• Title/Summary/Keyword: chemical testing

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Evaluation on the Lightning Breakdown Voltages of Palm Oil and Coconut Oil under Non-Uniform Field at Small Gap Distances

  • Thien, Yee Von;Azis, Norhafiz;Jasni, Jasronita;Kadir, Mohd Zainal Abidin Ab;Yunus, Robiah;Ishak, Mohd Taufiq;Yaakub, Zaini
    • Journal of Electrical Engineering and Technology
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    • v.11 no.1
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    • pp.184-191
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    • 2016
  • In recent years, there are a number of studies that have been carried out to explore the alternative for Mineral Oil (MO) as dielectric insulating fluid in transformers due to the increasing tight regulation on safety and environment. Vegetable oils have been identified as suitable candidate since it is biodegradable, non-toxic and high flash/fire points which ensure more in-service safety. Among the types of vegetable oils considered for transformers application are Palm Oil (PO) and Coconut Oil (CO). This paper presents an experimental study on the lightning breakdown voltages of PO and CO under non-uniform electric field based on needle-sphere electrodes configuration at 3 small gap distances. The type of PO used in this study is Refined Bleached and Deodorized Palm Oil (RBDPO) Olein. The main focus of this study is to examine the lightning breakdown performance of RBDPO and CO under different test conditions and assess its suitability as dielectric insulating fluid in transformers. The effect of voltage polarities (positive and negative) and testing methods (rising-voltage, up-and-down and multiple-voltage) were investigated. The data obtained from all tests were analysed by Weibull distribution in order to determine the withstand voltages for each type of oils. It was found that the breakdown voltages of RBDPO and CO are comparable with MO under positive lightning impulse. Under negative lightning impulse, the breakdown voltage of MO is slightly higher than RBDPO and CO. There is no significant effect of testing methods and voltage polarities on lightning breakdown voltages of RBDPO and CO. Based on the statistical analysis, it is found that the breakdown voltages of RBDPO and CO at 1% probability are slightly lower than MO.

Ultrasonic Nonlinearity of AISI316 Austenitic Steel Subjected to Long-Term Isothermal Aging (장시간 등온열화된 AISI316 오스테나이트강의 초음파 비선형성)

  • Gong, Won-Sik;Kim, ChungSeok
    • Journal of the Korean Society for Nondestructive Testing
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    • v.34 no.3
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    • pp.241-247
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    • 2014
  • This study presents the ultrasonic nonlinearity of AISI316 austenitic stainless steels subjected to longterm isothermal aging. These steels are attractive materials for use in industrial mechanical structures because of their strength at high-temperatures and their chemical stability. The test materials were subjected to accelerated heat-treatment in an electrical furnace for a predetermined aging duration. The variations in the ultrasonic nonlinearity and microstructural damage were carefully evaluated through observation of the microstructure. The ultrasonic nonlinearity stiffly dropped after aging for up to 1000 h and, then, monotonously decreased. The polygonal shape of the initial grain structures changed to circular, especially as the annealing twins in the grains dissolved and disappeared. The delta ferrite on the grain boundaries could not be observed at 1000 h of aging, and these continuously transformed into their sigma phases. Consequently, in the intial aging period, the rapid decrease in the ultrasonic nonlinearity was caused by voids, dislocations, and twin annihilation. The continuous monotonic decrease in the ultrasonic nonlinearity after the first drop resulted from the generation of $Cr_{23}C_6$ precipitates and ${\sigma}$ phases.

A Study on Subchronic Inhalation Toxicity of 2-Methylpentane (2-Methylpentane 아만성 흡입독성 연구)

