• Title/Summary/Keyword: chemical-biological protection

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Development and evaluation of a model for management of plant pests in organic cucumber cultivation

  • Ko, S.J.;Kang, B.R.;Kim, D.I.;Choi, D.S.;Kim, S.G.;Kim, H.K.;Kim, H.J.;Choi, K.J.;Kim, Y.C.
    • Korean Journal of Organic Agriculture
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    • v.19 no.spc
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    • pp.263-266
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    • 2011
  • Crop protection strategies in organic horticulture aim to prevent insect pest and plant disease problems through utilization of non-chemical based control means. In order to develop a model for management of plant diseases and insects in organic cucumber cultivation, we compared efficacies between chemical pesticide spraying system and biological control means in semi-forcing and retarding cucumber cultivation during 2005 and 2006. Conventional chemical spray program using various chemical pesticides was applied 5 - 10 days intervals, while two different non-chemical pesticide application programs using two formulated biopesticides Topseed$^{TM}$ and Q-fect$^{TM}$, Suncho$^{TM}$, and Sangsungje$^{TM}$ (biocontrol agents 1) and using egg-yolk and cooking oil(EYCO), Bordeaux mixture, Suncho$^{TM}$, and Sangsungje$^{TM}$ (biocontrol agents 2) were applied 5 - 7 days intervals during entire cucumber cultivation period. Efficacy of both biocontrol agents programs was effective to comparable to conventional chemical pesitice spray program to control plant diseases such as powdery mildew and downy mildew as well as insect pests such as aphids and thrips which are known as major threats in cucumber organic cultivation. In this study, we established and evaluated an effective and economic crop protection strategy using various biological resources can be used to control plant diseases and pests simultaneously in organic cucumber cultivation field.

Synthesis and Biological Evaluation of 2-Amino-4H-pyran-3,4,5-tricarboxylate Salt Derivatives

  • Akbari, Ali;Azami-Sardooei, Zabihollah;Hosseini-Nia, Asghar
    • Journal of the Korean Chemical Society
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    • v.57 no.4
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    • pp.455-460
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    • 2013
  • A novel and simple method for the synthesis of 2-amino-4H-pyran-3,4,5-tricarboxylate derivative and the evaluation of their antibacterial activity against Pseudomonas syringae, Xanthomonas citi and Pectobacterium carotovorum are reported. The structure of the isolated compounds has been determined by means of $^1H/^{13}C$ NMR and FT-IR Spectroscopy. The reaction of alkyl isocyanides with acetylenic esters in the presence of dimethyl acetone-1,3-dicarboxylate in the present of $BF_3.SiO_2$ at ambient temperature. Some of the compound showed significant inhibition to growth of bacteria.

Electrochemical Determination of Ciprofloxacin Based on the Enhancement Effect of Sodium Dodecyl Benzene Sulfonate

  • Zhang, Shenghui;Wei, Shuang
    • Bulletin of the Korean Chemical Society
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    • v.28 no.4
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    • pp.543-546
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    • 2007
  • Herein, a new electrochemical method was described for the determination of ciprofloxacin based on the enhancement effect of an anionic surfactant: sodium dodecyl benzene sulfonate (SDBS). In pH 4.0 phosphate buffer and in the presence of 1.0 × 10-4 mol/L SDBS, ciprofloxacin yields a well-defined and sensitive oxidation peak at the carbon paste electrode (CPE). Compared with that in the absence of SDBS, the oxidation peak current of ciprofloxacin remarkably increases in the presence of SDBS. The experimental parameters, such as supporting electrolyte, concentration of SDBS, and accumulation time, were optimized for ciprofloxacin determination. The oxidation peak current is proportional to the concentration of ciprofloxacin over the range from 8.0 × 10-8 to 5.0 × 10-6 mol L-1. The detection limit is 2.0 × 10-8 mol L-1 after 2 min of accumulation. This new voltammetric method was successfully used to detect ciprofloxacin in drugs.

