• Title/Summary/Keyword: chemical water quality

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Effect of Gypsum Application on Reducing Methane (CH4) Emission in a Reclaimed Coastal Paddy Soil (간척지 논 토양 개량제로서 석고처리가 메탄 배출량 저감에 미치는 영향)

  • Lim, Chang-Hyun;Kim, Sang-Yoon;Kim, Pil-Joo
    • Korean Journal of Environmental Agriculture
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    • v.30 no.3
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    • pp.243-251
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    • 2011
  • BACKGROUND: Gypsum($CaSO_4{\cdot}2H_2O$) is known as an ideal amendment to improve soil quality of the reclaimed coastal land. Since gypsum has very high concentration of electron acceptor like ${SO_4}^{2-}$, its application might be effective on reducing $CH_4$ emission during rice cultivation, but its effect has not been studied well. METHODS AND RESULTS: The effect of gypsum on $CH_4$ emission and rice growth characteristics was studied by pot test, which was packed by reclaimed paddy soils collected from Galsa, Hadong, Gyeongnam province. Chemical-grade gypsum was applied in two soils having EC 2.25 and 9.48 dS/m at rates of 0, 0.5, 1.0 and 2.0%(wt/wt). $CH_4$ emission was characterized a week interval by closed chamber method during rice cultivation. $CH_4$ emission rate was significantly decreased with increasing salt accumulation and gypsum application levels. With increasing gypsum application, dissolved ${SO_4}^{2-}$ concentration in the leachate water was significantly increased, which might have suppressed $CH_4$ production in soil. Total $CH_4$ flux was dramatically decreased with increasing gypsum application. In contrast, rice yield was increased with increasing gypsum application and then achieved maximum productivity at 1.0% gypsum application in two soils. CONCLUSION(s): Gypsum is a very good soil amendment to suppress $CH_4$ emission in reclaimed coastal paddy soils, and improve rice productivity and soil properties. The optimum application level of gypsum is assumed at ca. 1% to improve soil productivity with reducing effectively $CH_4$ emission during rice cultivation.

Characteristics of wastewater treatment of sewage mixed with industrial wastewater (공장폐수가 혼합된 하수처리장의 하수처리 특성)

  • Ahn, June-Shu;Park, Wook-Keun;Cho, Jung-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.7
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    • pp.3341-3352
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    • 2011
  • In this study, characteristics of wastewater treatment of sewage intermittently mixed with industrial wastewater is examined by investigating the operational status of each unit operation and measuring water quality. The bioreactor operating condition was measured for MLSS concentration 2,000~3,000 mg/L, HRT 5.3~16.3 hour, SRT 2.8~66.6 day, and SVI frequently showed the value above 200 which was higher than the optimal range of 50~150. It is thought that the sludge is not in suitable condition for sedimentation caused by the incoming industrial wastewater. When industrial wastewater is come into the system, MLDO inside of bioreactor rapidly increased, rate of nitrification is steeply decreased, and Pin floc. is spilled in the secondary clarifier. In the observance of microorganism showed that various bacterial floc. and ciliata were found as well as actinomycetes and filamentous bacteria(Sphaeotilus) which is known to cause bulking. Efficiency of each unit operation was fairly good in average. However, efficiency of the bioreactor treatment showed high fluctuation by unstable operating condition by intermittently incoming industrial wastewater.

Development of the Waxed Rice Straw Pulp Tray Reduced in Moisture Absorption (흡습억제기능을 보유한 왁스처리 볏짚 트레이의 개발)

  • Ahn, Byoung-Kuk;Park, Sung-Min;Park, Noh-Hyun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.1 no.1
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    • pp.29-37
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    • 1995
  • The purpose of this study was to development the waxed rice straw pulp tray(WRSPT) which had low water sensitivity. The quality changes of mushrooms(Agaricus bisporus) packaged respectively in the WRSPT, non-treated rice straw pulp tray(NRSPT) and expanded polystyrene tray(EPST) were observed during storage. The weight losses of mushrooms in the WRSPTs were less than in the NRSPTs by maintaining below 3% at $0^{\circ}C$ and the applications of WRSPTs were more effective at $20^{\circ}C$. The weight increases of WRSPTs were more lowered than those of NRSPTs by marking below 15% during storage at $0^{\circ}C$. There were no significant differences in the Hunter L values and hardness values of mushrooms in the three types of trays at $0^{\circ}C$. The cap openings of mushrooms were more proceeded in NRSPTs than in WRSPTs and EPSTs at $20^{\circ}C$. As a result, it may be favorable to control excessive moisture absorption of the NRSPT mainly composed of cellulose pulp by introducing such chemical treatments as wax treatment.

