• Title/Summary/Keyword: chemical testing

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The Inhibitor Effect of (E)-5-[(4-(benzyl(methyl)amino)phenyl)diazenyl]-1,4-dimethyl-1H-1,2,4-triazol-4-ium zinc(II) Chloride, an Industrial Cationic Azo Dye, onto Reducing Acidic Corrosion Rate of Mild Steel

  • Ozkir, Demet;Kayakirilmaz, Kadriye
    • Journal of Electrochemical Science and Technology
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    • v.11 no.3
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    • pp.257-272
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    • 2020
  • This study covers the stages of testing whether the azo dye with chemical name (E)-5-[(4-(benzyl(methyl)amino)phenyl)diazenyl]-1,4-dimethyl-1H-1,2,4-triazol-4-ium zinc (II) chloride (DMT), known as Maxilon Red GRL in the dye industry, can be used as an anticorrosive feasible inhibitory agent, especially in industrial areas other than carpet, yarn and fibre dyeing. These test stages consist of the electrochemical measurement techniques such as potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and linear polarization resistance (LPR) for diverse concentrations and durations. The adsorption of the viewed DMT molecule on the mild steel surface obeyed the Langmuir isotherm. The zero charge potential (PZC) of mild steel was also found to assess the inhibition mechanism in containing DMT solution. The inhibition performance of DMT on the mild steel in a 1.0 M HCl solution was also investigated using methods such as metal microscope, atomic force microscope (AFM) and field emission scanning electron microscope (FE-SEM).

Development of Pilot-Scale Scrubber for Simultaneous Removal of $SO_2/NO$

  • Jung, Seung-Ho;Jeong, Gwi-Taek;Lee, Gwang-Yeon;Park, Don-Hee;Cha, Jin-Myeong
    • 한국생물공학회:학술대회논문집
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    • 2005.10a
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    • pp.468-474
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    • 2005
  • SOx and NOx are known major precursors of acid rain and thus the abatement of their emissions is a major target in air pollution control. To obtain basic data on the removal process of simultaneous $SO_2/NO$, the optimal reaction condition and the composition of reaction solution for simultaneous removal of $SO_2/NO$, ware investigated using a bubble column reactor. Pilot scrubber was consisted of scrubber, filter and control box. Dust removal rate was 83, 92, and 97% with catalyst flux of 0.5, 0.8, 1.5 L/min, respectively Average dust removal efficiency with a kind of nozzle was about 94 and 90% in STS FF6.5 (5/8in.) and 14 of P.P W(1.0in.), respectively Dust and $SO_2$ were removed more than 98-96% regardless of reactor number. In the case of NO gas, removal yield of 83.3% was achieved after 48 hours in 1 stage, also removal yield of 95.7% was reached in 2 stages. In tile case of application of STS (5/8 in.) and P.P (1.0 in.) as used fill packing, removal efficiency was reached higher than 98% without related to of kind of fill packing.

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Specimen Geometry Effects on Oxidation Behavior of Nuclear Graphite

  • Cho, Kwang-Youn;Kim, Kyung-Ja;Lim, Yun-Soo;Chung, Yun-Joong;Chi, Se-Hwan
    • Carbon letters
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    • v.7 no.3
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    • pp.196-200
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    • 2006
  • Graphite has hexagonal closed packing structure with two bonding characteristics of van der Waals bonding between the carbon layers at c axis, and covalent bonding in the carbon layer at a and b axis. Graphite has high tolerant to the extreme conditions of high temperature and neutron irradiations rather than any other materials of metals and ceramics. However, carbon elements easily react with oxygen at as low as 400C. Considering the increasing production of today of hydrogen and electricity with a nuclear reactor, study of oxidation characteristics of graphite is very important, and essential for the life evaluation and design of the nuclear reactor. Since the oxidation behaviors of graphite are dependent on the shapes of testing specimen, critical care is required for evaluation of nuclear reactor graphite materials. In this work, oxidation rate and amounts of the isotropic graphite (IG-110, Toyo Carbon), currently being used for the Koran nuclear reactor, are investigated at various temperature. Oxidation process or principle of graphite was figured out by measuring the oxidation rate, and relation between oxidation rate and sample shape are understood. In the oxidation process, shape effect of volume, surface area, and surface to volume ratio are investigated at $600^{\circ}C$, based on the sample of ASTM C 1179-91.

