• Korean Journal of Fisheries and Aquatic Sciences
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• v.11 no.2
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• pp.55-64
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• 1978

The present investigations were carried out for the purpose of making clear the fundamental features of the seasonal variations in carrageenan content and its chemical composition. The samples, Chondrus ocellatus, were collected every month from the same locality on the coast of Haewundae from March, 1975 to February, 1976, and analyzed monthly to determine their carrageenan content, sulphate and 3,6-anhydro-D-galactose over a year period. En addition, some chemical characteristics were also tested on the fractions separated by the different concentrations of potassium chloride. In seasonal variation, the maximum carrageenan content occurred from summer through autumn, and the minimum in winter, especially in February. It is noted in the seasonal variations of the sulphate content of total carrageenan and three fractions that the maximums appreared in October and minimums in february. With seasonal variations of percent 3,6-anhydro-D-galactose of total carrageenan and three fractions, maximum values occur in June and minimum values in December. Seasonal variations in sulphate and 3,6-anhydro-D-galactose contents of the three fractions were on the whole similar in mode of variation, and there could be no substancial differences. Seeing seasonal variations in the sulphate and 3,6-anhydro-D-galactose contents of three fractions, carrageenan extracted from the algae gathered in spring shelved higher portion of fraction I than that gathered in autumn. In these respects, it seems that a more weakly gelling k-carrageenan exists in the spring than in the autumn.

• Magazine of the Korea Concrete Institute
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• v.10 no.4
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• pp.205-212
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• 1998

Frost damage of a storage tank for chemical admixtures caused by a low temperature in winter and quality deterioration of chemical admixtures have been often reported. However, there have been few regulations and researches related to the frost damage of chemical admixtures and facilities. Therefore, this paper is intend to investigate not only, the freezing points of chemical admixtures such as AE admixtures and water-reducing AE admixtures, etc., but also the quality variation of concrete used with chemical admixtures before freezing and after freeze-thaw cycles. According to the results of experiments, most chemical admixtures except anti-freezing agent and accelerating water-reducing AE admixtures should be kept from being frozen in low winter temperatures. However, full agitation of frozen chemical admixtures dose not cause the problems of concrete related to the quality of chemical admixtures.

• Economic and Environmental Geology
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• v.27 no.1
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• pp.1-9
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• 1994

The Kyungju pyrophyllite deposits were formed by the hydrothermal alteration of andesitic rocks, which were intruded by Cretaceous granite mass. The major minerals are pyrophyllite, kaolinite and chlorite. The deposits may be zoned outward into pyrophyllite zone, silicified pyrophyllite zone and weakly altered zone (propyrilite zone) according to mineral assemblages. Chemical compositions vary in close relation with the mineralogical assemblages: $Al_2O_3$ content is high due to pyrophyllitization at the deposits and altered zones in comparison to andesitic country rocks, while the contents of $Na_2O$, CaO and MgO are generally low due to leaching during the alteration. This variation of chemical elements may be applicable in the geochemical exploration of pyrophyllite deposits.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.436-438
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• 2009

To evaluate short rotation forestry candidates, seven clones of Salix hultenii were investigated as focused on chemical compositions and energy contents. There were significant variations in chemical compositions and energy contents among different clones. Variations in hot-water extractives content were 6.6-16.0% and 19.6-25.4% variation in lignin content. In carbohydrate compositional analysis, xylan contents were 7.5-13.1% with variation among different clones. Higher heating values were 17.69-20.02 MJ/kg.

• Transactions on Electrical and Electronic Materials
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• v.3 no.4
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• pp.5-9
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• 2002

Chemical mechanical polishing (CMP) has become the preferred planarization method for multilevel interconnect technology due to its ability to achieve a high degree of feature level planarity. Especially, to achieve the higher density and greater performance, shallow trench isolation (STI)-CMP process has been attracted attention for multilevel interconnection as an essential isolation technology. Also, it was possible to apply the direct STI-CMP process without reverse moat etch step using high selectivity slurry (HSS). In this work, we determined the process margin with optimized process conditions to apply HSS STI-CMP process. Then, we evaluated the reliability and reproducibility of STI-CMP process through the optimal process conditions. The wafer-to-wafer thickness variation and day-by-day reproducibility of STI-CMP process after repeatable tests were investigated. Our experimental results show, quite acceptable and reproducible CMP results with a wafer-to-wafer thickness variation within 400$\AA$.

• Journal of Environmental Science International
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• v.8 no.2
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• pp.189-195
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• 1999

Determining factors and temporal & spatial characteristics of COD(Chemical Oxygen Demand) at the sea surface in Jinhae bay have been examined by using seasonal data, taken at twenty six stations over the whole bay during 1989~1994 by NERDA. The data have been analyzed in terms of long term means, anomalously large values. Jinhae bay is divided into three regions based on the time mean : mouth of Jinhae bay, inner sea of Masan bay, western sea of Jinhae bay called region 1,2 and 3, respectively. The horizontal distribution of the long term mean of COD at each station is similar to those of nitrogen and phosphorus. Characteristics of whole mean variation in the year shows high range of variation in region 2. It was appear to decreases every year in whole trend. Factors determining seasonal variation in whole COD mean are relative to salinity and nutrient, affected by precipitation in summer. Spatial variation shows high range of fluctuation in region 2 compare to other region. Factors determining of spatial variation of COD was appear to nutrient, affected by pollutant load of land area and bottom sediment. The long term mean of COD at each station is closely related with thats of nutrients. The correlation coefficient between COD and nitrogen, phosphate phosphorus was found to be high as 0.75, 0.78, respectively. Anomalously large COD was observed 14 times at 6 stations. These stations are located in inner sea of Masan bay(Region 2) and Songjeong bay(Region 1). The seasonal frequency of the observed anomalous COD is large in April, and other seasons are much the same.