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Analysis of Fish Guild Compositions and Total Mercury Contents of Fish Tissues in Analysis in Mangyeong River. (만경강 중.상류의 어류 길드특성 및 어류 조직내 수은 함량 분석)

  • Park, Hyang-Mi;Lee, Eui-Haeng;An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.42 no.2
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    • pp.172-182
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    • 2009
  • This study was to analyze characteristics based on tolerance and trophic guilds and to determine the level of total mercury in tissues of sentinel species, Zacco platypus at 3 sampling sites of the Mangyeong River in 2007. Total sampled fishes were 26 species and the most dominant species was Zacco temminckii (47%). Fish community analysis was resulted that eveness index and diversity index showed low value at S1. However, diversity index and richness index at other sites showed high. According to various guilds analysis, relative abundance of sensitive species was 70% and 42% at S1 and S2, respectively. While sensitive species were decreased (1%) and tolerant species were increased (60%) at S3. It was mainly carried to the impacts of wastewater treatment plants near the location. Relative abundance of insectivore species was decreased from up (S1) to midstream area (S3). In addition, chemical water quality, based on analyses of BOD, COD, TP, TN, EC, MPN and SS concentration showed similar trends. Qualitative Habitat Evaluation Index (QHEI) was averaged 164, judged as "good" habitat condition. Average concentrations of total [Hg] was 146.9 ${\mu}g$ $kg^{-1}$. In the muscles of total [Hg] was the highest, and then followed by kidney, vertebrae, liver, and gills. According to FDA standards (500 ${\mu}g$ $kg^{-1}$) of Korea, total [Hg] has not affected to the individual fish health.

Effect of Waste Nutrient Solution and Reclaimed Wastewater on Chinese Cabbage Growth and Soil Properties (폐양액과 하수처리수 재이용이 배추생육 및 토양에 미치는 영향)

  • Choi, Bong-Su;Lim, Jung-Eun;Shin, Yong-Keon;Yang, Jae-E.;Lee, Sang-Soo;Ok, Yong-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.3
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    • pp.394-399
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    • 2011
  • This study evaluated the effect of using waste nutrient solution (WNS) and reclaimed wastewater (WW) on the growth of Chinese cabbage and soil quality. The pH and electrical conductivity (EC) values of waste nutrient solution were 6.3 and $1.5dS\;m^{-1}$ and being 6.8 and $0.4dS\;m^{-1}$ in reclaimed WW, respectively. WNS found to be included more than $10g\;m^{-2}$ of $NO_3^-$, $K^+$, $SO_4^{2-}$ and $Ca^{2+}$, thereby enhancing Chinese cabbage growth. However, $Cl^-$ and $Na^+$ contents were higher than other nutrients in WW. Among the three irrigation resources, no significant differences were found for the growth of Chinese cabbage plants. On the other hand, pH was decreased in WNS-treated soil when compare to that in WW-treated soil which pH was increased. In spite of the uptake of nutrients by the growing plants, irrigation of the WNS led to an increase in available $P_2O_5$ and exchangeable cations such as $K^+$ and $Mg^{2+}$ in the soil when compared to soil that irrigated by groundwater or WW. Taken together, the use of WNS can remarkably reduce the amount of the chemical fertilizer for Chinese cabbage production; however, WNS can possibly cause a problem as nutrients accumulation in soil.