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Identification of Differentially Expressed Genes in Human Mesenchymal Stem Cell-Derived Neurons

  • Heo, Ji-Hye;Cho, Kyung-Jin;Choi, Dal-Woong;Kim, Suhng-Wook
    • Toxicological Research
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    • v.26 no.1
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    • pp.15-19
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    • 2010
  • Mesenchymal stem cells (MSCs) have greater potential for immediate clinical and toxicological applications, due to their ability to self-renew, proliferate, and differentiate into a variety of cell types. To identify novel candidate genes that were specifically expressed during transdifferentiation of human MSCs to neuronal cells, we performed a differential expression analysis with random priming approach using annealing control primer-based differential display reverse transcription-polymerase chain reaction approach. We identified genes for acyl-CoA thioesterase, tissue inhibitor of metalloproteinases-1, brain glycogen phosphorylase, ubiquitin C-terminal hydrolase and aldehyde reductase were up-regualted, whereas genes for transgelin and heparan sulfate proteoglycan were down-regulated in MSC-derived neurons. These differentially expressed genes may have potential role in regulation of neurogenesis. This study could be applied to environmental toxicology in the field of testing the toxicity of a chemical or a physical agent.

Synthesis of Bimodally Porous γ-Alumina Granules by Sol-Gel/Oil-Drop Method (솔-젤/Oil-Drop법을 이용한 이중 다공성 γ-알루미나 그래뉼의 제조)

  • Choi, Junseo;Kim, Jinsoo;Lee, Tai-Gye
    • Applied Chemistry for Engineering
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    • v.18 no.2
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    • pp.111-115
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    • 2007
  • Bimodally porous ${\gamma}$-alumina granules, including mesopores (2~50 nm) and macropores (>50 nm), were prepared by sol-gel and oil-drop method. Mesopores are made from the voids among the alumina crystallites, while macropores are from the space of the decomposed PS particles used as physical templates during the granulation process. The product ${\gamma}$-alumina granules with the average diameter of 2 mm were characterized by FE-SEM, XRD, FT-IR, $N_2$ porosimetry, and universal mechanical testing system.

Model for simulating the effects of particle size distribution on the hydration process of cement

  • Chen, Changjiu;An, Xuehui
    • Computers and Concrete
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    • v.9 no.3
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    • pp.179-193
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    • 2012
  • The hydration of cement contributes to the performance characteristics of concrete, such as strength and durability. In order to improve the utilization efficiency of cement and its early properties, the particle size distribution (PSD) of cement varies considerably, and the effects of the particle size distribution of cement on the hydration process should be considered. In order to evaluate effects of PSD separately, experiments testing the isothermal heat generated during the hydration of cements with different particle size distributions but the same chemical composition have been carried out. The measurable hydration depth for cement hydration was proposed and deduced based on the experimental results, and a PSD hydration model was developed in this paper for simulating the effects of particle size distribution on the hydration process of cement. First, a reference hydration rate was derived from the isothermal heat generated by the hydration of ordinary Portland cement. Then, the model was extended to take into account the effect of water-to-cement ratio, hereinafter which was referred to as PSD hydration model. Finally, the PSD hydration model was applied to simulate experiments measuring the isothermal heat generated by the hydration of cement with different particle size distributions at different water-to-cement ratios. This showed that the PSD hydration model had simulated the effects of particle size distribution and water-to-cement ratio on the hydration process of cement with satisfactory accuracy.

Effect of Welding Processes on Corrosion Resistance of UNS S31803 Duplex Stainless Steel

  • Chiu, Liu-Ho;Hsieh, Wen-Chin
    • Corrosion Science and Technology
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    • v.2 no.1
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    • pp.36-40
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    • 2003
  • An attractive combination of corrosion resistance and mechanical properties in the temperature range -50 to $250^{\circ}C$ is offered by duplex stainless steel. However, undesirable secondary precipitation phase such as $\sigma$, $\gamma_2$ and $Cr_2N$ may taken place at the cooling stage from the welding processes. Therefore, this paper describes the influence of different welding procedures such as manual metal arc welding (MMA), tungsten inert gas welding (TIG) and vacuum brazing on corrosion resistance of the welded joint for UNS S31803 duplex stainless steel. Microstructure and chemical compositions of the welded joint were examined. The weight loss of specimens immersed in 6% $FeCl_3$ solution at $47.5^{\circ}C$ for 24-hours was determined and used to evaluate the pitting resistance of duplex stainless steel and their welds. The region of heat-affected zone of specimen obtained by the MMA is much wider than that resulted from TIG, therefore, the weight loss of welds by MMA was larger than that of weld by TIG. The weight loss of brazed specimens cooled from slow cooling rate was larger than those of specimens cooled from high cooling rate, because the precipitation of $\sigma$ phase. Beside that, the weight loss of brazed specimen is greater than those of the welded specimens. The galvanic corrosion was observed in brazed duplex stainless steel joints in the chloride solution.