Comparison of the plant uptake factor of perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS) from the three different concentrations of PFOA and PFOS in soil to spinach and Welsh onion

  • Lee, Deuk-Yeong;Choi, Geun-Hyoung;Rho, Jin-Ho;Lee, Hyo-Sup;Park, Sang-Won;Oh, Kyeong-Yeol;Kim, Jin-Hyo
    • Journal of Applied Biological Chemistry
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    • v.63 no.3
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    • pp.243-248
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    • 2020
  • The long-chained perfluoroalkyl acids (PFAAs), perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS), are a potential exposure risk in the environment, specifically for humans due to high levels of bioaccumulation, persistence, and toxicity. In the current study, the plant uptake factors (PUFs) of spinach and Welsh onion were investigated on the three different concentration levels of PFOA and PFOS in soil. Spinach and Welsh onion were divided into three residue groups, a control group and two levels of PFOA and PFOS. The PFAAs spiked soils were aged for six months and the extractable residue of PFOS in the aged soil was reduced to 30-59% of the initial spiked concentrations for PFOS, while PFOA showed almost the same initial spiked concentrations. The PUFs for PFOA and PFOS were 0.111-2.821 and 0.047-3.175 for spinach, and 0.203-0.738 and 0.035-0.181 for Welsh onion, respectively. The highest PUF values in both vegetable were displayed when the residual concentration of PFAAs were part-per-billion (ppb) or sub-ppb in soil.

Comparison of residue patterns between foliar application and drenching in export strawberry (경엽 및 관주 처리에 따른 딸기 중 침투성 농약 잔류패턴 비교)

  • Lee, Hyo-Sub;Hong, Su-Myeong;Kwon, Hye-Young;Kim, Dan-bi;Moon, Byeong-Chul
    • Journal of Applied Biological Chemistry
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    • v.60 no.4
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    • pp.313-319
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    • 2017
  • Strawberries are one of the main commodities in Korea and have been exported over 30 million dollar. And the safety has recently become an important issue in the agro-trade, pesticide residue is most important matter of safe agricultural products. As strawberries can be cultivated using elevated production system, so it is possible to use the drenching. When spraying the pesticides, the use of drenching can be lower amount of residual than using foliar treatment. In this study, time sequential residual amount of pesticides were compared between drenching and foliar application in strawberries. Pesticides were treated with the standard and double dosage and samples were collected at 0, 3, 6, 9, 13, 16 and 21 day and analyzed by LC and LC-MS/MS after liquid-liquid extraction and QuEChERS. Two pesticides were detected less than 1 mg/kg in all samples for drenching treatment. Carbendazim residues in drenching treatment were 5 to 25 times lower than foliar application. And azoxystrobin was not detected in strawberries of drenching treatment.

Pesticide residual characteristics in Strawberry, treated by drenching under hydroponics (관주처리에 따른 양액재배 딸기의 농약잔류 특성)

  • Lee, Hyo-Sub;Hwnag, In-Seong;Cheon, Jae-In;Kwon, Hye-Young;Hong, Su-Myeong
    • Journal of Applied Biological Chemistry
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    • v.62 no.1
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    • pp.11-17
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    • 2019
  • Strawberries are one of the main commodities in Korea and have been exported over 40 million dollar. Because the strawberry cultivation using hydroponics has increased, treatment of pesticide by drenching draw interest recently. However, detailed researches for drenching treatment of pesticide are limited, which results in difficulties in proper pesticide applications in agricultural fields. To activate use of drenching and improve safety in agricultural products, In this study, time-dependent residual characteristic of pesticides were compared with between different applications of pesticides in strawberries. The characteristics of azoxystrobin, prochloraz and thiamethoxam were investigated with drenching treatment at different applications: the time of treatment, concentration etc. at hydroponic cultivation for 40 days. Azoxystrobin and prochloraz were not detected at 14 day after application. Thiamethoxam was detected from 0.02 to 0.85 mg/kg. Crop uptake of pesticides was strongly affected with octanol-water partition coefficient and solubility in water. Residual amount in crops are highly dependent on the concentration of active ingredient of pesticides.

Biological Control Strategy of Uzi Fly in Sericulture

  • Singh, R.N.;Saratchandra, Beera
    • International Journal of Industrial Entomology and Biomaterials
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    • v.6 no.2
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    • pp.125-132
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    • 2003
  • Uzi fly (Exorista bombycis Louis) is one of the major larval endo-parasitoid of silkworm (Bombyx mori). It causes extensive damage to sericulture industry. The application of synthetic organic pesticides has tremendous impact on minimizing pest population but their overuse and frequent misuse and high sensitivity towards the silkworms, has forced the entomologists to search for alternatives to chemical control, which is safe to silkworm, environment and farm workers. Biological control continues to offer exciting possibilities for the control of fly pest population. It is environmentally safe alternative to chemical control and offering a long-term protection. Several potential hymenopteran parasitoids have been screened. Among successful natural enemies, Nesolynx thymus, Trichomalopsis apanteloctena, Trichopria sp., Brachymeria lasus, Pediobius sp., Spalangia sp., Spilomicrus karnatakensis and Dhirhinus sp. are important. It is essential to predict accurately the efficacy of these natural enemies in a new habitat prior to its introduction. The important desirable attributes of these potential parasitoids viz., host searching capacity, specificity, power of increase and fitness and adaptability of the parasitoid in new environment has been recorded. Results of the host parasitoid interaction indicate that the aging of the host function as a factor that influence the host finding efficiency of the parasitoid. It is highly scored with 15-20 hrs old pupa of the host. However, aging of the parasitoid does not significantly affect it. The sex ratio is female biased which is advantageous from biological control point of view, Biological suppression methods involving conservation and utilization of natural enemies have been discussed in detail.