  • Chung, Yong Hyun;Lim, Cheol Hong;Han, Jeong Hee
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.2
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    • pp.169-181
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    • 2014
  • Objectives: The purpose of this study was to obtain information regarding classification and health hazards that may result from a 13-week inhalation exposure to 2-methylpentane by Sprague-Dawley rats. Materials: The testing method was conducted in accordance with OECD guidelines for the testing of chemicals No. 413. The rats were divided into four groups(ten male and ten female rats in each group) and exposed to 0 ppm, 290 ppm, 1,160 ppm, 4,640 ppm 2-Methylpentane in each exposure chamber for six hours per day, five days per week, for 13 weeks. Results: No death or particular clinical presentation including weight change and change of feed rate was observed. The relationships between dose, gender and response were also not significantly changed in urinalysis, hematologic examination, or biochemical examination of blood(except for total cholesterol being up, total protein being up, and chloride ion being down in males), and blood coagulation time. For the relative weight measurement of organs, in the male group the weight change of both kidney and liver were increased in proportion to dose. In histopathological examination, nephropathy in the kidney(cystic change of renal tubules, regenerative tubule, inflammatory cell infiltration and necrosis in the interstitial tissue) was increased in a dose-dependent manner in the male group(290 ppm, 1,160 ppm, 4,640 ppm). However, other organs were not affected by the test substance. Conclusions: 2-methylpentane was estimated as a chemical causing nephropathy in the male group. NOAEL(No Observable Adverse Effect Level) in the female group is more than 4,640 ppm, while inthe male group it is less than 290 ppm.

CB6F1-Tg rasH2 Mouse Carrying Human Prototype c-Ha-ras Gene As an Alternative Model For Carcinogenicity Testing For Pharmaceuticals

  • Usui, T.;Urano, K.;Suzuki, S.;Hioki, K.;Maruyama, Ch.;Tomisawa, M.;Ohnishi, Y.;Suemizu, H.;Yamamoto, S.
    • Toxicological Research
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    • v.17
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    • pp.293-297
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    • 2001
  • The international pharmaceutical and regulatory communities had been recognizing the limited utility of conventional rodent carcinogenicity study particularly on the second species, mouse, after intense investigation of carcinogenicity data base worldwide, and a new scheme for carcinogenicity testing for pharmaceuticals was proposed at the Expert Working Group on Safety in the International Conference on Harmonization (ICH) in 1996. CB6F 1-Tg rasH2 mouse carrying human prototype c-Ha-ras gene with its own promoter/enhancer is one oj the new carcinogenicity assay model for human cancer risk assessment. Studies have been conducted since 1992 to validate the transgenic (Tg) mice for rapid carcinogenicity test-ing, short term (26 weeks) studies with genotoxic (by Salmonella), non-genotoxic carcinogens, genotoxic non-carcinogens, non-genotoxic non-carcinogens revealed relatively high concordance oj the response of the Tg mouse with classical bioassay across classes of carcinogenic agents. Mechanistic basis for carcinogensis in the model are being elucidated in terms of the role of overexpression and/or point mutation of the transgene. This report review the initial studies of validation of the model and preliminary results of on-going ILSI HESI ACT project will be presented.

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Evaluation of Early-age Properties of Controlled Low Strength Material Using Non-destructive Testing (비파괴 기법을 이용한 유동성 채움재의 초기경화특성 평가)

  • Kim, Dong-Ju;Kim, Sang-Cheol;Han, WooJin;Lee, Jong-Sub;Byun, Yong-Hoon
    • Journal of The Korean Society of Agricultural Engineers
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    • v.62 no.2
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    • pp.31-38
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    • 2020
  • Controlled Low Strength Material (CLSM) has high fluidity and self-compaction characteristics. CLSM is mainly used for backfilling the excavated road. Early-age properties of CLSM should be characterized for fast restoration of the road. In this study, shear wave monitoring and Vicat needle test are performed to investigate the early-age properties of CLSM depending on the setting time. CLSM consists of CSA cement, fly ash, silt and sand, accelerator, and water. Five fly ashes with different chemical properties are used for CLSM samples. The penetration of CLSM along setting time is obtained through the Vicat needle test. A pair of bender elements are placed in a mold for shear wave measurement, and the change in shear waves with the setting time is monitored. The experimental results show that, regardless of the type of fly ash, the penetration depth decreases and the shear wave velocity increases with the setting time. Depending on the type of fly ash, initial and final times and shear wave velocity change. After testing, the correlation between penetration and shear wave velocity is obtained with high coefficient of determination. The shear wave measurement technique using the bender element can be used to identify early-age properties.

