• Title/Summary/Keyword: chloride environment

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Distribution properties of seasonal airborne sea salt in the seashore (해안가의 계절별 비래염분량의 분포 특성)

  • Lee, Jong-Suk;Choi, Won-Sung;Moon, Han-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.237-240
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    • 2004
  • When the concrete structures are in contact with seawater, concentration of chloride for estimating chloride diffusion coefficient can be defined as the chloride concentration of sea water. However, in case the concrete structures, constructed in the seashore, aren't directly in contact with seawater, it is difficult to establish the interface concentration of chloride. In addition, marine concrete structures are greatly affected by salt attack such as rebar corrosion, among the cause of salt attack, airborne sea salt is primary factor. Therefore, in this study, salt attack environment by airborne sea salt was investigated in terms of a seasonal distribution at 33 spots, 6 areas in the East, West, South coast for 1 year. Results indicated that in the South coast, the amount of the airborne sea salt is comparatively higher in summer. in the West coast. higher in winter. On the other hand, in the East coast, the amount of the airborne sea salt is rarely affected by a season.

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Chloride Diffusion Coefficient and Steel Corrosion Properties of Concrete containing Hydrotalcite-based Corrosion Inhibitor (하이드로탈사이트계 방청제를 혼입한 콘크리트의 염화물확산계수 및 철근부식특성)

  • Kang, In-Young;Kim, Gyu-Yong;Yoon, Min-Ho;Hwang, Eui-Chul;Seo, Won-Woo;Son, Min-Jae
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.90-91
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    • 2017
  • Concrete can be used semi-permanently unless the steel is corroded. However, the concrete exposed to the marine environment is exposed to sea breeze, so chloride ions penetrate into the concrete and the steel is corroded accordingly. In order to solve these problems, there is a method of increasing the covering depth of the concrete and an application of the epoxy paint to the steel. In this study, the hydrotalcite type corrosion inhibitor was mixed with the concrete and the compressive strength, chloride diffusion coefficient and the corrosion properties of the steel were examined.

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Stress Corrosion Cracking of Heat Exchanger Tubes in District Heating System

  • Cho, Sangwon;Kim, Seon-Hong;Kim, Woo-Cheol;Kim, Jung-Gu
    • Corrosion Science and Technology
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    • v.18 no.2
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    • pp.49-54
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    • 2019
  • The purpose of this paper is to present failure analysis, of the heat exchanger tube in a district heating system. SS304 stainless steel is used, as material for the heat exchanger tube. The heat exchanger operates in a soft water environment containing a small amount of chloride ions, and regularly repeats operation and standstill period. This causes concentration of chloride ions on the outer surface of the tube, as well as repeat of thermal expansion, and shrinkage of the tube. As a result of microscopic examination, cracks showed transgranular as well as branched propagation, and many pits were present, at the initiation point of each crack. Energy disperstive spectroscopy analysis showed Fe and O peak, as well as Cl peak, meaning that cracks were affected by Cl ion. Failure of the tube was caused by chloride-induced stress corrosion cracking by thermal stress, high temperature, and localized enrichment of chloride ions.

Prediction of Deterioration Process for Concrete Considering Combined Deterioration of Carbonation and Chlorides Ion (중성화와 염해를 고려한 콘크리트의 복합열화 예측)

  • Lee, Chang-Soo;Yoon, In-Seok
    • Journal of the Korea Concrete Institute
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    • v.15 no.6
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    • pp.902-912
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    • 2003
  • The most common deteriorating processes of concrete structures are carbonation and chloride ion ingress. Many concrete structures have been suffered from chloride ions diffusion or carbonation induced reinforcement corrosion damage and many studies have been done on it. However, those studies were confined mostly to the single deterioration of carbonation or chloride attack only, although actual environment is rather of combined conditions. In case of many in-situ concrete structures, deterioration happened more for the case of combined attack than the single case of carbonation or chloride attack. In this paper, chloride profiles of carbonated concrete is predicted by considering two layer composite model, which is based on Fick's 2nd law. From the experimental result on combined deterioration of chloride and carbonation, it was examined that high chloride concentration was built up to 3∼5 mm over depth from carbonation depth. The analytical modeling of chloride diffusion was suggested to depict the relative influence of the carbonation depth. The diffusion coefficients of carbonation concrete and uncarbonated concrete with elapsed time were considered in this modeling.

