• Title/Summary/Keyword: choice properties

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Reference Electrode at Molten Salt: A Comparative Analysis of Electroceramic Membranes

  • Yoon, Seokjoo;Kang, Dokyu;Sohn, Sungjune;Park, Jaeyeong;Lee, Minho;Choi, Sungyeol
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.2
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    • pp.143-155
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    • 2020
  • A reference electrode is important for controlling electrochemical reactions. Evaluating properties such as the reduction potential of the elements is necessary to optimize the electrochemical processes in pyroprocessing, especially in a multicomponent environment. In molten chloride systems, which are widely used in pyroprocessing, a reference electrode is made by enclosing the silver wire and molten salt solution containing silver chloride into the membranes. However, owing to the high temperature of the molten salt, the choice of the membrane for the reference electrode is limited. In this study, three types of electroceramic, mullite, Pyrex, and quartz, were compared as reference electrode membranes. They are widely used in molten salt electrochemical processes. The potential measurements between the two reference electrode systems showed that the mullite membrane has potential deviations of approximately 50 mV or less at temperatures higher than 650℃, Pyrex at temperatures lower than 500℃, and quartz at temperatures higher than 800℃. Cyclic voltammograms with different membranes showed a significant potential shift when different membranes were utilized. This research demonstrated the uncertainties of potential measurement by a single membrane and the potential shift that occurs because of the use of different membranes.

Advances in the design of macroporous polymer scaffolds for potential applications in dentistry

  • Bencherif, Sidi A.;Braschler, Thomas M.;Renaud, Philippe
    • Journal of Periodontal and Implant Science
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    • v.43 no.6
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    • pp.251-261
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    • 2013
  • A paradigm shift is taking place in medicine and dentistry from using synthetic implants and tissue grafts to a tissue engineering approach that uses degradable porous three-dimensional (3D) material hydrogels integrated with cells and bioactive factors to regenerate tissues such as dental bone and other oral tissues. Hydrogels have been established as a biomaterial of choice for many years, as they offer diverse properties that make them ideal in regenerative medicine, including dental applications. Being highly biocompatible and similar to native extracellular matrix, hydrogels have emerged as ideal candidates in the design of 3D scaffolds for tissue regeneration and drug delivery applications. However, precise control over hydrogel properties, such as porosity, pore size, and pore interconnectivity, remains a challenge. Traditional techniques for creating conventional crosslinked polymers have demonstrated limited success in the formation of hydrogels with large pore size, thus limiting cellular infiltration, tissue ingrowth, vascularization, and matrix mineralization (in the case of bone) of tissue-engineered constructs. Emerging technologies have demonstrated the ability to control microarchitectural features in hydrogels such as the creation of large pore size, porosity, and pore interconnectivity, thus allowing the creation of engineered hydrogel scaffolds with a structure and function closely mimicking native tissues. In this review, we explore the various technologies available for the preparation of macroporous scaffolds and their potential applications.

The Coating Materials of Electrode Materials on Machinability of W-EDM (와이어전극의 도금재료가 W-EDM 가공성에 미치는 영향)

  • 김창호;허관도
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.05a
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    • pp.735-738
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    • 2000
  • The characteristics of wire electrical discharge machining (WEDM) are governed by many factors such as the power supply type, operating condition and electrode material. This work deals with the effect of wire electrode materials on the machining characteristics such as, metal removal rate, surface characteristics and surface roughness during WEDM A wire's thermal physical properties are melting point, electrical conductivity and vapor pressure. One of the desired qualities of wire is a low melting point and high vapor pressure to help expel the contaminants from the gap. They are determined by the mix of alloying elements (in the case of plain brass and coated wire) or the base core material(i.e. molybdenum). Experiments have been conducted regarding the choice of suitable wire electrode materials and influence of the properties of these materials on the machinability and surface characteristics in WEDM, the experimental results are presented and discussed from their metallurgical aspect. And the coating effect of various alloying elements(Au, Ag, Cu, Zn, Cr, Mn, etc.) to the Cu or 65-35 brass core on them was reviewed also. The removal rate of some coated wires are higher than that of 65-35 brass electrode wire because the wire is difficult to break due to the wire cooling effect of Zn evaporation latent heat and the Zn oxide on the surface is effective in preventing short circuit. The removal rate increases with increasing Zn content from 35, 40 and Zn coated wire

