• Proceedings of the Korea Concrete Institute Conference
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• 1996.04a
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• pp.141-145
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• 1996

The primary purpose of this study is to investigate reusal techniques of by-product produced the combined heat power plant in the construction field, which may contribute to the savings of construction materials and the conservation of enviornment. This study is compared and evaluated by testing the chemical resistance, adiabatic temperature rising test, creep and drying shrinkage. As the result of the study, the following conclusions are derived : (1) hydration heat of the fly ash concrete is less than the plain concrete in adiabatic temperature rising test, (2) the fly axh concrete (FA 30%) is similar to the plain concrete in the chemical resistamce, (3) the fly ash concrete (FA 10, 30%) is similar to the plain concrete in drying shrinkage, but the fly ash concrete (FA 50%) is highly increased, (4) the fly ash concrete (FA 30%) is less than the plain concrete in creep test.

• Journal of Environmental Science International
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• v.6 no.4
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• pp.351-357
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• 1997

In the Atmosphere under the various physical and chemical condition different chemical reactions occur and there are a number of air pollutants which are generated by photochemical reaction by absorbing solar energy. Therefor various testing simulation was done as foundation work to develop the numerical model for the prediction of concentration of air pollutants. It was shown change of msjor air pollutants concentration In according to variation of photodissociation speed constant, Kl and Initial condition of air pollutants concentration which plays major role In photochemical reaction. The photochemical reaction model which was used In this study Is found to be useful for understanding relationship among the concentration of reacting air pollutants and the prediction of concentration of air pollutants in urban atmosphere.

• Proceedings of the KSRS Conference
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• 2007.10a
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• pp.41-44
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• 2007

Korea Aerospace Research Institute (KARI) has jointly developed a bipropellant propulsion system for Communication, Ocean and Meteorological Satellite (COMS) with EADS Astrium in UK. The technology relevant to a bipropellant propulsion system is quite new one in Korea, which is transferred for the first time, with development of COMS propulsion system. It hasn't ever attempted before, and hasn't got any general idea itself as well, in Korea. The COMS Chemical Propulsion System (CPS) is designed to perform both the orbital injection function, to take the spacecraft from transfer orbit to Geostationary Earth Orbit (GEO), and all on-station propulsive functions throughout the lifetime of the satellite. All station keeping manoeuvres are performed using the CPS. The design, manufacture and testing of COMS CPS are addressed in this paper. Feasibility of COMS CPS applicable to the other advanced mission is investigated as well.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 1999.11a
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• pp.42-48
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• 1999

An experimental study was performed to discover the effect of environment on the tribological behavior of Si-incorporated diamond-like carbon(Si-DLC) film slid on a steel ball. The films were deposited on Si(100) wafers from radio-frequency glow discharge of mixtures of benzene and dilute silane gases. Experiments using a ball-on-disk test-rig was performed under vacuum, dry air and ambient air conditions. It was observed that coefficient of friction was decreased as the environmental condition changes from vacuum, to dry air. It was also observed that the coefficient of friction decreased with increasing silicon concentration in the film. Chemical analyses of debris suggested that the low and stable friction coefficient is closely related to the silicon rich oxide debris and the rolling action.

• Molecular & Cellular Toxicology
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• v.3 no.2
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• pp.113-118
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• 2007

Chlorobenzenes due to their acute toxicity and the capability of bioaccumulating are of great health and environmental concern. Especially, 1, 2-dichlorobenzene (CAS No. 95-50-1) is used for organic synthesis, dye manufacture, as a solvent and for other applications in chemical industry. Adverse effects of 1, 2-dichlorobenzene includes increases in liver and kidney weights and hepatotoxicity. In this study, we evaluated the genetic toxicity of 1, 2-dichlorobenzene with more advanced methods, in vitro mouse lymphoma assay $tk^{+/-}$ gene assay (MLA) and in vitro mouse supravital micronucleus (MN) assay. 1, 2-Dichlorobenzene appeared the significantly positive results and the induction of large mutant colonies only in the presence of metabolic activation system with MLA. But in vitro testing of 1, 2-dichlorobenzene yielded negative results with supravital MN assay. These results suggest that 1, 2-dichlorobenzene may play a mutagen rather than clastogen in vitro mammalian system.