Theoretical Analysis of Critical Chloride Content in (Non)Carbonated Concrete Based on Characteristics of Hydration of Cement (시멘트 수화 특성 및 탄산화를 고려한 콘크리트의 임계 염소이온량에 대한 해석 기법)

  • Yoon, In-Seok
    • Journal of the Korea Concrete Institute
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    • v.19 no.3
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    • pp.367-375
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    • 2007
  • Critical chloride content for corrosion initiation is a crucial parameter in determining the durability and integrity of reinforced concrete structures, however, the value is still ambiguous. Most of the studies reporting critical threshold chloride content have involved the experimental measurement of the average amount of the total chloride content at arbitrary time. The majority of these researches have not dealt with this issue combined with carbonation of concrete, although carbonation can significantly impact on critical threshold chloride content. Furthermore, the studies have tried to define the critical chloride content within the scope of their experimental concrete mix proportion at arbitrary time. However, critical chloride content for corrosion initiation is known to be affected by a lot of factors including cement content, type of binder, chloride binding, concentration of hydroxyl ions, and so on. It is necessary to define the unified formulation to express the critical chloride content for various mix proportions of concrete. The purpose of this study is to establish an analytical formulation of the critical chloride content of concrete. In this formulation, affecting factors, such as mix proportion, environment, chemical evolution of pore solution with elapsed time, carbonation of concrete and so on are taken into account. Based on the Gouda's experimental results, critical chloride content is defined as a function of $[Cl^-]$ vs. $[OH^-]$ in pore solution. This is expressed as free chloride content with mass unit to consider time evolution of $[OH^-]$ content in pore solution using the numerical simulation programme of cementitious materials, HYMOSTRUC. The result was compared with other experimental studies and various codes. It is believed that the approach suggested in this study can provide a good solution to determine the reasonable critical chloride content with original source of chloride ions, for example, marine sand at initial time, and sea water penetration later on.

Evaluate the Concrete mix by Type Accelerated Corrosion Test and Chloride Penetration Analysis with Artificial Seawater Cyclic Wet and Dry Condition (인공해수 건습반복조건에 따른 콘크리트배합별 부식촉진시험법과 염화물 침투해석평가)

  • Park, Sang-Soon;Kim, Min-Wook
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.3
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    • pp.211-218
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    • 2013
  • Cyclic wet and dry conditions in the marine environment structures corrosion is known to be the fastest rising. For that reason, accelerated corrosion test methods for the reproduction of tidal environment has been actively conducted. However, many studies have estimated threshold value for steel corrosion or concentrated in chloride penetration analysis. In this study, cyclic wet and dry conditions to reproduce the structure of the environment in accelerated corrosion and chloride penetration test analysis was performed. Corrosion was determined by the result of reinforcement corrosion monitoring based on galvanic potential measurement and half-cell potential method. Accelerated corrosion test results for each formulation was different corrosion periods, the order OPC> FA> BS> High-strength concrete. FEM durability interpretation program DuCOM was conducted under the same conditions as in accelerated corrosion test. The experimental RCPT tests demonstrated the validity of the result.

Isolation and Physiological Properties of a Moderately Halophilic Bacterium Listeria denitrificans HB-38 (호염성 제균 Listeria denitrificans HB-38 균주의 분리 및 생리적 성질)

  • HONG Yong Ki;SEU Jung Hwn
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.16 no.2
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    • pp.68-74
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    • 1983
  • A moderately halophilic bacterium, Listeria denitrificans HB-38, isolated from mud on the seashore in Sooyoung bay, Pusan, showed the requirement of $4\%$ sodium chloride for cell growth in a medium with salts typical of a marine environment, and showed that of $10\%$ in a medium with salts typical of a terrestrial environment. The optimum temperature and pH for growth were $40^{circ}C$ and pH 7.5 in the medium containing $10\%$ sodium chloride and ions typical of a terrestrial environment. Sodium chloride as a protoplast stabilizer gave more stability than sorbitol or sucrose, meanwhile the protoplast did not require higher concentration of stabilizer than that of E. coli protoplast. Succinic dehydrogenase of HB-38 had a halophilic property showing maximal activity in the presence of $9\%$ sodium chloride. The strain HB-38 did not harbor an extrach-romosomal DNA.