Marine ecosystem risk assessment using a land-based marine closed mesocosm: Proposal of objective impact assessment tool (육상 기반 해양 폐쇄형 인공생태계를 활용한 해양생태계 위해성 평가: 객관적인 영향 평가 tool 제시)

  • Yoon, Sung-Jin
    • Korean Journal of Environmental Biology
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    • v.39 no.1
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    • pp.88-99
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    • 2021
  • In this study, a land-based marine closed mesocosm (LMCM) experiment was performed to objectively assess the initial stability of an artificial ecosystem experiment against biological and non-biological factors when evaluating ecosystem risk assessment. Changes in the CV (coefficient of value) amplitude were used as data to analyze the stability of the experimental system. The CV of the experimental variables in the LMCM groups (200, 400, 600, and 1,000 L) was maintained within the range of 20-30% for the abiotic variables in this study. However, the difference in CV amplitude in biological factors such as chlorophyll-a, phytoplankton, and zooplankton was high in the 600 L and 1,000 L LMCM groups. This result was interpreted as occurring due to the lack of control over biological variables at the beginning of the experiment. In addition, according to the ANOVA results, significant differences were found in biological contents such as COD (chemical oxygen demand), chlorophyll-a, phosphate, and zooplankton in the CV values between the LMCM groups(p<0.05). In this study, the stabilization of biological variables was necessary to to control and maintain the rate of changes in initial biological variables except for controllable water quality and nutrients. However, given the complexity of the eco-physiological activities of large-scale LMCMs and organisms in the experimental group, it was difficult to do. In conclusion, artificial ecosystem experiments as a scientific tool can distinguish biological and non-biological factors and compare and analyze clear endpoints. Therefore, it is deemed necessary to establish research objectives, select content that can maintain stability, and introduce standardized analysis techniques that can objectively interpret the experimental results.

Improvement Method for the Post-Management End System of a Landfill by Applying Total Pollutant Load Concept (오염총량 개념을 적용한 매립장 사후관리종료제도 개선 방안)

  • Chun, Seung-Kyu;Sim, Nak-Jong;Jeon, Eun-Jeong;Ryu, Don-Sik
    • Journal of the Korean GEO-environmental Society
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    • v.22 no.2
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    • pp.15-23
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    • 2021
  • A method of improving the post-management end system of a landfill that reflected total pollutant load was applied to the SUDOKWON 1st Landfill Site. Modeling results showed that the ratio of remaining methane, when compared to the total maximum potential of 2,521 × 106 Nm3, was estimated to be 8.8% in 2020, 7.0% in 2030, and 6.5% in 2040. If the average oxidation rate of 89.1% in 2005-2019 was applied, the ratio decreased by 1.01% in 2020, 0.76% in 2030, and 0.70% in 2040. This suggests that if the amount of methane generated is all emitted from the surface of the landfill after 2025, the real amount emitted to the atmosphere is less than that in 2019; therefore, the post-management end is possible. According to the results of trend analysis of the quality of leachate water, effluent criteria for Biochemical Oxygen Demand (BOD) can be satisfied in 2024, while those for Chemical Oxygen Demand (COD) and Total Nitrogen (T-N) can be satisfied in 2047 and 2117, respectively. If the post-management end system changed based on total pollutant load, the post-management can be terminated BOD today and COD within a few years; however, the fact that T-N could be terminated only after 2041 shows the need to fundamentally change management methods.

Effects of Azolla Incorporation During Paddy Cultivation on Weed Control, Nitrogen Supply and Rice Yield (물개구리밥(Azolla)이 논 잡초 발생, 질소공급 및 쌀 수량에 미치는 영향)