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A Study on the Choice of Optimal Mixtures and Sensibility Properties of High Strength Concrete and Mass Concrete to apply the High Rising Building (초고층구조물에 적용하기 위한 고강도콘크리트 및 매스콘크리트의 최적배합선정 및 민감도특성에 관한 연구)

  • Lee, Sang-Soo;Song, Ha-Young;Kim, Eul-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.5 no.2 s.16
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    • pp.153-159
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    • 2005
  • This study is to choose the optimal mixture and to analyze the sensibility properties of High strength concrete and mass concrete to apply the high rising building. The main experimental variables were water/binder ratio $39\%,\;33\%,\;35\%\;and\;37\%$, replacement ratio of fly ash $5\%,\;10\%\;and\;15\%$, in the high strength concrete and water/binder ratio $39\%,\;41\%\;and\;43\%$, replacement ratio of fly ash $10\%,\;20\%\;and\;30\%$, in the man concrete. According to the test results, the principal conclusions are summarized as follows. 1) The slump(or slump flow) and air content of fresh concrete were found to be the highest in the elapsed time 30 minutes. 2) The optimal mixture conditions are W/B $40\%$, FA $25\%$ in the mass concrete and W/B $33.4\%$, FA $15\%$ in the high strength concrete. 3) The ranges of sensibility are satisfied in the moisture content ${\pm}l\%\;and\;S/a\;{\pm}2\%$.

Point load actuation on plate structures based on triangular piezoelectric patches

  • Tondreau, Gilles;Raman, Sudharsana Raamanujan;Deraemaeker, Arnaud
    • Smart Structures and Systems
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    • v.13 no.4
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    • pp.547-565
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    • 2014
  • This paper investigates the design of a perfect point load actuator based on flat triangular piezoelectric patches. Applying a difference of electric potential between the electrodes of a triangular patch leads to point loads at the tips and distributed moments along the edges of the electrodes. The previously derived analytical expressions of these forces show that they depend on two factors: the width over height (b/l) ratio of the triangle, and the ratio of the in-plane piezoelectric properties ($e_{31}/e_{32}$) of the active layer of the piezoelectric patch. In this paper, it is shown that by a proper choice of b/l and of the piezoelectric properties, the moments can be cancelled, so that if one side of the triangle is clamped, a perfect point load actuation can be achieved. This requires $e_{31}/e_{32}$ to be negative, which imposes the use of interdigitated electrodes instead of continuous ones. The design of two transducers with interdigitated electrodes for perfect point load actuation on a clamped plate is verified with finite element calculations. The first design is based on a full piezoelectric ceramic patch and shows superior actuation performance than the second design based on a piezocomposite patch with a volume fraction of fibres of 86%. The results show that both designs lead to perfect point load actuation while the use of an isotropic PZT patch with continuous electrodes gives significantly different results.

Properties of Sol-gel Coating Materials Synthesized from Colloidal Silicas and Methyltrimethoxysilane (Colloidal Silica와 Methyltrimethoxysilane간의 졸겔반응으로 합성된 코팅제 특성 연구)

  • 강동필;박효열;안명상;이태희;명인혜;강귀태
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.9
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    • pp.967-972
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    • 2004
  • Hardness and surface property of coated gel materials are considerably different according to kinds(particle size/stabilized ion) of colloidal silica(CS), kinds of silanes, content ratio of silane versus CS, and reaction degree in sol solution. We report the properties of sol-gel coating materials in which the factors of reaction are kinds of CS, contents ratio of CS and MTMS, and reaction time of sol. The contact angles of the coated films obtained from the mixed CS system showed a little good relationship with MTMS content increase to those from HSA CS reaction system and the change of contact angle didn't have much effect on reaction time of sol. In the coating films obtained from HSA CS reaction system, the surface was much rough in case of that the content MTMS decreased and the reaction of sol kept long. The surface roughness of films obtained from the mixed CS reaction system showed similar tendency, though its degree was a little different. In synthesis of sol-gel coating materials, we could identify that choice of CS kinds and content ratio of CS and silane were important and it was desirable the reaction time of sol is not long.

