulsan arsenopyrite may be classified into the following three species with different generation on the basis of its mode of occurrence, chronological order during polymetallic mineralization and chemical composition; arsenopyrites I, II and III. 1) Arsenopyrite I-(Ni, Co)-bearing species belonging to the oldest generation, which has crystallized together with (Ni, Co)-arsenides and -sulpharsenides in the early stage of polymetallic mineralization. In rare cases, it contains a negligible amount of antimony. It occurs usually as discrete grains with irregular outline, showing rarely subhedral form, and is diffused in skarn zone. The maximum contents of nickel and cobalt are 10.04 Ni and 2.45 Co (in weight percent). Occasionally, it shows compositional zoning with narrow rim of lower (Ni+Co) content. 2) Arsenopyrite II-arsenian species, in which (Ni+Co) content is almost negligible, may occur widely in arsenic ores, and its crystallization has followed that of arsenopyrite I. It usually shows subhedral to euhedral form and is closely associated with $l{\ddot{o}}llingite$, bismuth, bismuthinite, chalcopyrite, sphalerite, bismuthian tennantite, etc. It is worthy of note that arsenopyrite II occasionally contains particles consisting of both bismuth and bismuthinite. 3) Arsenopyrite III-(Ni, Co)-free, S-excess and As-deficient species is close to the stoichiometric composition, FeAsS. It occurs in late hydrothermal veins, which cut clearly the Fe-W ore pipe and the surrounding skarn zone. It shows euhedral to subhedral form, being extremely coarse-grained, and is closely associated with pyrite, "primary" monoclinic pyrrhotite, galena, sphalerite, etc. Among three species of the Ulsan arsenopyrite, arsenopyrite I does not serve as a geothermometer, because (Ni+Co) content always exceeds 1 weight percent. In spite of the absence of Fe-S minerals as sulphur-buffer assemblage, the presence of $Bi(l)-Bi_2S_3$ sulphur-buffer enables arsenopyrite II to apply successfully to the estimation of either temperature and sulphur fugacity, the results are, $T=460{\sim}470^{\circ}C$, and log $f(S_2)=-7.4{\sim}7.0$. With reference to arsenopyrite III, only arsenopyrite coexisting with pyrite and "primary" monoclinic pyrrhotite may serve to restrict the range of both temperature and sulphur fugacity, $T=320{\sim}440^{\circ}C$, log $f(S_2)=-9.0{\sim}7.0$. These temperature data are consistent with those obtained by fluid inclusion geothermometry on late grandite garnet somewhat earlier than arsenopyrite II. At the beginning of this paper, the geological environments of the ore formation at Ulsan are considered from regional and local geologic settings, and physicochemical conditions are suspected, in particular the formation pressure (lithostatic pressure) is assumed to be 0.5kb (50MPa). The present study on arsenopyrite geothermometry, however, does not bring about any contradictions against the above premises. Thus, the following genetical view on the Ulsan ore deposit previously advocated by two of the present authors (Choi and Imai) becomes more evident; the ore deposit was formed at shallow depth and relatively high-temperature with steep geothermal gradient-xenothermal conditions.

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Geochemical Occurrence of Uranium and Radon-222 in Groundwater at Test Borehole Site in the Daejeon area (대전지역 시험용 시추공 지하수내 우라늄 및 라돈-222의 지화학적 산출특성)

  • Jeong, Chan Ho;Ryu, Kun Seok;Kim, Moon Su;Kim, Tae Sung;Han, Jin Suk;Jo, Byung Uk
    • The Journal of Engineering Geology
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    • v.23 no.2
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    • pp.171-186
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    • 2013
  • A drilling project was undertaken to characterize the geochemical relationship and the occurrence of radioactive materials at a test site among public-use groundwaters previously known to have high occurrence of uranium and radon-222 in the Daejeon area. A borehole (121 m deep) was drilled and core rocks mainly consist of two-mica granite, and associated with pegmatite and dykes of intermediate composition. The groundwater samples collected at six different depths in the borehole by a double-packed system showed the pH values ranging from neutral to alkaline (7.10-9.3), and electrical conductivity ranging from 263 to 443 ${\mu}S/cm$. The chemical composition of the borehole groundwaters was of the $Ca-HCO_3(SO_4+Cl)$ type. The uranium and Rn-222 contents in the groundwater were 109-1,020 ppb and 9,190-32,800 pCi/L, respectively. These levels exceed the regulation guidelines of US EPA. The zone of the highest groundwater uranium content occurred at depths of 45 to 55m. The groundwater chemistry in this zone (alkaline, oxidated, and high in bicarbonate) is favorable for the dissolution of uranium into groundwater. The dominant uranium complex in groundwater is likely to be $(UO_2CO_3)^0$ or $(UO_2HCO_3)^+$. Radon-222 content in groundwater shows an increasing trend with depth. The uranium and thorium contents in the core were 0.372-47.42 ppm and 0.388-11.22 ppm, respectively. These levels are higher values than those previously been reported in Korea. Microscopic observations and electron microprobe analysis(EPMA) revealed that the minerals containing U and Th are monazite, apatite, epidote, and feldspar. U and Th in these minerals are likely to substitute for major elements in crystal lattice.