High-Temperature Fracture Strength of a CVD-SiC Coating Layer for TRISO Nuclear Fuel Particles by a Micro-Tensile Test

  • Lee, Hyun Min;Park, Kwi-Il;Park, Ji-Yeon;Kim, Weon-Ju;Kim, Do Kyung
    • Journal of the Korean Ceramic Society
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    • v.52 no.6
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    • pp.441-448
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    • 2015
  • Silicon carbide (SiC) coatings for tri-isotropic (TRISO) nuclear fuel particles were fabricated using a chemical vapor deposition (CVD) process onto graphite. A micro-tensile-testing system was developed for the mechanical characterization of SiC coatings at high temperatures. The fracture strength of the SiC coatings was characterized by the developed micro-tensile test in the range of $25^{\circ}C$ to $1000^{\circ}C$. Two types of CVD-SiC films were prepared for the micro-tensile test. SiC-A exhibited a large grain size (0.4 ~ 0.6 m) and the [111] preferred orientation, while SiC-B had a small grain size (0.2 ~ 0.3 mm) and the [220] preferred orientation. Free silicon (Si) was co-deposited onto SiC-B, and stacking faults also existed in the SiC-B structure. The fracture strengths of the CVD-SiC coatings, as measured by the high-temperature micro-tensile test, decreased with the testing temperature. The high-temperature fracture strengths of CVD-SiC coatings were related to the microstructure and defects of the CVD-SiC coatings.

A STUDY ON THE STAINING TENDENCY OF ETHETIC RESTORATIVE MATERIALS (심미성 수복재료의 착생경향에 관한 연구)

  • Shin, Heung-Soo;Hwang, Ho-Keel;Cho, Young-Gon
    • Restorative Dentistry and Endodontics
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    • v.20 no.1
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    • pp.372-383
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    • 1995
  • The staining tendency of esthetic restorative material was very important factor for the people who are great concern about the esthetics. Most external stains were superficial and adjustable by routine prophylactic procedure. But some of these stains were remained under superficial stain. Some of these stains were accumulative on external tooth surface and it's removal alter the anatomic contour of restoration. The purpose of this study was to evaluate and compare the staining tendency of esthetic restorative materials to staining solution. In this study two glass-ionomer cements (Fuji II Glass-Ionomer Cement and Fuji II LC Glass-Ionomer Cement) and three composite resins (Sil$\ddot{u}$x Plus, APH and P-50) were evaluated and compared. Total 8 disc-shaped specimens of each material (17mm diameter, Imm thick) were immersed in coffee staining solution. These specimens were divided into one control and 3 experimental groups according to the immersion period as follows : Control: immersed in distilled water during each testing period Group 1 : immersed in staining solution for 6 hours Group 2 : immersed in staining solution for 24 hours Group 3 : immersed in staining solution for 72 hours Staining tendency was evaluated by total color difference(${\Delta}E^*$) of specimen before and after staining by spectorcolorimeteric readings (ColorQUEST Spectrophotometer, U.SA.). The results were as follows : 1. The total color differences of each testing materials were increased with time. 2. Among the experimental groups, the Fuji II Glass Ionomer Cement showed the highest total color difference(6.803) and the Silux Plus showed the lowest total color difference(1.637). 3. In comparison of glass ionomer cements, the total color difference of chemical cured glass ionomer cements(6.803) were higher than light cured glass ionomer cements(3.891) (P<0.01). 4. In comparison of composite resins, the P-50 showed the highest total color difference and the Silux Plus showed the lowest total color difference, but there was not significant difference among composite resins(P>0.05).