Use of water retention curves predicted from particle-size distribution data for simulation of transport of Benzo[a]pyrene in soil

  • Cho Young-A;Hwang Sang-Il;Jang Yong-Chul;Lee Dong-Soo
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.216-219
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    • 2006
  • Water retention curve (WRC), one of soil hydraulic properties, is often approximated by property-transfer models (PTMs). Using the PTMs, we can estimate the WRCs from other physical properties such as particle-size distribution (PSD). The objective of this work was to investigate the performance of two PTMs with different origins for numerical simulations on transport of Benzo[a]pyrene in a soil. To do this, we chose both PTMs with different origins, i.e., (1) the lognormal distribution model (L anti NL models), and (2) the modified $Kov\'{a}cs$ model (MK model). The MK model showed tile worse performance in estimation of the WRCs. When transport of B[a]P was simulated, the MK model predicted to move farther than the L and NL models did, indicating that transport of B[a]P in a soil can be greatly influenced by the choice of PTMs.

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Behaviors of Microstructure and Properties in API X70 SAW Weld (API X70 후육강관 SAW용접부 미세조직 및 인성 거동에 대한 연구)

  • Uhm Sang-Ho;Kim Sung-Wook;Kim Jong-Hyun;Lee Chang-Hee;Kim Gwang-Soo
    • Journal of Welding and Joining
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    • v.23 no.2
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    • pp.66-74
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    • 2005
  • API(American Petroleum Institute) steel, as a line pipe material, requires the enhanced mechanical and chemical properties with the environmental severity. Especially, the weld part(weld metal and heat affected zone) is an important region for the safety. However, the study for the behavior of microstructure and toughness in multi-pass welding is seldom. In this study, the relationship between the microstructure and toughness of welds with several welding, bending and heat-treatment conditions was examined. In particular, HIC property in the weld metal was evaluated. The microstructure and toughness in multi-passed HAZ seemed to be determined by the final welding thermal cycle and the low toughness was attributed to the MA constituents formed in the intercritically reheated region. The weld metal showed very low toughness and it was not improved by the change in bending and heat treatment conditions. Additionally, the cracks are observed in the weld metal. from these results, it was found that the choice of welding wire/flux is very important.

Physicochemical Properties of Non-Formaldehyde Resin Finished Cotton Fabric and their Optimal Treatment Condition (비포름알데하이드계 수지 가공제 처리한 면직물의 물리화학적 특성 변화와 최적 처리 조건에 관한 연구)

  • Kim, Han-Gi;Yoon, Nam-Sik;Huh, Man-Woo;Kim, Ick-Soo
    • Textile Coloration and Finishing
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    • v.24 no.2
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    • pp.121-130
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    • 2012
  • Cotton fabrics were treated with some commercial non-formaldehyde and low-formaldehyde resins, and then their effect on the physicochemical properties were respectively investigated including formaldehyde release, tear strength, shrinkage, and wrinkle recovery. Formaldehyde release less than 10ppm was obtained only by non-formaldehyde resin. Considering other factors, the optimal concentration of non-formaldehyde resin was shown to be 9-11%. In case of low-formaldehyde type, 5-7% resin concentration and curing temperature of $160{\sim}170^{\circ}C$ were recommended for optimal finishing condition. The choice and combination of resins and catalysts were also important factors, and preliminary considerations before treating cotton fabrics with resins used in this study are also important to get much better results.

A Study on the Production and Market of Technology Information (기술정보의 생산과 시장에 관한 연구)

  • Park, Hyun-Woo
    • Journal of Information Management
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    • v.30 no.2
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    • pp.20-30
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    • 1999
  • Technology information as an economic good has several properties that would seem to cause difficulties for market transactions. There are several institutions used to over-come problems caused by the peculiar natures of information. The supply of information has exploded, thus bringing about the overload of information. We should be able to choose useful information. Production of technology information has externalities of public goods. Financial support is essential to the national service of technology information. The project should consider the properties of technology information and its market.

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