Effect of Ventilation on Heat Stress in the System of Short-Sleeve T-Shirt-Combat Uniform-Chemical, Biological, and Radioactive Protective Clothing (반팔 내의-전투복-화생방보호의 시스템에서 환기가 열적 스트레스에 미치는 영향)

  • Lee, Okkyung;Eom, Rani;Jung, Heesoo;Cho, Kyeong Min;Lee, Yejin
    • Journal of the Korean Society of Clothing and Textiles
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    • v.46 no.5
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    • pp.836-847
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    • 2022
  • This study establishes basic data for the development of a new Chemical, Biological, and Radioactive (CBR) protective clothing by selecting the ventilation position to optimize thermal comfort on the basis of the opening and closing of each part. Participants were eight men in their 20s who had previously worn CBR protective clothing. After vigorous exercise and perspiration, the microclimate of the clothing and skin temperature was measured. Results revealed that when the ventilation zipper was opened after exercising, the skin and clothing microclimate temperatures, which had increased during the exercise, decreased in the chest and shoulder blade regions. The clothing microclimate humidity decreased in the chest area. The change was greatest in the chest region; the skin temperature decreased by 0.2℃, the clothing microclimate temperature by 2.7℃, and the clothing microclimate humidity by 3.2%RH through ventilation. Thus, the opening that allows the exchange of accumulated heat and moisture while wearing the CBR protective clothing is efficient.

A Study on Status Survey for the Improvement of Shelter Facilities for Residents (주민대피시설의 성능개선을 위한 실태조사에 관한 연구)

  • Park, Namkwun;Kang, Shinwook
    • Journal of the Society of Disaster Information
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    • v.10 no.1
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    • pp.91-97
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    • 2014
  • purpose of this study was to conduct status survey on existing shelter facilities for residents and use it as basic material to plan and design improved shelter facilities in the future. As the result, first, although existing shelter facilities are judged to have been designed in consideration only of the protection from high explosive shells, actual protection capability is significantly low against high explosive shells when exit direction and protection capabilities of main entrances were investigated. Second, all the 7 facilities did not have air purifier with filters installed for the air that flows into the inside from outside and since the height of air exhausts and intake pipes in the outside are also close to the earth, there are possibilities that heavy contaminated air can flow into the inside. Third, although some facilities have anti-explosion doors installed, it is impossible to use them as chemical, biological and radiological (CBR) shelter because of improper installation of openings and anti-explosion valves as well as poor plumbing that cannot ensure air-tightness and poor finish of piping penetration.

Preparation of Selectively Permeable Membrane Materials with Enhanced Protective Capability against Blister Agents (수포작용제 방호성능이 향상된 선택투과막 제조)

  • Kwon, Tae-Geun;Kim, Jin-Won;Kang, Jae-Sung;Park, Hyen-Bae;Lee, Hae-Wan;Seo, Hyeon-Kwan
    • Membrane Journal
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    • v.24 no.2
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    • pp.167-175
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    • 2014
  • For selectively permeable membrane based on cellulose acetate butyrate (CAB) and polyethyleneimine (PEI) with water vapor transportability and DMMP protective performance, we intended to improve protective performance of the membrane against CEES using several additives. Results showed that CAB/PEI membranes possessed performance with good water vapor permeation (${\geq}1,800g/m^2/day$) and enhanced protective capability against CEES contamination ($7.1{\sim}11.5{\mu}g/cm^2{\cdot}day$). Of these membranes, the membrane containing $Ag^+$ ion and ionic exchange resin showed the best protective performance. And, we identified that the CAB/PEI membranes show excellent protection against aerosols with various particle sizes ($0.005{\sim}3{\mu}m$) simulating biological agents.