  • Shin, Jong-Hee;Han, Chae-Min;Kwon, Jung-Bae;Won, Jong-Gun
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.66 no.4
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    • pp.271-278
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    • 2021
  • Azolla is a genus of small aquatic ferns native to Asia, Africa, and America. Azolla is potentially significant as a nitrogen source in agriculture, particularly in conjunction with rice (Oryza sativa L.) cultivation. In addition, Azolla may either control weeds or act as a weed depending on management; therefore, we aimed to determine the effect of Azolla incorporation on weed (e.g., Monochoria vaginalis, Rotala indica, Aeschynomene indica, and Cyperus amuricus) control and its other benefits during rice cultivation. The effects of Azolla on weed emergence were evaluated based on plot area coverage by the Azolla mat, which appears as a green sheet over water, and the rate of weed emergence in paddy field. Weed occurrence was investigated 40 days after Azolla inoculation. Soil samples from the experimental plots were collected following harvest in 2014-2015, and analyzed. Moreover, rice growth, yield, and grain quality were measured. Azolla suppressed weed growth by 72%. Azolla mat incorporation in rice fields suppressed weed growth by over 60%. In addition, Azolla promoted nitrogen fixation. Compared with nitrogen management using chemical fertilizers, Azolla incorporation showed the potential for various positive effects, including the improvement of soil fertility by increasing total nitrogen, and organic matter content. Rice grown with Azolla maintained its yield without additional herbicide treatment. Moreover, the palatability of cooked rice was better when grown with Azolla.

Effect of Experimental Factors on Reduction of Nitrogen Compounds Contained in Crude Methylnaphthalene Oil by Formamide Extraction (포름아미드 추출에 의한 조제 메틸나프탈렌유에 함유된 질소화합물의 저감에 관한 실험인자의 영향)

  • Su Jin Kim
    • Applied Chemistry for Engineering
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    • v.34 no.6
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    • pp.665-669
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    • 2023
  • The crude methylnaphthalene oil (CMNO) contains nitrogen compounds (NCs) such as quinoline (QU), isoquinoline (IQU), and indole (IN). These NCs in the CMNO are treated as impurities contained in the CMNO due to contamination of the atmospheric environment and unpleasant odors. In order to improve the quality of CMNO, this study examined the effect of extraction experimental factors on the reduction of NCs contained in CMNO using CMNO as a raw material and an aqueous formamide solution as a solvent, respectively. The increase in the volume ratio of solvent to feed in initial (S/F)0 in initial increased the distribution coefficient of NCs and the selectivity of NCs in reference to 2-methylnaphthalene (2MNA). Additionally, an increase in operating temperature (T) increased the distribution coefficient of NCs but conversely decreased selectivity. The compositions of QU, IQU, and IN in the raffinate oil recovered through equilibrium extraction under a constant condition (volume fraction of water to solvent in initial (yw,0) = 0.1, (S/F)0 = 9, T = 303 K, liquid-liquid contacting time = 72 h) were reduced by about 58.5 wt%, 61.9 wt%, and 73.4 wt%, respectively, compared to those of CMNO. The formamide extraction method in this study was expected to be an effective reduction method for NCs contained in CMNO.

Identifying Degradation Causes of Endangered Freshwater Fish, Microphysogobio rapidus Using Habitat-Environmental Characteristics (멸종위기 야생생물 I급 여울마자 서식지 환경 특성 파악을 통한 훼손 원인 분석)

  • Ju-Duk Yoon;Keun-Sik Kim;Chang-Deuk Park;Dong-Won Kang;Heung-Heon Lee;Chi-Hong Lim;Nam-Shin Kim
    • Korean Journal of Ecology and Environment
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    • v.56 no.3
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    • pp.229-241
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    • 2023
  • Microphysogobio rapidus is designated as endangered species class I by Ministry of Environment, and its distribution and population have been gradually declining, and it is now limited to the Nam River and some tributary streams of the Nakdong River Watershed. For the restoration of this highly endangered species, it is important to identify the causes of the decline and establish appropriate restoration plans. However, due to lack of basic data and ecological research, most steps are stagnant. Therefore, in this study, we identified the differences in the physical, biological, and sociological habitats between current and past distributed sites through field surveys and literature reviews. As a result of the field survey, there were differences in conductivity between the current and past distributed sites, and fish communities were also showed differences. The literature data also showed that the physico-chemical values of the past distributed sites were generally unfavorable, which generated negative consequences on biological factors. In particular, the effects of urbanization were found to be a major factor affecting the habitat of M. rapidus. Habitat stabilization is crucial for the recovery of this endangered species. However, in the past distributed sites, disturbances such as stream development and weir construction have altered streams physico-chemically and result in changes of M. rapidus. Therefore, a comprehensive plan that considers both stream connectivity and water quality is needed to manage and restore the habitat of M. rapidus.