• Korean Chemical Engineering Research
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• v.47 no.4
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• pp.459-464
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• 2009

Gas-liquid mass transfer characteristics were investigated in pressurized three-phase slurry bubble columns with variation of column diameter. Effects of gas velocity, operating pressure, liquid viscosity, solid content in the slurry phase and column diameter on the gas-liquid volumetric mass transfer coefficient($k_La$) were determined. The effects of operating variables on the mass transfer coefficient tended to change with variation of column diameter. The mass transfer coefficient increased with increasing gas velocity or operating pressure but decreased with increasing column diameter, liquid viscosity or solid concentration in the slurry phase. The increase trend of $k_La$ value with increasing gas velocity and the decrease trend of $k_La$ value with increasing liquid viscosity, tended to decrease gradually with increasing column diameter. However, the effects of operating pressure and solid concentration in the slurry phase on the $k_La$ value did not change considerably with variation of column diameter. The values of $k_La$ were well correlated with operating variables with in this experimental conditions as $k_La=0.02D^{-0.26}U_G^{0.28}P^{0.43}{\mu}_L^{-0.04}S_c^{-0.35}$.

• Journal of Biomedical Engineering Research
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• v.31 no.5
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• pp.412-416
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• 2010

In this study, we measured the chemical shift change of metabolite peaks in the brain-metabolite phantom according to the temperature variation using nuclear magnetic resonance(NMR). The temperature range in NMR system was controled from 25 to 80 (5 step) by internal temperature controller. Temperature coefficients of each metabolite peaks were also calculated from the measured chemical shift depending on the temperature. The chemical shift changes depending on temperature were validated by linear regression method for each metabolite peaks. The temperature coefficients of $_{tot}Cr$, Cho, Cr, NAA, and Lac were 0.0086, 0.0088, 0.0091, 0.0089, and 0.0088ppm/$^{\circ}C$, respectively. This study shows that chemical shift change of brain metabolite and temperature variation have linear relationship each other. This also makes authors believe that brain temperature measurement is possible using MR spectroscopic imaging technique.

• Macromolecular Research
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• v.12 no.5
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• pp.519-527
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• 2004

Stable poly(methyl methacrylate-co-divinylbenzene) (poly(MMA-co-DVB)) microspheres were prepared by precipitation polymerization using acetonitrile as the main medium under various polymerization conditions, including modifications of the agitation speed, monomer and initiator concentrations, DVB content in the monomer mixture, and the use of various cosolvents. Gentle agitation was required to obtain smooth spherical particles. The individually stable microspheres were obtained at monomer concentrations of up to 15 vol% in an acetonitrile medium. The number-average diameter increased linearly with respect to increases in the monomer and initiator concentrations. We found, however, that the uniformity of the microspheres was independent of the variation of the polymerization ingredients because nuclei formation was solely influenced by the crosslinking reaction of the monomers. We obtained higher yields for the polymerization at higher concentrations of monomer and initiator. The concentration of DVB in the monomer mixture composition played an important role in determining not only the size of the microspheres but also the yield of the polymerization. In addition, although we employed various cosolvents as the polymerization medium, we found that acetonitrile/2-methoxyethanol was the only system that provided spherical particles without coagulation. This finding indicates that the precipitation polymerization is strongly dependent on the solvent used as the medium.

• Bulletin of the Korean Chemical Society
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• v.32 no.10
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• pp.3730-3734
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• 2011

The degree of self-assembly and the size variation of nanotubular structures in anodic titanium oxide prepared by the anodization of titanium in ethylene glycol containing 0.25 wt % $NH_4F$ at 40 V were investigated as a function of anodization time. We found that the degree of self-assembly and the size of the nanotubes were strongly dependent on thickness deviation and thus indirectly on anodization time, as the thickness deviation was caused by the dissolution of the topmost tubular structures at local areas during long anodization. A large deviation in thickness led to a large deviation in the size and number of nanotubes per unit area. The dissolution primarily occurred at the bottoms of the nanotubes ($D_{bottom}$) in the initial stage of anodization (up to 6 h), which led to the growth of nanotubes. Dissolution at the tops ($D_{top}$) was accompanied by $D_{bottom}$ after the formed structures contacted the electrolyte after 12 h, generating the thickness deviation. After extremely long anodization (here, 70 h), $D_{top}$ was the dominant mode due to increase in pH, meaning that there was insufficient driving force to overcome the size distribution of nanotubes at the bottom. Thus, the nanotube array became disorder in this regime.