• Title/Summary/Keyword: chemical warfare

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Expression and Characterization of Escherichia coli Prolidase with Organophosphorus Compounds

  • Hong, Jin-Kyu;Park, Min-Sun;Frank M. Raushel;Khang, Yong-Ho
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.8 no.2
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    • pp.126-129
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    • 2003
  • A relatively high homology between Escherichia coli prolidase and Alteromonas organophosphorous acid anhydrolase suggests that E. coli prolidase may have an activity to d egrade toxic organophosphorous compounds. To confirm this suggestion, we cloned and expressed a prolidase gene (pepQ) of E. coliBL2l. The recombinant E. coli prolidase that consisted of 443 amino acid residues exhibited activity and stereochemical selectivity against organopho sphorous compounds, although its activity was two to three orders of magnitude less than that of the other organophosphorous acid hydrolase isolated from Pseudomonas diminuta.

Predictions of Local Circulation and Dispersion with Microscale Numerical Model (수치모의를 통한 미세규모 순환과 확산에 대한 예측)

  • 안광득;이용희;장동언;조천호
    • Journal of the Korea Institute of Military Science and Technology
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    • v.6 no.4
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    • pp.147-158
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    • 2003
  • The prediction of wind field is very important fact in the radioactive and chemical warfare. In spite of advanced numerical weather prediction modelling and computing technology, the high resolution prediction of wind field is limited by the very high integration costs. In this study we coupled the mesoscale numerical model and microscale diagnostic numerical model with minimized integration costs. This coupled model has not only the ability of prediction of high resolution wind field including complex building but also microscale pollutant diffusion fields. For military operation this system can help making a practical and cost-effective decision in a battle field.

Terrorism using biological weapons and Countermeasures (생물무기에 의한 테러와 대응책)

  • Jo, Sung-Ho
    • Korean Security Journal
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    • no.7
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    • pp.287-307
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    • 2004
  • Mass killing and injuring by purpose, the countries that is hurrying countermeasure preparation of investigators who enforce that necessity to compare to intimidation of doing creature weapon is common concerns of the several countries including advanced nation such as the United States of America. Development and use of biological weapon have increased too recently to private citizens unlike development of military purpose in country dimension. The latest WHO is preparing proposal of standard stroke model who each department solidifies preparedness for chemical biological and electronic weapon revising report about biological weapon. But in case of korea, confrontation plan that bamboo broom about possibility of attack to the common people and attack comparing actual state in case of attained nothing but is readying remedy about biological warfare partially in military dimension was not readied. The purpose of this article is a study on threat of bio-weapons and the countermeasure.

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Study on the analytical method using GC-MS for the accident preparedness substances (실험실 GC-MS를 이용한 사고대비물질 분석방법 연구)

  • Kim, Kijoon;Lee, Jinseon;Lee, Suyeong;Hwang, Seungryul;Kim, Younghee;Seok, Gwangseol
    • Analytical Science and Technology
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    • v.26 no.1
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    • pp.80-85
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    • 2013
  • The sixty nine accident preparedness substances (APS) having high probability of chemical accident are controlled under the Toxic Chemicals Control Act (TCCA). Around the world, there has been a growing interest in the analysis of chemical warfare agent (CWAs). When a chemical accident occurs, it is generally required to detect and identify APS. However, the quantitative analytical data remain limited in Korea. In this study, an analytical method using GC/MS for volatile organic chemicals was established and a quantitative analysis method was studied. The calibration curve for 25 chemicals were obtained and 21 chemicals showed higher coefficient of determination ($r^2$ >0.998).

Analysis of a Gas Mask Using CFD Simulation (CFD모사기법을 이용한 가스 여과기 성능 해석)

  • Jeon, Rakyoung;Kwon, Kihyun;Yoon, Soonmin;Park, Myungkyu;Lee, Changha;Oh, Min
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.475-483
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    • 2019
  • Special chemical warfare agents are lethal gases that attack the human respiratory system. One of such gases are blood agents that react with the irons present in the electron transfer system of the human body. This reaction stops internal respiration and eventually causes death. The molecular sizes of these agents are smaller than the pores of an activated carbon, making chemical adsorption the only alternative method for removing them. In this study, we carried out a Computational Fluid Dynamics simulation by passing a blood agent: cyanogen chloride gas through an SG-1 gas mask canister developed by SG Safety Corporation. The adsorption bed consisted of a Silver-Zinc-Molybdenum-Triethylenediamine activated carbon impregnated with copper, silver, zinc and molybdenum ions. The kinetic analysis of the chemical adsorption was performed in accordance with the test procedure for the gas mask canister and was validated by the kinetic data obtained from experimental results. We predicted the dynamic behaviors of the main variables such as the pressure drop inside the canister and the amount of gas adsorbed by chemisorption. By using a granular packed bed instead of the Ergun equation that is used to model porous materials in Computational Fluid Dynamics, applicable results of the activated carbon were obtained. Dynamic simulations and flow analyses of the chemical adsorption with varying gas flow rates were also executed.

Detection of Blood Agent Gas Using $SnO_2$ Thin Film Gas Sensor

  • Choi, Nak-Jin;Kwak, Jun-Hyuk;Lim, Yeon-Tae;Joo, Byung-Su;Lee, Duk-Dong;Bahn, Tae-Hyun
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.E2
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    • pp.69-75
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    • 2004
  • In this study, thin film gas sensor based on tin oxide was fabricated to examine its characteristics. Target gas is acetonitrile ($CH_3$CN) which is a blood simulant for the chemical warfare agent. Sensing materials are SnO$_2$ SnO$_2$/Pt, and Sn/Pt with thickness from 1000 to 3000 $\AA$. The sensor consists of a sensing electrode with inter-digit (IDT) type in front side and a heater in rear side. Resistance changes of sensing materials are monitored on real time basis using a data acquisition board with a 12-bit analog to digital converter. Sensitivities are measured at different operating temperatures also with different gas concentrations and film thickness. The high sensitivity is obtained for Sn (3000 $\AA$)/Pt (30 $\AA$) at 30$0^{\circ}C$ for 3 ppm. Response and recovery times were about 40 and 160 s, respectively. Repetition measurements showed very good results with $\pm$3% in full scale range.