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A study on performance evaluation of rod rubber bushing under static and fatigue loadings (토크 로드 부품의 정하중 및 피로하중하에서의 성능평가 연구)

  • 이순복;김완두
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.5
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    • pp.1320-1329
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    • 1990
  • A static performance tester for a torque rod assembly was developed to evaluate the three characteristics of the rod rubber bushing : radial spring characteristic, thrust spring characteristic, and rotational torque characteristic. Among the various schemes considered in the conceptual design stage, the final versatile type was determined to perform three different tests in one machine. The performance testing machine carried out radial spring test, thrust spring test, and torque test of the torque rod assembly. Static performance of the torque rod assembly was evaluated with the tester developed and fatigue strength of the assembly was also tested with the servo-hydraulic structural fatigue testing machine. The life of the component was found to be related with the rubber quality and adhesionability between the rubber and the steel rod. The optimum rubber hardness was experimentally found by changing the chemical compositions of rubber, and the adhesion was improved by optimizing the shape of the outer section of a the rubber, this study ensured the development of a reliable torque rod assembly.

Correlating the Fineness and Residual Gum Content of Degummed Hemp Fibres

  • Beltran, Rafael;Hurren, Christopher J.;Kaynak, Akif;Wang, Xungai
    • Fibers and Polymers
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    • v.3 no.4
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    • pp.129-133
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    • 2002
  • It is well known residual gum exists in degummed or rotted hemp fibers. Gum removal results in improvement in fiber fineness and the properties of the resultant hemp yams. However, it is not known what correlation if any exists between the residual gum content in retted hemp fibers and the fiber fineness, described in terms of fiber width in this paper. This study examined the mean width and coefficient of variation (CV) of fiber width of seventeen chemically rotted hemp samples with reference to residual gum content. The mean and CV of fiber width were obtained from an Optical fiber diameter analyser (OFDA 100). The linear regression analysis results show that the mean fiber width is directly proportional to the residual gum content. A slightly weaker linear correlation also exists between the coefficient of variation of fiber width and the residual gum content. The strong linear co-relation between the mean of fiber width and the residual gum content is a significant outcome, since testing for fiber width using the OFDA is a much simpler and quicker process than testing the residual gum content. Scanning Electron Microscopy (SEM) reinforces the OFDA findings. SEM micrographs show a flat ribbon like fiber cross-section hence the term \"fiber width\" is used instead of fiber diameter. Spectral differences in the untreated dry decorticated skin samples and chemically treated and subsequently carded samples indicate delignification. The peaks at $1370cm^{-1}$, $1325cm^{-1}$, $1733cm^{-1}$, and $1600cm^{-1}$ attributed to lignin in the untreated samples are missing from the spectra of the treated samples. The spectra of the treated samples are more amine-dominated with some of the OH character lost.cter lost.

Development of Cr cold spray-coated fuel cladding with enhanced accident tolerance

  • Sevecek, Martin;Gurgen, Anil;Seshadri, Arunkumar;Che, Yifeng;Wagih, Malik;Phillips, Bren;Champagne, Victor;Shirvan, Koroush
    • Nuclear Engineering and Technology
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    • v.50 no.2
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    • pp.229-236
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    • 2018
  • Accident-tolerant fuels (ATFs) are currently of high interest to researchers in the nuclear industry and in governmental and international organizations. One widely studied accident-tolerant fuel concept is multilayer cladding (also known as coated cladding). This concept is based on a traditional Zr-based alloy (Zircaloy-4, M5, E110, ZIRLO etc.) serving as a substrate. Different protective materials are applied to the substrate surface by various techniques, thus enhancing the accident tolerance of the fuel. This study focuses on the results of testing of Zircaloy-4 coated with pure chromium metal using the cold spray (CS) technique. In comparison with other deposition methods, e.g., Physical vapor deposition (PVD), laser coating, or Chemical vapor deposition techniques (CVD), the CS technique is more cost efficient due to lower energy consumption and high deposition rates, making it more suitable for industry-scale production. The Cr-coated samples were tested at different conditions ($500^{\circ}C$ steam, $1200^{\circ}C$ steam, and Pressurized water reactor (PWR) pressurization test) and were precharacterized and postcharacterized by various techniques, such as scanning electron microscopy, Energy-dispersive X-ray spectroscopy (EDX), or nanoindentation; results are discussed. Results of the steady-state fuel performance simulations using the Bison code predicted the concept's feasibility. It is concluded that CS Cr coating has high potential benefits but requires further optimization and out-of-pile and in-pile testing.