International Research Trend on Mountainous Sediment-related Disasters Induced by Earthquakes (지진 유발 산지토사재해 관련 국외 연구동향 분석)

  • Lee, Sang-In;Seo, Jung-Il;Kim, Jin-Hak;Ryu, Dong-Seop;Seo, Jun-Pyo;Kim, Dong-Yeob;Lee, Chang-Woo
    • Journal of Korean Society of Forest Science
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    • v.106 no.4
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    • pp.431-440
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    • 2017
  • The 2016 Gyeongju Earthquake ($M_L$ 5.8) (occurred on September 12, 2016) and the 2017 Pohang Earthquake ($M_L$ 5.4) (occurred on November 15, 2017) caused unprecedented damages in South Korea. It is necessary to establish basic data related to earthquake-induced mountainous sediment-related disasters over worldwide. In this study, we analyzed previous international studies on the earthquake-induced mountainous sediment-related disasters, then classified research areas according to research themes using text-mining and co-word analysis in VOSviewer program, and finally examined spatio-temporal research trends by research area. The result showed that the related-researches have been rapidly increased since 2005, which seems to be affected by recent large-scale earthquakes occurred in China, Taiwan and Japan. In addition, the research area related to mountainous sediment-related disasters induced by earthquakes was classified into four subjects: (i) mechanisms of disaster occurrence; (ii) rainfall parameters controlling disaster occurrence; (iii) prediction of potential disaster area using aerial and satellite photographs; and (iv) disaster risk mapping through the modeling of disaster occurrence. These research areas are considered to have a strong correlation with each other. On the threshold year (i.e., 2012-2013), when cumulative number of research papers was reached 50% of total research papers published since 1987, proportions per unit year of all research areas should increase. Especially, the proportion of the research areas related to prediction of potential disaster area using aerial and satellite photographs is highly increased compared to other three research areas. These trends are responsible for the rapidly increasing research papers with study sites in China, and the research papers examined in Taiwan, Japan, and the United States have also contributed to increases in all research areas. The results are could be used as basic data to present future research direction related to mountainous sediment-related disasters induced by earthquakes in South Korea.

Occurrence and Chemical Composition of Dolomite from Zhenzigou Pb-Zn Deposit, China (중국 젠지고우 연-아연 광상의 돌로마이트 산상과 화학조성)

  • Yoo, Bong Chul
    • Korean Journal of Mineralogy and Petrology
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    • v.34 no.3
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    • pp.177-191
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    • 2021
  • The Zhenzigou Pb-Zn deposit, one of the largest Pb-Zn deposit in the northeast of China, is located at the Qingchengzi mineral field in Jiao Liao Ji belt. The geology of this deposit consists of Archean granulite, Paleoproterozoinc migmatitic granite, Paleo-Mesoproterozoic sodic granite, Paleoproterozoic Liaohe group, Mesozoic diorite and monzoritic granite. The Zhenzigou deposit which is a strata bound SEDEX or SEDEX type deposit occurs as layer ore and vein ore in Langzishan formation and Dashiqiao formation of the Paleoproterozoic Liaohe group. Based on mineral petrography and paragenesis, dolomites from this deposit are classified three type (1. dolomite (D0) as hostrock, 2. dolomite (D1) in layer ore associated with white mica, quartz, K-feldspar, sphalerite, galena, pyrite, arsenopyrite from greenschist facies, 3. dolomite (D2) in vein ore associated with quartz, apatite and pyrite from quartz vein). The structural formulars of dolomites are determined to be Ca1.00-1.03Mg0.94-0.98Fe0.00-0.06As0.00-0.01(CO3)2(D0), Ca0.97-1.16Mg0.32-0.83Fe0.10-0.50Mn0.01-0.12Zn0.00-0.01Pb0.00-0.03As0.00-0.01(CO3)2(D1), Ca1.00-1.01Mg0.85-0.92Fe0.06-0.11 Mn0.01-0.03As0.01(CO3)2(D2), respectively. It means that dolomites from the Zhenzigou deposit have higher content of trace elements compared to the theoretical composition of dolomite. Feo and MnO contents of these dolomites (D0, D1 and D2) contain 0.05-2.06 wt.%, 0.00-0.08 wt.% (D0), 3.53-17.22 wt.%, 0.49-3.71 wt.% (D1) and 2.32-3.91 wt.%, 0.43-0.95 wt.% (D2), respectively. The dolomite (D1) from layer ore has higher content of these trace elements (FeO, MnO, ZnO and PbO) than dolomite (D0) from hostrock and dolomite (D2) from quartz vein. Dolomites correspond to Ferroan dolomite (D0 and D2), and ankerite and Ferroan dolomite (D1), respectively. Therefore, 1) dolomite (D0) from hostrock is a Ferroan dolomite formed by marine evaporative lagoon environment in Paleoproterozoic Jiao Liao Ji basin. 2) Dolomite (D1) from layer ore is a ankerite and Ferroan dolomite formed by hydrothermal metasomatism origined metamorphism (greenschist facies) associated with Paleoproterozoic intrusion. 3) Dolomte (D2) from quartz vein is a Ferroan dolomite formed by hydrothermal fluid origined Mesozoic intrusion.

