• Title/Summary/Keyword: chemical testing

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State of the Art in Life Assessment for High Temperature Components Using Replication Method (표면복제기법을 이용한 고온 설비의 수명평가 현황과 적용사례)

  • Kim, Duck-Hee;Choi, Hyun-Sun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.5
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    • pp.489-496
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    • 2010
  • The power generation and chemical industry have been subjected to further material degradation with long term operations and need to predict the remaining service life of components, such as reformer tube and steam turbine rotor, that have operated at elevated temperatures. As a non-destructive technique, replication method with reliable metallurgical life and microstructural soundness assessment has been recognized with strongly useful method until now. Developments of this method have variously accomplished by new quantitative approach, such as carbide analysis, with A-parameter and grain deformation method. An overview of replication, some new techniques for material degradation and life assessment were introduced in this paper. Also, on-site applications and its reasonableness were described. As a result of having analyzed microstructure by replication method, carbide approach was quantitatively useful to life assessment.

A Survey and Studies on the Residual Content of Dimethylformamide and its Reduction in Polyurethane-Based Consumer Products (폴리우레탄 기반 소비자 제품의 디메틸포름아미드 잔류량과 이의 저감화를 위한 조사 및 연구)

  • Park, Yong Gi;Ji, Wonha;Han, Kyeong Seok;Jee, Min Ho
    • Journal of Korean Society for Quality Management
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    • v.45 no.4
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    • pp.769-780
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    • 2017
  • Purpose: The aim of this study is to conduct a survey of dimethylformamide(DMF) content in polyurethane(PU)-based consumer products and provide the information for the PU manufacturer and company to prepare a countermeasure for improving the quality competitiveness. Methods: This study selected PU-based consumer products(toddler shoes, children's bag, children's play mat, safety gloves), which is closely used in everyday life, and analyzed the residual DMF content in the consumer products. Results: In this study, it was confirmed that the average DMF content of toddler shoes, children's bag, children's play mat and safety gloves are 38 ppm, 119 ppm, 396 ppm and 826 ppm, respectively. In addition, most of the samples were found to meet the internationally accepted standard of 1,000 ppm and the DMF contents were reduced from at least 63 % to 85 % with a single washing process. Conclusion: The domestic PU manufacturers should seek ways to reduce the DMF through their production facility applications and introducing new materials such as water-soluble PU, and preparing the process development for their quality competitiveness.

A Study on the Application of Phased Array Ultrasonic Testing to Main Steam Line in Nuclear Power Plants (원전 주증기배관 웰더렛 용접부 위상배열초음파검사 적용연구)

  • Lee, Seung-Pyo;Kim, Jin-Hoi
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.7 no.3
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    • pp.40-47
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    • 2011
  • KSNPs(Korea Standard Nuclear Power Plant) have been applied the break exclusion criteria to the high energy lines passing through containment penetration area to ensure that piping failures would not cause the loss of containment isolation function, and to reduce the resulting dynamic effects. Systems with the criteria are the Main Steam system, Feed Water system, Steam Generator Blowdown system, and Chemical & Volume Control system. In accordance with FSAR(Final Safety Analysis Report), a 100% volumetric examination by augmented in-service inspection of all pipe welds appled the break exclusion criteria is required for the break exclusion application piping. However, it is difficult to fully satisfy the requirements of inspection because 12", 8" and 6" weldolet weldments of Main Steam pipe line have complex structural shapes. To resolve the difficulty on the application of conventional UT(Ultrasonic Testing) technique, realistic mock-ups and UT calibration blocks were made. Simulations of conventional UT were performed utilizing CIVA, a commercial NDE(Nondestructive Examination) simulation software. Phased array UT experiments were performed through mock-up including artificial notch type flaws. A phased array UT technique is finally developed to improve the reliability of ultrasonic test at main steam line pipe to 12", 8" and 6" branch connection weld.

