• Journal of the Korean Wood Science and Technology
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• 제24권1호
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• pp.48-53
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• 1996

Brown rot fungus, Tyromyces palustris, has been reported to cause the loss of strength accelerated by oxalate, a non-enzymatic low molecular weight acid, with minute weight loss of decaying wood in early stage. The production of oxalate in relation to wood decaying and the presence of oxaloacetase. an oxalate producing enzyme, were identified during the process. Tyromyces palustris produced the largest amount of oxalate among brown rot fungi. In order to find out the cleavage of pulp fiber, we submerged pulp fiber in oxalate solution and the results showed that the number of short pulp fiber was highly increased, compared with control solution. The pH of decaying wood was decreased to 1.77 which was close to that of saturated oxalate solution, pH 1.2, Thus, the oxalate was thought to be accumulated in the decaying wood, The oxaloacetase which accelerates production of oxalate was derived from fungus, and the production of oxalate by the enzyme was determined by using on UV/Vis spectrophotometer. Therefore, the oxalate was found to be produced by oxaloacetase during decay. The oxalate may cause the acid-hydrolysis of cellulose and hemicellulose. The oxalate was thought to reduce the degree of polymerization and increase the enzyme activity, which resulted in rapid loss of strength in early stage-an identical feature of brown rot fungus.

• 한국염색가공학회지
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• 제34권3호
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• pp.197-206
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• 2022

The purpose of this study was to confirm the optimal spinning conditions for PLA (Polylactic acid) as a fiber forming polymer. According to the melt spinning test results of PLA, the optimal spinning temperature was 258℃. However, it needs to note that relatively high pack pressure was required for spinning at 258℃. At an elevated temperature, 262℃, mono filament was broken easily due to hydrolysis of PLA at a higher temperature. In case of fiber strength, it was confirmed that the draw ratios of 2.7 to 3.3 were optimal for maximum strength of melt spun PLA. Above the draw ratio, 3.3, the strength of the PLA fibers was lowered. It was presumed that cleavage of the PLA polymer chain over maximum elongation. The heat setting temperature of GR (Godet roller) showed that the maximum strength of the PLA fibers was revealed around 100℃. The degree of crystallinity and the strength of the PLA fibers were decreased above 100℃. The optimal take-up speed (Spinning speed) was around 4,000m/min. Thermal analysis of PLA showed 170℃ and 57℃ as Tm (melting temperature) and Tg (glass transition temperature), respectively.

• 한국해양공학회지
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• 제24권1호
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• pp.146-152
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• 2010

Recently, the applied frequency of composite materials was increased from the viewpoint of lightweight, high strength and low cost when a leisure boat and a fishing boatwere built. However, studies on the mechanical properties of composite material with ship are rare. Specially, a leisure boat and fishing boat with FRP had been built by hand lay-up method. However, the vacuum infusion method is rising recently for ship building. The manufactured these FRP plates were combined by using the adhesive. Therefore, in this study Cleavage peel strength, Shear strength and fatigue limit of adhesive bonds by tensileloading were estimated. From test results, the strengths of FRP specimens made by the vacuum infusion method are higher than that of the hand lay-up method.

• 한국의류학회지
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• 제37권7호
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• pp.962-971
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• 2013

We compared the effectiveness of amidase (amano acylase, AA) and an endopeptidase, (trypsin, TR) in modifying the hydrophobicity of polyamide fabric. We evaluated the number of amino groups released into the reaction mixture in order to optimize the treatment conditions. We found that a large number of amino groups were released into the reaction mixture due to the cleavage of amide bonds by AA hydrolysis; however, the TR hydrolysis exhibited a relatively lower activity compared to AA hydrolysis. In AA and TR hydrolysis, significant differences were observed in the K/S values and moisture regain. Amide bonds in polyamide fabric were hydrolyzed by AA hydrolysis effectively. Compared to TR, AA formed more hydrolysis product (amino groups) on the fabric surface. Thus, the hydrophobicity of polyamide fabric was modified using AA hydrolysis (as verified by the wettability test) without any deterioration of fiber strength.

• 한국염색가공학회지
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• 제1권1호
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• pp.1-6
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• 1989

The reaction of silk with a disulfide-containing crosslinking agent, i.e. bis($\beta$-isocyanatoethyl)disulfide(BIED), was studied in an attempt to obtain disulfide-crosslinked silk. The setting properties of disulfide-crosslinked silk fibers were studied. The permanent set values of single fibers were evaluated after the set fibers were relaxed in boiling water. When single fibers were set in boiling water or in boiling alkaline solution, the permanent set values of BIED-treated silk fibers were less than those of untreated silk fibers. When the fibers were treated with 2% thioglycolic acid solution at $60^\circ{C}$ followed by oxidation, settability of BIED-treated silk was better than that of untreated silk. The rearrangement of secondary bonds faciliated by cleavage of crosslinks as well as the rearrangement of crosslinks itself seems to be an important role in the set stability.