• Journal of the Korean Chemical Society
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• v.8 no.4
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• pp.142-146
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• 1964

The author proposed an equation of fading rate, expressed as ${\Delta}E$=${\Delta}E_{1{\infty}}({{1-e^{-k}}_1}^t)+k_2t$, where ${\Delta}E$=fading of dye (colour difference of N.B.S. unit), ${\Delta}E_{1{\infty}}$=extremity value of fading of molecularly dispersed dye, $k_1$, $k_2$=constants, t=exposure (hours). The validity of above equation, which is connected with the state of dye in fibre, was confirmed by experimental in a range of 2-3 colour fading in grey scale value for assessing change in colour visually, except the case of increasing the fading rate with the time resulted from the break-down of dye particles through the heat effect of light; it was also discussed about possiblity of evaluating of fastness to light of dye in early stage.

• Proceedings of the KSR Conference
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• 2009.05a
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• pp.206-212
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• 2009

Chemical behaviors of each surface material for interior facilities affect to fire initiation and growth in general fire situation. These chemical behaviors were characterized by thermal properties (Heat release rate, Pyrolysis rate, specific heat, etc) which could be derived from experimental test. Especially, Heat release rate which indicates aspect of fire size is one of the most important property to asses fire hazard and protection needs. The cone calorimeter test (ISO 5660) has recently assumed to a dominant role in bench scale fire testing to obtain the Heat release rate of materials. This value could be calculated by the 'Oxygen Consumption Method' under various producing irradiances to each surface of materials. In this study, Process of the cone calorimeter test was simulated by Pyrolysis model of FDS (Fire Dynamics Simulator by NIST) base on the ISO 5660 international standard. Then, we could estimate the simulation method of FDS in case of single materials through the comparative study with test results.

• Journal of the Korean Chemical Society
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• v.7 no.3
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• pp.197-202
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• 1963

The ${\alpha}-and\;{\beta}$-isomer of 4-nitroazoxybenzenes have been separated by liquid chromatography and their U.V. spectra were examined. The n${\to}{\pi}^{\ast}$ transition band of the compounds did not appear, likewise the cases of other compounds of the series. Transition band of the new isomer were as usual as those of other azoxy-compounds, whereas the ${\pi}{\to}{\pi}^{\ast}$ transition band of the other isomer which is reported in the literature shown peculier hypochromic shift and hypochromic effect. From the spectroscopic point of view it is very likely that the new isomer (m.p. $184-5^{\circ}C$) is ${\alpha}$-isomer and the other one (m.p. $152^{circ}C$) is ${\beta}$-isomer contrary to the literature.

• Journal of Powder Materials
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• v.11 no.2
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• pp.130-136
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• 2004

The passivation and oxidation process of tungsten and molybdenum narlopowders, produced by electrical explosion of wires was studied by means of FE-SEM, XPS. XRD, TEM, DIA-TGA and sire distribution analysis. In addition, the phase transformation of W and Mo nanopowders under oxidation in air was investigated. A chemical process is suggested for the oxidation of W and Mo nano-particles after a comprehensive testing of passivated and oxidized powders.

• Bulletin of the Korean Chemical Society
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• v.31 no.4
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• pp.895-900
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• 2010

In order to find a relationship between firefly luciferases structure and bioluminescence spectra, we focus on excited substrate geometries which may be affected by rigid luciferases. Density functional theory (DFT) and time dependent DFT (TDDFT) were employed. Changes in only six bond lengths of the excited substrate are important in determining the emission spectra. Analysis of these bonds suggests the mechanism whereby luciferases restrict more or less the excited substrate geometries and to produce multicolor bioluminescence.