Processing and Quality Control of Flux Data at Gwangneung Forest (광릉 산림의 플럭스 자료 처리와 품질 관리)

  • Lim, Hee-Jeong;Lee, Young-Hee
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.10 no.3
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    • pp.82-93
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    • 2008
  • In order to ensure a standardized data analysis of the eddy covariance measurements, Hong and Kim's quality control program has been updated and used to process eddy covariance data measured at two levels on the main flux tower at Gwangneung site from January to May in 2005. The updated program was allowed to remove outliers automatically for $CO_2$ and latent heat fluxes. The flag system consists of four quality groups(G, D, B and M). During the study period, the missing data were about 25% of the total records. About 60% of the good quality data were obtained after the quality control. The number of record in G group was larger at 40m than at 20m. It is due that the level of 20m was within the roughness sublayer where the presence of the canopy influences directly on the character of the turbulence. About 60% of the bad data were due to low wind speed. Energy balance closure at this site was about 40% during the study period. Large imbalance is attributed partly to the combined effects of the neglected heat storage terms, inaccuracy of ground heat flux and advection due to local wind system near the surface. The analysis of wind direction indicates that the frequent occurrence of positive momentum flux was closely associated with mountain valley wind system at this site. The negative $CO_2$ flux at night was examined in terms of averaging time. The results show that when averaging time is larger than 10min, the magnitude of calculated $CO_2$ fluxes increases rapidly, suggesting that the 30min $CO_2$ flux is influenced severely by the mesoscale motion or nonstationarity. A proper choice of averaging time needs to be considered to get accurate turbulent fluxes during nighttime.

진도의 담수산 물벼룩류와 요각류의 출현특성에 관한 생태학적 연구

  • Yoon, Seong-Myeong;Chang, Cheon-Young;Kim, Won
    • Animal Systematics, Evolution and Diversity
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    • v.11 no.1
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    • pp.39-64
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    • 1995
  • A faunistic and ecological study on the occurrence of freshwater cladocerans and copepods was accomplished from Chindo, South Korea. Collections were made from total 35 stations, comprising the various freshwater habitats like reservoirs, streams, swamps, bogs, ricefields, ditch, pond, and spring during the periods of July 23-25, and November 1-3 in 1994. Twenty seven cladoceran species of 17 genera of 6 families in 2 orders, and 28 copepod species of 21 genera of 6 families in 3 orders were collected during this research period, of which Daphnia obtusa Kurz and Elaphoidella bidens (Schmeil) are newly recorded from Korea. In reservoirs, Diaphanosoma sp. and Thermocyclops taihokuensis were dominant in July, and then succeeded by Bosmina longirostris and Cyclops vicinus vicinus in November. Thermocyclops crassus co-occurred with 7: taihokuensis at both seasons, was frequent in November after T. taihokuensis precipitately decreased. In other stagnant waters, 7: taihokuensis and Moina weismanni were dominant at ponds in July and in November, respectively. At ricefields in July Moina macrocopa and T. taihokuensis were dominant, but in November M. macrocopa and Paracyclops fimbriatus were. At streams, cladocerans were relatively rare, but became more rich in November. The representative cladoceran species were Bosmina longirostris as a plankton, and Chydorus sphaericus as a epibenthic species. Concerning copepods, nearly all the stations of streams except a few ones adjacent to seashore showed the similiar species constitutions, of which E. serrulatus and M, pehpeiensis were most frequent and abundant. At a mountain streamlet and a spring, the occurrence of Alona sp., Attheyella byblis Chang and Kim, 1992 and A. tetraspinosa Chang, 1993 is quite interesting and deserved much attention in the taxonomical point of view. Seventeen major cladocerans and copepods from lentic habitats and 13 major cladocerans and copepods from lotic habitatats were clustered using average taxonomic distance and UPGMA to infer the co-occurrence relations among species. As for lentic habitats, two large phena were appeared at first. The one phenon consisted of Diaphanosoma sp. and T taihokuensis, and showed its predominancy over the various habitats and its dominancy was rapidly decreased in November. The other phenon frequently occurred rather in November, and subdivided into three subgroups. On the other hand, as for lotic habitats, 13 species were also grouped into 2 large phena. The first one comprised 4 species, which were dominant and highly frequent at nearly all the lotic habitats, and subdivided into three subgroups according to their seasonal fluctuation types. The second one was also subdivided into three phena, the first of which comprised only one species, Microcyclops varicans, and occurred at most of the stations along stream with steadiness through the research period; the second phenon, Chydorus sphaericus, occurred much frequently in November; the last phenon included a few heterogenous subgroups.