The Vietnam War and the Reception of Ecocide Consciousness (베트남전쟁과 에코사이드 의식의 수용)

  • Kim, Ilgu
    • English & American cultural studies
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    • v.18 no.4
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    • pp.1-31
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    • 2018
  • It is needless to say that America's indiscriminate artillery and chemical attacks have worsened the conditions of Vietnam's tropical rain forests, causing war-torn combat troops and civilians to suffer more from the participation and aftermath of the Vietnam war. Around two decades after the Vietnam War, American and Vietnamese writers dealing with the destruction of the human and nature of the Vietnam War and the following traumatic experience commonly report the horrors of inhumane warfare, but some differences among them appear in the reception of the ecocide consciousness. For American writers who had been involuntarily involved or who had stayed in the back area as interpreters and counter-intelligence force, the Vietnam War was often a kind of exotic "addicted adventure" which their American hometown could not provide. But apart from overcoming postwar post-traumatic stress by writing of healing which was shared with American war writers, Vietnamese writers have been able to overcome the scars of war as the communal memorial, which Jonathan Shay emphasized as the necessary comforting ritual by community members showing the sign of honor and care. On the other hand, American war writers were on the side of "separate peace," as Jeong stressed, and the Vietnam War to them was more racist like the case of "body count." Nevertheless, it is fortunate that the hideous experience of war could turn them all into the creativity pool, just as the 5,000 square mile of bomb creators have been used as the postwar fish ponds.

Recent Trend in Catalysis for Degradation of Toxic Organophosphorus Compounds (유기인 계열 독성화합물 분해를 위한 촉매반응의 최신 연구 동향)

  • Kye, Young-Sik;Jeong, Keunhong;Kim, Dongwook
    • Applied Chemistry for Engineering
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    • v.30 no.5
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    • pp.513-522
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    • 2019
  • Catalysts based on organic compounds, transition metal and metal-organic frameworks (MOFs) have been applied to degrade or remove organophosphorus toxic compounds (OPs). During the last 20 years, various MOFs were designed and synthesized to suit application purposes. MOFs with $Zr_6$ based metal node and organic linker were widely used as catalysts due to their tunability for the pore size, porosity, surface area, Lewis acidic sites, and thermal stability. In this review, effect on catalytic efficiency between MOFs properties according to the structure, stability, particle size, number of connected-ligand, organic functional group, and so on will be discussed.

Evaluation on South and North Korean Military Power by Military Officers (남북 군사력 우열에 대한 군간부들의 인식 평가)

  • Lee Sang-Jin
    • Survey Research
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    • v.7 no.1
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    • pp.29-53
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    • 2006
  • This paper analyzes which of the military sub-fields has an effect on a soldier's evaluation of South and North Korean military power. There are three objectives of this paper. First, it is to analyze whether the South is superior to the North in the overall military power and military sub -fields, without the presence of the US armed forces in South Korea. Second, it is to assess which of the military sub-fields influences the overall evaluation of military power through a regression analysis. Finally, it is to look at whether the professional soldiers have a motivational bias, due to an argument that the military personnel tend to exaggerate the inferiority of their own military power to get more budget for defense construction. Research in 2002 and 2003 tell us that South Korean military power is slightly inferior to North Korea's. However, research in 2005 shows that military power of South and North Korea is almost equal. The sub-fields in which South Korea is superior are in the order of War Sustainability, Information Warfare, Air Force, and Navy. North Korea is regarded to be superior in the fields of Atomic Biological Chemical Warfare Capability, Special Force, Reserve Mobilization, and Army. The higher ranked soldiers tend to evaluate that the North is superior to the South.

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Chemical/Biological/Radiological Protective Facility Entering Time Estimation Simulation with Procedure Analysis (화생방 방호시설의 행동 절차 분석을 통한 진입 소요시간 예측 시뮬레이션)

  • Park, Sun Ho;Lee, Hyun-Soo;Park, Moonseo;Kim, Sooyoung
    • Korean Journal of Construction Engineering and Management
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    • v.15 no.5
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    • pp.40-48
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    • 2014
  • As CBR(Chemical, Biological, and Radiological) attack increases, the importance of CBR protective facilities is being emphasized. When CBR warfare emerges, a task force team, who exist outside of CBR protective facility, should enter the CBR protective facility through neutralizing process in CCA(Contamination Control Area) and TFA(Toxic Free Area). If a bottleneck occurs in the process or zones, the task force team cannot enter the CBR protective facility efficiently and may cause inefficiency in its operation performance or result in casualties. The current design criteria of the CBR protective facility is only limited to ventilation system and it does not consider how much time it takes to enter the facility. Therefore, this research aims to propose the entering time estimation model with discrete event simulation. To make the simulation model, the procedure performed through CCA and TFA is defined and segmented. The actual time of the procedure are measured and adapted for the simulation model. After running the simulation model, variables effecting the entering time are selected for alternatives with adjustments. This entering time estimation model for CBR protective facility is expected to help take time into consideration during the designing phase of CBR protective facility and help CBR protective facility managers to plan facility operation in a more realistic approach.