Comparison of QSAR mutagenicity prediction data with Ames test results (Ames test 결과와 QSAR을 이용한 변이원성예측치와의 비교)

  • 양숙영;맹승희;이종윤;이용욱;정호근;정해원;유일재
    • Environmental Mutagens and Carcinogens
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    • v.20 no.1
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    • pp.21-25
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    • 2000
  • Recently there is increasing interest in the use of structure activity relationships for predicting the biological activity of chemicals. The reasons for the interest include the decrease cost and time per chemical as compared with animal or cell system for identifying toxicological effects of chemicals and the reduction in the use of animals for toxicological testing. This study is to test the validity of the mutagenicity data generated from QSAR (Quantitative Structure Activity Relationship) program. Thirty chemicals, which had been evaluated by Ames test during 1997-1999, were assessed with TOPKAT QSAR mutagenicity prediction module. Among 30chemicals experimented, 28 were negative and 2 were positive for Ames test. On the contrary, 23 chemicals showed the high confidence level indicating high prediction rate in mutagenicity evaluation, and 7 chemicals showed the lsow to moderate confidence level indicating low prediction in mutagenicity evaluation. Overall mutagenicity prediction rate was 77% (23/30). The prediction rates for non-mutagenic chemicals were 79% (22/28) and mutagenic chemicals were 50% (1/2). QSAR could be a useful tool in providing toxicological data for newly introduced chemicals or in furnishing data for MSDS or in determining the dose in toxicity testing for chemicals with no known toxicological data.

Leakage-free Rotating Seal Systems with Magnetic Nanofluids and Magnetic Composite Fluids Designed for Various Applications

  • Borbath, Tunde;Bica, Doina;Potencz, Iosif;Borbath, Istvan;Boros, Tibor;Vekas, Ladislau
    • International Journal of Fluid Machinery and Systems
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    • v.4 no.1
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    • pp.67-75
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    • 2011
  • Recent results are presented concerning the development of magnetofluidic leakage-free rotating seals for vacuum and high pressure gases, evidencing significant advantages compared to mechanical seals. The micro-pilot scale production of various types of magnetizable sealing fluids is shortly reviewed, in particular the main steps of the chemical synthesis of magnetic nanofluids and magnetic composite fluids with light hydrocarbon, mineral oil and synthetic oil carrier liquids. Design concepts and some constructive details of the magnetofluidic seals are discussed in order to obtain high sealing capacity. Different types of magnetofluidic sealing systems and applications are reviewed. Testing procedures and equipment are presented, as well as the sealing capabilities of different types of magnetizable fluids.

Accelerated Tensile Creep Test Method of Geosynthetics for Soil Reinforcement (보강용 지오신세틱스의 가속 인장 크리프 시험방법)

  • Koo, Hyun-Jin;Cho, Hang-Won
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.10a
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    • pp.196-203
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    • 2008
  • Durability of geosynthetics for soil reinforcement is accounted for creep and creep rupture, installation damage and weathering, chemical and biological degradation. Among these, the long-term creep properties have been considered as the most important factors which are directly related to the failure of geosynthetic-reinforced soil(GRS). However, the creep test methods and strain limits are too various to compare the test results with each other. The most widely used test methods are conventional creep test, time-temperature superposition and stepped isothermal method as accelerated creep tests. Recently developed design guidelines recommend that creep-rupture curve be used to determine the creep reduction factor($RF_{CR}$) which is a conservative approach. In this study, the different creep test methods were compared and the creep reduction factors were estimated at different creep strain limits of 10% of total creep strain and creep rupture. In order to minimize the impact of creep strain to the GRS structures, the various creep reduction factors using different creep test methods should be investigated and then the most appropriated one should be selected for incorporating into the design.

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Advanced Indentation Studies on the Effects of Hydrogen Attack on Tensile Property Degradation of Heat-Resistant Steel Heat-Affected Zones