Reliability Tests for BLDC Motors Used in Green-Cars (그린카 BLDC 모터의 신뢰성 시험)

  • Yoo, Ki-Hoon;Park, Boo-Hee;Kim, Ki-Tae;Kim, Gi-Young;Kim, Dal-Seok;Jang, Joong-Soon;Hahn, Chang-Su;Cho, Han-Sam
    • Journal of Applied Reliability
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    • v.11 no.1
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    • pp.97-110
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    • 2011
  • BLDC(Brushless Direct Current) motor is a powerful device to control the automotive electronic components used in green cars such as HEV/EVs(Hybrid Electric Vehicle and Electric Vehicle). This study is to propose reliability test items derived through pretesting, suitability analysis abd classification of previous BLDC motor tests. For environmental stress tests are determined by analysing environmental conditions and relevant failure mechanisms induced by climate loads, mechanical loads, chemical loads, etc. ATL and HALT are also considered for life testing and screening.

Technical and Political Approaches for Successful Settling of the Environmental Agriculture System in Korea (한국 환경농업의 성공적 정착을 위한 정책적 및 기술적 접근과제)

  • 손상목;정길생
    • Korean Journal of Organic Agriculture
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    • v.5 no.2
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    • pp.13-36
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    • 1997
  • This study aims to point out the basic strategy of agrotechnical and -political approaches toward successful settling for the environmental agriculture system in Korea. Although environmental agriculture & forestry strategy toward the 21st century and it's action program were released in 1996, some scientist from environmental agriculture and organic agriculture still argue on the errors of it's strategy and action program in terms of environmental sound functions. Especially it's strategy and action program of government did not focus the reduction of fertilizer and pesticide as the matters of weight and importance to reduction of fertilizer and pesticide as the matters of weight and importance to realize an environmental sound agriculture system. And korean organic agriculture gets a point in dispute, because 1) they do not practice of Basic Standard of IFOAM and FAO/WHO Codex draft, and 2) organic farming is defined quite differently from internationally recognized core aspects of organic agriculture. Organic farming, in Korea, is taken to mean the replacement of chemical fertilizer by organic manure and avoidance of agricultural chemicals. In the paper it is discussed the necessity, purpose, effect and consequence of basic standard for korean organic agriculture. The reformation of the certification system and t he direct payment system in environmental agriculture & forestry strategy toward the 21st century and it's action program by government, and on the need of the teaching program and curriculum in high education institution, the breeding program of resistant cultivars, the soil testing for optimum fertilization strategy, the nutrient management program, the declaration for 2020 environemntal agriculture are also discussed.

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비정질 탄소막 (a-C:H) 내에 존재하는 수소에 관한 연구

  • 박노길;박형국;손영호;정재인
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.133-133
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    • 1999
  • 비정질 탄소막 제조에 있어서 수소가 포함된 반응성 가스를 사용할 경우 제작된 탄소막 내부에는 수소가 포함되게 되며, 이러한 수소원자들은 막의 특성에 중요한 영향을 주는 것으로 알려져 있다. 따라서, 본 연구에서는 비정질 탄소막(a-C:H) 내부에 존재하는 수소가 탄소막의 특성에 미치는 영향을 알아보고, 막 내부에 포함된 수소의 함량과 공정조건 사이의 함수계를 조사함으로써 수소의 함량을 인위적으로 통제할 수 있는 가능성을 제시하고자 한다. 수소가 포함된 비정질 탄소막은 2.45 GHz의 전자기파를 사용하는 electron cyclotron resonance plasma enhanced chemical vapor deposition (ECR-PECVD) 방법과 DC magnetron sputtering 법을 사용하여 제작하였다. 기판으로는 Si(001) wafer를 사용하였으며, 아세톤과 에탄올을 사용하여 표면의 유기성분을 제거하고, 진공챔버속에서 Ar 플라즈마를 발생시켜 sputter etching 방법으로 표면을 세척하였다. ECR-PECVD 방법에서는 반응가스로 메탄(CH4)과 수소(H2)의 혼합가스를 사용하였으며, 혼합가스의 비는 5~50% 범위내에서 변화를 주었다. 수소가스의 유량은 100SCCM으로 고정하였으며, 마이크로웨이브의 power는 360~900W였고, 기판에 가해준 negative DC bias 전압은 0~-500V이었다. DC magnetron sputtering 방법에서는 반응가스로 아세틸린(C2H2) 가스를 사용하였으며, 플라즈마 발생을 용이하게 하기 위해서 Ar 가스와 혼합하여 사용하였다. Ar 가스의 유량은 10SCCM으로 고정하였으며, 아세틸렌 가스의 유량은 5~20SCCM 범위내에서 주입하였다. 이때, 기판에 가해준 negative DC bias 전압은 0~-100V이었다. 제작된 탄소막의 수소 함량을 조사하기 위하여 Fourier Transform Infrared (FTIR) 분광법과 Elastic Recoil Detection Analysis (EFDA) 법을 사용하였으며, 증착율은 SEM 단면촬영과 a-step을 이용하여 측정하였고, 막의 경도는 Micro-Hardness Testing 법을 사용하여 측정하였다.

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