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Material and Behavior Characteristics of Lightweight Embankment for Road Constructed on Soft Ground (연약지반에 시공된 도로용 경량성토체의 재료 및 거동특성)

  • Yea, Geu-Guwen;Lee, Yong-Jae;Kim, Hong-Yeon;Yoon, Gil-Lim;Han, Sang-Hyun
    • Journal of the Korean Geosynthetics Society
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    • v.17 no.2
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    • pp.41-49
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    • 2018
  • The purpose of this study is to fabricate a full scale road embankment using lightweight air foamed soil as a soil material on soft ground and to investigate its material characteristics and behavior in order to promote dredged soil utilization and minimize ground improvement. As a result of the laboratory test of the onsite mixed samples, the total unit weight of the specimens decreased almost linearly until curing 28 days. In particular, the total unit weight after 28 days of curing was reduced to about 81% of the slurry state before curing, which will be useful in the formulation of similar native soil materials in the future. The unconfined compressive strength began to decrease with the 14th day of curing as shown in the previous study. When the cement content is increased, the strength decreases sharply at a small strain change after the occurrence of the maximum compressive strength, and the maximum strength is exhibited in a range of a smaller axial strain than normal range. The settlement at the surface layer of the ground due to the lightweight embankment was about 1 / 2.75 of the soil embankment and was in agreement with the unit weight ratio (1 / 2.7) of the embankment materials. This indicates the cause and effect of the settlement due to the difference in self weight of the embankments. Also, the difference in settlement between soil and lightweight embankment increased with increasing depth. This shows that the difference in the point at which the settlement is terminated is clear. The ground horizontal displacement under the lightweight embankment was about 15~20% smaller than that of the soil embankment and the depth of occurrence was also 4.5~5.0m shallower in the lightweight embankment.

A Case Study on Deformation Behaviors of CFRD with Water Level Change (수위변화에 따른 CFRD의 변형거동 사례분석)

  • Yun, Jung-Mann;Yea, Geu-Guwen;Kim, Hong-Yeon;Lee, Jae-Yeon
    • Journal of the Korean Geosynthetics Society
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    • v.17 no.1
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    • pp.21-31
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    • 2018
  • This paper analyzes the displacements of CFRD which was completed by field measurement. It is to understand the deformation behavior of the dam body according to the water level change from the impounding time. And it was compared with numerical analysis results. As a result of measuring the behavior of the dam crest and downstream slope according to impounding, horizontal displacements in axis direction of the dam, upstream and downstream displacements and settlements occurred mostly when the water level reaches about half of the dam height. The displacements continued until the water level reached its maximum. After that, it showed a constant convergence regardless of the water level. Horizontal displacements of the face slab which is the most important in CFRD were similar at all locations. The Horizontal displacements of the face slab showed the trends of increasing in winter and decreasing in summer due to the effect of the outside temperature before impounding. Also, the displacements increased until the water level reached about half of the dam height. After that, they decreased with rising in water level. As a result, the face slab behaviors according to seasonal change after impounding as well as water level condition. It is judged because of the material characteristics of the concrete slab. Numerical analysis showed slightly different maximum settlement and depth of occurrence from the measuring data after construction of the dam. It is considered that this is due to various design and construction differences such as the estimation of input parameters in analysis, construction period, and the layer thickness of construction. For the overall period of the dam, the settlements were mostly completed during the construction period and some settlements occurred in the early days of impounding and then converged.