  • Choi, Yeol;Jang, Jae-il;Lee, Yun-Hee;Kwon, Dongil;Kim, Jeong-Tae
    • Corrosion Science and Technology
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    • v.2 no.6
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    • pp.266-271
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    • 2003
  • Safety diagnosis of various structural components and facilities is indispensable for preventing catastrophic failure of material by time-dependent and environment accelerating degradation. Also, this diagnosis of operating components should be done periodically for safe maintenance and economical repair. However, conventional standard methods for mechanical properties have the problems of bulky specimen, destructive procedure and complex procedure of specimen sampling. So, a non-destructive and simple mechanical testing method using small specimen is needed. Therefore, an advanced indentation technique was developed as a potential method for non-destructive testing of in-field structures. This technique measures indentation load-depth curve during indentation and analyzes the mechanical properties related to deformation such as yield strength, tensile strength and work-hardening index. In this paper, we characterized the tensile properties including yield and tensile strengths of the V-modified Cr-Mo steels in petro-chemical and thermo-electrical plants. And also, the effects of hydrogen-assisted degradation of the V-modified Cr-Mo steels were analyzed in terms of work-hardening index and yield ratio.

International Harmonization of Compendium Monographs of Pharmaceutical Excipients: Its Progress and the Matters at Issue (의약품 첨가제의 공정서 각조의 국제 규격화 : 그 진행과 문제점)

  • Sekigawa, Fujio
    • Journal of Pharmaceutical Investigation
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    • v.23 no.4
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    • pp.231-254
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    • 1993
  • These days, it is not uncommon that a same kind of drug is circulated globally. However, the qualities of excipients used in the same drug have to be sometimes different depending on the different requirements in the qualities stipulated by each country. For a supplier of pharmaceutical excipients, it is generally necessary to carry out different tests on the same kind of testing criteria depending on the country of destination. Thus, the discrepancies between compendium requirements of pharmaceutical excipients create severe problems in various area of industrial activities. The decision of the United States Pharmacopoeia, European Pharmacopoeia and Japanese Pharmacopoeia Commissions to harmonize the requirements is a unique chance for the industries to overcome these problems. On the other hand, discrepancies of general test methods and requirements in each monograph of pharmaceutical excipient between the compendia valid at present are in most cases extensive. Consequently their harmonization needs a lot of detailed work requiring strong support from the industry. Based on these circumstances, pharmaceutical excipients councils have been established first in U.S.A. and successively in Europe and in Japan to contribute to the harmorization process. We should like to review here the progress since the Orlando Conference in 1991 and comment about the matters at issue with regard to the international harmonization of pharmaceutical excipients.

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Geotechnical Characteristics of a Waste Lime Embankment (부산물석회 성토지반의 지반공학적 특성)

  • Hong, Seung Seo;Kim, YoungSeok;Bae, Gu-Jin
    • The Journal of Engineering Geology
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    • v.25 no.4
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    • pp.547-555
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    • 2015
  • This work investigated the geotechnical characteristics of an embankment constructed with a mixture of soil and waste lime. The waste lime was a by-product of the manufacture of Na2CO3 at a near by chemical factory in Incheon. Field measurements were take three years after construction, and included geotechnical tests such as field density measurement, plate loading testing, dynamic cone penetration testing, and field CBR measurement. The results indicate that the geotechnical characteristics of waste lime mixtures are suitable for embankment works.

Predicting Shelf-life of Ice Cream by Accelerated Conditions

  • Park, Jung-Min;Koh, Jong-Ho;Kim, Jin-Man
    • Food Science of Animal Resources
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    • v.38 no.6
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    • pp.1216-1225
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    • 2018
  • Shelf-life is defined as the amount of time during which a food product retains its desired sensory, chemical, and physical characteristics while remaining safe for consumption. The food industry needs to rapidly obtain the necessary information for determining the shelf life of its products. Here we studied the approaches available for conducting accelerated shelf-life tests. Accelerated shelf-life testing is applied to a variety of products to rapidly estimate change in characteristics with time. The aim of this work was to use accelerated shelf-life testing to study the changes in pH, microbiology, and sensory characteristics of ice cream by the application of a kinetic approach and, based on the observations, to estimate its shelf life. As per the current law, there is no shelf life on ice cream. Our results suggest that the shelf life of an ice cream sample was 24.27 months at $-18^{\circ}C$, 2.29 months at $-6^{\circ}C$, 0.39 months at $-1^{\circ}C$, and 0.15 months at $4^{\circ}C$. Results of this study suggest that a set expiration date on ice cream might also contribute to effective management of ice cream characteristics in the retail chilled chain.