• 한국광물학회지
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• 제28권4호
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• pp.333-341
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• 2015

동아광산에서 채취한 암석 시료의 X-선 회절분석 결과 주 구성광물은 백운석(Dolomite : $CaMg(Co_3)_2$, 투각섬석(Tremolite : $Ca_2Mg_5Si_{18}O_{22}(OH)_2$), 활석(Talc : $Mg_3Si_4O_{10}(OH)_2$), 방해석(Calcite : $CaCO_3$)이며, 소량의 석영(Quartz : $SiO_2$)을 포함하고 있다. 편광현미경 관찰 결과 종횡비는 일반적으로 정의하는 3 : 1의 수치보다 높은 값을 나타내며 신장방향에 대한 소광각은 $8.0-19.5^{\circ}$의 범위로 사소광을 나타낸다. 주사전자현미경 관찰 결과 석면의 장경은 $5{\mu}m$ 이상이고 최대 $250{\mu}m$ 정도이며 종횡비는 3 : 1 정도이다. 암석시료에서 나타나는 석면결정은 벽개면을 따라 성장하고 있으며 결정의 끝부분이 침상형태를 나타낸다. 에너지분산분광분석결과 투각섬석이 주 구성광물인 시료는 대체로 Fe의 함량이 높게 나타난다.

• 비파괴검사학회지
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• 제27권1호
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• pp.1-7
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• 2007

섬유강화 복합재료가 항공기, 우주 구조물, 로봇 팔 등에 널리 사용됨에 따라 복합재료의 신뢰도와 안전성을 향상시키기 위하여 이에 대한 비파괴검사법은 매우 중요한 연구분야로 대두되고 있다. AE법은 복합재의 균열, 섬유 또는 수지재의 파손, 층간분리 등의 발생 및 성장과정에서 발생되는 탄성파로 인한 스트레인 에너지를 검출하는 방법이다. 본 논문에서는 $8{\times}8$ 매트릭스형 피에조 센서를 사용하여 인장시험 하에서 발생되는 AE신호를 측정하고 분석하였다. 이를 위하여 AE신호의 전달거리를 제어할 수 있는 전용회로를 설계하고 제작하였다. 또한 64채널의 AE신호를 획득하기 위하여 발광다이오드를 사용한 광학 저장장치를 구성하였다. 실험결과, $8{\times}8$ 매트릭스형 피에조 센서를 이용하여 복합재료에서 발생되는 AE신호의 발생지점과 전파경로를 효과적으로 검출할 수 있었다.

• Fibers and Polymers
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• 제2권2호
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• pp.92-97
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• 2001

New film forming aromatic poly(amide-imide)s containing isoindoloquinazolinedione (IQ) unit in the backbone chain (polymer XIV) have been successfully synthesized by preparing prepolymers of poly(amic acid-carbonamide). followed by subsequent thermal cyclization of the prepolymers. 4,4-Diamino-3-carbamoylbenzanilide (DACB) V has been synthesized by reduction of 3-carbamoyl-4-amino-4-nitrobenzanilide IV. The prepolymers of poly(amic-acid-carbonamide) (polymers VII and VIII) which exhibit viscosities ranging from 1.4 to 1.7 dl/g have been prepared by a condensation polymerization of monomers such as BPDA, ODA, and DACB. Polymer XIV has been obtained by thermal cyclization of the polymers VII and VIII. During the thermal cyclization reaction, imide ring structure was first introduced and then transformed to the structure of IQ unit. The thermal degradation rate of the resultant polymers were influenced by the cleavage of amide bond but the final char yield was comparable to that of poly(BPDA-ODA).

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 춘계학술대회논문집A
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• pp.148-152
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• 2000

The aluminum alloy 6061-T6 has been successfully used in structural applications especially the pressure vessel of the Advanced Neutron Source research reactor. And aluminum alloys, including 6061-T6, have a face-centered-cubic crystals structure. Under normal circumstances face-centered-cubic crystal structures do not exhibit cleavage fractures even at very lo9w temperatures. In aluminum-based structures, plates frequently find use as connecting links. Mechanical fasteners are often utilized in instances where ease of application, familiarity with fabrication processes, and severe dynamic loading are of concern. Plates frequently find use as connecting elements in structures built from aluminum alloys. Many structural elements employ mechanical fasteners. Twenty and twenty aluminum alloy 6061-T6 plates, representing four different bolt patterns, were mechanically deformed. And variable materials such as A1 6061-T6, Al 2024-T3, Carbon/Epoxy, Glass/Epoxy Composite and Woven fiber composite, are used as patch materials. From this experiment, it has been shown that the strength of patch-repaired specimens is different with the patch materials.

• Composites Research
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• 제24권3호
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• pp.25-30
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• 2011

복합재료의 비파괴 검사 방법에 관한 연구는 복합재료의 신뢰성 및 안전성을 개선시키는데 매우 중요하다. AE기법은 소성변형, 섬유파손, 모재균열 또는 박리에 의해 생성되는 탄성파에서 감지되는 변형 에너지를 감지하여 결함을 평가하는 기법이다. 본 논문에서는 외부 수압을 받는 필라멘트 와인딩 복합재 원통과 샌드위치 원통의 수압시험이 수행되었고, PVDF센서로부터 측정된 AE 신호특성을 분석하였다. 또한, L-C 동조회로와 Band-pass filter 회로를 가진 AE 신호분석기를 설계, 제작 하였으며, 필라멘트 와인딩 원통과 샌드위치 원통에 대한 수압실험에서 제작된 AE 신호분석기의 균열 검출 능력을 평가하였다.