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A study on the Application Effect of Friction Stir Processing for Enhanced Pitting Corrosion Resistance of Stainless Steel Welds in Chloride Environment (염화물 환경에서 스테인리스강 용접부의 공식저항성 향상을 위한 마찰교반공정 적용효과에 관한 연구)

  • Jong Moon Ha;Deog Nam Shim;Seung Hyun Kim
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.19 no.2
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    • pp.84-92
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    • 2023
  • As temporary storage facilities for spent nuclear fuels in domestic nuclear power plants are expected to be saturated, external intermediate storage facilities would be required in the future. Spent nuclear fuels are stored in metal canisters and then placed in a dry environment within concrete or metal casing for operation. In the United States, the dry storage method for spent nuclear fuels has been operated for an extended period. Based on the corrosion experiences of dry storage canisters in chloride environments, numerous studies have been conducted to reduce corrosion in welds. With the construction of intermediate storage facilities in Korea for spent nuclear fuels expected near coastal areas adjacent to nuclear power plants, there is a need for research on the corrosion occurrence of welds and mitigation methods for canisters in chloride environments. In this paper, we measured and compared the residual stresses in the Heat-Affected Zones (HAZ) after electron beam welding (EBW) and gas tungsten arc welding (GTAW) processes for candidate materials such as 304L, 316L, and duplex stainless steel(DSS). We investigated the possibility of microstructure control through the application of surface modification processes using friction stir processing (FSP). Corrosion tests on each welded specimen revealed a higher corrosion rate in EBW welds compared to GTAW. Furthermore, it was confirmed that corrosion resistance improved due to phase refinement and redistribution of precipitates when FSP was applied.

Repair of Highway Bridge damaged by Chloride Attack in Marine Environment(2) - Application of Cathodic Protection (해양에 위치한 고속도로교량에 대한 내염보수 공법(2)-전기방식시공결과)

  • Chi, Han-Sang;Han, Bog-Kyu;Cheong, Hai-Moon;Ahn, Tae-Song;Ryu, Jong-Hyun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.786-789
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    • 2004
  • Corrosion of reinforced concrete structures in marine environment is one of the most important mechanism of deterioration. However, conventional rehabilitation techniques in tidal zone, which consist of removing delaminated areas of concrete, cleaning affected steel and patching with portland cements mortar, have proven to be ineffective for marine structures. Also, repairs are often repeated every several years. The purpose of this report is to announce appropriate repair method of highway bridge damaged by chloride attack in marine environment (application of cathodic protection) using FRP and antiwashout underwater mortar.

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Repair of Seonjingang Bridge in Namhae Highway Route Deteriorated by Chloride Attack (남해고속도로 섬진강교 내염보수공사 시공)

  • Han Bog Kyu;Chi Han Sang;Cheong Hai Moon;Ahn Tae Song
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.355-358
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    • 2005
  • Corrosion of reinforced concrete structures in marine environment is one of the most important mechanisms of deterioration. Under Korean highway bridge, the time for the steel reinforcement in the concrete to exhibit initial signs of corrosion is within three decades. Therefore, 'SUM JIN' highway bridge, located in a corrosive marine environment on the south of Korea, had been examined the current condition of the steel reinforcement corrosion in concrete by half-cell potentials, chloride contamination of concrete and so on. According to the tests, the protecting film around the reinforcement is deteriorated and corrosion activity developed in tidal zone. The purpose of this paper is to report the effects of 'SUM JIN' highway bridge damaged by chlodide attack and to present the results of repair of 'SUM JIN' highway concrete bridge in domestic marine environment.

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